Articles | Volume 19, issue 17
https://doi.org/10.5194/acp-19-11253-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-19-11253-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
05 Sep 2019
Research article |
| 05 Sep 2019
| 05 Sep 2019
Chamber-based insights into the factors controlling epoxydiol (IEPOX) secondary organic aerosol (SOA) yield, composition, and volatility
Emma L. D'Ambro
Department of Atmospheric Sciences, University of Washington, Seattle, WA, USA
Department of Chemistry, University of Washington, Seattle, WA, USA
Siegfried Schobesberger
Department of Atmospheric Sciences, University of Washington, Seattle, WA, USA
Department of Applied Physics, University of Eastern Finland, Kuopio, Finland
Cassandra J. Gaston
Department of Atmospheric Sciences, University of Washington, Seattle, WA, USA
now at: Rosenstiel School of Marine & Atmospheric Science,
University of Miami, FL, USA
Felipe D. Lopez-Hilfiker
Department of Atmospheric Sciences, University of Washington, Seattle, WA, USA
now at: TofWerk AG, Thun, Switzerland
Ben H. Lee
Department of Atmospheric Sciences, University of Washington, Seattle, WA, USA
Jiumeng Liu
Atmospheric Sciences and Global Change Division, Pacific Northwest
National Laboratory, Richland, WA, USA
now at: School of Environment, Harbin Institute of Technology, Harbin, Heilongjiang, China
Alla Zelenyuk
Environmental Molecular Sciences Laboratory, Pacific Northwest
National Laboratory, Richland, WA, USA
David Bell
Environmental Molecular Sciences Laboratory, Pacific Northwest
National Laboratory, Richland, WA, USA
now at: Laboratory of Atmospheric Chemistry, Paul Scherrer Institute, PSI-Villigen, Switzerland
Christopher D. Cappa
Department of Civil and Environmental Engineering, University of
California, Davis, CA, USA
Atmospheric Science Graduate Group, University of California, Davis,
CA, USA
Taylor Helgestad
Department of Civil and Environmental Engineering, University of
California, Davis, CA, USA
now at: California Air Resources Board, Sacramento, CA, USA
Atmospheric Science Graduate Group, University of California, Davis,
CA, USA
Alex Guenther
Environmental Molecular Sciences Laboratory, Pacific Northwest
National Laboratory, Richland, WA, USA
now at: Department of Earth System Science, University of California, Irvine, USA
Jian Wang
Environmental and Climate Sciences Department, Brookhaven National
Laboratory, Upton, NY, USA
now at: Center for Aerosol Science and Engineering, Department of
Energy, Environmental and Chemical Engineering, Washington University in St.
Louis, St. Louis, MO, USA
Matthew Wise
Department of Math and Science, Concordia University, Portland, OR, USA
now at: Department of Chemistry, University of Colorado, Boulder, CO, USA
Ryan Caylor
Department of Math and Science, Concordia University, Portland, OR, USA
Jason D. Surratt
Department of Environmental Sciences and Engineering, Gillings School of Global and Public Health, University of North Carolina, Chapel Hill, NC, USA
Theran Riedel
Department of Environmental Sciences and Engineering, Gillings School of Global and Public Health, University of North Carolina, Chapel Hill, NC, USA
Noora Hyttinen
Department of Chemistry and Institute for Atmospheric and Earth
System Research (INAR), University of Helsinki, Helsinki, Finland
now at: Nano and Molecular Systems Research Unit, University of Oulu, Oulu, Finland
Vili-Taneli Salo
Department of Chemistry and Institute for Atmospheric and Earth
System Research (INAR), University of Helsinki, Helsinki, Finland
Galib Hasan
Department of Chemistry and Institute for Atmospheric and Earth
System Research (INAR), University of Helsinki, Helsinki, Finland
Theo Kurtén
Department of Chemistry and Institute for Atmospheric and Earth
System Research (INAR), University of Helsinki, Helsinki, Finland
John E. Shilling
Atmospheric Sciences and Global Change Division, Pacific Northwest
National Laboratory, Richland, WA, USA
Joel A. Thornton
CORRESPONDING AUTHOR
Department of Atmospheric Sciences, University of Washington, Seattle, WA, USA
Department of Chemistry, University of Washington, Seattle, WA, USA
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43 citations as recorded by crossref.
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- Isomer-resolved unimolecular dynamics of the hydroperoxyalkyl intermediate (•QOOH) in cyclohexane oxidation Y. Qian et al. 10.1073/pnas.2401148121
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- Modeling the Size Distribution and Chemical Composition of Secondary Organic Aerosols during the Reactive Uptake of Isoprene-Derived Epoxydiols under Low-Humidity Condition M. Octaviani et al. 10.1021/acsearthspacechem.1c00303
- Monoterpene Photooxidation in a Continuous-Flow Chamber: SOA Yields and Impacts of Oxidants, NOx, and VOC Precursors J. Liu et al. 10.1021/acs.est.2c02630
- Natural and Anthropogenically Influenced Isoprene Oxidation in Southeastern United States and Central Amazon L. Yee et al. 10.1021/acs.est.0c00805
- Future changes in isoprene-epoxydiol-derived secondary organic aerosol (IEPOX SOA) under the Shared Socioeconomic Pathways: the importance of physicochemical dependency D. Jo et al. 10.5194/acp-21-3395-2021
- Size distributions of molecular markers for biogenic secondary organic aerosol in urban Beijing D. Liu et al. 10.1016/j.envpol.2023.121569
- Decreases in Epoxide-Driven Secondary Organic Aerosol Production under Highly Acidic Conditions: The Importance of Acid–Base Equilibria M. Cooke et al. 10.1021/acs.est.3c10851
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- Nocturnal survival of isoprene linked to formation of upper tropospheric organic aerosol P. Palmer et al. 10.1126/science.abg4506
- New formation and fate of Isoprene SOA markers revealed by field data-constrained modeling J. Zhang et al. 10.1038/s41612-023-00394-3
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- The effect of temperature and relative humidity on secondary organic aerosol formation from ozonolysis of Δ3-carene D. Thomsen et al. 10.1039/D3EA00128H
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- Pathways to Highly Oxidized Products in the Δ3-Carene + OH System E. D’Ambro et al. 10.1021/acs.est.1c06949
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- Molecular dynamics investigation of IEPOX chemical behavior at the interface and in the bulk phase of acidic aerosols X. Liu et al. 10.1016/j.chemosphere.2024.143586
- Long-term observational constraints of organic aerosol dependence on inorganic species in the southeast US Y. Zheng et al. 10.5194/acp-20-13091-2020
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41 citations as recorded by crossref.
- Boiling of Catechol Secondary Organic Aerosol When Heated to Mild Temperatures (36–52 °C) Due to Carbon Dioxide Formation and High Viscosity K. Kiland et al. 10.1021/acsestair.4c00027
- Molecular characteristics and formation mechanisms of biogenic secondary organic aerosols in the mountainous background atmosphere of southern China S. Zhang et al. 10.1016/j.atmosenv.2024.120540
- Impact of Aerosol-Cloud Cycling on Aqueous Secondary Organic Aerosol Formation W. Tsui et al. 10.3390/atmos10110666
- Comparison of saturation vapor pressures of <i>α</i>-pinene + O<sub>3</sub> oxidation products derived from COSMO-RS computations and thermal desorption experiments N. Hyttinen et al. 10.5194/acp-22-1195-2022
- Isomer-resolved unimolecular dynamics of the hydroperoxyalkyl intermediate (•QOOH) in cyclohexane oxidation Y. Qian et al. 10.1073/pnas.2401148121
- Determination of Volatility Parameters of Secondary Organic Aerosol Components via Thermal Analysis F. Ashraf et al. 10.3390/atmos13050709
- A Near-Explicit Mechanistic Evaluation of Isoprene Photochemical Secondary Organic Aerosol Formation and Evolution: Simulations of Multiple Chamber Experiments with and without Added NOx J. Thornton et al. 10.1021/acsearthspacechem.0c00118
- Modeling the Size Distribution and Chemical Composition of Secondary Organic Aerosols during the Reactive Uptake of Isoprene-Derived Epoxydiols under Low-Humidity Condition M. Octaviani et al. 10.1021/acsearthspacechem.1c00303
- Monoterpene Photooxidation in a Continuous-Flow Chamber: SOA Yields and Impacts of Oxidants, NOx, and VOC Precursors J. Liu et al. 10.1021/acs.est.2c02630
- Natural and Anthropogenically Influenced Isoprene Oxidation in Southeastern United States and Central Amazon L. Yee et al. 10.1021/acs.est.0c00805
- Future changes in isoprene-epoxydiol-derived secondary organic aerosol (IEPOX SOA) under the Shared Socioeconomic Pathways: the importance of physicochemical dependency D. Jo et al. 10.5194/acp-21-3395-2021
- Size distributions of molecular markers for biogenic secondary organic aerosol in urban Beijing D. Liu et al. 10.1016/j.envpol.2023.121569
- Decreases in Epoxide-Driven Secondary Organic Aerosol Production under Highly Acidic Conditions: The Importance of Acid–Base Equilibria M. Cooke et al. 10.1021/acs.est.3c10851
- An intercomparison study of four different techniques for measuring the chemical composition of nanoparticles L. Caudillo et al. 10.5194/acp-23-6613-2023
- The C5–Alkene Triol Conundrum: Structural Characterization and Quantitation of Isoprene-Derived C5H10O3 Reactive Uptake Products M. Frauenheim et al. 10.1021/acs.estlett.2c00548
- Nocturnal survival of isoprene linked to formation of upper tropospheric organic aerosol P. Palmer et al. 10.1126/science.abg4506
- New formation and fate of Isoprene SOA markers revealed by field data-constrained modeling J. Zhang et al. 10.1038/s41612-023-00394-3
- Secondary Organic Aerosols in PM2.5 in Bengbu, a Typical City in Central China: Concentration, Seasonal Variation and Sources S. Zhang et al. 10.3390/atmos12070854
- Variation in chemical composition and volatility of oxygenated organic aerosol in different rural, urban, and mountain environments W. Huang et al. 10.5194/acp-24-2607-2024
- Combined application of online FIGAERO-CIMS and offline LC-Orbitrap mass spectrometry (MS) to characterize the chemical composition of secondary organic aerosol (SOA) in smog chamber studies M. Du et al. 10.5194/amt-15-4385-2022
- The effect of temperature and relative humidity on secondary organic aerosol formation from ozonolysis of Δ3-carene D. Thomsen et al. 10.1039/D3EA00128H
- Evaluating Organic Aerosol Sources and Evolution with a Combined Molecular Composition and Volatility Framework Using the Filter Inlet for Gases and Aerosols (FIGAERO) J. Thornton et al. 10.1021/acs.accounts.0c00259
- Strong anthropogenic control of secondary organic aerosol formation from isoprene in Beijing D. Bryant et al. 10.5194/acp-20-7531-2020
- Deconvolution of FIGAERO–CIMS thermal desorption profiles using positive matrix factorisation to identify chemical and physical processes during particle evaporation A. Buchholz et al. 10.5194/acp-20-7693-2020
- Observationally Constrained Modeling of the Reactive Uptake of Isoprene-Derived Epoxydiols under Elevated Relative Humidity and Varying Acidity of Seed Aerosol Conditions J. Zhang et al. 10.1021/acsearthspacechem.2c00358
- Characterization of thermal decomposition of oxygenated organic compounds in FIGAERO-CIMS L. Yang et al. 10.1080/02786826.2021.1945529
- Linking gas, particulate, and toxic endpoints to air emissions in the Community Regional Atmospheric Chemistry Multiphase Mechanism (CRACMM) H. Pye et al. 10.5194/acp-23-5043-2023
- Decrease in sulfate aerosol light backscattering by reactive uptake of isoprene epoxydiols C. Dubois et al. 10.1039/D0CP05468B
- Applying a Phase-Separation Parameterization in Modeling Secondary Organic Aerosol Formation from Acid-Driven Reactive Uptake of Isoprene Epoxydiols under Humid Conditions Y. Chen et al. 10.1021/acsestair.4c00002
- Isoprene Epoxydiol-Derived Sulfated and Nonsulfated Oligomers Suppress Particulate Mass Loss during Oxidative Aging of Secondary Organic Aerosol N. Armstrong et al. 10.1021/acs.est.2c03200
- Seasonal Contribution of Isoprene-Derived Organosulfates to Total Water-Soluble Fine Particulate Organic Sulfur in the United States Y. Chen et al. 10.1021/acsearthspacechem.1c00102
- Thermodynamic properties of isoprene- and monoterpene-derived organosulfates estimated with COSMO<i>therm</i> N. Hyttinen et al. 10.5194/acp-20-5679-2020
- A robust clustering algorithm for analysis of composition-dependent organic aerosol thermal desorption measurements Z. Li et al. 10.5194/acp-20-2489-2020
- Resolving Ambient Organic Aerosol Formation and Aging Pathways with Simultaneous Molecular Composition and Volatility Observations B. Lee et al. 10.1021/acsearthspacechem.9b00302
- Infrared signature of the hydroperoxyalkyl intermediate (·QOOH) in cyclohexane oxidation: An isomer-resolved spectroscopic study T. Roy et al. 10.1063/5.0219431
- Predictions of the glass transition temperature and viscosity of organic aerosols from volatility distributions Y. Li et al. 10.5194/acp-20-8103-2020
- Pathways to Highly Oxidized Products in the Δ3-Carene + OH System E. D’Ambro et al. 10.1021/acs.est.1c06949
- Observed and CMIP6-model-simulated organic aerosol response to drought in the contiguous United States during summertime W. Li & Y. Wang 10.5194/acp-24-9339-2024
- Tight Coupling of Surface and In-Plant Biochemistry and Convection Governs Key Fine Particulate Components over the Amazon Rainforest M. Shrivastava et al. 10.1021/acsearthspacechem.1c00356
- A Coupled Volatility and Molecular Composition Based Source Apportionment of Atmospheric Organic Aerosol P. Rund et al. 10.1021/acsearthspacechem.3c00034
- Molecular dynamics investigation of IEPOX chemical behavior at the interface and in the bulk phase of acidic aerosols X. Liu et al. 10.1016/j.chemosphere.2024.143586
2 citations as recorded by crossref.
- Long-term observational constraints of organic aerosol dependence on inorganic species in the southeast US Y. Zheng et al. 10.5194/acp-20-13091-2020
- Chemistry and deposition in the Model of Atmospheric composition at Global and Regional scales using Inversion Techniques for Trace gas Emissions (MAGRITTE v1.1) – Part 1: Chemical mechanism J. Müller et al. 10.5194/gmd-12-2307-2019
Discussed (final revised paper)
Latest update: 23 Nov 2024
Short summary
Isoprene is the most abundantly emitted reactive organic gas globally, and thus it is important to understand its fate and role in aerosol formation and growth. A major product of its oxidation is an epoxydiol, IEPOX, which can be efficiently taken up by acidic aerosol to generate substantial amounts of secondary organic aerosol (SOA). We present chamber experiments exploring the properties of IEPOX SOA and reconcile discrepancies between field, laboratory, and model studies of this process.
Isoprene is the most abundantly emitted reactive organic gas globally, and thus it is important...
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