Atmospheric Chemistry and Physics
Atmospheric Chemistry and Physics
ACP
Articles | Volume 17, issue 13
Articles | Volume 17, issue 13
https://doi.org/10.5194/acp-17-8357-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-17-8357-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.
Articles | Volume 17, issue 13
Research article
 | 
10 Jul 2017
Research article |  | 10 Jul 2017

Comprehensive atmospheric modeling of reactive cyclic siloxanes and their oxidation products

Nathan J. Janechek, Kaj M. Hansen, and Charles O. Stanier

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Short summary
Gas-phase cyclic volatile methyl siloxanes and their oxidation products, which are likely precursors to secondary organic aerosol, were modeled using an atmospheric transport model over North America. Typical concentrations, spatial patterns, seasonal variability, and vertical profiles were quantified. Urban parent compound concentrations were sensitive to transport factors, while rural parent and oxidized product concentrations were sensitive to large-scale seasonal variability in OH.
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