Articles | Volume 19, issue 17
https://doi.org/10.5194/acp-19-11253-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-19-11253-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Chamber-based insights into the factors controlling epoxydiol (IEPOX) secondary organic aerosol (SOA) yield, composition, and volatility
Emma L. D'Ambro
Department of Atmospheric Sciences, University of Washington, Seattle, WA, USA
Department of Chemistry, University of Washington, Seattle, WA, USA
Siegfried Schobesberger
Department of Atmospheric Sciences, University of Washington, Seattle, WA, USA
Department of Applied Physics, University of Eastern Finland, Kuopio, Finland
Cassandra J. Gaston
Department of Atmospheric Sciences, University of Washington, Seattle, WA, USA
now at: Rosenstiel School of Marine & Atmospheric Science,
University of Miami, FL, USA
Felipe D. Lopez-Hilfiker
Department of Atmospheric Sciences, University of Washington, Seattle, WA, USA
now at: TofWerk AG, Thun, Switzerland
Ben H. Lee
Department of Atmospheric Sciences, University of Washington, Seattle, WA, USA
Jiumeng Liu
Atmospheric Sciences and Global Change Division, Pacific Northwest
National Laboratory, Richland, WA, USA
now at: School of Environment, Harbin Institute of Technology, Harbin, Heilongjiang, China
Alla Zelenyuk
Environmental Molecular Sciences Laboratory, Pacific Northwest
National Laboratory, Richland, WA, USA
David Bell
Environmental Molecular Sciences Laboratory, Pacific Northwest
National Laboratory, Richland, WA, USA
now at: Laboratory of Atmospheric Chemistry, Paul Scherrer Institute, PSI-Villigen, Switzerland
Christopher D. Cappa
Department of Civil and Environmental Engineering, University of
California, Davis, CA, USA
Atmospheric Science Graduate Group, University of California, Davis,
CA, USA
Taylor Helgestad
Department of Civil and Environmental Engineering, University of
California, Davis, CA, USA
now at: California Air Resources Board, Sacramento, CA, USA
Atmospheric Science Graduate Group, University of California, Davis,
CA, USA
Alex Guenther
Environmental Molecular Sciences Laboratory, Pacific Northwest
National Laboratory, Richland, WA, USA
now at: Department of Earth System Science, University of California, Irvine, USA
Jian Wang
Environmental and Climate Sciences Department, Brookhaven National
Laboratory, Upton, NY, USA
now at: Center for Aerosol Science and Engineering, Department of
Energy, Environmental and Chemical Engineering, Washington University in St.
Louis, St. Louis, MO, USA
Matthew Wise
Department of Math and Science, Concordia University, Portland, OR, USA
now at: Department of Chemistry, University of Colorado, Boulder, CO, USA
Ryan Caylor
Department of Math and Science, Concordia University, Portland, OR, USA
Jason D. Surratt
Department of Environmental Sciences and Engineering, Gillings School of Global and Public Health, University of North Carolina, Chapel Hill, NC, USA
Theran Riedel
Department of Environmental Sciences and Engineering, Gillings School of Global and Public Health, University of North Carolina, Chapel Hill, NC, USA
Noora Hyttinen
Department of Chemistry and Institute for Atmospheric and Earth
System Research (INAR), University of Helsinki, Helsinki, Finland
now at: Nano and Molecular Systems Research Unit, University of Oulu, Oulu, Finland
Vili-Taneli Salo
Department of Chemistry and Institute for Atmospheric and Earth
System Research (INAR), University of Helsinki, Helsinki, Finland
Galib Hasan
Department of Chemistry and Institute for Atmospheric and Earth
System Research (INAR), University of Helsinki, Helsinki, Finland
Theo Kurtén
Department of Chemistry and Institute for Atmospheric and Earth
System Research (INAR), University of Helsinki, Helsinki, Finland
John E. Shilling
Atmospheric Sciences and Global Change Division, Pacific Northwest
National Laboratory, Richland, WA, USA
Joel A. Thornton
CORRESPONDING AUTHOR
Department of Atmospheric Sciences, University of Washington, Seattle, WA, USA
Department of Chemistry, University of Washington, Seattle, WA, USA
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Short summary
Isoprene is the most abundantly emitted reactive organic gas globally, and thus it is important to understand its fate and role in aerosol formation and growth. A major product of its oxidation is an epoxydiol, IEPOX, which can be efficiently taken up by acidic aerosol to generate substantial amounts of secondary organic aerosol (SOA). We present chamber experiments exploring the properties of IEPOX SOA and reconcile discrepancies between field, laboratory, and model studies of this process.
Isoprene is the most abundantly emitted reactive organic gas globally, and thus it is important...
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