Articles | Volume 19, issue 2
https://doi.org/10.5194/acp-19-1343-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-19-1343-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
01 Feb 2019
Research article |
| 01 Feb 2019
| 01 Feb 2019
Nitrogen-containing secondary organic aerosol formation by acrolein reaction with ammonia/ammonium
Zhijian Li
Shanghai Key Laboratory of Atmospheric Particle Pollution and
Prevention, Department of Environmental Science and Engineering, Fudan
University, Shanghai 200433, China
Sergey A. Nizkorodov
Department of Chemistry, University of California, Irvine, California
92697, USA
Hong Chen
Shanghai Key Laboratory of Atmospheric Particle Pollution and
Prevention, Department of Environmental Science and Engineering, Fudan
University, Shanghai 200433, China
Xiaohui Lu
CORRESPONDING AUTHOR
Shanghai Key Laboratory of Atmospheric Particle Pollution and
Prevention, Department of Environmental Science and Engineering, Fudan
University, Shanghai 200433, China
Shanghai Key Laboratory of Atmospheric Particle Pollution and
Prevention, Department of Environmental Science and Engineering, Fudan
University, Shanghai 200433, China
Shanghai Institute of Pollution Control and Ecological Security,
Shanghai 200092, China
Jianmin Chen
Shanghai Key Laboratory of Atmospheric Particle Pollution and
Prevention, Department of Environmental Science and Engineering, Fudan
University, Shanghai 200433, China
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21 citations as recorded by crossref.
- Molecular characterization of carbonyl compounds in atmospheric fine particulate matters (PM2.5) in Beijing by derivatization with Girard's reagent T combined with positive-ion ESI Orbitrap MS Z. Wang et al. 10.1016/j.atmosres.2022.106176
- Unveiling the Molecular Characteristics, Origins, and Formation Mechanism of Reduced Nitrogen Organic Compounds in the Urban Atmosphere of Shanghai Using a Versatile Aerosol Concentration Enrichment System M. Abudumutailifu et al. 10.1021/acs.est.3c04071
- Aging of Atmospheric Brown Carbon Aerosol R. Hems et al. 10.1021/acsearthspacechem.0c00346
- Assessing the role of mineral particles in the atmospheric photooxidation of typical carbonyl compound Y. Ji et al. 10.1016/j.jes.2020.12.026
- Research progress on secondary formation, photosensitive reaction mechanism and human health effects of chromophoric brown carbon B. Chen et al. 10.1016/j.jes.2024.04.003
- Acidity and the multiphase chemistry of atmospheric aqueous particles and clouds A. Tilgner et al. 10.5194/acp-21-13483-2021
- Theoretical study on atmospheric gaseous reactions of glyoxal with sulfuric acid and ammonia X. Lin et al. 10.1016/j.comptc.2022.113950
- Influence of Ammonia and Relative Humidity on the Formation and Composition of Secondary Brown Carbon from Oxidation of 1-Methylnaphthalene and Longifolene Y. Cui et al. 10.1021/acsearthspacechem.0c00353
- Aqueous-phase formation of N-containing secondary organic compounds affected by the ionic strength Y. Gan et al. 10.1016/j.jes.2023.03.003
- Production of Atmospheric Organosulfates via Mineral-Mediated Photochemistry M. Schmidt et al. 10.1021/acsearthspacechem.8b00178
- New mechanistic pathways for the formation of organosulfates catalyzed by ammonia and carbinolamine formation catalyzed by sulfuric acid in the atmosphere X. Tan et al. 10.1039/C9CP06297A
- ROS-generation potential of Humic-like substances (HULIS) in ambient PM2.5 in urban Shanghai: Association with HULIS concentration and light absorbance X. Xu et al. 10.1016/j.chemosphere.2020.127050
- Direct contribution of ammonia to <i>α</i>-pinene secondary organic aerosol formation L. Hao et al. 10.5194/acp-20-14393-2020
- Factors Influencing the Molecular Compositions and Distributions of Atmospheric Nitrogen‐Containing Compounds H. Jiang et al. 10.1029/2021JD036284
- Aqueous-Phase Reactions of Anthropogenic Emissions Lead to the High Chemodiversity of Atmospheric Nitrogen-Containing Compounds during the Haze Event H. Jiang et al. 10.1021/acs.est.3c06648
- High secondary formation of nitrogen-containing organics (NOCs) and its possible link to oxidized organics and ammonium G. Zhang et al. 10.5194/acp-20-1469-2020
- N-nitration of secondary aliphatic amines in the particle phase T. Chen et al. 10.1016/j.chemosphere.2022.133639
- Insight into the Mechanism of Glycerol Dehydration and Subsequent Pyridine Synthesis D. Jiang et al. 10.1021/acssuschemeng.0c07460
- Kinetics of CH2OO and syn-CH3CHOO reaction with acrolein X. Zhou et al. 10.1039/D1CP00492A
- Gas- and Particle-Phase Amide Emissions from Cooking: Mechanisms and Air Quality Impacts J. Ditto et al. 10.1021/acs.est.2c01409
- Influence of temperature on the heterogeneous reaction of toluene to N-containing organic compounds using in situ DRIFTS X. He et al. 10.1016/j.atmosenv.2023.120084
21 citations as recorded by crossref.
- Molecular characterization of carbonyl compounds in atmospheric fine particulate matters (PM2.5) in Beijing by derivatization with Girard's reagent T combined with positive-ion ESI Orbitrap MS Z. Wang et al. 10.1016/j.atmosres.2022.106176
- Unveiling the Molecular Characteristics, Origins, and Formation Mechanism of Reduced Nitrogen Organic Compounds in the Urban Atmosphere of Shanghai Using a Versatile Aerosol Concentration Enrichment System M. Abudumutailifu et al. 10.1021/acs.est.3c04071
- Aging of Atmospheric Brown Carbon Aerosol R. Hems et al. 10.1021/acsearthspacechem.0c00346
- Assessing the role of mineral particles in the atmospheric photooxidation of typical carbonyl compound Y. Ji et al. 10.1016/j.jes.2020.12.026
- Research progress on secondary formation, photosensitive reaction mechanism and human health effects of chromophoric brown carbon B. Chen et al. 10.1016/j.jes.2024.04.003
- Acidity and the multiphase chemistry of atmospheric aqueous particles and clouds A. Tilgner et al. 10.5194/acp-21-13483-2021
- Theoretical study on atmospheric gaseous reactions of glyoxal with sulfuric acid and ammonia X. Lin et al. 10.1016/j.comptc.2022.113950
- Influence of Ammonia and Relative Humidity on the Formation and Composition of Secondary Brown Carbon from Oxidation of 1-Methylnaphthalene and Longifolene Y. Cui et al. 10.1021/acsearthspacechem.0c00353
- Aqueous-phase formation of N-containing secondary organic compounds affected by the ionic strength Y. Gan et al. 10.1016/j.jes.2023.03.003
- Production of Atmospheric Organosulfates via Mineral-Mediated Photochemistry M. Schmidt et al. 10.1021/acsearthspacechem.8b00178
- New mechanistic pathways for the formation of organosulfates catalyzed by ammonia and carbinolamine formation catalyzed by sulfuric acid in the atmosphere X. Tan et al. 10.1039/C9CP06297A
- ROS-generation potential of Humic-like substances (HULIS) in ambient PM2.5 in urban Shanghai: Association with HULIS concentration and light absorbance X. Xu et al. 10.1016/j.chemosphere.2020.127050
- Direct contribution of ammonia to <i>α</i>-pinene secondary organic aerosol formation L. Hao et al. 10.5194/acp-20-14393-2020
- Factors Influencing the Molecular Compositions and Distributions of Atmospheric Nitrogen‐Containing Compounds H. Jiang et al. 10.1029/2021JD036284
- Aqueous-Phase Reactions of Anthropogenic Emissions Lead to the High Chemodiversity of Atmospheric Nitrogen-Containing Compounds during the Haze Event H. Jiang et al. 10.1021/acs.est.3c06648
- High secondary formation of nitrogen-containing organics (NOCs) and its possible link to oxidized organics and ammonium G. Zhang et al. 10.5194/acp-20-1469-2020
- N-nitration of secondary aliphatic amines in the particle phase T. Chen et al. 10.1016/j.chemosphere.2022.133639
- Insight into the Mechanism of Glycerol Dehydration and Subsequent Pyridine Synthesis D. Jiang et al. 10.1021/acssuschemeng.0c07460
- Kinetics of CH2OO and syn-CH3CHOO reaction with acrolein X. Zhou et al. 10.1039/D1CP00492A
- Gas- and Particle-Phase Amide Emissions from Cooking: Mechanisms and Air Quality Impacts J. Ditto et al. 10.1021/acs.est.2c01409
- Influence of temperature on the heterogeneous reaction of toluene to N-containing organic compounds using in situ DRIFTS X. He et al. 10.1016/j.atmosenv.2023.120084
Latest update: 18 Apr 2024
Short summary
In this work, we found that acrolein, the smallest α,β-unsaturated aldehyde, has the potential to form light-absorbing heterocyclic secondary organic aerosol. In the gaseous phase, acrolein can react with gaseous ammonia, forming 3-picoline. In the liquid phase, the dissolved acrolein can react with ammonium to form higher molecular-weight pyridinium compounds. All the pyridinium compounds can increase the light absorptivity of aerosol particles.
In this work, we found that acrolein, the smallest α,β-unsaturated aldehyde, has the potential...
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