Articles | Volume 18, issue 17
https://doi.org/10.5194/acp-18-13231-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-18-13231-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
13 Sep 2018
Research article |
| 13 Sep 2018
| 13 Sep 2018
The role of H2SO4-NH3 anion clusters in ion-induced aerosol nucleation mechanisms in the boreal forest
Institute for Atmospheric and Earth System Research / Physics,
Faculty of Science, University of Helsinki, P. O. Box 64, 00014, Helsinki,
Finland
Lubna Dada
Institute for Atmospheric and Earth System Research / Physics,
Faculty of Science, University of Helsinki, P. O. Box 64, 00014, Helsinki,
Finland
Clémence Rose
Institute for Atmospheric and Earth System Research / Physics,
Faculty of Science, University of Helsinki, P. O. Box 64, 00014, Helsinki,
Finland
Tuija Jokinen
Institute for Atmospheric and Earth System Research / Physics,
Faculty of Science, University of Helsinki, P. O. Box 64, 00014, Helsinki,
Finland
Wei Nie
Institute for Atmospheric and Earth System Research / Physics,
Faculty of Science, University of Helsinki, P. O. Box 64, 00014, Helsinki,
Finland
Joint International Research Laboratory of Atmospheric and Earth
System Sciences, School of Atmospheric Sciences, Nanjing University,
Nanjing, 210046, China
Siegfried Schobesberger
Institute for Atmospheric and Earth System Research / Physics,
Faculty of Science, University of Helsinki, P. O. Box 64, 00014, Helsinki,
Finland
Department of Applied Physics, University of Eastern Finland, 70211
Kuopio, Finland
Heikki Junninen
Institute for Atmospheric and Earth System Research / Physics,
Faculty of Science, University of Helsinki, P. O. Box 64, 00014, Helsinki,
Finland
Institute of Physics, University of Tartu, Ülikooli 18, 50090 Tartu, Estonia
Katrianne Lehtipalo
Institute for Atmospheric and Earth System Research / Physics,
Faculty of Science, University of Helsinki, P. O. Box 64, 00014, Helsinki,
Finland
Nina Sarnela
Institute for Atmospheric and Earth System Research / Physics,
Faculty of Science, University of Helsinki, P. O. Box 64, 00014, Helsinki,
Finland
Ulla Makkonen
Finnish Meteorological Institute, 00560 Helsinki, Finland
Olga Garmash
Institute for Atmospheric and Earth System Research / Physics,
Faculty of Science, University of Helsinki, P. O. Box 64, 00014, Helsinki,
Finland
Yonghong Wang
Institute for Atmospheric and Earth System Research / Physics,
Faculty of Science, University of Helsinki, P. O. Box 64, 00014, Helsinki,
Finland
Qiaozhi Zha
Institute for Atmospheric and Earth System Research / Physics,
Faculty of Science, University of Helsinki, P. O. Box 64, 00014, Helsinki,
Finland
Pauli Paasonen
Institute for Atmospheric and Earth System Research / Physics,
Faculty of Science, University of Helsinki, P. O. Box 64, 00014, Helsinki,
Finland
Federico Bianchi
Institute for Atmospheric and Earth System Research / Physics,
Faculty of Science, University of Helsinki, P. O. Box 64, 00014, Helsinki,
Finland
Mikko Sipilä
Institute for Atmospheric and Earth System Research / Physics,
Faculty of Science, University of Helsinki, P. O. Box 64, 00014, Helsinki,
Finland
Mikael Ehn
Institute for Atmospheric and Earth System Research / Physics,
Faculty of Science, University of Helsinki, P. O. Box 64, 00014, Helsinki,
Finland
Tuukka Petäjä
Institute for Atmospheric and Earth System Research / Physics,
Faculty of Science, University of Helsinki, P. O. Box 64, 00014, Helsinki,
Finland
Joint International Research Laboratory of Atmospheric and Earth
System Sciences, School of Atmospheric Sciences, Nanjing University,
Nanjing, 210046, China
Veli-Matti Kerminen
Institute for Atmospheric and Earth System Research / Physics,
Faculty of Science, University of Helsinki, P. O. Box 64, 00014, Helsinki,
Finland
Douglas R. Worsnop
Institute for Atmospheric and Earth System Research / Physics,
Faculty of Science, University of Helsinki, P. O. Box 64, 00014, Helsinki,
Finland
Aerodyne Research, Inc., Billerica, MA 01821, USA
Markku Kulmala
Institute for Atmospheric and Earth System Research / Physics,
Faculty of Science, University of Helsinki, P. O. Box 64, 00014, Helsinki,
Finland
Joint International Research Laboratory of Atmospheric and Earth
System Sciences, School of Atmospheric Sciences, Nanjing University,
Nanjing, 210046, China
Aerosol and Haze Laboratory, Beijing Advanced Innovation Center for
Soft Matter Science and Engineering, Beijing University of Chemical
Technology, Beijing, 100029, China
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34 citations as recorded by crossref.
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- Acid–Base Clusters during Atmospheric New Particle Formation in Urban Beijing R. Yin et al. 10.1021/acs.est.1c02701
- Tropical and Boreal Forest – Atmosphere Interactions: A Review P. Artaxo et al. 10.16993/tellusb.34
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- New particle formation (NPF) events in China urban clusters given by sever composite pollution background Q. Zhang et al. 10.1016/j.chemosphere.2020.127842
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34 citations as recorded by crossref.
- Long-term measurement of sub-3 nm particles and their precursor gases in the boreal forest J. Sulo et al. 10.5194/acp-21-695-2021
- The synergistic role of sulfuric acid, ammonia and organics in particle formation over an agricultural land L. Dada et al. 10.1039/D3EA00065F
- Acid–Base Clusters during Atmospheric New Particle Formation in Urban Beijing R. Yin et al. 10.1021/acs.est.1c02701
- Tropical and Boreal Forest – Atmosphere Interactions: A Review P. Artaxo et al. 10.16993/tellusb.34
- The behaviour of charged particles (ions) during new particle formation events in urban Leipzig, Germany A. Rowell et al. 10.5194/acp-24-10349-2024
- Sources and sinks driving sulfuric acid concentrations in contrasting environments: implications on proxy calculations L. Dada et al. 10.5194/acp-20-11747-2020
- Measurement of ammonia, amines and iodine compounds using protonated water cluster chemical ionization mass spectrometry J. Pfeifer et al. 10.5194/amt-13-2501-2020
- Wintertime subarctic new particle formation from Kola Peninsula sulfur emissions M. Sipilä et al. 10.5194/acp-21-17559-2021
- Probing Anion–Molecule Complexes of Atmospheric Relevance Using Anion Photoelectron Detachment Spectroscopy C. Jarrold 10.1021/acsphyschemau.2c00060
- Atmospheric new particle formation in India: Current understanding and knowledge gaps V. Kanawade et al. 10.1016/j.atmosenv.2021.118894
- Measurement report: Increasing trend of atmospheric ion concentrations in the boreal forest J. Sulo et al. 10.5194/acp-22-15223-2022
- New particle formation in the volcanic eruption plume of the Piton de la Fournaise: specific features from a long-term dataset C. Rose et al. 10.5194/acp-19-13243-2019
- Competitive formation of HSO4- and HSO5- from ion-induced SO2 oxidation: Implication in atmospheric aerosol formation N. Tsona et al. 10.1016/j.atmosenv.2021.118362
- New particle formation (NPF) events in China urban clusters given by sever composite pollution background Q. Zhang et al. 10.1016/j.chemosphere.2020.127842
- Diurnal evolution of negative atmospheric ions above the boreal forest: from ground level to the free troposphere L. Beck et al. 10.5194/acp-22-8547-2022
- Investigation of several proxies to estimate sulfuric acid concentration under volcanic plume conditions C. Rose et al. 10.5194/acp-21-4541-2021
- Revealing the sources and sinks of negative cluster ions in an urban environment through quantitative analysis R. Yin et al. 10.5194/acp-23-5279-2023
- Theoretical study of the formation and nucleation mechanism of highly oxygenated multi-functional organic compounds produced by α-pinene X. Shi et al. 10.1016/j.scitotenv.2021.146422
- Influence of open ocean biogeochemistry on aerosol and clouds: Recent findings and perspectives K. Sellegri et al. 10.1525/elementa.2023.00058
- New particle formation from sulfuric acid and ammonia: nucleation and growth model based on thermodynamics derived from CLOUD measurements for a wide range of conditions A. Kürten 10.5194/acp-19-5033-2019
- Chemical precursors of new particle formation in coastal New Zealand M. Peltola et al. 10.5194/acp-23-3955-2023
- The effect of meteorological conditions and atmospheric composition in the occurrence and development of new particle formation (NPF) events in Europe D. Bousiotis et al. 10.5194/acp-21-3345-2021
- The neglected autoxidation pathways for the formation of highly oxygenated organic molecules (HOMs) and the nucleation of the HOMs generated by limonene S. Wang et al. 10.1016/j.atmosenv.2023.119727
- How the understanding of atmospheric new particle formation has evolved along with the development of measurement and analysis methods K. Lehtipalo et al. 10.1016/j.jaerosci.2024.106494
- Source apportionment of particle number size distribution in urban background and traffic stations in four European cities I. Rivas et al. 10.1016/j.envint.2019.105345
- Measurement report: Molecular-level investigation of atmospheric cluster ions at the tropical high-altitude research station Chacaltaya (5240 m a.s.l.) in the Bolivian Andes Q. Zha et al. 10.5194/acp-23-4559-2023
- A potential source of atmospheric sulfate from O<sub>2</sub><sup>−</sup>-induced SO<sub>2</sub> oxidation by ozone N. Tsona & L. Du 10.5194/acp-19-649-2019
- Atmospheric new particle formation from the CERN CLOUD experiment J. Kirkby et al. 10.1038/s41561-023-01305-0
- Heatwave reveals potential for enhanced aerosol formation in Siberian boreal forest O. Garmash et al. 10.1088/1748-9326/ad10d5
- Investigation of new particle formation mechanisms and aerosol processes at Marambio Station, Antarctic Peninsula L. Quéléver et al. 10.5194/acp-22-8417-2022
- Molecular insights into new particle formation in Barcelona, Spain J. Brean et al. 10.5194/acp-20-10029-2020
- On the existence of CO32− microsolvated clusters: a theoretical study P. Rublev et al. 10.1039/D3CP00955F
- Identification of molecular cluster evaporation rates, cluster formation enthalpies and entropies by Monte Carlo method A. Shcherbacheva et al. 10.5194/acp-20-15867-2020
- The annual cycle and sources of relevant aerosol precursor vapors in the central Arctic during the MOSAiC expedition M. Boyer et al. 10.5194/acp-24-12595-2024
Latest update: 25 Dec 2024
Short summary
Ions can play an important role in atmospheric new particle formation by stabilizing the embryonic clusters. Such a process is called ion-induced nucleation (IIN). We found two distinct IIN mechanisms – driven by H2SO4-NH3 clusters and by organic vapors, respectively. The concentration ratio of organic vapors to H2SO4 regulates via which pathway the IIN occur. As the organic vapor concentration is influenced by temperature, a seasonal variation in the main IIN mechanism can be expected.
Ions can play an important role in atmospheric new particle formation by stabilizing the...
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