Articles | Volume 18, issue 17
Atmos. Chem. Phys., 18, 13231–13243, 2018
https://doi.org/10.5194/acp-18-13231-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Atmos. Chem. Phys., 18, 13231–13243, 2018
https://doi.org/10.5194/acp-18-13231-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
13 Sep 2018
Research article
| 13 Sep 2018
The role of H2SO4-NH3 anion clusters in ion-induced aerosol nucleation mechanisms in the boreal forest
Chao Yan et al.
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17 citations as recorded by crossref.
- Atmospheric new particle formation in India: Current understanding and knowledge gaps V. Kanawade et al. 10.1016/j.atmosenv.2021.118894
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- Long-term measurement of sub-3 nm particles and their precursor gases in the boreal forest J. Sulo et al. 10.5194/acp-21-695-2021
- Competitive formation of HSO4- and HSO5- from ion-induced SO2 oxidation: Implication in atmospheric aerosol formation N. Tsona et al. 10.1016/j.atmosenv.2021.118362
- New particle formation (NPF) events in China urban clusters given by sever composite pollution background Q. Zhang et al. 10.1016/j.chemosphere.2020.127842
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- Acid–Base Clusters during Atmospheric New Particle Formation in Urban Beijing R. Yin et al. 10.1021/acs.est.1c02701
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- New particle formation from sulfuric acid and ammonia: nucleation and growth model based on thermodynamics derived from CLOUD measurements for a wide range of conditions A. Kürten 10.5194/acp-19-5033-2019
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- Sources and sinks driving sulfuric acid concentrations in contrasting environments: implications on proxy calculations L. Dada et al. 10.5194/acp-20-11747-2020
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- Wintertime subarctic new particle formation from Kola Peninsula sulfur emissions M. Sipilä et al. 10.5194/acp-21-17559-2021
- Molecular insights into new particle formation in Barcelona, Spain J. Brean et al. 10.5194/acp-20-10029-2020
- Identification of molecular cluster evaporation rates, cluster formation enthalpies and entropies by Monte Carlo method A. Shcherbacheva et al. 10.5194/acp-20-15867-2020
17 citations as recorded by crossref.
- Atmospheric new particle formation in India: Current understanding and knowledge gaps V. Kanawade et al. 10.1016/j.atmosenv.2021.118894
- New particle formation in the volcanic eruption plume of the Piton de la Fournaise: specific features from a long-term dataset C. Rose et al. 10.5194/acp-19-13243-2019
- Long-term measurement of sub-3 nm particles and their precursor gases in the boreal forest J. Sulo et al. 10.5194/acp-21-695-2021
- Competitive formation of HSO4- and HSO5- from ion-induced SO2 oxidation: Implication in atmospheric aerosol formation N. Tsona et al. 10.1016/j.atmosenv.2021.118362
- New particle formation (NPF) events in China urban clusters given by sever composite pollution background Q. Zhang et al. 10.1016/j.chemosphere.2020.127842
- Investigation of several proxies to estimate sulfuric acid concentration under volcanic plume conditions C. Rose et al. 10.5194/acp-21-4541-2021
- Acid–Base Clusters during Atmospheric New Particle Formation in Urban Beijing R. Yin et al. 10.1021/acs.est.1c02701
- Theoretical study of the formation and nucleation mechanism of highly oxygenated multi-functional organic compounds produced by α-pinene X. Shi et al. 10.1016/j.scitotenv.2021.146422
- New particle formation from sulfuric acid and ammonia: nucleation and growth model based on thermodynamics derived from CLOUD measurements for a wide range of conditions A. Kürten 10.5194/acp-19-5033-2019
- The effect of meteorological conditions and atmospheric composition in the occurrence and development of new particle formation (NPF) events in Europe D. Bousiotis et al. 10.5194/acp-21-3345-2021
- Source apportionment of particle number size distribution in urban background and traffic stations in four European cities I. Rivas et al. 10.1016/j.envint.2019.105345
- Sources and sinks driving sulfuric acid concentrations in contrasting environments: implications on proxy calculations L. Dada et al. 10.5194/acp-20-11747-2020
- Measurement of ammonia, amines and iodine compounds using protonated water cluster chemical ionization mass spectrometry J. Pfeifer et al. 10.5194/amt-13-2501-2020
- A potential source of atmospheric sulfate from O<sub>2</sub><sup>−</sup>-induced SO<sub>2</sub> oxidation by ozone N. Tsona & L. Du 10.5194/acp-19-649-2019
- Wintertime subarctic new particle formation from Kola Peninsula sulfur emissions M. Sipilä et al. 10.5194/acp-21-17559-2021
- Molecular insights into new particle formation in Barcelona, Spain J. Brean et al. 10.5194/acp-20-10029-2020
- Identification of molecular cluster evaporation rates, cluster formation enthalpies and entropies by Monte Carlo method A. Shcherbacheva et al. 10.5194/acp-20-15867-2020
Latest update: 08 Aug 2022
Short summary
Ions can play an important role in atmospheric new particle formation by stabilizing the embryonic clusters. Such a process is called ion-induced nucleation (IIN). We found two distinct IIN mechanisms – driven by H2SO4-NH3 clusters and by organic vapors, respectively. The concentration ratio of organic vapors to H2SO4 regulates via which pathway the IIN occur. As the organic vapor concentration is influenced by temperature, a seasonal variation in the main IIN mechanism can be expected.
Ions can play an important role in atmospheric new particle formation by stabilizing the...
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