Articles | Volume 19, issue 15
https://doi.org/10.5194/acp-19-10073-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-19-10073-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
09 Aug 2019
Research article |
| 09 Aug 2019
| 09 Aug 2019
Predictions of diffusion rates of large organic molecules in secondary organic aerosols using the Stokes–Einstein and fractional Stokes–Einstein relations
Department of Chemistry, University of British Columbia, 2036 Main
Mall, Vancouver, BC, V6T 1Z1, Canada
Adrian M. Maclean
Department of Chemistry, University of British Columbia, 2036 Main
Mall, Vancouver, BC, V6T 1Z1, Canada
Grazia Rovelli
School of Chemistry, University of Bristol, Bristol, BS8 1TS, UK
now at: Chemical Science Division, Lawrence Berkeley National
Laboratory, Berkeley, California 94611, USA
Department of Chemistry, University of California, Irvine,
California 92697-2025, USA
Alexandra P. Tsimpidi
Atmospheric Chemistry Department, Max Planck Institute for Chemistry,
55128 Mainz, Germany
National Observatory of Athens, Institute for Environmental
Research & Sustainable Development, 15236 Palea Penteli, Greece
Vlassis A. Karydis
Atmospheric Chemistry Department, Max Planck Institute for Chemistry,
55128 Mainz, Germany
Forschungszentrum Jülich, Institute of Energy & Climate
Research, IEK-8, 52425 Jülich, Germany
Saeid Kamal
Department of Chemistry, University of British Columbia, 2036 Main
Mall, Vancouver, BC, V6T 1Z1, Canada
Jos Lelieveld
Atmospheric Chemistry Department, Max Planck Institute for Chemistry,
55128 Mainz, Germany
Energy, Environment and Water Research Center, The Cyprus Institute, Nicosia 1645, Cyprus
Manabu Shiraiwa
Department of Chemistry, University of California, Irvine,
California 92697-2025, USA
Jonathan P. Reid
School of Chemistry, University of Bristol, Bristol, BS8 1TS, UK
Allan K. Bertram
Department of Chemistry, University of British Columbia, 2036 Main
Mall, Vancouver, BC, V6T 1Z1, Canada
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- Kinetic modeling of formation and evaporation of secondary organic aerosol from NO<sub>3</sub> oxidation of pure and mixed monoterpenes T. Berkemeier et al. 10.5194/acp-20-15513-2020
- Tutorial: Electrodynamic balance methods for single particle levitation and the physicochemical analysis of aerosol R. Kaur Kohli et al. 10.1016/j.jaerosci.2023.106255
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- Current State of Atmospheric Aerosol Thermodynamics and Mass Transfer Modeling: A Review K. Semeniuk & A. Dastoor 10.3390/atmos11020156
- Secondary organic aerosols derived from intermediate-volatility n-alkanes adopt low-viscous phase state T. Galeazzo et al. 10.5194/acp-24-5549-2024
- Predictions of the glass transition temperature and viscosity of organic aerosols from volatility distributions Y. Li et al. 10.5194/acp-20-8103-2020
- Viscosity, Glass Formation, and Mixing Times within Secondary Organic Aerosol from Biomass Burning Phenolics K. Kiland et al. 10.1021/acsearthspacechem.3c00039
- Unified Description of Diffusion Coefficients from Small to Large Molecules in Organic–Water Mixtures E. Evoy et al. 10.1021/acs.jpca.9b11271
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- Insect Infestation Increases Viscosity of Biogenic Secondary Organic Aerosol N. Smith et al. 10.1021/acsearthspacechem.3c00007
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- Viscosity and liquid–liquid phase separation in healthy and stressed plant SOA N. Smith et al. 10.1039/D0EA00020E
- Estimation of secondary organic aerosol viscosity from explicit modeling of gas-phase oxidation of isoprene and <i>α</i>-pinene T. Galeazzo et al. 10.5194/acp-21-10199-2021
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- Non-Fickian diffusion in viscous aerosol particles T. Preston 10.1139/cjc-2021-0187
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- Exploring the hygroscopicity, water diffusivity, and viscosity of organic–inorganic aerosols – a case study on internally-mixed citric acid and ammonium sulfate particles C. Sheldon et al. 10.1039/D2EA00116K
- Correlating the Viscosity and Rate of Water Diffusion in Semisolid Gel-Forming Aerosol Particles C. Sheldon et al. 10.1021/acsearthspacechem.3c00241
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Latest update: 23 Nov 2024
Short summary
We measured the diffusion rates of organic molecules in a number of proxies for secondary organic aerosol (SOA) and compared measured diffusion with predictions from two relations: the Stokes–Einstein relation and a fractional Stokes–Einstein relation. The fractional relation does a better job of predicting diffusion rates in this case. Output from an atmospheric model shows that mixing times predicted using the two relations differ by up to 1 order of magnitude at an altitude of ~ 3 km.
We measured the diffusion rates of organic molecules in a number of proxies for secondary...
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