Articles | Volume 16, issue 5
https://doi.org/10.5194/acp-16-3041-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-16-3041-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Simulating secondary organic aerosol in a regional air quality model using the statistical oxidation model – Part 2: Assessing the influence of vapor wall losses
Department of Civil and Environmental Engineering, University of
California, Davis, CA, USA
Shantanu H. Jathar
Department of Mechanical Engineering, Colorado State University, Fort
Collins, CO, USA
Michael J. Kleeman
Department of Civil and Environmental Engineering, University of
California, Davis, CA, USA
Kenneth S. Docherty
Alion Science and Technology, Research Triangle Park, NC, USA
Jose L. Jimenez
Cooperative Institute for Research in Environmental Sciences and
Department Chemistry and Biochemistry, University of Colorado, Boulder, CO,
USA
John H. Seinfeld
Division of Chemistry and Chemical Engineering and Division of
Engineering and Applied Science, California Institute of Technology,
Pasadena, CA, USA
Anthony S. Wexler
Department of Civil and Environmental Engineering, University of
California, Davis, CA, USA
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Saved (preprint)
Latest update: 14 Dec 2024
Short summary
Losses of vapors to walls of chambers can negatively bias SOA formation measurements, consequently leading to low predicted SOA concentrations in air quality models. Here, we show that accounting for such vapor losses leads to substantial increases in the predicted amount of SOA formed from VOCs and to notable increases in the O : C atomic ratio in two US regions. Comparison with a variety of observational data suggests generally improved model performance when vapor wall losses are accounted for.
Losses of vapors to walls of chambers can negatively bias SOA formation measurements,...
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