Articles | Volume 17, issue 12
https://doi.org/10.5194/acp-17-7807-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-17-7807-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Estimating the atmospheric concentration of Criegee intermediates and their possible interference in a FAGE-LIF instrument
Anna Novelli
Atmospheric Chemistry Department, Max Planck Institute
for Chemistry, 55128 Mainz, Germany
now at: Institute of Energy and Climate Research, IEK-8:
Troposphere, Forschungszentrum Jülich GmbH, 52428 Jülich,
Germany
Korbinian Hens
Atmospheric Chemistry Department, Max Planck Institute
for Chemistry, 55128 Mainz, Germany
Cheryl Tatum Ernest
Atmospheric Chemistry Department, Max Planck Institute
for Chemistry, 55128 Mainz, Germany
now at: Department of Neurology University Medical Center
of the Johannes Gutenberg University Mainz, 55131 Mainz, Germany
Monica Martinez
Atmospheric Chemistry Department, Max Planck Institute
for Chemistry, 55128 Mainz, Germany
Anke C. Nölscher
Atmospheric Chemistry Department, Max Planck Institute
for Chemistry, 55128 Mainz, Germany
now at: Division of Geological and Planetary Sciences,
California Institute of Technology, Pasadena, USA
Vinayak Sinha
Department of Earth and Environmental Sciences, Indian
Institute of Science Education and Research Mohali, Sector 81 S.A.S. Nagar,
Manauli PO, Mohali 140 306, Punjab, India
Pauli Paasonen
Department of Physics., P.O. Box 64. 00014 University of
Helsinki, Helsinki, Finland
Tuukka Petäjä
Department of Physics., P.O. Box 64. 00014 University of
Helsinki, Helsinki, Finland
Mikko Sipilä
Department of Physics., P.O. Box 64. 00014 University of
Helsinki, Helsinki, Finland
Thomas Elste
German Meteorological Service, Meteorological Observatory
Hohenpeissenberg (MOHp), 83282 Hohenpeissenberg, Germany
Christian Plass-Dülmer
German Meteorological Service, Meteorological Observatory
Hohenpeissenberg (MOHp), 83282 Hohenpeissenberg, Germany
Gavin J. Phillips
Atmospheric Chemistry Department, Max Planck Institute
for Chemistry, 55128 Mainz, Germany
Department of Natural Sciences, University of Chester,
Thornton Science Park, Chester, CH2 4NU, UK
Dagmar Kubistin
Atmospheric Chemistry Department, Max Planck Institute
for Chemistry, 55128 Mainz, Germany
German Meteorological Service, Meteorological Observatory
Hohenpeissenberg (MOHp), 83282 Hohenpeissenberg, Germany
University of Wollongong, School of Chemistry,
Wollongong, Australia
Jonathan Williams
Atmospheric Chemistry Department, Max Planck Institute
for Chemistry, 55128 Mainz, Germany
Luc Vereecken
Atmospheric Chemistry Department, Max Planck Institute
for Chemistry, 55128 Mainz, Germany
now at: Institute of Energy and Climate Research, IEK-8:
Troposphere, Forschungszentrum Jülich GmbH, 52428 Jülich,
Germany
Jos Lelieveld
Atmospheric Chemistry Department, Max Planck Institute
for Chemistry, 55128 Mainz, Germany
Atmospheric Chemistry Department, Max Planck Institute
for Chemistry, 55128 Mainz, Germany
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79 citations as recorded by crossref.
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- Temperature-Dependent Kinetics of the Reactions of the Criegee Intermediate CH2OO with Aliphatic Aldehydes J. Enders et al. 10.1021/acs.jpca.4c04990
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- Temperature-Dependent Kinetics of the Reactions of the Criegee Intermediate CH2OO with Hydroxyketones Z. Cornwell et al. 10.1021/acs.jpca.4c00156
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- Kinetics for the reaction of Criegee intermediate CH2OO with n-butyraldehyde and its atmospheric implications S. Liu et al. 10.1016/j.atmosenv.2023.120012
- Direct kinetic measurements and theoretical predictions of an isoprene-derived Criegee intermediate R. Caravan et al. 10.1073/pnas.1916711117
- Investigation of kinetics and mechanistic insights of the reaction of criegee intermediate (CH2OO) with methyl-ethyl ketone (MEK) under tropospherically relevant conditions A. Debnath & B. Rajakumar 10.1016/j.chemosphere.2022.137217
- OH, HO2, and RO2 radical chemistry in a rural forest environment: measurements, model comparisons, and evidence of a missing radical sink B. Bottorff et al. 10.5194/acp-23-10287-2023
- Temperature-Dependent Rate Coefficient for the Reaction of CH3SH with the Simplest Criegee Intermediate Y. Li et al. 10.1021/acs.jpca.8b12553
- Measurements of a potential interference with laser-induced fluorescence measurements of ambient OH from the ozonolysis of biogenic alkenes P. Rickly & P. Stevens 10.5194/amt-11-1-2018
- Comparison of temperature-dependent calibration methods of an instrument to measure OH and HO2 radicals using laser-induced fluorescence spectroscopy F. Winiberg et al. 10.5194/amt-16-4375-2023
- Formation of alkoxymethyl hydroperoxides and alkyl formates from simplest Criegee intermediate (CH2OO) + ROH (R=CH3, CH3CH2, and (CH3)2CH) reaction systems M. Dash et al. 10.1007/s00214-024-03104-1
- Surprisingly long lifetime of methacrolein oxide, an isoprene derived Criegee intermediate, under humid conditions Y. Lin et al. 10.1038/s42004-021-00451-z
- Impacts of the Degradation of 2,3,3,3-Tetrafluoropropene into Trifluoroacetic Acid from Its Application in Automobile Air Conditioners in China, the United States, and Europe Z. Wang et al. 10.1021/acs.est.7b05960
- Kinetics of the gas phase reaction of the Criegee intermediate CH2OO with SO2as a function of temperature L. Onel et al. 10.1039/D1CP02932K
- OH and HO<sub>2</sub> radical chemistry at a suburban site during the EXPLORE-YRD campaign in 2018 X. Ma et al. 10.5194/acp-22-7005-2022
- Criegee Intermediate–Alcohol Reactions, A Potential Source of Functionalized Hydroperoxides in the Atmosphere M. McGillen et al. 10.1021/acsearthspacechem.7b00108
- Atmospheric Kinetics: Bimolecular Reactions of Carbonyl Oxide by a Triple-Level Strategy B. Long et al. 10.1021/jacs.1c02029
- Experimental and theoretical study of Criegee intermediate (CH2OO) reactions with n-butyraldehyde and isobutyraldehyde: kinetics, implications and atmospheric fate A. Debnath & B. Rajakumar 10.1039/D3CP05482A
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4 citations as recorded by crossref.
- Detection and identification of Criegee intermediates from the ozonolysis of biogenic and anthropogenic VOCs: comparison between experimental measurements and theoretical calculations C. Giorio et al. 10.1039/C7FD00025A
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- OH production from the photolysis of isoprene-derived peroxy radicals: cross-sections, quantum yields and atmospheric implications R. Hansen et al. 10.1039/C6CP06718B
Latest update: 25 Dec 2024
Short summary
The ambient concentration of stabilised Criegee intermediates (SCIs) was estimated for two
environments using field data. The low concentrations predicted indicate that SCIs are
unlikely to have a large impact on atmospheric chemistry. Concurrent measurements of an OH background signal using the Mainz IPI-LIF-FAGE instrument were found to be consistent with the chemistry of SCIs during the measurement campaigns.
The ambient concentration of stabilised Criegee intermediates (SCIs) was estimated for two...
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