Articles | Volume 16, issue 7
https://doi.org/10.5194/acp-16-4511-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-16-4511-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Molecular transformations of phenolic SOA during photochemical aging in the aqueous phase: competition among oligomerization, functionalization, and fragmentation
Lu Yu
Department of Environmental Toxicology, University of California, 1 Shields Ave., Davis, CA 95616, USA
Jeremy Smith
Department of Land, Air and Water Resources, University of California, 1 Shields Ave., Davis, CA 95616, USA
Alexander Laskin
Environmental Molecular Sciences Laboratory, Pacific Northwest National Laboratory, Richland, WA 99352, USA
Katheryn M. George
Crocker Nuclear Laboratory, University of California, 1 Shields Ave., Davis, CA 95616, USA
Cort Anastasio
Department of Land, Air and Water Resources, University of California, 1 Shields Ave., Davis, CA 95616, USA
Julia Laskin
Physical Sciences Division, Pacific Northwest National Laboratory, Richland, WA 99352, USA
Ann M. Dillner
Crocker Nuclear Laboratory, University of California, 1 Shields Ave., Davis, CA 95616, USA
Department of Environmental Toxicology, University of California, 1 Shields Ave., Davis, CA 95616, USA
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Short summary
The chemical evolution of SOA formed during aqueous reactions of phenolic compounds is studied via combined bulk and molecular analysis. Phenolic SOA evolve dynamically during photochemical aging, with different reaction mechanisms (oligomerization, fragmentation, and functionalization) leading to different generations of products that span an enormous range in volatilities and a large range in oxidation state and composition. Aqueous reactions of phenols are likely an important source of ELVOC.
The chemical evolution of SOA formed during aqueous reactions of phenolic compounds is studied...
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