Articles | Volume 19, issue 11
https://doi.org/10.5194/acp-19-7255-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-19-7255-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
03 Jun 2019
Research article |
| 03 Jun 2019
| 03 Jun 2019
Low-volatility compounds contribute significantly to isoprene secondary organic aerosol (SOA) under high-NOx conditions
Division of Geological and Planetary Sciences, California Institute of Technology, 1200 East California Boulevard, Pasadena, California 91125, USA
currently at: National Center for Atmospheric Research, Boulder, Colorado 80307, USA
Sophia M. Charan
Division of Chemistry and Chemical Engineering, California Institute of Technology, 1200 East California Boulevard, Pasadena, California 91125, USA
Kelvin H. Bates
Division of Chemistry and Chemical Engineering, California Institute of Technology, 1200 East California Boulevard, Pasadena, California 91125, USA
currently at: Faculty of Arts and Sciences, Harvard University, Cambridge, Massachusetts 02138, USA
Yuanlong Huang
Division of Geological and Planetary Sciences, California Institute of Technology, 1200 East California Boulevard, Pasadena, California 91125, USA
Tran B. Nguyen
Department of Environmental Toxicology, University of California – Davis, Davis, California 95616, USA
Huajun Mai
Division of Geological and Planetary Sciences, California Institute of Technology, 1200 East California Boulevard, Pasadena, California 91125, USA
Weimeng Kong
Division of Chemistry and Chemical Engineering, California Institute of Technology, 1200 East California Boulevard, Pasadena, California 91125, USA
Richard C. Flagan
Division of Chemistry and Chemical Engineering, California Institute of Technology, 1200 East California Boulevard, Pasadena, California 91125, USA
John H. Seinfeld
Division of Chemistry and Chemical Engineering, California Institute of Technology, 1200 East California Boulevard, Pasadena, California 91125, USA
Division of Engineering and Applied Science, California Institute of Technology, Pasadena, California 91125, USA
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- PM2.5-bound biogenic secondary organic aerosol tracers over a regionally representative site in central India: Characteristics and sources J. Nirmalkar et al. 10.1016/j.atmosenv.2022.119516
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- A Four Carbon Organonitrate as a Significant Product of Secondary Isoprene Chemistry E. Tsiligiannis et al. 10.1029/2021GL097366
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- Concurrent dominant pathways of multifunctional products formed from nocturnal isoprene oxidation H. Li et al. 10.1016/j.chemosphere.2023.138185
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45 citations as recorded by crossref.
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- Key Role of NO3 Radicals in the Production of Isoprene Nitrates and Nitrooxyorganosulfates in Beijing J. Hamilton et al. 10.1021/acs.est.0c05689
- Enhanced daytime secondary aerosol formation driven by gas–particle partitioning in downwind urban plumes M. Cai et al. 10.5194/acp-24-13065-2024
- Multifunctional Products of Isoprene Oxidation in Polluted Atmosphere and Their Contribution to SOA Z. Xu et al. 10.1029/2020GL089276
- Review of the influencing factors of secondary organic aerosol formation and aging mechanism based on photochemical smog chamber simulation methods Y. Zhang et al. 10.1016/j.jes.2022.10.033
- Effect of NOx and RH on the secondary organic aerosol formation from toluene photooxidation S. Liu et al. 10.1016/j.jes.2021.06.017
- Secondary organic aerosol formation from cis-3-hexen-1-ol/NOx photo-oxidation: The roles of cis-3-hexen-1-ol concentration, illumination intensity, NOx and NH3 D. Shi et al. 10.1016/j.atmosenv.2022.119090
- Strong anthropogenic control of secondary organic aerosol formation from isoprene in Beijing D. Bryant et al. 10.5194/acp-20-7531-2020
- Secondary organic aerosol formation from camphene oxidation: measurements and modeling Q. Li et al. 10.5194/acp-22-3131-2022
- PM2.5-bound biogenic secondary organic aerosol tracers over a regionally representative site in central India: Characteristics and sources J. Nirmalkar et al. 10.1016/j.atmosenv.2022.119516
- Secondary organic aerosol and organic nitrogen yields from the nitrate radical (NO<sub>3</sub>) oxidation of alpha-pinene from various RO<sub>2</sub> fates K. Bates et al. 10.5194/acp-22-1467-2022
- A large contribution of anthropogenic organo-nitrates to secondary organic aerosol in the Alberta oil sands A. Lee et al. 10.5194/acp-19-12209-2019
- Long-term observational constraints of organic aerosol dependence on inorganic species in the southeast US Y. Zheng et al. 10.5194/acp-20-13091-2020
- Effects of Nitrogen Oxides on the Production of Reactive Oxygen Species and Environmentally Persistent Free Radicals from α-Pinene and Naphthalene Secondary Organic Aerosols K. Edwards et al. 10.1021/acs.jpca.2c05532
- Joint impact of atmospheric SO2and NH3on the formation of nanoparticles from photo-oxidation of a typical biomass burning compound X. Jiang et al. 10.1039/D0EN00520G
- A Four Carbon Organonitrate as a Significant Product of Secondary Isoprene Chemistry E. Tsiligiannis et al. 10.1029/2021GL097366
- Evidence for Anthropogenic Organic Aerosols Contributing to Ice Nucleation P. Tian et al. 10.1029/2022GL099990
- Evaluation of isoprene nitrate chemistry in detailed chemical mechanisms A. Mayhew et al. 10.5194/acp-22-14783-2022
- Large contribution to secondary organic aerosol from isoprene cloud chemistry H. Lamkaddam et al. 10.1126/sciadv.abe2952
- Molecular composition and volatility of multi-generation products formed from isoprene oxidation by nitrate radical R. Wu et al. 10.5194/acp-21-10799-2021
- Observation-constrained kinetic modeling of isoprene SOA formation in the atmosphere C. Shen et al. 10.5194/acp-24-6153-2024
- Synergistic generation mechanisms of SOA and ozone from the photochemical oxidation of 1,3,5-trimethylbenzene: Influence of precursors ratio, temperature and radiation intensity H. Zhang et al. 10.1016/j.atmosres.2023.106924
- Size-dependent depositional loss of inorganic, organic, and mixed composition particles to Teflon chamber walls under various environmental and chemical conditions A. Nakagawa et al. 10.1080/02786826.2023.2298219
- Gas-Phase Oxidation Rates and Products of 1,2-Dihydroxy Isoprene K. Bates et al. 10.1021/acs.est.1c04177
- Importance of Oxidants and Temperature in the Formation of Biogenic Organosulfates and Nitrooxy Organosulfates D. Bryant et al. 10.1021/acsearthspacechem.1c00204
- FORest Canopy Atmosphere Transfer (FORCAsT) 2.0: model updates and evaluation with observations at a mixed forest site D. Wei et al. 10.5194/gmd-14-6309-2021
- Weekly derived top-down volatile-organic-compound fluxes over Europe from TROPOMI HCHO data from 2018 to 2021 G. Oomen et al. 10.5194/acp-24-449-2024
- Computational Simulation of Secondary Organic Aerosol Formation in Laboratory Chambers S. Charan et al. 10.1021/acs.chemrev.9b00358
- New formation and fate of Isoprene SOA markers revealed by field data-constrained modeling J. Zhang et al. 10.1038/s41612-023-00394-3
- Particle-phase accretion forms dimer esters in pinene secondary organic aerosol C. Kenseth et al. 10.1126/science.adi0857
- A new model mechanism for atmospheric oxidation of isoprene: global effects on oxidants, nitrogen oxides, organic products, and secondary organic aerosol K. Bates & D. Jacob 10.5194/acp-19-9613-2019
- Secondary organic aerosol formation from the oxidation of decamethylcyclopentasiloxane at atmospherically relevant OH concentrations S. Charan et al. 10.5194/acp-22-917-2022
- Large simulated future changes in the nitrate radical under the CMIP6 SSP scenarios: implications for oxidation chemistry S. Archer-Nicholls et al. 10.5194/acp-23-5801-2023
- A Near-Explicit Mechanistic Evaluation of Isoprene Photochemical Secondary Organic Aerosol Formation and Evolution: Simulations of Multiple Chamber Experiments with and without Added NOx J. Thornton et al. 10.1021/acsearthspacechem.0c00118
- Modeling Secondary Organic Aerosols in China: State of the Art and Perspectives J. Li et al. 10.1007/s40726-022-00246-3
- Daytime isoprene nitrates under changing NOx and O3 A. Mayhew et al. 10.5194/acp-23-8473-2023
- Synthesis of Carboxylic Acid and Dimer Ester Surrogates to Constrain the Abundance and Distribution of Molecular Products in α-Pinene and β-Pinene Secondary Organic Aerosol C. Kenseth et al. 10.1021/acs.est.0c01566
- Chemical characterization of secondary organic aerosol at a rural site in the southeastern US: insights from simultaneous high-resolution time-of-flight aerosol mass spectrometer (HR-ToF-AMS) and FIGAERO chemical ionization mass spectrometer (CIMS) measurements Y. Chen et al. 10.5194/acp-20-8421-2020
- Secondary organic aerosol formation from the ozonolysis and oh-photooxidation of 2,5-dimethylfuran M. Tajuelo et al. 10.1016/j.atmosenv.2020.118041
- Secondary organic aerosol formation from photooxidation of furan: effects of NO<sub><i>x</i></sub> and humidity X. Jiang et al. 10.5194/acp-19-13591-2019
- Effects of NO and SO2 on the secondary organic aerosol formation from the photooxidation of 1,3,5-trimethylbenzene: A new source of organosulfates Z. Yang et al. 10.1016/j.envpol.2020.114742
- Contribution of Terpenes to Ozone Formation and Secondary Organic Aerosols in a Subtropical Forest Impacted by Urban Pollution C. Salvador et al. 10.3390/atmos11111232
- Assessing the influence of environmental conditions on secondary organic aerosol formation from a typical biomass burning compound X. Jiang et al. 10.1016/j.jes.2021.08.016
- Concurrent dominant pathways of multifunctional products formed from nocturnal isoprene oxidation H. Li et al. 10.1016/j.chemosphere.2023.138185
- Low-NO atmospheric oxidation pathways in a polluted megacity M. Newland et al. 10.5194/acp-21-1613-2021
Latest update: 14 Dec 2024
Short summary
Oxidation of isoprene, the dominant non-methane biogenic volatile organic compound emitted into the atmosphere, is a significant source of secondary organic aerosol (SOA). Here formation of SOA from isoprene oxidation by the hydroxyl radical (OH) under high-NO conditions is measured. This work improves our understanding of isoprene SOA formation by demonstrating that low-volatility compounds formed under high-NO conditions produce significantly more aerosol than previously thought.
Oxidation of isoprene, the dominant non-methane biogenic volatile organic compound emitted into...
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