Articles | Volume 15, issue 14
Atmos. Chem. Phys., 15, 8165–8178, 2015
Atmos. Chem. Phys., 15, 8165–8178, 2015

Research article 23 Jul 2015

Research article | 23 Jul 2015

Characteristics and formation mechanism of continuous hazes in China: a case study during the autumn of 2014 in the North China Plain

Y. R. Yang1, X. G. Liu1, Y. Qu2, J. L. An2, R. Jiang3, Y. H. Zhang4, Y. L. Sun2, Z. J. Wu4, F. Zhang5, W. Q. Xu2, and Q. X. Ma6 Y. R. Yang et al.
  • 1State Key Laboratory of Water Environment Simulation, School of Environment, Beijing Normal University, Beijing 100875, China
  • 2State Key Laboratory of Atmospheric Boundary Layer Physics and Atmospheric Chemistry, Institute of Atmospheric Physics, Chinese Academy of Sciences, Beijing 100029, China
  • 3Shanghai Key Laboratory for Urban Ecological Processes and Eco-Restoration, School of Ecological and Environmental Sciences, East China Normal University, Shanghai 200241, China
  • 4State Key Joint Laboratory of Environment Simulation and Pollution Control, College of Environmental Sciences and Engineering, Peking University, Beijing 100871, China
  • 5College of Global Change and Earth System Science, Beijing Normal University, Beijing 100875, China
  • 6Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing, 100085, China

Abstract. Four extreme haze episodes occurred in October 2014 in the North China Plain (NCP). To clarify the formation mechanism of hazes in autumn, strengthened observations were conducted in Beijing from 5 October to 2 November. The meteorological parameters, satellite data, chemical compositions and optical properties of aerosols were obtained. The hazes originated from the NCP, developing in the southwest and northeast directions, with the highest concentration of PM2.5 of 469 μg m−3 in Beijing. The NCP was dominated by a weak high pressure system during the haze episode, which resulted in low surface wind speed and relatively stagnant weather. Moreover, the wind slowed down around Beijing city. The secondary aerosols NO3 was always higher than that of SO42−, which indicated the motor vehicles played a more important part in the hazes in October 2014, even though the oxidation rate from SO2 to SO42− was faster than that of NOx to NO3. Sudden increases of the concentrations of organic matter, Cl and BC (black carbon) before each haze episode implied that regional transport of pollutants by biomass burning was important for haze formation during autumn. A satellite map of fire points and the backward trajectories of the air masses also indicated this pollution source. The distinct decrease in the PBL (planetary boundary layer) height during four haze episodes restrained the vertical dispersion of the air pollutants. Water vapor also played a vital role in the formation of hazes by accelerating the chemical transformation of secondary pollutants, leading to hygroscopic growth of aerosols and altering the thermal balance of the atmosphere.

Final-revised paper