Articles | Volume 16, issue 13
https://doi.org/10.5194/acp-16-8461-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-16-8461-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
12 Jul 2016
Research article |
| 12 Jul 2016
Investigation of processes controlling summertime gaseous elemental mercury oxidation at midlatitudinal marine, coastal, and inland sites
Zhuyun Ye
Department of Chemistry, State University of New York, College of Environmental Science and Forestry, Syracuse, NY 13210, USA
Department of Chemistry, State University of New York, College of Environmental Science and Forestry, Syracuse, NY 13210, USA
Che-Jen Lin
Center for Advances in Water and Air Quality, Lamar University, Beaumont, TX 77710, USA
Department of Civil and Environmental Engineering, Lamar University, Beaumont, TX 77710, USA
Su Youn Kim
R&D Program Evaluation Division Office of National Evaluation and Analysis Korea Institute of S&T Evaluation and Planning (KISTEP), Seoul, South Korea
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Cited
31 citations as recorded by crossref.
- Heterogeneous Chemistry of Mercuric Chloride on Inorganic Salt Surfaces N. Mao et al. https://doi.org/10.1021/acs.jpca.1c02220
- Mercury in Atmospheric Air and Precipitation at the Monitoring Station Listvyanka (Southern Baikal Region) in 2022–2023 E. Lutskin et al. https://doi.org/10.1134/S102485602470088X
- Atmospheric Chemistry of HOHg(II)O• Mimics That of a Hydroxyl Radical D. Hewa Edirappulige et al. https://doi.org/10.1021/acs.jpca.3c04159
- Mercury stable isotopes revealing the atmospheric mercury circulation: A review of particulate bound mercury in China X. Qin et al. https://doi.org/10.1016/j.earscirev.2024.104681
- Primary effects of changes in meteorology vs. anthropogenic emissions on mercury wet deposition: A modeling study Z. Ye et al. https://doi.org/10.1016/j.atmosenv.2018.10.052
- Dynamics of gaseous oxidized mercury at Villum Research Station during the High Arctic summer J. Pernov et al. https://doi.org/10.5194/acp-21-13287-2021
- Earth system modeling of mercury using CESM2 – Part 1: Atmospheric model CAM6-Chem/Hg v1.0 P. Zhang & Y. Zhang https://doi.org/10.5194/gmd-15-3587-2022
- Is oxidation of atmospheric mercury controlled by different mechanisms in the polluted continental boundary layer vs. remote marine boundary layer? M. Gabay et al. https://doi.org/10.1088/1748-9326/ab7b26
- Evidence against Rapid Mercury Oxidation in Photochemical Smog S. Lyman et al. https://doi.org/10.1021/acs.est.2c02224
- An updated review of atmospheric mercury S. Lyman et al. https://doi.org/10.1016/j.scitotenv.2019.135575
- Measure-specific environmental benefits of air pollution control for coal-fired industrial boilers in China from 2015 to 2017 K. Wang et al. https://doi.org/10.1016/j.envpol.2021.116470
- Recent Advances in Atmospheric Chemistry of Mercury L. Si & P. Ariya https://doi.org/10.3390/atmos9020076
- First kinetic study of the atmospherically important reactions BrHg˙ + NO2and BrHg˙ + HOO Y. Jiao & T. Dibble https://doi.org/10.1039/C6CP06276H
- New evidence for atmospheric mercury transformations in the marine boundary layer from stable mercury isotopes B. Yu et al. https://doi.org/10.5194/acp-20-9713-2020
- Mercury transformations by reactive oxygen species: Occurrence, detection, evidence, and challenges Y. Zhou et al. https://doi.org/10.1080/10643389.2025.2478037
- A review of global environmental mercury processes in response to human and natural perturbations: Changes of emissions, climate, and land use D. Obrist et al. https://doi.org/10.1007/s13280-017-1004-9
- Role of the stratosphere in the global mercury cycle A. Saiz-Lopez et al. https://doi.org/10.1126/sciadv.ads1459
- Health risk assessment of gaseous elemental mercury (GEM) in Mexico City B. Schiavo et al. https://doi.org/10.1007/s10661-022-10107-7
- Sources and outflows of atmospheric mercury at Mt. Changbai, northeastern China C. Liu et al. https://doi.org/10.1016/j.scitotenv.2019.01.332
- Characteristics of atmospheric mercury in a suburban area of east China: sources, formation mechanisms, and regional transport X. Qin et al. https://doi.org/10.5194/acp-19-5923-2019
- Atmospheric Chemistry of Gaseous Oxidized Mercury at a Coastal Site in Atlantic Canada I. Cheng et al. https://doi.org/10.1175/JAS-D-19-0120.1
- A synthesis of research needs for improving the understanding of atmospheric mercury cycling L. Zhang et al. https://doi.org/10.5194/acp-17-9133-2017
- Evaluation of CMAQ Coupled With a State‐of‐the‐Art Mercury Chemical Mechanism (CMAQ‐newHg‐Br) Z. Ye et al. https://doi.org/10.1002/2017MS001161
- Long-Term Observations of Atmospheric Speciated Mercury at a Coastal Site in the Northern Gulf of Mexico during 2007–2018 X. Ren et al. https://doi.org/10.3390/atmos11030268
- Speciated atmospheric mercury during haze and non-haze periods in winter at an urban site in Beijing, China: Pollution characteristics, sources, and causes analyses C. Wang et al. https://doi.org/10.1016/j.atmosres.2020.105209
- Speciated atmospheric mercury and sea–air exchange of gaseous mercury in the South China Sea C. Wang et al. https://doi.org/10.5194/acp-19-10111-2019
- Improvements to the Accuracy of Atmospheric Oxidized Mercury Measurements S. Lyman et al. https://doi.org/10.1021/acs.est.0c02747
- Two years measurement of speciated atmospheric mercury in a typical area of the north coast of China: Sources, temporal variations, and influence of regional and long-range transport C. Wang et al. https://doi.org/10.1016/j.atmosenv.2019.117235
- Mercury transformation processes in nature: Critical knowledge gaps and perspectives for moving forward Z. Gao et al. https://doi.org/10.1016/j.jes.2022.07.013
- Stable Mercury Isotopes Revealing Photochemical Processes in the Marine Boundary Layer Y. Qiu et al. https://doi.org/10.1029/2021JD034630
- Together, Not Separately, OH and O3 Oxidize Hg(0) to Hg(II) in the Atmosphere P. Castro et al. https://doi.org/10.1021/acs.jpca.2c04364
31 citations as recorded by crossref.
- Heterogeneous Chemistry of Mercuric Chloride on Inorganic Salt Surfaces N. Mao et al. https://doi.org/10.1021/acs.jpca.1c02220
- Mercury in Atmospheric Air and Precipitation at the Monitoring Station Listvyanka (Southern Baikal Region) in 2022–2023 E. Lutskin et al. https://doi.org/10.1134/S102485602470088X
- Atmospheric Chemistry of HOHg(II)O• Mimics That of a Hydroxyl Radical D. Hewa Edirappulige et al. https://doi.org/10.1021/acs.jpca.3c04159
- Mercury stable isotopes revealing the atmospheric mercury circulation: A review of particulate bound mercury in China X. Qin et al. https://doi.org/10.1016/j.earscirev.2024.104681
- Primary effects of changes in meteorology vs. anthropogenic emissions on mercury wet deposition: A modeling study Z. Ye et al. https://doi.org/10.1016/j.atmosenv.2018.10.052
- Dynamics of gaseous oxidized mercury at Villum Research Station during the High Arctic summer J. Pernov et al. https://doi.org/10.5194/acp-21-13287-2021
- Earth system modeling of mercury using CESM2 – Part 1: Atmospheric model CAM6-Chem/Hg v1.0 P. Zhang & Y. Zhang https://doi.org/10.5194/gmd-15-3587-2022
- Is oxidation of atmospheric mercury controlled by different mechanisms in the polluted continental boundary layer vs. remote marine boundary layer? M. Gabay et al. https://doi.org/10.1088/1748-9326/ab7b26
- Evidence against Rapid Mercury Oxidation in Photochemical Smog S. Lyman et al. https://doi.org/10.1021/acs.est.2c02224
- An updated review of atmospheric mercury S. Lyman et al. https://doi.org/10.1016/j.scitotenv.2019.135575
- Measure-specific environmental benefits of air pollution control for coal-fired industrial boilers in China from 2015 to 2017 K. Wang et al. https://doi.org/10.1016/j.envpol.2021.116470
- Recent Advances in Atmospheric Chemistry of Mercury L. Si & P. Ariya https://doi.org/10.3390/atmos9020076
- First kinetic study of the atmospherically important reactions BrHg˙ + NO2and BrHg˙ + HOO Y. Jiao & T. Dibble https://doi.org/10.1039/C6CP06276H
- New evidence for atmospheric mercury transformations in the marine boundary layer from stable mercury isotopes B. Yu et al. https://doi.org/10.5194/acp-20-9713-2020
- Mercury transformations by reactive oxygen species: Occurrence, detection, evidence, and challenges Y. Zhou et al. https://doi.org/10.1080/10643389.2025.2478037
- A review of global environmental mercury processes in response to human and natural perturbations: Changes of emissions, climate, and land use D. Obrist et al. https://doi.org/10.1007/s13280-017-1004-9
- Role of the stratosphere in the global mercury cycle A. Saiz-Lopez et al. https://doi.org/10.1126/sciadv.ads1459
- Health risk assessment of gaseous elemental mercury (GEM) in Mexico City B. Schiavo et al. https://doi.org/10.1007/s10661-022-10107-7
- Sources and outflows of atmospheric mercury at Mt. Changbai, northeastern China C. Liu et al. https://doi.org/10.1016/j.scitotenv.2019.01.332
- Characteristics of atmospheric mercury in a suburban area of east China: sources, formation mechanisms, and regional transport X. Qin et al. https://doi.org/10.5194/acp-19-5923-2019
- Atmospheric Chemistry of Gaseous Oxidized Mercury at a Coastal Site in Atlantic Canada I. Cheng et al. https://doi.org/10.1175/JAS-D-19-0120.1
- A synthesis of research needs for improving the understanding of atmospheric mercury cycling L. Zhang et al. https://doi.org/10.5194/acp-17-9133-2017
- Evaluation of CMAQ Coupled With a State‐of‐the‐Art Mercury Chemical Mechanism (CMAQ‐newHg‐Br) Z. Ye et al. https://doi.org/10.1002/2017MS001161
- Long-Term Observations of Atmospheric Speciated Mercury at a Coastal Site in the Northern Gulf of Mexico during 2007–2018 X. Ren et al. https://doi.org/10.3390/atmos11030268
- Speciated atmospheric mercury during haze and non-haze periods in winter at an urban site in Beijing, China: Pollution characteristics, sources, and causes analyses C. Wang et al. https://doi.org/10.1016/j.atmosres.2020.105209
- Speciated atmospheric mercury and sea–air exchange of gaseous mercury in the South China Sea C. Wang et al. https://doi.org/10.5194/acp-19-10111-2019
- Improvements to the Accuracy of Atmospheric Oxidized Mercury Measurements S. Lyman et al. https://doi.org/10.1021/acs.est.0c02747
- Two years measurement of speciated atmospheric mercury in a typical area of the north coast of China: Sources, temporal variations, and influence of regional and long-range transport C. Wang et al. https://doi.org/10.1016/j.atmosenv.2019.117235
- Mercury transformation processes in nature: Critical knowledge gaps and perspectives for moving forward Z. Gao et al. https://doi.org/10.1016/j.jes.2022.07.013
- Stable Mercury Isotopes Revealing Photochemical Processes in the Marine Boundary Layer Y. Qiu et al. https://doi.org/10.1029/2021JD034630
- Together, Not Separately, OH and O3 Oxidize Hg(0) to Hg(II) in the Atmosphere P. Castro et al. https://doi.org/10.1021/acs.jpca.2c04364
Saved (final revised paper)
Latest update: 23 Jun 2026
Short summary
In this study, a state-of-the-art chemical mechanism was incorporated into a box model to investigate the atmospheric Hg cycling in different environments. As a result, for each of the three environments, GOM diurnal cycles of over half the selected cases were reasonably represented by the box model. A realistic model can be a powerful tool, providing important information on atmospheric Hg cycling and implications for policy makers.
In this study, a state-of-the-art chemical mechanism was incorporated into a box model to...
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