Articles | Volume 19, issue 9
https://doi.org/10.5194/acp-19-5959-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-19-5959-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Timescales of secondary organic aerosols to reach equilibrium at various temperatures and relative humidities
Department of Chemistry, University of California, Irvine, California, USA
Department of Chemistry, University of California, Irvine, California, USA
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Cited
55 citations as recorded by crossref.
- Predicting glass transition temperature and melting point of organic compounds via machine learning and molecular embeddings T. Galeazzo & M. Shiraiwa 10.1039/D1EA00090J
- Current State of Atmospheric Aerosol Thermodynamics and Mass Transfer Modeling: A Review K. Semeniuk & A. Dastoor 10.3390/atmos11020156
- Indoor air aerosol modeling and evaluation based on simulation chamber experiments C. Berger et al. 10.1016/j.jaerosci.2023.106161
- Machine-Learning-Based Prediction of the Glass Transition Temperature of Organic Compounds Using Experimental Data G. Armeli et al. 10.1021/acsomega.2c08146
- On evaporation kinetics of multicomponent aerosols: Characteristic times and implications for volatility measurements A. Khlystov 10.1080/02786826.2024.2385640
- Viscosity and liquid–liquid phase separation in healthy and stressed plant SOA N. Smith et al. 10.1039/D0EA00020E
- The relative humidity-dependent viscosity of single quasi aerosol particles and possible implications for atmospheric aerosol chemistry Y. Tong et al. 10.1039/D2CP00740A
- Evaluating Indoor Air Chemical Diversity, Indoor-to-Outdoor Emissions, and Surface Reservoirs Using High-Resolution Mass Spectrometry R. Sheu et al. 10.1021/acs.est.1c01337
- Accelerated Keto–Enol Tautomerization Kinetics of Malonic Acid in Aqueous Droplets P. Kim & R. Continetti 10.1021/acsearthspacechem.1c00221
- Effects of Phase State and Phase Separation on Dimethylamine Uptake of Ammonium Sulfate and Ammonium Sulfate–Sucrose Mixed Particles W. DeRieux et al. 10.1021/acsearthspacechem.9b00142
- Insect Infestation Increases Viscosity of Biogenic Secondary Organic Aerosol N. Smith et al. 10.1021/acsearthspacechem.3c00007
- Predicting the influence of particle size on the glass transition temperature and viscosity of secondary organic material M. Petters & S. Kasparoglu 10.1038/s41598-020-71490-0
- Distinct Temperature Trends in the Uptake of Gaseous n-Butylamine on Two Solid Diacids Y. Li et al. 10.1021/acsestair.3c00032
- Influence of Relative Humidity and Composition on PM2.5 Phases in Northeast Asia C. Seong et al. 10.1021/acsearthspacechem.4c00019
- Non-equilibrium interplay between gas–particle partitioning and multiphase chemical reactions of semi-volatile compounds: mechanistic insights and practical implications for atmospheric modeling of polycyclic aromatic hydrocarbons J. Wilson et al. 10.5194/acp-21-6175-2021
- Isothermal evaporation of α-pinene secondary organic aerosol particles formed under low NOx and high NOx conditions Z. Li et al. 10.5194/acp-23-203-2023
- Effect of relative humidity on the molecular composition of secondary organic aerosols from α-pinene ozonolysis H. Luo et al. 10.1039/D3EA00149K
- Changing Nature of Organic Carbon over the United States A. Christiansen et al. 10.1021/acs.est.0c02225
- Indoor aerosol water content and phase state in U.S. residences: impacts of relative humidity, aerosol mass and composition, and mechanical system operation B. Cummings et al. 10.1039/D0EM00122H
- Particle Size Distribution Dynamics Can Help Constrain the Phase State of Secondary Organic Aerosol Y. He et al. 10.1021/acs.est.0c05796
- Diurnal and Seasonal Variations in the Phase State of Secondary Organic Aerosol Material over the Contiguous US Simulated in CMAQ Y. Li et al. 10.1021/acsearthspacechem.1c00094
- Quantifying Atmospheric Parameter Ranges for Ambient Secondary Organic Aerosol Formation W. Porter et al. 10.1021/acsearthspacechem.1c00090
- Evolution of volatility and composition in sesquiterpene-mixed and <i>α</i>-pinene secondary organic aerosol particles during isothermal evaporation Z. Li et al. 10.5194/acp-21-18283-2021
- Effects of volatility, viscosity, and non-ideality on particle–particle mixing timescales of secondary organic aerosols M. Schervish et al. 10.1080/02786826.2023.2256827
- Global Distribution of the Phase State and Mixing Times within Secondary Organic Aerosol Particles in the Troposphere Based on Room-Temperature Viscosity Measurements A. Maclean et al. 10.1021/acsearthspacechem.1c00296
- Mass accommodation and gas–particle partitioning in secondary organic aerosols: dependence on diffusivity, volatility, particle-phase reactions, and penetration depth M. Shiraiwa & U. Pöschl 10.5194/acp-21-1565-2021
- Hygroscopicity of Water‐Soluble PM2.5 in Rural Northwest China: Contrasting Contributors Between Summer and Winter Y. Chen et al. 10.1029/2021JD034977
- Impact of aging on the sources, volatility, and viscosity of organic aerosols in Chinese outflows T. Feng et al. 10.5194/acp-23-611-2023
- The Aarhus Chamber Campaign on Highly Oxygenated Organic Molecules and Aerosols (ACCHA): particle formation, organic acids, and dimer esters from <i>α</i>-pinene ozonolysis at different temperatures K. Kristensen et al. 10.5194/acp-20-12549-2020
- Predictions of the glass transition temperature and viscosity of organic aerosols from volatility distributions Y. Li et al. 10.5194/acp-20-8103-2020
- Organic aerosol volatility and viscosity in the North China Plain: contrast between summer and winter W. Xu et al. 10.5194/acp-21-5463-2021
- Emerging investigator series: chemical and physical properties of organic mixtures on indoor surfaces during HOMEChem R. O'Brien et al. 10.1039/D1EM00060H
- An unexpected feasible route for the formation of organosulfates by the gas phase reaction of sulfuric acid with acetaldehyde catalyzed by dimethylamine in the atmosphere J. Yang et al. 10.1039/D2EA00159D
- Desorption lifetimes and activation energies influencing gas–surface interactions and multiphase chemical kinetics D. Knopf et al. 10.5194/acp-24-3445-2024
- Simulated phase state and viscosity of secondary organic aerosols over China Z. Zhang et al. 10.5194/acp-24-4809-2024
- Impact of phase state and non-ideal mixing on equilibration timescales of secondary organic aerosol partitioning M. Schervish & M. Shiraiwa 10.5194/acp-23-221-2023
- Impact of aerosol concentration changes on carbon sequestration potential of rice in a temperate monsoon climate zone during the COVID-19: a case study on the Sanjiang Plain, China X. Zuo & H. Wang 10.1007/s11356-024-33149-5
- The Cooling Rate- and Volatility-Dependent Glass-Forming Properties of Organic Aerosols Measured by Broadband Dielectric Spectroscopy Y. Zhang et al. 10.1021/acs.est.9b03317
- Estimation of secondary organic aerosol viscosity from explicit modeling of gas-phase oxidation of isoprene and <i>α</i>-pinene T. Galeazzo et al. 10.5194/acp-21-10199-2021
- Toward closure between predicted and observed particle viscosity over a wide range of temperatures and relative humidity S. Kasparoglu et al. 10.5194/acp-21-1127-2021
- Particle phase state and aerosol liquid water greatly impact secondary aerosol formation: insights into phase transition and its role in haze events X. Meng et al. 10.5194/acp-24-2399-2024
- Molecular composition and gas-particle partitioning of indoor cooking aerosol: Insights from a FIGAERO-CIMS and kinetic aerosol modeling C. Masoud et al. 10.1080/02786826.2022.2133593
- Modeling the Effects of Dimerization and Bulk Diffusion on the Evaporative Behavior of Secondary Organic Aerosol Formed from α-Pinene and 1,3,5-Trimethylbenzene Y. Morino et al. 10.1021/acsearthspacechem.0c00106
- Optical properties of biomass burning aerosol during the 2021 Oregon fire season: comparison between wild and prescribed fires A. Marsavin et al. 10.1039/D2EA00118G
- The influence of saturation on the surface structure of mixed fatty acid-on-water aerosol: a molecular dynamics study A. Stewart et al. 10.1039/D2EA00089J
- Particle-Phase Diffusion Modulates Partitioning of Semivolatile Organic Compounds to Aged Secondary Organic Aerosol R. Zaveri et al. 10.1021/acs.est.9b05514
- A computationally efficient model to represent the chemistry, thermodynamics, and microphysics of secondary organic aerosols (simpleSOM): model development and application to α-pinene SOA S. Jathar et al. 10.1039/D1EA00014D
- Kinetic multi‐layer model of film formation, growth, and chemistry (KM‐FILM): Boundary layer processes, multi‐layer adsorption, bulk diffusion, and heterogeneous reactions P. Lakey et al. 10.1111/ina.12854
- Kinetics, SOA yields, and chemical composition of secondary organic aerosol from β-caryophyllene ozonolysis with and without nitrogen oxides between 213 and 313 K L. Gao et al. 10.5194/acp-22-6001-2022
- Joint Impacts of Acidity and Viscosity on the Formation of Secondary Organic Aerosol from Isoprene Epoxydiols (IEPOX) in Phase Separated Particles Y. Zhang et al. 10.1021/acsearthspacechem.9b00209
- Sunlight can convert atmospheric aerosols into a glassy solid state and modify their environmental impacts V. Baboomian et al. 10.1073/pnas.2208121119
- Aerosol Mass and Optical Properties, Smoke Influence on O3, and High NO3 Production Rates in a Western U.S. City Impacted by Wildfires V. Selimovic et al. 10.1029/2020JD032791
- Effects of Nitrogen Oxides on the Production of Reactive Oxygen Species and Environmentally Persistent Free Radicals from α-Pinene and Naphthalene Secondary Organic Aerosols K. Edwards et al. 10.1021/acs.jpca.2c05532
- Species-specific effect of particle viscosity and particle-phase reactions on the formation of secondary organic aerosol Z. Luo et al. 10.1016/j.scitotenv.2024.175207
- Glass surface evolution following gas adsorption and particle deposition from indoor cooking events as probed by microspectroscopic analysis V. Or et al. 10.1039/D0EM00156B
55 citations as recorded by crossref.
- Predicting glass transition temperature and melting point of organic compounds via machine learning and molecular embeddings T. Galeazzo & M. Shiraiwa 10.1039/D1EA00090J
- Current State of Atmospheric Aerosol Thermodynamics and Mass Transfer Modeling: A Review K. Semeniuk & A. Dastoor 10.3390/atmos11020156
- Indoor air aerosol modeling and evaluation based on simulation chamber experiments C. Berger et al. 10.1016/j.jaerosci.2023.106161
- Machine-Learning-Based Prediction of the Glass Transition Temperature of Organic Compounds Using Experimental Data G. Armeli et al. 10.1021/acsomega.2c08146
- On evaporation kinetics of multicomponent aerosols: Characteristic times and implications for volatility measurements A. Khlystov 10.1080/02786826.2024.2385640
- Viscosity and liquid–liquid phase separation in healthy and stressed plant SOA N. Smith et al. 10.1039/D0EA00020E
- The relative humidity-dependent viscosity of single quasi aerosol particles and possible implications for atmospheric aerosol chemistry Y. Tong et al. 10.1039/D2CP00740A
- Evaluating Indoor Air Chemical Diversity, Indoor-to-Outdoor Emissions, and Surface Reservoirs Using High-Resolution Mass Spectrometry R. Sheu et al. 10.1021/acs.est.1c01337
- Accelerated Keto–Enol Tautomerization Kinetics of Malonic Acid in Aqueous Droplets P. Kim & R. Continetti 10.1021/acsearthspacechem.1c00221
- Effects of Phase State and Phase Separation on Dimethylamine Uptake of Ammonium Sulfate and Ammonium Sulfate–Sucrose Mixed Particles W. DeRieux et al. 10.1021/acsearthspacechem.9b00142
- Insect Infestation Increases Viscosity of Biogenic Secondary Organic Aerosol N. Smith et al. 10.1021/acsearthspacechem.3c00007
- Predicting the influence of particle size on the glass transition temperature and viscosity of secondary organic material M. Petters & S. Kasparoglu 10.1038/s41598-020-71490-0
- Distinct Temperature Trends in the Uptake of Gaseous n-Butylamine on Two Solid Diacids Y. Li et al. 10.1021/acsestair.3c00032
- Influence of Relative Humidity and Composition on PM2.5 Phases in Northeast Asia C. Seong et al. 10.1021/acsearthspacechem.4c00019
- Non-equilibrium interplay between gas–particle partitioning and multiphase chemical reactions of semi-volatile compounds: mechanistic insights and practical implications for atmospheric modeling of polycyclic aromatic hydrocarbons J. Wilson et al. 10.5194/acp-21-6175-2021
- Isothermal evaporation of α-pinene secondary organic aerosol particles formed under low NOx and high NOx conditions Z. Li et al. 10.5194/acp-23-203-2023
- Effect of relative humidity on the molecular composition of secondary organic aerosols from α-pinene ozonolysis H. Luo et al. 10.1039/D3EA00149K
- Changing Nature of Organic Carbon over the United States A. Christiansen et al. 10.1021/acs.est.0c02225
- Indoor aerosol water content and phase state in U.S. residences: impacts of relative humidity, aerosol mass and composition, and mechanical system operation B. Cummings et al. 10.1039/D0EM00122H
- Particle Size Distribution Dynamics Can Help Constrain the Phase State of Secondary Organic Aerosol Y. He et al. 10.1021/acs.est.0c05796
- Diurnal and Seasonal Variations in the Phase State of Secondary Organic Aerosol Material over the Contiguous US Simulated in CMAQ Y. Li et al. 10.1021/acsearthspacechem.1c00094
- Quantifying Atmospheric Parameter Ranges for Ambient Secondary Organic Aerosol Formation W. Porter et al. 10.1021/acsearthspacechem.1c00090
- Evolution of volatility and composition in sesquiterpene-mixed and <i>α</i>-pinene secondary organic aerosol particles during isothermal evaporation Z. Li et al. 10.5194/acp-21-18283-2021
- Effects of volatility, viscosity, and non-ideality on particle–particle mixing timescales of secondary organic aerosols M. Schervish et al. 10.1080/02786826.2023.2256827
- Global Distribution of the Phase State and Mixing Times within Secondary Organic Aerosol Particles in the Troposphere Based on Room-Temperature Viscosity Measurements A. Maclean et al. 10.1021/acsearthspacechem.1c00296
- Mass accommodation and gas–particle partitioning in secondary organic aerosols: dependence on diffusivity, volatility, particle-phase reactions, and penetration depth M. Shiraiwa & U. Pöschl 10.5194/acp-21-1565-2021
- Hygroscopicity of Water‐Soluble PM2.5 in Rural Northwest China: Contrasting Contributors Between Summer and Winter Y. Chen et al. 10.1029/2021JD034977
- Impact of aging on the sources, volatility, and viscosity of organic aerosols in Chinese outflows T. Feng et al. 10.5194/acp-23-611-2023
- The Aarhus Chamber Campaign on Highly Oxygenated Organic Molecules and Aerosols (ACCHA): particle formation, organic acids, and dimer esters from <i>α</i>-pinene ozonolysis at different temperatures K. Kristensen et al. 10.5194/acp-20-12549-2020
- Predictions of the glass transition temperature and viscosity of organic aerosols from volatility distributions Y. Li et al. 10.5194/acp-20-8103-2020
- Organic aerosol volatility and viscosity in the North China Plain: contrast between summer and winter W. Xu et al. 10.5194/acp-21-5463-2021
- Emerging investigator series: chemical and physical properties of organic mixtures on indoor surfaces during HOMEChem R. O'Brien et al. 10.1039/D1EM00060H
- An unexpected feasible route for the formation of organosulfates by the gas phase reaction of sulfuric acid with acetaldehyde catalyzed by dimethylamine in the atmosphere J. Yang et al. 10.1039/D2EA00159D
- Desorption lifetimes and activation energies influencing gas–surface interactions and multiphase chemical kinetics D. Knopf et al. 10.5194/acp-24-3445-2024
- Simulated phase state and viscosity of secondary organic aerosols over China Z. Zhang et al. 10.5194/acp-24-4809-2024
- Impact of phase state and non-ideal mixing on equilibration timescales of secondary organic aerosol partitioning M. Schervish & M. Shiraiwa 10.5194/acp-23-221-2023
- Impact of aerosol concentration changes on carbon sequestration potential of rice in a temperate monsoon climate zone during the COVID-19: a case study on the Sanjiang Plain, China X. Zuo & H. Wang 10.1007/s11356-024-33149-5
- The Cooling Rate- and Volatility-Dependent Glass-Forming Properties of Organic Aerosols Measured by Broadband Dielectric Spectroscopy Y. Zhang et al. 10.1021/acs.est.9b03317
- Estimation of secondary organic aerosol viscosity from explicit modeling of gas-phase oxidation of isoprene and <i>α</i>-pinene T. Galeazzo et al. 10.5194/acp-21-10199-2021
- Toward closure between predicted and observed particle viscosity over a wide range of temperatures and relative humidity S. Kasparoglu et al. 10.5194/acp-21-1127-2021
- Particle phase state and aerosol liquid water greatly impact secondary aerosol formation: insights into phase transition and its role in haze events X. Meng et al. 10.5194/acp-24-2399-2024
- Molecular composition and gas-particle partitioning of indoor cooking aerosol: Insights from a FIGAERO-CIMS and kinetic aerosol modeling C. Masoud et al. 10.1080/02786826.2022.2133593
- Modeling the Effects of Dimerization and Bulk Diffusion on the Evaporative Behavior of Secondary Organic Aerosol Formed from α-Pinene and 1,3,5-Trimethylbenzene Y. Morino et al. 10.1021/acsearthspacechem.0c00106
- Optical properties of biomass burning aerosol during the 2021 Oregon fire season: comparison between wild and prescribed fires A. Marsavin et al. 10.1039/D2EA00118G
- The influence of saturation on the surface structure of mixed fatty acid-on-water aerosol: a molecular dynamics study A. Stewart et al. 10.1039/D2EA00089J
- Particle-Phase Diffusion Modulates Partitioning of Semivolatile Organic Compounds to Aged Secondary Organic Aerosol R. Zaveri et al. 10.1021/acs.est.9b05514
- A computationally efficient model to represent the chemistry, thermodynamics, and microphysics of secondary organic aerosols (simpleSOM): model development and application to α-pinene SOA S. Jathar et al. 10.1039/D1EA00014D
- Kinetic multi‐layer model of film formation, growth, and chemistry (KM‐FILM): Boundary layer processes, multi‐layer adsorption, bulk diffusion, and heterogeneous reactions P. Lakey et al. 10.1111/ina.12854
- Kinetics, SOA yields, and chemical composition of secondary organic aerosol from β-caryophyllene ozonolysis with and without nitrogen oxides between 213 and 313 K L. Gao et al. 10.5194/acp-22-6001-2022
- Joint Impacts of Acidity and Viscosity on the Formation of Secondary Organic Aerosol from Isoprene Epoxydiols (IEPOX) in Phase Separated Particles Y. Zhang et al. 10.1021/acsearthspacechem.9b00209
- Sunlight can convert atmospheric aerosols into a glassy solid state and modify their environmental impacts V. Baboomian et al. 10.1073/pnas.2208121119
- Aerosol Mass and Optical Properties, Smoke Influence on O3, and High NO3 Production Rates in a Western U.S. City Impacted by Wildfires V. Selimovic et al. 10.1029/2020JD032791
- Effects of Nitrogen Oxides on the Production of Reactive Oxygen Species and Environmentally Persistent Free Radicals from α-Pinene and Naphthalene Secondary Organic Aerosols K. Edwards et al. 10.1021/acs.jpca.2c05532
- Species-specific effect of particle viscosity and particle-phase reactions on the formation of secondary organic aerosol Z. Luo et al. 10.1016/j.scitotenv.2024.175207
- Glass surface evolution following gas adsorption and particle deposition from indoor cooking events as probed by microspectroscopic analysis V. Or et al. 10.1039/D0EM00156B
Latest update: 20 Nov 2024
Short summary
Timescales for secondary organic aerosols (SOA) to reach equilibrium were estimated under various temperatures and relative humidities. Equilibration timescales in free troposphere can be longer than hours or days, even at moderate or relatively high relative humidities. These results provide critical insights into thermodynamic or kinetic treatments of SOA partitioning for accurate predictions of gas- and particle-phase concentrations of semi-volatile compounds in chemical transport models.
Timescales for secondary organic aerosols (SOA) to reach equilibrium were estimated under...
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