Observation of isoprene hydroxynitrates in the southeastern United States and implications for the fate of NO<sub><i>x</i></sub>

Xiong, F.; McAvey, K. M.; Pratt, K. A.; Groff, C. J.; Hostetler, M. A.; Lipton, M. A.; Starn, T. K.; Seeley, J. V.; Bertman, S. B.; Teng, A. P.; Crounse, J. D.; Nguyen, T. B.; Wennberg, P. O.; Misztal, P. K.; Goldstein, A. H.; Guenther, A. B.; Koss, A. R.; Olson, K. F.; de Gouw, J. A.; Baumann, K.; Edgerton, E. S.; Feiner, P. A.; Zhang, L.; Miller, D. O.; Brune, W. H.; Shepson, P. B.

doi:https://doi.org/10.5194/acp-15-11257-2015

Articles | Volume 15, issue 19

https://doi.org/10.5194/acp-15-11257-2015

© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.

https://doi.org/10.5194/acp-15-11257-2015

© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.

Articles | Volume 15, issue 19

Research article

|

09 Oct 2015

Research article |

| 09 Oct 2015

Observation of isoprene hydroxynitrates in the southeastern United States and implications for the fate of NO_x

F. Xiong, K. M. McAvey, K. A. Pratt, C. J. Groff, M. A. Hostetler, M. A. Lipton, T. K. Starn, J. V. Seeley, S. B. Bertman, A. P. Teng, J. D. Crounse, T. B. Nguyen, P. O. Wennberg, P. K. Misztal, A. H. Goldstein, A. B. Guenther, A. R. Koss, K. F. Olson, J. A. de Gouw, K. Baumann, E. S. Edgerton, P. A. Feiner, L. Zhang, D. O. Miller, W. H. Brune, and P. B. Shepson

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AC: Author comment | RC: Referee comment | SC: Short comment | EC: Editor comment

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RC C5313: 'Review', Anonymous Referee #1, 28 Jul 2015
- AC C7021: 'response to referee #1', Fulizi Xiong, 19 Sep 2015
RC C6063: 'Review of Xiong et al', Anonymous Referee #2, 19 Aug 2015
- AC C7022: 'response to referee #2', Fulizi Xiong, 19 Sep 2015

Peer-review completion

AR: Author's response | RR: Referee report | ED: Editor decision

AR by Fulizi Xiong on behalf of the Authors (19 Sep 2015) Author's response Manuscript

ED: Publish subject to technical corrections (28 Sep 2015) by Anne Perring

AR by Fulizi Xiong on behalf of the Authors (01 Oct 2015) Manuscript

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Short summary

Hydroxynitrates from isoprene oxidation were quantified both in the laboratory and through field studies. The yield of hydroxynitrates 9(+4/-3)% derived from chamber experiments was applied in a zero-dimensional model to simulate the production and loss of isoprene hydroxynitrates in an ambient environment during the 2013 Southern Oxidant and Aerosol Study (SOAS). NOx was determined to be the limiting factor for the formation of isoprene hydroxynitrates during SOAS.

Observation of isoprene hydroxynitrates in the southeastern United States and implications for the fate of NOx

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Observation of isoprene hydroxynitrates in the southeastern United States and implications for the fate of NO_x