Atmospheric Chemistry and Physics
Atmospheric Chemistry and Physics
ACP
Articles | Volume 19, issue 9
Articles | Volume 19, issue 9
https://doi.org/10.5194/acp-19-6205-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-19-6205-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.
Articles | Volume 19, issue 9
Research article
 | 
10 May 2019
Research article |  | 10 May 2019

UV spectroscopic determination of the chlorine monoxide (ClO) ∕ chlorine peroxide (ClOOCl) thermal equilibrium constant

J. Eric Klobas and David M. Wilmouth

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Latest update: 23 Apr 2025
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Short summary
The thermal equilibrium constant governing the partitioning of the chlorine monoxide radical (ClO) and its dimer, chlorine peroxide (ClOOCl), was measured by broadband UV spectroscopy in the temperature range of 228–301 K. Uncertainty in the value of this equilibrium constant produces significant uncertainty in model determinations of expected polar ozone loss extent. The key results of this study indicate that the currently recommended uncertainty for this reaction may be reduced.
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