Articles | Volume 19, issue 5
Atmos. Chem. Phys., 19, 2833–2844, 2019
https://doi.org/10.5194/acp-19-2833-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Special issue: Multiphase chemistry of secondary aerosol formation under...
Atmos. Chem. Phys., 19, 2833–2844, 2019
https://doi.org/10.5194/acp-19-2833-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article 04 Mar 2019
Research article | 04 Mar 2019
Understanding the catalytic role of oxalic acid in SO3 hydration to form H2SO4 in the atmosphere
Guochun Lv et al.
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Cited
14 citations as recorded by crossref.
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- Brønsted Acid and H‐Bond Activation in Boronic Acid Catalysis S. Zhang et al. 10.1002/chem.202001902
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- The significance of the metal cation in guanine-quartet – metalloporphyrin complexes A. Stanojević et al. 10.1039/D0CP05798C
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13 citations as recorded by crossref.
- Aldehyde as a potential source of aminol in troposphere: Influence of water and formic acid catalysis on ammonolysis of formaldehyde S. Sarkar et al. 10.1016/j.atmosenv.2019.05.069
- Hydrolysis of HNSO 2 : A potential route for atmospheric production of H 2 SO 4 and NH 3 G. Manonmani et al. 10.1002/qua.26182
- Intriguing Intermolecular Interplay in Guanine Quartet Complexes with Alkali and Alkaline Earth Cations B. Milovanović et al. 10.1021/acs.jpcb.0c01165
- Large Discrepancy in the Formation of Secondary Organic Aerosols from Structurally Similar Monoterpenes D. Thomsen et al. 10.1021/acsearthspacechem.0c00332
- Self‐catalyzed keto‐enol tautomerization of malonic acid C. Sutton et al. 10.1002/qua.26114
- Reactions of Criegee Intermediates are Enhanced by Hydrogen‐Atom Relay Through Molecular Design M. Kuo et al. 10.1002/cphc.202000585
- Brønsted Acid and H‐Bond Activation in Boronic Acid Catalysis S. Zhang et al. 10.1002/chem.202001902
- Unprecedented Ambient Sulfur Trioxide (SO3) Detection: Possible Formation Mechanism and Atmospheric Implications L. Yao et al. 10.1021/acs.estlett.0c00615
- Determination of the amine-catalyzed SO3 hydrolysis mechanism in the gas phase and at the air-water interface X. Ma et al. 10.1016/j.chemosphere.2020.126292
- The role of air-water interface in the SO3 hydration reaction G. Lv & X. Sun 10.1016/j.atmosenv.2020.117514
- The significance of the metal cation in guanine-quartet – metalloporphyrin complexes A. Stanojević et al. 10.1039/D0CP05798C
- Determination of reactions between Criegee intermediates and methanesulfonic acid at the air-water interface X. Ma et al. 10.1016/j.scitotenv.2019.135804
- Synergistic Reaction of SO2 with NO2 in Presence of H2O and NH3: A Potential Source of Sulfate Aerosol Z. Wang et al. 10.3390/ijms20153746
1 citations as recorded by crossref.
Latest update: 16 Apr 2021
Short summary
The hydration of SO3 to produce H2SO4 is an important process in the atmosphere. Using quantum chemical calculations, we investigated the catalytic role of oxalic acid in the SO3 hydration reaction. The results show that oxalic acid is effective in facilitating the hydration of SO3 to form H2SO4. The kinetic analysis result indicates that the oxalic-acid-catalyzed SO3 hydration can play an important role in the upper troposphere.
The hydration of SO3 to produce H2SO4 is an important process in the atmosphere. Using quantum...
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