Articles | Volume 15, issue 19
https://doi.org/10.5194/acp-15-11257-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-15-11257-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Observation of isoprene hydroxynitrates in the southeastern United States and implications for the fate of NOx
F. Xiong
Department of Chemistry, Purdue University, West Lafayette, IN, USA
K. M. McAvey
Department of Chemistry, Purdue University, West Lafayette, IN, USA
K. A. Pratt
Department of Chemistry, Purdue University, West Lafayette, IN, USA
Department of Chemistry, University of Michigan, Ann Arbor, MI, USA
C. J. Groff
Department of Chemistry, Purdue University, West Lafayette, IN, USA
M. A. Hostetler
Department of Chemistry, Purdue University, West Lafayette, IN, USA
M. A. Lipton
Department of Chemistry, Purdue University, West Lafayette, IN, USA
T. K. Starn
Department of Chemistry, West Chester University of Pennsylvania, West Chester, PA, USA
J. V. Seeley
Department of Chemistry, Oakland University, Rochester, MI, USA
S. B. Bertman
Department of Chemistry, Western Michigan University, Kalamazoo, MI, USA
A. P. Teng
Division of Engineering and Applied Science, California Institute of Technology, Pasadena, CA, USA
J. D. Crounse
Division of Geophysical and Planetary Sciences, California Institute of Technology, Pasadena, CA, USA
T. B. Nguyen
Division of Geophysical and Planetary Sciences, California Institute of Technology, Pasadena, CA, USA
P. O. Wennberg
Division of Engineering and Applied Science, California Institute of Technology, Pasadena, CA, USA
Division of Geophysical and Planetary Sciences, California Institute of Technology, Pasadena, CA, USA
P. K. Misztal
Department of Environmental Science, Policy, & Management, University of California at Berkeley, Berkeley, CA, USA
A. H. Goldstein
Department of Environmental Science, Policy, & Management, University of California at Berkeley, Berkeley, CA, USA
Department of Civil and Environmental Engineering, University of California at Berkeley, Berkeley, CA, USA
A. B. Guenther
Atmospheric Sciences and Global Change Division, Pacific Northwest National Laboratory, Richland, WA, USA
A. R. Koss
Cooperative Institute for Research in Environmental Sciences, Boulder, CO, USA
NOAA Earth System Research Laboratory, Boulder, CO, USA
K. F. Olson
Department of Environmental Science, Policy, & Management, University of California at Berkeley, Berkeley, CA, USA
J. A. de Gouw
Cooperative Institute for Research in Environmental Sciences, Boulder, CO, USA
NOAA Earth System Research Laboratory, Boulder, CO, USA
K. Baumann
Atmospheric Research & Analysis, Inc., Cary, NC, USA
E. S. Edgerton
Atmospheric Research & Analysis, Inc., Cary, NC, USA
P. A. Feiner
Department of Meteorology, Pennsylvania State University, University Park, PA, USA
L. Zhang
Department of Meteorology, Pennsylvania State University, University Park, PA, USA
D. O. Miller
Department of Meteorology, Pennsylvania State University, University Park, PA, USA
W. H. Brune
Department of Meteorology, Pennsylvania State University, University Park, PA, USA
P. B. Shepson
CORRESPONDING AUTHOR
Department of Chemistry, Purdue University, West Lafayette, IN, USA
Department of Earth, Atmospheric and Planetary Sciences, Purdue University, West Lafayette, IN, USA
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Short summary
Hydroxynitrates from isoprene oxidation were quantified both in the laboratory and through field studies. The yield of hydroxynitrates 9(+4/-3)% derived from chamber experiments was applied in a zero-dimensional model to simulate the production and loss of isoprene hydroxynitrates in an ambient environment during the 2013 Southern Oxidant and Aerosol Study (SOAS). NOx was determined to be the limiting factor for the formation of isoprene hydroxynitrates during SOAS.
Hydroxynitrates from isoprene oxidation were quantified both in the laboratory and through field...
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