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ACP | Articles | Volume 19, issue 15
ACP | Articles | Volume 19, issue 15
Atmos. Chem. Phys., 19, 9887–9902, 2019
https://doi.org/10.5194/acp-19-9887-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.

Special issue: Multiphase chemistry of secondary aerosol formation under...

Atmos. Chem. Phys., 19, 9887–9902, 2019
https://doi.org/10.5194/acp-19-9887-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.
ACP | Articles | Volume 19, issue 15

Research article 07 Aug 2019

Research article | 07 Aug 2019

Photochemical aging of atmospherically reactive organic compounds involving brown carbon at the air–aqueous interface

Siyang Li et al.

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We stimulated the photochemical aging of organic film coated on aqueous aerosol in the presence of imidazole-2-carboxaldehyde, humic acid, an atmospheric PM2.5 sample, and a secondary organic aerosol sample from the lab. The unsaturated lipid mixed with photosensitizer under UV irradiation produced hydroperoxides, leading to surface area increase in organic film. Our results reveal the modification of organic film on aqueous aerosol has potential influence on the hygroscopic growth of droplets.
We stimulated the photochemical aging of organic film coated on aqueous aerosol in the presence...
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Atmospheric Chemistry and Physics

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