Articles | Volume 18, issue 20
https://doi.org/10.5194/acp-18-14757-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-18-14757-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
15 Oct 2018
Research article |
| 15 Oct 2018
| 15 Oct 2018
A model framework to retrieve thermodynamic and kinetic properties of organic aerosol from composition-resolved thermal desorption measurements
Siegfried Schobesberger
CORRESPONDING AUTHOR
Department of Atmospheric Sciences, University of Washington, Seattle,
Washington 98195, USA
Department of Applied Physics, University of Eastern Finland, Kuopio,
70211, Finland
Emma L. D'Ambro
Department of Atmospheric Sciences, University of Washington, Seattle,
Washington 98195, USA
Department of Chemistry, University of Washington, Seattle, Washington
98195, USA
Felipe D. Lopez-Hilfiker
Department of Atmospheric Sciences, University of Washington, Seattle,
Washington 98195, USA
now at: Tofwerk AG, Thun, 3600, Switzerland
Claudia Mohr
Department of Atmospheric Sciences, University of Washington, Seattle,
Washington 98195, USA
Department of Environmental Science and Analytical Chemistry,
Stockholm University, Stockholm, 10691, Sweden
Joel A. Thornton
Department of Atmospheric Sciences, University of Washington, Seattle,
Washington 98195, USA
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Latest update: 25 Dec 2024
Short summary
Current mass spectrometers allow us to measure the composition of individual organic molecules in aerosol particles, as well as how they evaporate from the particles when those are slowly heated up to 200 °C. We have developed a detailed computer model to simulate the physical and chemical processes that underlie that evaporation and thus help us understand important aerosol properties. Among other factors, we discuss the roles of vapor pressures, and accretion and decomposition reactions.
Current mass spectrometers allow us to measure the composition of individual organic molecules...
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