Articles | Volume 19, issue 5
https://doi.org/10.5194/acp-19-2833-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Special issue:
https://doi.org/10.5194/acp-19-2833-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
04 Mar 2019
Research article |
| 04 Mar 2019
| 04 Mar 2019
Understanding the catalytic role of oxalic acid in SO3 hydration to form H2SO4 in the atmosphere
Guochun Lv
Environment Research Institute, Shandong University, Jinan 250100, China
Xiaomin Sun
CORRESPONDING AUTHOR
Environment Research Institute, Shandong University, Jinan 250100, China
Chenxi Zhang
College of Biological and Environmental Engineering, Binzhou University, Binzhou 256600, China
Mei Li
CORRESPONDING AUTHOR
Institute of Mass Spectrometer and Atmospheric Environment, Jinan University, Guangzhou 510632, China
Guangdong Provincial Engineering Research Center for On-line Source Apportionment System Of Air Pollution, Guangzhou 510632, China
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28 citations as recorded by crossref.
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- Hydrolysis of HNSO2: A potential route for atmospheric production of H2SO4 and NH3 G. Manonmani et al. 10.1002/qua.26182
- Computational chemistry of cluster: Understanding the mechanism of atmospheric new particle formation at the molecular level X. Zhang et al. 10.1016/j.chemosphere.2022.136109
- Metal-free catalysis for the reaction of nitrogen dioxide dimer with phenol: An unexpected favorable source of nitrate and aerosol precursors in vehicle exhaust F. Bai et al. 10.1016/j.chemosphere.2021.132705
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- Self‐catalyzed keto‐enol tautomerization of malonic acid C. Sutton et al. 10.1002/qua.26114
- Reactions of Criegee Intermediates are Enhanced by Hydrogen‐Atom Relay Through Molecular Design M. Kuo et al. 10.1002/cphc.202000585
- Significant influence of water molecules on the SO3 + HCl reaction in the gas phase and at the air–water interface Y. Cheng et al. 10.1039/D3CP03172A
- Reaction of SO3 with H2SO4 and its implications for aerosol particle formation in the gas phase and at the air–water interface R. Wang et al. 10.5194/acp-24-4029-2024
- Determination of the amine-catalyzed SO3 hydrolysis mechanism in the gas phase and at the air-water interface X. Ma et al. 10.1016/j.chemosphere.2020.126292
- The role of sulfur cycle in new particle formation: Cycloaddition reaction of SO3 to H2S H. Zhang et al. 10.1016/j.jes.2023.09.010
- Molecular-Scale Mechanism of Sequential Reaction of Oxalic Acid with SO3: Potential Participator in Atmospheric Aerosol Nucleation Y. Yang et al. 10.1021/acs.jpca.1c02113
- Reactions of sulfur trioxide with hypochlorous acid catalyzed by water in gas phase and at the air-water nanodroplet interface in the atmosphere: An important sink for hypochlorous acid Q. Gao et al. 10.1016/j.atmosenv.2024.120574
- Synergistic Reaction of SO2 with NO2 in Presence of H2O and NH3: A Potential Source of Sulfate Aerosol Z. Wang et al. 10.3390/ijms20153746
- Hydrolysis of SO3 in Small Clusters of Sulfuric Acid: Mechanistic and Kinetic Study Y. Cheng et al. 10.1021/acsearthspacechem.2c00290
- Intriguing Intermolecular Interplay in Guanine Quartet Complexes with Alkali and Alkaline Earth Cations B. Milovanović et al. 10.1021/acs.jpcb.0c01165
- Atmospheric Chemistry of NH2SO3H in Polluted Areas: An Unexpected Isomerization of NH2SO3H in Acid-Polluted Regions Y. Zhang et al. 10.1021/acs.jpca.3c04982
- Brønsted Acid and H‐Bond Activation in Boronic Acid Catalysis S. Zhang et al. 10.1002/chem.202001902
- Unprecedented Ambient Sulfur Trioxide (SO3) Detection: Possible Formation Mechanism and Atmospheric Implications L. Yao et al. 10.1021/acs.estlett.0c00615
- Hydrolysis of acrolein promoted by water, ammonia or formic acid in the atmosphere: A theoretical investigation B. Du & W. Zhang 10.1016/j.comptc.2024.114667
- The role of air-water interface in the SO3 hydration reaction G. Lv & X. Sun 10.1016/j.atmosenv.2020.117514
- The significance of the metal cation in guanine-quartet – metalloporphyrin complexes A. Stanojević et al. 10.1039/D0CP05798C
- Pyruvic acid, an efficient catalyst in SO3 hydrolysis and effective clustering agent in sulfuric-acid-based new particle formation N. Tsona Tchinda et al. 10.5194/acp-22-1951-2022
- Metal-free catalysis on the reactions of nitric acid with aliphatic aldehydes: A new potential source of organic nitrates F. Bai et al. 10.1016/j.atmosenv.2023.119673
- Determination of reactions between Criegee intermediates and methanesulfonic acid at the air-water interface X. Ma et al. 10.1016/j.scitotenv.2019.135804
- Theoretical study of the reaction mechanism between Criegee intermediates and hydroxyl radicals in the presence of ammonia and amine Y. Wei et al. 10.1016/j.chemosphere.2021.131877
- Trade as International Transmission Mechanism: The Case of Central and Eastern European 'New' EU Member Countries R. de Santis 10.2139/ssrn.602341
27 citations as recorded by crossref.
- Intermolecular Hydrogen-Bonded Interactions of Oxalic Acid Conformers with Sulfuric Acid and Ammonia E. Carvalho et al. 10.1021/acsomega.4c06290
- Aldehyde as a potential source of aminol in troposphere: Influence of water and formic acid catalysis on ammonolysis of formaldehyde S. Sarkar et al. 10.1016/j.atmosenv.2019.05.069
- Hydrolysis of HNSO2: A potential route for atmospheric production of H2SO4 and NH3 G. Manonmani et al. 10.1002/qua.26182
- Computational chemistry of cluster: Understanding the mechanism of atmospheric new particle formation at the molecular level X. Zhang et al. 10.1016/j.chemosphere.2022.136109
- Metal-free catalysis for the reaction of nitrogen dioxide dimer with phenol: An unexpected favorable source of nitrate and aerosol precursors in vehicle exhaust F. Bai et al. 10.1016/j.chemosphere.2021.132705
- Large Discrepancy in the Formation of Secondary Organic Aerosols from Structurally Similar Monoterpenes D. Thomsen et al. 10.1021/acsearthspacechem.0c00332
- Self‐catalyzed keto‐enol tautomerization of malonic acid C. Sutton et al. 10.1002/qua.26114
- Reactions of Criegee Intermediates are Enhanced by Hydrogen‐Atom Relay Through Molecular Design M. Kuo et al. 10.1002/cphc.202000585
- Significant influence of water molecules on the SO3 + HCl reaction in the gas phase and at the air–water interface Y. Cheng et al. 10.1039/D3CP03172A
- Reaction of SO3 with H2SO4 and its implications for aerosol particle formation in the gas phase and at the air–water interface R. Wang et al. 10.5194/acp-24-4029-2024
- Determination of the amine-catalyzed SO3 hydrolysis mechanism in the gas phase and at the air-water interface X. Ma et al. 10.1016/j.chemosphere.2020.126292
- The role of sulfur cycle in new particle formation: Cycloaddition reaction of SO3 to H2S H. Zhang et al. 10.1016/j.jes.2023.09.010
- Molecular-Scale Mechanism of Sequential Reaction of Oxalic Acid with SO3: Potential Participator in Atmospheric Aerosol Nucleation Y. Yang et al. 10.1021/acs.jpca.1c02113
- Reactions of sulfur trioxide with hypochlorous acid catalyzed by water in gas phase and at the air-water nanodroplet interface in the atmosphere: An important sink for hypochlorous acid Q. Gao et al. 10.1016/j.atmosenv.2024.120574
- Synergistic Reaction of SO2 with NO2 in Presence of H2O and NH3: A Potential Source of Sulfate Aerosol Z. Wang et al. 10.3390/ijms20153746
- Hydrolysis of SO3 in Small Clusters of Sulfuric Acid: Mechanistic and Kinetic Study Y. Cheng et al. 10.1021/acsearthspacechem.2c00290
- Intriguing Intermolecular Interplay in Guanine Quartet Complexes with Alkali and Alkaline Earth Cations B. Milovanović et al. 10.1021/acs.jpcb.0c01165
- Atmospheric Chemistry of NH2SO3H in Polluted Areas: An Unexpected Isomerization of NH2SO3H in Acid-Polluted Regions Y. Zhang et al. 10.1021/acs.jpca.3c04982
- Brønsted Acid and H‐Bond Activation in Boronic Acid Catalysis S. Zhang et al. 10.1002/chem.202001902
- Unprecedented Ambient Sulfur Trioxide (SO3) Detection: Possible Formation Mechanism and Atmospheric Implications L. Yao et al. 10.1021/acs.estlett.0c00615
- Hydrolysis of acrolein promoted by water, ammonia or formic acid in the atmosphere: A theoretical investigation B. Du & W. Zhang 10.1016/j.comptc.2024.114667
- The role of air-water interface in the SO3 hydration reaction G. Lv & X. Sun 10.1016/j.atmosenv.2020.117514
- The significance of the metal cation in guanine-quartet – metalloporphyrin complexes A. Stanojević et al. 10.1039/D0CP05798C
- Pyruvic acid, an efficient catalyst in SO3 hydrolysis and effective clustering agent in sulfuric-acid-based new particle formation N. Tsona Tchinda et al. 10.5194/acp-22-1951-2022
- Metal-free catalysis on the reactions of nitric acid with aliphatic aldehydes: A new potential source of organic nitrates F. Bai et al. 10.1016/j.atmosenv.2023.119673
- Determination of reactions between Criegee intermediates and methanesulfonic acid at the air-water interface X. Ma et al. 10.1016/j.scitotenv.2019.135804
- Theoretical study of the reaction mechanism between Criegee intermediates and hydroxyl radicals in the presence of ammonia and amine Y. Wei et al. 10.1016/j.chemosphere.2021.131877
1 citations as recorded by crossref.
Latest update: 23 Apr 2025
Short summary
The hydration of SO3 to produce H2SO4 is an important process in the atmosphere. Using quantum chemical calculations, we investigated the catalytic role of oxalic acid in the SO3 hydration reaction. The results show that oxalic acid is effective in facilitating the hydration of SO3 to form H2SO4. The kinetic analysis result indicates that the oxalic-acid-catalyzed SO3 hydration can play an important role in the upper troposphere.
The hydration of SO3 to produce H2SO4 is an important process in the atmosphere. Using quantum...
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