Research article
04 Dec 2017
Research article
| 04 Dec 2017
Impact of uncertainties in inorganic chemical rate constants on tropospheric composition and ozone radiative forcing
Ben Newsome and Mat Evans
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Total article views: 2,301 (including HTML, PDF, and XML)
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Total article views: 1,462 (including HTML, PDF, and XML)
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Total article views: 839 (including HTML, PDF, and XML)
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Cited
19 citations as recorded by crossref.
- Observed NO/NO2 Ratios in the Upper Troposphere Imply Errors in NO-NO2 -O3 Cycling Kinetics or an Unaccounted NOx Reservoir R. Silvern et al. 10.1029/2018GL077728
- Worldwide Evaluation of Ozone Radiative Forcing in the UV-B Range between 1979 and 2014 D. Mateos & M. Antón 10.3390/rs12030436
- Global inorganic nitrate production mechanisms: comparison of a global model with nitrate isotope observations B. Alexander et al. 10.5194/acp-20-3859-2020
- Kinetics of the OH + NO<sub>2</sub> reaction: rate coefficients (217–333 K, 16–1200 mbar) and fall-off parameters for N<sub>2</sub> and O<sub>2</sub> bath gases D. Amedro et al. 10.5194/acp-19-10643-2019
- The Common Representative Intermediates Mechanism Version 2 in the United Kingdom Chemistry and Aerosols Model S. Archer‐Nicholls et al. 10.1029/2020MS002420
- Ozone production and precursor emission from wildfires in Africa J. Lee et al. 10.1039/D1EA00041A
- Tropospheric Ozone Assessment Report A. Archibald et al. 10.1525/elementa.2020.034
- Pressure and Temperature Dependencies of Rate Coefficients for the Reaction OH + NO2 + M → Products F. Winiberg et al. 10.1021/acs.jpca.0c08920
- Reaction kinetics of OH + HNO3 under conditions relevant to the upper troposphere/lower stratosphere F. Winiberg et al. 10.1039/C8CP04193H
- Interactive effects of changing stratospheric ozone and climate on tropospheric composition and air quality, and the consequences for human and ecosystem health S. Wilson et al. 10.1039/C8PP90064G
- Improving the prediction of an atmospheric chemistry transport model using gradient-boosted regression trees P. Ivatt & M. Evans 10.5194/acp-20-8063-2020
- Monte Carlo analyses of the uncertainties in the predictions from global tropospheric ozone models: Tropospheric burdens and seasonal cycles R. Derwent 10.1016/j.atmosenv.2020.117545
- Kinetics of the OH + NO<sub>2</sub> reaction: effect of water vapour and new parameterization for global modelling D. Amedro et al. 10.5194/acp-20-3091-2020
- Global sensitivity analysis of chemistry–climate model budgets of tropospheric ozone and OH: exploring model diversity O. Wild et al. 10.5194/acp-20-4047-2020
- Temperature-(208–318 K) and pressure-(18–696 Torr) dependent rate coefficients for the reaction between OH and HNO<sub>3</sub> K. Dulitz et al. 10.5194/acp-18-2381-2018
- Global Warming Potential (GWP) for Methane: Monte Carlo Analysis of the Uncertainties in Global Tropospheric Model Predictions R. Derwent 10.3390/atmos11050486
- Global sensitivity analysis of GEOS-Chem modeled ozone and hydrogen oxides during the INTEX campaigns K. Christian et al. 10.5194/acp-18-2443-2018
- Perspective on Mechanism Development and Structure-Activity Relationships for Gas-Phase Atmospheric Chemistry L. Vereecken et al. 10.1002/kin.21172
- Intercomparison of the representations of the atmospheric chemistry of pre-industrial methane and ozone in earth system and other global chemistry-transport models R. Derwent et al. 10.1016/j.atmosenv.2021.118248
19 citations as recorded by crossref.
- Observed NO/NO2 Ratios in the Upper Troposphere Imply Errors in NO-NO2 -O3 Cycling Kinetics or an Unaccounted NOx Reservoir R. Silvern et al. 10.1029/2018GL077728
- Worldwide Evaluation of Ozone Radiative Forcing in the UV-B Range between 1979 and 2014 D. Mateos & M. Antón 10.3390/rs12030436
- Global inorganic nitrate production mechanisms: comparison of a global model with nitrate isotope observations B. Alexander et al. 10.5194/acp-20-3859-2020
- Kinetics of the OH + NO<sub>2</sub> reaction: rate coefficients (217–333 K, 16–1200 mbar) and fall-off parameters for N<sub>2</sub> and O<sub>2</sub> bath gases D. Amedro et al. 10.5194/acp-19-10643-2019
- The Common Representative Intermediates Mechanism Version 2 in the United Kingdom Chemistry and Aerosols Model S. Archer‐Nicholls et al. 10.1029/2020MS002420
- Ozone production and precursor emission from wildfires in Africa J. Lee et al. 10.1039/D1EA00041A
- Tropospheric Ozone Assessment Report A. Archibald et al. 10.1525/elementa.2020.034
- Pressure and Temperature Dependencies of Rate Coefficients for the Reaction OH + NO2 + M → Products F. Winiberg et al. 10.1021/acs.jpca.0c08920
- Reaction kinetics of OH + HNO3 under conditions relevant to the upper troposphere/lower stratosphere F. Winiberg et al. 10.1039/C8CP04193H
- Interactive effects of changing stratospheric ozone and climate on tropospheric composition and air quality, and the consequences for human and ecosystem health S. Wilson et al. 10.1039/C8PP90064G
- Improving the prediction of an atmospheric chemistry transport model using gradient-boosted regression trees P. Ivatt & M. Evans 10.5194/acp-20-8063-2020
- Monte Carlo analyses of the uncertainties in the predictions from global tropospheric ozone models: Tropospheric burdens and seasonal cycles R. Derwent 10.1016/j.atmosenv.2020.117545
- Kinetics of the OH + NO<sub>2</sub> reaction: effect of water vapour and new parameterization for global modelling D. Amedro et al. 10.5194/acp-20-3091-2020
- Global sensitivity analysis of chemistry–climate model budgets of tropospheric ozone and OH: exploring model diversity O. Wild et al. 10.5194/acp-20-4047-2020
- Temperature-(208–318 K) and pressure-(18–696 Torr) dependent rate coefficients for the reaction between OH and HNO<sub>3</sub> K. Dulitz et al. 10.5194/acp-18-2381-2018
- Global Warming Potential (GWP) for Methane: Monte Carlo Analysis of the Uncertainties in Global Tropospheric Model Predictions R. Derwent 10.3390/atmos11050486
- Global sensitivity analysis of GEOS-Chem modeled ozone and hydrogen oxides during the INTEX campaigns K. Christian et al. 10.5194/acp-18-2443-2018
- Perspective on Mechanism Development and Structure-Activity Relationships for Gas-Phase Atmospheric Chemistry L. Vereecken et al. 10.1002/kin.21172
- Intercomparison of the representations of the atmospheric chemistry of pre-industrial methane and ozone in earth system and other global chemistry-transport models R. Derwent et al. 10.1016/j.atmosenv.2021.118248
Latest update: 01 Feb 2023
Short summary
We explore the uncertainty in the predictions of a chemical transport model (GEOS-Chem) from uncertainty in 60 inorganic rate constants and photolysis rates. We find uncertainty in the global mean ozone burden of 10 %, in global mean OH of 16 %, methane lifetimes of 16 %, and tropospheric ozone radiative forcings of 13 %. Reductions in the uncertainty of rate constants of these simple reactions would reduce uncertainty in our understanding of atmospheric composition.
We explore the uncertainty in the predictions of a chemical transport model (GEOS-Chem) from...
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