Articles | Volume 17, issue 2
https://doi.org/10.5194/acp-17-1453-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-17-1453-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
31 Jan 2017
Research article |
| 31 Jan 2017
Real-time detection of highly oxidized organosulfates and BSOA marker compounds during the F-BEACh 2014 field study
Martin Brüggemann
Institute of Inorganic and Analytical Chemistry, University of Mainz, Duesbergweg 10–14, 55128 Mainz, Germany
Max Planck Graduate Center, Staudinger Weg 9, 55128 Mainz, Germany
now at: CNRS – UMR5256, IRCELYON, Institut de Recherches sur la Catalyse et l'Environnement de Lyon, 69626 Villeurbanne, France
Laurent Poulain
Leibniz-Institut für Troposphärenforschung (TROPOS), Permoserstr. 15, 04318 Leipzig, Germany
Andreas Held
University of Bayreuth, Atmospheric Chemistry, Dr.-Hans-Frisch-Straße 1–3, 95448 Bayreuth, Germany
Torsten Stelzer
Institute of Inorganic and Analytical Chemistry, University of Mainz, Duesbergweg 10–14, 55128 Mainz, Germany
Christoph Zuth
Institute of Inorganic and Analytical Chemistry, University of Mainz, Duesbergweg 10–14, 55128 Mainz, Germany
Stefanie Richters
Leibniz-Institut für Troposphärenforschung (TROPOS), Permoserstr. 15, 04318 Leipzig, Germany
Anke Mutzel
Leibniz-Institut für Troposphärenforschung (TROPOS), Permoserstr. 15, 04318 Leipzig, Germany
Dominik van Pinxteren
Leibniz-Institut für Troposphärenforschung (TROPOS), Permoserstr. 15, 04318 Leipzig, Germany
Yoshiteru Iinuma
Leibniz-Institut für Troposphärenforschung (TROPOS), Permoserstr. 15, 04318 Leipzig, Germany
Sarmite Katkevica
University of Bayreuth, Atmospheric Chemistry, Dr.-Hans-Frisch-Straße 1–3, 95448 Bayreuth, Germany
René Rabe
Leibniz-Institut für Troposphärenforschung (TROPOS), Permoserstr. 15, 04318 Leipzig, Germany
Hartmut Herrmann
Leibniz-Institut für Troposphärenforschung (TROPOS), Permoserstr. 15, 04318 Leipzig, Germany
Thorsten Hoffmann
CORRESPONDING AUTHOR
Institute of Inorganic and Analytical Chemistry, University of Mainz, Duesbergweg 10–14, 55128 Mainz, Germany
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Cited
36 citations as recorded by crossref.
- Quantification of known and unknown terpenoid organosulfates in PM10 using untargeted LC–HRMS/MS: contrasting summertime rural Germany and the North China Plain M. Brüggemann et al. 10.1071/EN19089
- OH Group Orientation Leads to Organosulfate Formation at the Liquid Aerosol Surface S. Tan et al. 10.1021/jacs.2c05807
- Impact of biogenic secondary organic aerosol (SOA) loading on the molecular composition of wintertime PM2.5 in urban Tianjin: an insight from Fourier transform ion cyclotron resonance mass spectrometry S. Zhong et al. 10.5194/acp-23-2061-2023
- Urban organic aerosol composition in eastern China differs from north to south: molecular insight from a liquid chromatography–mass spectrometry (Orbitrap) study K. Wang et al. 10.5194/acp-21-9089-2021
- Organosulfate produced from consumption of SO3 speeds up sulfuric acid–dimethylamine atmospheric nucleation X. Zhang et al. 10.5194/acp-24-3593-2024
- Formation of Organosulfur Compounds from Aqueous Phase Reactions of S(IV) with Methacrolein and Methyl Vinyl Ketone in the Presence of Transition Metal Ions L. Huang et al. 10.1021/acsearthspacechem.9b00173
- The secondary formation of organosulfates under interactions between biogenic emissions and anthropogenic pollutants in summer in Beijing Y. Wang et al. 10.5194/acp-18-10693-2018
- Chemical Characteristics of Organic Aerosols in Shanghai: A Study by Ultrahigh‐Performance Liquid Chromatography Coupled With Orbitrap Mass Spectrometry X. Wang et al. 10.1002/2017JD026930
- Molecular characterization of atmospheric particulate organosulfates in a port environment using ultrahigh resolution mass spectrometry: Identification of traffic emissions L. Qi et al. 10.1016/j.jhazmat.2021.126431
- Seasonal Contribution of Isoprene-Derived Organosulfates to Total Water-Soluble Fine Particulate Organic Sulfur in the United States Y. Chen et al. 10.1021/acsearthspacechem.1c00102
- Gas phase transformation from organic acid to organic sulfuric anhydride: Possibility and atmospheric fate in the initial new particle formation H. Zhang et al. 10.1016/j.chemosphere.2018.08.074
- Quality assurance and quality control of atmospheric organosulfates measured using hydrophilic interaction liquid chromatography (HILIC) P. Liu et al. 10.5194/amt-17-3067-2024
- Experimental Study of the Formation of Organosulfates from α-Pinene Oxidation. 2. Time Evolution and Effect of Particle Acidity G. Duporté et al. 10.1021/acs.jpca.9b07156
- Recent advances in mass spectrometry techniques for atmospheric chemistry research on molecular‐level W. Zhang et al. 10.1002/mas.21857
- Application of time-of-flight aerosol mass spectrometry for the real-time measurement of particle-phase organic peroxides: an online redox derivatization–aerosol mass spectrometer (ORD-AMS) M. Weloe & T. Hoffmann 10.5194/amt-13-5725-2020
- Relative Humidity Changes the Role of SO2 in Biogenic Secondary Organic Aerosol Formation L. Xu et al. 10.1021/acs.jpclett.1c01550
- Highly Oxygenated Organic Molecules (HOM) from Gas-Phase Autoxidation Involving Peroxy Radicals: A Key Contributor to Atmospheric Aerosol F. Bianchi et al. 10.1021/acs.chemrev.8b00395
- Analytical methods for organosulfate detection in aerosol particles: Current status and future perspectives K. Gao & T. Zhu 10.1016/j.scitotenv.2021.147244
- Evaluating the mutagenic potential of aerosol organic compounds using informatics-based screening S. Decesari et al. 10.5194/acp-18-2329-2018
- Atmospheric “HULIS” in Different Environments: Polarities, Molecular Sizes, and Sources Suggest More Than 50% Are Not “Humic-like” T. Spranger et al. 10.1021/acsearthspacechem.9b00299
- Production of Atmospheric Organosulfates via Mineral-Mediated Photochemistry M. Schmidt et al. 10.1021/acsearthspacechem.8b00178
- Radical Formation by Fine Particulate Matter Associated with Highly Oxygenated Molecules H. Tong et al. 10.1021/acs.est.9b05149
- Temperature and acidity dependence of secondary organic aerosol formation from <i>α</i>-pinene ozonolysis with a compact chamber system Y. Deng et al. 10.5194/acp-21-5983-2021
- An extractive electrospray ionization time-of-flight mass spectrometer (EESI-TOF) for online measurement of atmospheric aerosol particles F. Lopez-Hilfiker et al. 10.5194/amt-12-4867-2019
- A review of secondary organic aerosols formation focusing on organosulfates and organic nitrates W. Fan et al. 10.1016/j.jhazmat.2022.128406
- Molecular composition of fresh and aged aerosols from residential wood combustion and gasoline car with modern emission mitigation technology E. Schneider et al. 10.1039/D4EM00106K
- Organic Peroxides in Aerosol: Key Reactive Intermediates for Multiphase Processes in the Atmosphere S. Wang et al. 10.1021/acs.chemrev.2c00430
- Mass Spectrometry Analysis in Atmospheric Chemistry J. Laskin et al. 10.1021/acs.analchem.7b04249
- Exploring Volatility Properties of Discrete Secondary Organic Aerosol Constituents of α-Pinene and Polycyclic Aromatic Hydrocarbons Z. Babar et al. 10.1021/acsearthspacechem.0c00210
- Organosulfates in atmospheric aerosols in Shanghai, China: seasonal and interannual variability, origin, and formation mechanisms Y. Wang et al. 10.5194/acp-21-2959-2021
- Molecular Characterization and Source Identification of Atmospheric Particulate Organosulfates Using Ultrahigh Resolution Mass Spectrometry K. Wang et al. 10.1021/acs.est.9b02628
- Organosulfates in Ambient Aerosol: State of Knowledge and Future Research Directions on Formation, Abundance, Fate, and Importance M. Brüggemann et al. 10.1021/acs.est.9b06751
- Abundance of organosulfates derived from biogenic volatile organic compounds: Seasonal and spatial contrasts at four sites in China Y. Wang et al. 10.1016/j.scitotenv.2021.151275
- Beyond the formation: unveiling the atmospheric transformation of organosulfatesviaheterogeneous OH oxidation S. Ng & M. Chan 10.1039/D3CC03700B
- Molecular characterization of ultrafine particles using extractive electrospray time-of-flight mass spectrometry M. Surdu et al. 10.1039/D1EA00050K
- Ultrahigh-Resolution Mass Spectrometry in Real Time: Atmospheric Pressure Chemical Ionization Orbitrap Mass Spectrometry of Atmospheric Organic Aerosol C. Zuth et al. 10.1021/acs.analchem.8b00671
35 citations as recorded by crossref.
- Quantification of known and unknown terpenoid organosulfates in PM10 using untargeted LC–HRMS/MS: contrasting summertime rural Germany and the North China Plain M. Brüggemann et al. 10.1071/EN19089
- OH Group Orientation Leads to Organosulfate Formation at the Liquid Aerosol Surface S. Tan et al. 10.1021/jacs.2c05807
- Impact of biogenic secondary organic aerosol (SOA) loading on the molecular composition of wintertime PM2.5 in urban Tianjin: an insight from Fourier transform ion cyclotron resonance mass spectrometry S. Zhong et al. 10.5194/acp-23-2061-2023
- Urban organic aerosol composition in eastern China differs from north to south: molecular insight from a liquid chromatography–mass spectrometry (Orbitrap) study K. Wang et al. 10.5194/acp-21-9089-2021
- Organosulfate produced from consumption of SO3 speeds up sulfuric acid–dimethylamine atmospheric nucleation X. Zhang et al. 10.5194/acp-24-3593-2024
- Formation of Organosulfur Compounds from Aqueous Phase Reactions of S(IV) with Methacrolein and Methyl Vinyl Ketone in the Presence of Transition Metal Ions L. Huang et al. 10.1021/acsearthspacechem.9b00173
- The secondary formation of organosulfates under interactions between biogenic emissions and anthropogenic pollutants in summer in Beijing Y. Wang et al. 10.5194/acp-18-10693-2018
- Chemical Characteristics of Organic Aerosols in Shanghai: A Study by Ultrahigh‐Performance Liquid Chromatography Coupled With Orbitrap Mass Spectrometry X. Wang et al. 10.1002/2017JD026930
- Molecular characterization of atmospheric particulate organosulfates in a port environment using ultrahigh resolution mass spectrometry: Identification of traffic emissions L. Qi et al. 10.1016/j.jhazmat.2021.126431
- Seasonal Contribution of Isoprene-Derived Organosulfates to Total Water-Soluble Fine Particulate Organic Sulfur in the United States Y. Chen et al. 10.1021/acsearthspacechem.1c00102
- Gas phase transformation from organic acid to organic sulfuric anhydride: Possibility and atmospheric fate in the initial new particle formation H. Zhang et al. 10.1016/j.chemosphere.2018.08.074
- Quality assurance and quality control of atmospheric organosulfates measured using hydrophilic interaction liquid chromatography (HILIC) P. Liu et al. 10.5194/amt-17-3067-2024
- Experimental Study of the Formation of Organosulfates from α-Pinene Oxidation. 2. Time Evolution and Effect of Particle Acidity G. Duporté et al. 10.1021/acs.jpca.9b07156
- Recent advances in mass spectrometry techniques for atmospheric chemistry research on molecular‐level W. Zhang et al. 10.1002/mas.21857
- Application of time-of-flight aerosol mass spectrometry for the real-time measurement of particle-phase organic peroxides: an online redox derivatization–aerosol mass spectrometer (ORD-AMS) M. Weloe & T. Hoffmann 10.5194/amt-13-5725-2020
- Relative Humidity Changes the Role of SO2 in Biogenic Secondary Organic Aerosol Formation L. Xu et al. 10.1021/acs.jpclett.1c01550
- Highly Oxygenated Organic Molecules (HOM) from Gas-Phase Autoxidation Involving Peroxy Radicals: A Key Contributor to Atmospheric Aerosol F. Bianchi et al. 10.1021/acs.chemrev.8b00395
- Analytical methods for organosulfate detection in aerosol particles: Current status and future perspectives K. Gao & T. Zhu 10.1016/j.scitotenv.2021.147244
- Evaluating the mutagenic potential of aerosol organic compounds using informatics-based screening S. Decesari et al. 10.5194/acp-18-2329-2018
- Atmospheric “HULIS” in Different Environments: Polarities, Molecular Sizes, and Sources Suggest More Than 50% Are Not “Humic-like” T. Spranger et al. 10.1021/acsearthspacechem.9b00299
- Production of Atmospheric Organosulfates via Mineral-Mediated Photochemistry M. Schmidt et al. 10.1021/acsearthspacechem.8b00178
- Radical Formation by Fine Particulate Matter Associated with Highly Oxygenated Molecules H. Tong et al. 10.1021/acs.est.9b05149
- Temperature and acidity dependence of secondary organic aerosol formation from <i>α</i>-pinene ozonolysis with a compact chamber system Y. Deng et al. 10.5194/acp-21-5983-2021
- An extractive electrospray ionization time-of-flight mass spectrometer (EESI-TOF) for online measurement of atmospheric aerosol particles F. Lopez-Hilfiker et al. 10.5194/amt-12-4867-2019
- A review of secondary organic aerosols formation focusing on organosulfates and organic nitrates W. Fan et al. 10.1016/j.jhazmat.2022.128406
- Molecular composition of fresh and aged aerosols from residential wood combustion and gasoline car with modern emission mitigation technology E. Schneider et al. 10.1039/D4EM00106K
- Organic Peroxides in Aerosol: Key Reactive Intermediates for Multiphase Processes in the Atmosphere S. Wang et al. 10.1021/acs.chemrev.2c00430
- Mass Spectrometry Analysis in Atmospheric Chemistry J. Laskin et al. 10.1021/acs.analchem.7b04249
- Exploring Volatility Properties of Discrete Secondary Organic Aerosol Constituents of α-Pinene and Polycyclic Aromatic Hydrocarbons Z. Babar et al. 10.1021/acsearthspacechem.0c00210
- Organosulfates in atmospheric aerosols in Shanghai, China: seasonal and interannual variability, origin, and formation mechanisms Y. Wang et al. 10.5194/acp-21-2959-2021
- Molecular Characterization and Source Identification of Atmospheric Particulate Organosulfates Using Ultrahigh Resolution Mass Spectrometry K. Wang et al. 10.1021/acs.est.9b02628
- Organosulfates in Ambient Aerosol: State of Knowledge and Future Research Directions on Formation, Abundance, Fate, and Importance M. Brüggemann et al. 10.1021/acs.est.9b06751
- Abundance of organosulfates derived from biogenic volatile organic compounds: Seasonal and spatial contrasts at four sites in China Y. Wang et al. 10.1016/j.scitotenv.2021.151275
- Beyond the formation: unveiling the atmospheric transformation of organosulfatesviaheterogeneous OH oxidation S. Ng & M. Chan 10.1039/D3CC03700B
- Molecular characterization of ultrafine particles using extractive electrospray time-of-flight mass spectrometry M. Surdu et al. 10.1039/D1EA00050K
Latest update: 23 Nov 2024
Short summary
Using complementary mass spectrometric techniques during a field study in central Europe, characteristic contributors to the organic aerosol mass were identified. Besides common marker compounds for biogenic secondary organic aerosol, highly oxidized sulfur species were detected in the particle phase. High-time-resolution measurements revealed correlations between these organosulfates and particulate sulfate as well as gas-phase peroxyradicals, giving hints to underlying formation mechanisms.
Using complementary mass spectrometric techniques during a field study in central Europe,...
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