Articles | Volume 17, issue 13
https://doi.org/10.5194/acp-17-8357-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-17-8357-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
10 Jul 2017
Research article |
| 10 Jul 2017
Comprehensive atmospheric modeling of reactive cyclic siloxanes and their oxidation products
Nathan J. Janechek
Department of Chemical and Biochemical Engineering, University of Iowa, Iowa City, IA 52242, USA
IIHR Hydroscience and Engineering, University of Iowa, Iowa City, IA 52242, USA
Kaj M. Hansen
Department of Environmental Science, Aarhus University, Roskilde, Denmark
Charles O. Stanier
CORRESPONDING AUTHOR
Department of Chemical and Biochemical Engineering, University of Iowa, Iowa City, IA 52242, USA
IIHR Hydroscience and Engineering, University of Iowa, Iowa City, IA 52242, USA
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Cited
37 citations as recorded by crossref.
- Characterizing the regional concentrations and seasonality of the emerging pollutant decamethylcyclopentasiloxane (D5) using a WRF+CHIMERE modeling approach P. Jiménez-Guerrero & N. Ratola 10.1525/elementa.2020.00137
- Quantifying ambient concentration and emission profile of D5-siloxane of a residential neighborhood in the Greater Houston area K. McCary et al. 10.1039/D4EM00804A
- Atmospheric Concentrations of New Persistent Organic Pollutants and Emerging Chemicals of Concern in the Group of Latin America and Caribbean (GRULAC) Region C. Rauert et al. 10.1021/acs.est.8b00995
- Analysis of indoor particles and gases and their evolution with natural ventilation C. Fortenberry et al. 10.1111/ina.12584
- Secondary organic aerosol formation from the oxidation of decamethylcyclopentasiloxane at atmospherically relevant OH concentrations S. Charan et al. 10.5194/acp-22-917-2022
- Rate coefficients for the gas‐phase reaction of OH radicals with the L4, L5, D5, and D6 permethylsiloxanes F. Bernard & J. Burkholder 10.1002/kin.21769
- Identifying Volatile Chemical Product Tracer Compounds in U.S. Cities G. Gkatzelis et al. 10.1021/acs.est.0c05467
- Atmospheric Degradation of Cyclic Volatile Methyl Siloxanes: Radical Chemistry and Oxidation Products M. Alton & E. Browne 10.1021/acsenvironau.1c00043
- Comparison of the Yield and Chemical Composition of Secondary Organic Aerosol Generated from the OH and Cl Oxidation of Decamethylcyclopentasiloxane A. Avery et al. 10.1021/acsearthspacechem.2c00304
- Detection of a secondary organic aerosol tracer derived from personal care products A. Milani et al. 10.1016/j.atmosenv.2020.118078
- Lung cell exposure to secondary photochemical aerosols generated from OH oxidation of cyclic siloxanes B. King et al. 10.1016/j.chemosphere.2019.125126
- Cyclic volatile methyl siloxanes (D4, D5, and D6) as the emerging pollutants in environment: environmental distribution, fate, and toxicological assessments K. Kumari et al. 10.1007/s11356-023-25568-7
- Advances in the Separation and Detection of Secondary Organic Aerosol Produced by Decamethylcyclopentasiloxane (D5) in Laboratory-Generated and Ambient Aerosol J. Meepage et al. 10.1021/acsestair.3c00073
- Identification of organosiloxanes in ambient fine particulate matters using an untargeted strategy via gas chromatography and time-of-flight mass spectrometry Z. Cheng et al. 10.1016/j.envpol.2020.116128
- Application of multimedia models for understanding the environmental behavior of volatile methylsiloxanes: Fate, transport, and bioaccumulation M. Whelan & J. Kim 10.1002/ieam.4507
- Modeling secondary organic aerosol formation from volatile chemical products E. Pennington et al. 10.5194/acp-21-18247-2021
- Long-range transport potential and atmospheric persistence of cyclic volatile methylsiloxanes based on global measurements S. Xu et al. 10.1016/j.chemosphere.2019.04.130
- Simplified speciation and atmospheric volatile organic compound emission rates from non‐aerosol personal care products A. Yeoman et al. 10.1111/ina.12652
- Auto-Oxidation of a Volatile Silicon Compound: A Theoretical Study of the Atmospheric Chemistry of Tetramethylsilane Z. Ren & G. da Silva 10.1021/acs.jpca.0c02922
- Indoor Emission, Oxidation, and New Particle Formation of Personal Care Product Related Volatile Organic Compounds T. Wu et al. 10.1021/acs.estlett.4c00353
- Unraveling the role of silicon in atmospheric aerosol secondary formation: a new conservative tracer for aerosol chemistry D. Lu et al. 10.5194/acp-19-2861-2019
- PM2.5-bound silicon-containing secondary organic aerosols (Si-SOA) in Beijing ambient air J. Xu et al. 10.1016/j.chemosphere.2021.132377
- A review of contamination status, emission sources, and human exposure to volatile methyl siloxanes (VMSs) in indoor environments T. Tran et al. 10.1016/j.scitotenv.2019.07.168
- Temperature Dependent Rate Coefficients for the Gas-Phase Reaction of the OH Radical with Linear (L2, L3) and Cyclic (D3, D4) Permethylsiloxanes F. Bernard et al. 10.1021/acs.jpca.8b01908
- Reactive organic carbon emissions from volatile chemical products K. Seltzer et al. 10.5194/acp-21-5079-2021
- Secondary organic aerosols from OH oxidation of cyclic volatile methyl siloxanes as an important Si source in the atmosphere C. Han et al. 10.5194/acp-22-10827-2022
- Diurnal Variability and Emission Pattern of Decamethylcyclopentasiloxane (D5) from the Application of Personal Care Products in Two North American Cities M. Coggon et al. 10.1021/acs.est.8b00506
- Atmospheric Chemistry of Volatile Methyl Siloxanes: Kinetics and Products of Oxidation by OH Radicals and Cl Atoms M. Alton & E. Browne 10.1021/acs.est.0c01368
- Mobile measurements of atmospheric decamethylcyclopentasiloxane (D5) in Eastern China H. Yu et al. 10.1016/j.atmosenv.2024.121001
- Distribution of cyclic volatile methylsiloxanes in drinking water, tap water, surface water, and wastewater in Hanoi, Vietnam H. Nu Nguyen et al. 10.1016/j.envpol.2021.117260
- Assessment of distributional characteristics and ecological risks of cyclic volatile methylsiloxanes in sediments from urban rivers in northern Vietnam H. Nguyen et al. 10.1007/s11356-021-18487-y
- Concentrations of Volatile Methyl Siloxanes in New York City Reflect Emissions from Personal Care and Industrial Use C. Brunet et al. 10.1021/acs.est.3c10752
- Physical properties of secondary photochemical aerosol from OH oxidation of a cyclic siloxane N. Janechek et al. 10.5194/acp-19-1649-2019
- Volatile Methyl Siloxanes and Other Organosilicon Compounds in Residential Air B. Molinier et al. 10.1021/acs.est.2c05438
- Comprehensive atmospheric modeling of reactive cyclic siloxanes and their oxidation products N. Janechek et al. 10.5194/acp-17-8357-2017
- Aerosol Formation from OH Oxidation of the Volatile Cyclic Methyl Siloxane (cVMS) Decamethylcyclopentasiloxane Y. Wu & M. Johnston 10.1021/acs.est.7b00655
- Concentrations of Volatile Methyl Siloxanes in New York City Reflect Emissions from Personal Care and Industrial Use C. Brunet et al. 10.1021/acs.est.3c10752
34 citations as recorded by crossref.
- Characterizing the regional concentrations and seasonality of the emerging pollutant decamethylcyclopentasiloxane (D5) using a WRF+CHIMERE modeling approach P. Jiménez-Guerrero & N. Ratola 10.1525/elementa.2020.00137
- Quantifying ambient concentration and emission profile of D5-siloxane of a residential neighborhood in the Greater Houston area K. McCary et al. 10.1039/D4EM00804A
- Atmospheric Concentrations of New Persistent Organic Pollutants and Emerging Chemicals of Concern in the Group of Latin America and Caribbean (GRULAC) Region C. Rauert et al. 10.1021/acs.est.8b00995
- Analysis of indoor particles and gases and their evolution with natural ventilation C. Fortenberry et al. 10.1111/ina.12584
- Secondary organic aerosol formation from the oxidation of decamethylcyclopentasiloxane at atmospherically relevant OH concentrations S. Charan et al. 10.5194/acp-22-917-2022
- Rate coefficients for the gas‐phase reaction of OH radicals with the L4, L5, D5, and D6 permethylsiloxanes F. Bernard & J. Burkholder 10.1002/kin.21769
- Identifying Volatile Chemical Product Tracer Compounds in U.S. Cities G. Gkatzelis et al. 10.1021/acs.est.0c05467
- Atmospheric Degradation of Cyclic Volatile Methyl Siloxanes: Radical Chemistry and Oxidation Products M. Alton & E. Browne 10.1021/acsenvironau.1c00043
- Comparison of the Yield and Chemical Composition of Secondary Organic Aerosol Generated from the OH and Cl Oxidation of Decamethylcyclopentasiloxane A. Avery et al. 10.1021/acsearthspacechem.2c00304
- Detection of a secondary organic aerosol tracer derived from personal care products A. Milani et al. 10.1016/j.atmosenv.2020.118078
- Lung cell exposure to secondary photochemical aerosols generated from OH oxidation of cyclic siloxanes B. King et al. 10.1016/j.chemosphere.2019.125126
- Cyclic volatile methyl siloxanes (D4, D5, and D6) as the emerging pollutants in environment: environmental distribution, fate, and toxicological assessments K. Kumari et al. 10.1007/s11356-023-25568-7
- Advances in the Separation and Detection of Secondary Organic Aerosol Produced by Decamethylcyclopentasiloxane (D5) in Laboratory-Generated and Ambient Aerosol J. Meepage et al. 10.1021/acsestair.3c00073
- Identification of organosiloxanes in ambient fine particulate matters using an untargeted strategy via gas chromatography and time-of-flight mass spectrometry Z. Cheng et al. 10.1016/j.envpol.2020.116128
- Application of multimedia models for understanding the environmental behavior of volatile methylsiloxanes: Fate, transport, and bioaccumulation M. Whelan & J. Kim 10.1002/ieam.4507
- Modeling secondary organic aerosol formation from volatile chemical products E. Pennington et al. 10.5194/acp-21-18247-2021
- Long-range transport potential and atmospheric persistence of cyclic volatile methylsiloxanes based on global measurements S. Xu et al. 10.1016/j.chemosphere.2019.04.130
- Simplified speciation and atmospheric volatile organic compound emission rates from non‐aerosol personal care products A. Yeoman et al. 10.1111/ina.12652
- Auto-Oxidation of a Volatile Silicon Compound: A Theoretical Study of the Atmospheric Chemistry of Tetramethylsilane Z. Ren & G. da Silva 10.1021/acs.jpca.0c02922
- Indoor Emission, Oxidation, and New Particle Formation of Personal Care Product Related Volatile Organic Compounds T. Wu et al. 10.1021/acs.estlett.4c00353
- Unraveling the role of silicon in atmospheric aerosol secondary formation: a new conservative tracer for aerosol chemistry D. Lu et al. 10.5194/acp-19-2861-2019
- PM2.5-bound silicon-containing secondary organic aerosols (Si-SOA) in Beijing ambient air J. Xu et al. 10.1016/j.chemosphere.2021.132377
- A review of contamination status, emission sources, and human exposure to volatile methyl siloxanes (VMSs) in indoor environments T. Tran et al. 10.1016/j.scitotenv.2019.07.168
- Temperature Dependent Rate Coefficients for the Gas-Phase Reaction of the OH Radical with Linear (L2, L3) and Cyclic (D3, D4) Permethylsiloxanes F. Bernard et al. 10.1021/acs.jpca.8b01908
- Reactive organic carbon emissions from volatile chemical products K. Seltzer et al. 10.5194/acp-21-5079-2021
- Secondary organic aerosols from OH oxidation of cyclic volatile methyl siloxanes as an important Si source in the atmosphere C. Han et al. 10.5194/acp-22-10827-2022
- Diurnal Variability and Emission Pattern of Decamethylcyclopentasiloxane (D5) from the Application of Personal Care Products in Two North American Cities M. Coggon et al. 10.1021/acs.est.8b00506
- Atmospheric Chemistry of Volatile Methyl Siloxanes: Kinetics and Products of Oxidation by OH Radicals and Cl Atoms M. Alton & E. Browne 10.1021/acs.est.0c01368
- Mobile measurements of atmospheric decamethylcyclopentasiloxane (D5) in Eastern China H. Yu et al. 10.1016/j.atmosenv.2024.121001
- Distribution of cyclic volatile methylsiloxanes in drinking water, tap water, surface water, and wastewater in Hanoi, Vietnam H. Nu Nguyen et al. 10.1016/j.envpol.2021.117260
- Assessment of distributional characteristics and ecological risks of cyclic volatile methylsiloxanes in sediments from urban rivers in northern Vietnam H. Nguyen et al. 10.1007/s11356-021-18487-y
- Concentrations of Volatile Methyl Siloxanes in New York City Reflect Emissions from Personal Care and Industrial Use C. Brunet et al. 10.1021/acs.est.3c10752
- Physical properties of secondary photochemical aerosol from OH oxidation of a cyclic siloxane N. Janechek et al. 10.5194/acp-19-1649-2019
- Volatile Methyl Siloxanes and Other Organosilicon Compounds in Residential Air B. Molinier et al. 10.1021/acs.est.2c05438
3 citations as recorded by crossref.
- Comprehensive atmospheric modeling of reactive cyclic siloxanes and their oxidation products N. Janechek et al. 10.5194/acp-17-8357-2017
- Aerosol Formation from OH Oxidation of the Volatile Cyclic Methyl Siloxane (cVMS) Decamethylcyclopentasiloxane Y. Wu & M. Johnston 10.1021/acs.est.7b00655
- Concentrations of Volatile Methyl Siloxanes in New York City Reflect Emissions from Personal Care and Industrial Use C. Brunet et al. 10.1021/acs.est.3c10752
Latest update: 17 May 2025
Short summary
Gas-phase cyclic volatile methyl siloxanes and their oxidation products, which are likely precursors to secondary organic aerosol, were modeled using an atmospheric transport model over North America. Typical concentrations, spatial patterns, seasonal variability, and vertical profiles were quantified. Urban parent compound concentrations were sensitive to transport factors, while rural parent and oxidized product concentrations were sensitive to large-scale seasonal variability in OH.
Gas-phase cyclic volatile methyl siloxanes and their oxidation products, which are likely...
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