Articles | Volume 15, issue 19
https://doi.org/10.5194/acp-15-11257-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-15-11257-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
09 Oct 2015
Research article |
| 09 Oct 2015
Observation of isoprene hydroxynitrates in the southeastern United States and implications for the fate of NOx
F. Xiong
Department of Chemistry, Purdue University, West Lafayette, IN, USA
K. M. McAvey
Department of Chemistry, Purdue University, West Lafayette, IN, USA
K. A. Pratt
Department of Chemistry, Purdue University, West Lafayette, IN, USA
Department of Chemistry, University of Michigan, Ann Arbor, MI, USA
C. J. Groff
Department of Chemistry, Purdue University, West Lafayette, IN, USA
M. A. Hostetler
Department of Chemistry, Purdue University, West Lafayette, IN, USA
M. A. Lipton
Department of Chemistry, Purdue University, West Lafayette, IN, USA
T. K. Starn
Department of Chemistry, West Chester University of Pennsylvania, West Chester, PA, USA
J. V. Seeley
Department of Chemistry, Oakland University, Rochester, MI, USA
S. B. Bertman
Department of Chemistry, Western Michigan University, Kalamazoo, MI, USA
A. P. Teng
Division of Engineering and Applied Science, California Institute of Technology, Pasadena, CA, USA
J. D. Crounse
Division of Geophysical and Planetary Sciences, California Institute of Technology, Pasadena, CA, USA
T. B. Nguyen
Division of Geophysical and Planetary Sciences, California Institute of Technology, Pasadena, CA, USA
P. O. Wennberg
Division of Engineering and Applied Science, California Institute of Technology, Pasadena, CA, USA
Division of Geophysical and Planetary Sciences, California Institute of Technology, Pasadena, CA, USA
P. K. Misztal
Department of Environmental Science, Policy, & Management, University of California at Berkeley, Berkeley, CA, USA
A. H. Goldstein
Department of Environmental Science, Policy, & Management, University of California at Berkeley, Berkeley, CA, USA
Department of Civil and Environmental Engineering, University of California at Berkeley, Berkeley, CA, USA
A. B. Guenther
Atmospheric Sciences and Global Change Division, Pacific Northwest National Laboratory, Richland, WA, USA
A. R. Koss
Cooperative Institute for Research in Environmental Sciences, Boulder, CO, USA
NOAA Earth System Research Laboratory, Boulder, CO, USA
K. F. Olson
Department of Environmental Science, Policy, & Management, University of California at Berkeley, Berkeley, CA, USA
J. A. de Gouw
Cooperative Institute for Research in Environmental Sciences, Boulder, CO, USA
NOAA Earth System Research Laboratory, Boulder, CO, USA
K. Baumann
Atmospheric Research & Analysis, Inc., Cary, NC, USA
E. S. Edgerton
Atmospheric Research & Analysis, Inc., Cary, NC, USA
P. A. Feiner
Department of Meteorology, Pennsylvania State University, University Park, PA, USA
L. Zhang
Department of Meteorology, Pennsylvania State University, University Park, PA, USA
D. O. Miller
Department of Meteorology, Pennsylvania State University, University Park, PA, USA
W. H. Brune
Department of Meteorology, Pennsylvania State University, University Park, PA, USA
P. B. Shepson
CORRESPONDING AUTHOR
Department of Chemistry, Purdue University, West Lafayette, IN, USA
Department of Earth, Atmospheric and Planetary Sciences, Purdue University, West Lafayette, IN, USA
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Cited
64 citations as recorded by crossref.
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63 citations as recorded by crossref.
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- Agricultural fires in the southeastern U.S. during SEAC4RS: Emissions of trace gases and particles and evolution of ozone, reactive nitrogen, and organic aerosol X. Liu et al. 10.1002/2016JD025040
- Observations of speciated isoprene nitrates in Beijing: implications for isoprene chemistry C. Reeves et al. 10.5194/acp-21-6315-2021
- Isoprene photochemistry over the Amazon rainforest Y. Liu et al. 10.1073/pnas.1524136113
- Online Calibration of a Chemical Ionization Mass Spectrometer for Multifunctional Biogenic Organic Nitrates M. Robinson et al. 10.1021/acsestair.4c00056
- Field Measurement of Alkyl Nitrates in the Atmosphere C. Li et al. 10.6023/A23100460
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- Low-volatility compounds contribute significantly to isoprene secondary organic aerosol (SOA) under high-NO<sub><i>x</i></sub> conditions R. Schwantes et al. 10.5194/acp-19-7255-2019
- Speciation of OH reactivity above the canopy of an isoprene-dominated forest J. Kaiser et al. 10.5194/acp-16-9349-2016
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- Observations of highly oxidized molecules and particle nucleation in the atmosphere of Beijing J. Brean et al. 10.5194/acp-19-14933-2019
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- Barrierless Reactions with Loose Transition States Govern the Yields and Lifetimes of Organic Nitrates Derived from Isoprene I. Piletic et al. 10.1021/acs.jpca.7b08229
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- Isoprene research – 60 years later, the biology is still enigmatic T. Sharkey & R. Monson 10.1111/pce.12930
- Gas-Phase Reactions of Isoprene and Its Major Oxidation Products P. Wennberg et al. 10.1021/acs.chemrev.7b00439
- Climate-driven ground-level ozone extreme in the fall over the Southeast United States Y. Zhang & Y. Wang 10.1073/pnas.1602563113
- Comprehensive isoprene and terpene gas-phase chemistry improves simulated surface ozone in the southeastern US R. Schwantes et al. 10.5194/acp-20-3739-2020
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- Syntheses and Characterization of Chitosan-Expired Amoxicillin/Natural Rubber Copolymers for Slow-Release Fertilizer A. Kadhim Wasaf et al. 10.14233/ajchem.2023.27573
- The lifetime of nitrogen oxides in an isoprene-dominated forest P. Romer et al. 10.5194/acp-16-7623-2016
- Inland Sea Spray Aerosol Transport and Incomplete Chloride Depletion: Varying Degrees of Reactive Processing Observed during SOAS A. Bondy et al. 10.1021/acs.est.7b02085
- Controlled nitric oxide production via O(<sup>1</sup>D) + N<sub>2</sub>O reactions for use in oxidation flow reactor studies A. Lambe et al. 10.5194/amt-10-2283-2017
- Daytime isoprene nitrates under changing NOx and O3 A. Mayhew et al. 10.5194/acp-23-8473-2023
1 citations as recorded by crossref.
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Latest update: 23 Nov 2024
Short summary
Hydroxynitrates from isoprene oxidation were quantified both in the laboratory and through field studies. The yield of hydroxynitrates 9(+4/-3)% derived from chamber experiments was applied in a zero-dimensional model to simulate the production and loss of isoprene hydroxynitrates in an ambient environment during the 2013 Southern Oxidant and Aerosol Study (SOAS). NOx was determined to be the limiting factor for the formation of isoprene hydroxynitrates during SOAS.
Hydroxynitrates from isoprene oxidation were quantified both in the laboratory and through field...
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