Articles | Volume 15, issue 17
https://doi.org/10.5194/acp-15-10019-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-15-10019-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Ensemble data assimilation of total column ozone using a coupled meteorology–chemistry model and its impact on the structure of Typhoon Nabi (2005)
Department of Atmospheric Science and Engineering, Ewha Womans University, Seoul, Republic of Korea
Center for Climate/Environment Change Prediction Research, Ewha Womans University, Seoul, Republic of Korea
Severe Storm Research Center, Ewha Womans University, Seoul, Republic of Korea
Department of Atmospheric Science and Engineering, Ewha Womans University, Seoul, Republic of Korea
Department of Environmental Science and Engineering, Ewha Womans University, Seoul, Republic of Korea
Center for Climate/Environment Change Prediction Research, Ewha Womans University, Seoul, Republic of Korea
Severe Storm Research Center, Ewha Womans University, Seoul, Republic of Korea
M. Zupanski
Cooperative Institute for Research in the Atmosphere, Colorado State University, Fort Collins, CO, USA
Related authors
Sujeong Lim, Seon Ki Park, and Claudio Cassardo
Geosci. Model Dev. Discuss., https://doi.org/10.5194/gmd-2023-28, https://doi.org/10.5194/gmd-2023-28, 2023
Revised manuscript not accepted
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The ensembles in the numerical weather prediction system are under-dispersed near the land surface; therefore, an inflation method is required to increase it. In this study, we perturbed soil temperature and soil moisture to represent the near-surface uncertainty. Perturbations were obtained by the optimization algorithm taking into account diurnal variations in soil states. Consequently, it indirectly inflated the temperature and water vapor mixing ratio in the planetary boundary layer.
Sujeong Lim, Hyeon-Ju Gim, Ebony Lee, Seungyeon Lee, Won Young Lee, Yong Hee Lee, Claudio Cassardo, and Seon Ki Park
Geosci. Model Dev., 15, 8541–8559, https://doi.org/10.5194/gmd-15-8541-2022, https://doi.org/10.5194/gmd-15-8541-2022, 2022
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The land surface model (LSM) contains various uncertain parameters, which are obtained by the empirical relations reflecting the specific local region and can be a source of uncertainty. To seek the optimal parameter values in the snow-related processes of the Noah LSM over South Korea, we have implemented an optimization algorithm, a micro-genetic algorithm using the observations. As a result, the optimized snow parameters improve snowfall prediction.
S. K. Park, S. Lim, and M. Zupanski
Geosci. Model Dev., 8, 1315–1320, https://doi.org/10.5194/gmd-8-1315-2015, https://doi.org/10.5194/gmd-8-1315-2015, 2015
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The structure of an ensemble-based coupled atmosphere-chemistry forecast error covariance is examined using the WRF-Chem, a coupled atmosphere-chemistry model. It is found that the coupled error covariance has important cross-variable components that allow a physically meaningful adjustment of all control variables. Additional benefit of the coupled error covariance is that a cross-component impact is allowed; e.g., atmospheric observations can exert impact on chemistry analysis, and vice versa.
Sungmin O, Ji Won Yoon, and Seon Ki Park
Atmos. Meas. Tech., 18, 1471–1484, https://doi.org/10.5194/amt-18-1471-2025, https://doi.org/10.5194/amt-18-1471-2025, 2025
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Air pollutants such as particulate matter with diameters of 10 µm and 2.5 µm or less (PM10 and PM2.5) can cause adverse public health and environment effects; therefore their regular monitoring is crucial to keep pollutant concentrations under control. Our study demonstrates the potential of high-resolution aerosol optical depth (AOD) data from the Geostationary Environment Monitoring Spectrometer (GEMS) satellite to estimate ground-level PM concentrations using machine learning models.
Ji Won Yoon, Seungyeon Lee, Ebony Lee, and Seon Ki Park
Geosci. Model Dev. Discuss., https://doi.org/10.5194/gmd-2024-114, https://doi.org/10.5194/gmd-2024-114, 2024
Revised manuscript accepted for GMD
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This study evaluates the WRF-Chem model's prediction of a mega Asian Dust Storms (ADSs) over South Korea on March 28–29, 2021. We assessed five dust emission and four land surface schemes for predicting ADSs. Using surface observations and remote sensing data, we examined variables, such as temperature, humidity, wind speed, PM10, and aerosol optical depth. The UoC04 dust emission and CLM4 land surface scheme combination reduced RMSE for PM10 by up to 29.6 %, showing the best performance.
Sujeong Lim, Seon Ki Park, and Claudio Cassardo
Geosci. Model Dev. Discuss., https://doi.org/10.5194/gmd-2023-28, https://doi.org/10.5194/gmd-2023-28, 2023
Revised manuscript not accepted
Short summary
Short summary
The ensembles in the numerical weather prediction system are under-dispersed near the land surface; therefore, an inflation method is required to increase it. In this study, we perturbed soil temperature and soil moisture to represent the near-surface uncertainty. Perturbations were obtained by the optimization algorithm taking into account diurnal variations in soil states. Consequently, it indirectly inflated the temperature and water vapor mixing ratio in the planetary boundary layer.
Yoonjin Lee, Christian D. Kummerow, and Milija Zupanski
Atmos. Meas. Tech., 15, 7119–7136, https://doi.org/10.5194/amt-15-7119-2022, https://doi.org/10.5194/amt-15-7119-2022, 2022
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Vertical profiles of latent heating are derived from GOES-16 to be used in convective initialization. They are compared with other latent heating products derived from NEXRAD and GPM satellites, and the results show that their values are very similar to the radar-derived products. Finally, using latent heating derived from GOES-16 for convective initialization shows improvements in precipitation forecasts, which are comparable to the results using latent heating derived from NEXRAD.
Sujeong Lim, Hyeon-Ju Gim, Ebony Lee, Seungyeon Lee, Won Young Lee, Yong Hee Lee, Claudio Cassardo, and Seon Ki Park
Geosci. Model Dev., 15, 8541–8559, https://doi.org/10.5194/gmd-15-8541-2022, https://doi.org/10.5194/gmd-15-8541-2022, 2022
Short summary
Short summary
The land surface model (LSM) contains various uncertain parameters, which are obtained by the empirical relations reflecting the specific local region and can be a source of uncertainty. To seek the optimal parameter values in the snow-related processes of the Noah LSM over South Korea, we have implemented an optimization algorithm, a micro-genetic algorithm using the observations. As a result, the optimized snow parameters improve snowfall prediction.
Won Young Lee, Hyeon-Ju Gim, and Seon Ki Park
The Cryosphere Discuss., https://doi.org/10.5194/tc-2021-319, https://doi.org/10.5194/tc-2021-319, 2021
Manuscript not accepted for further review
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Snow cover or snow albedo plays a vital role in the atmosphere and land surface interaction. Especially, direct observation of snow is difficult and scarce. That's why a reliable Land Surface Model (LSM), including snow physical processes, is significant. In this study, we tried to give meaningful insights for improving the LSM in the future by identifying the main variables or parameters used and examining the different formulas for snow-related processes of the eight LSMs.
Sojung Park and Seon K. Park
Geosci. Model Dev., 14, 6241–6255, https://doi.org/10.5194/gmd-14-6241-2021, https://doi.org/10.5194/gmd-14-6241-2021, 2021
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One of the biggest uncertainties in numerical weather predictions (NWPs) comes from treating subgrid-scale physical processes. Physical processes, such as cumulus, microphysics, and planetary boundary layer processes, are parameterized in NWP models by empirical and theoretical backgrounds. We developed an interface between a micro-genetic algorithm and the WRF model for a combinatorial optimization of physics for heavy rainfall events in Korea. The system improved precipitation forecasts.
Yoonjin Lee, Christian D. Kummerow, and Milija Zupanski
Atmos. Meas. Tech. Discuss., https://doi.org/10.5194/amt-2021-97, https://doi.org/10.5194/amt-2021-97, 2021
Preprint withdrawn
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Latent heating released from phase changes of water is an important factor in driving convection, and thus used in short-term weather forecast models to initiate convection. Typically, radars have been used to retrieve latent heating to be used in the forecast model, but continuous radar data are only available over land. Therefore, this study uses geostationary satellite data to retrieve latent heating so that it can be used to initiate convection in regions where radar data are not available.
Yoonjin Lee, Christian D. Kummerow, and Milija Zupanski
Atmos. Meas. Tech., 14, 3755–3771, https://doi.org/10.5194/amt-14-3755-2021, https://doi.org/10.5194/amt-14-3755-2021, 2021
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This study suggests two methods to detect convection using 1 min data from GOES-16: one method detects early convective clouds using their vertical growth rate and the other method detects mature convective clouds using their lumpy cloud top surfaces. Applying the two methods to 1-month data showed that the accuracy of the combined methods was 85.8 % and showed their potential to be used in regions where radar data are not available.
Steven D. Miller, Louie D. Grasso, Qijing Bian, Sonia M. Kreidenweis, Jack F. Dostalek, Jeremy E. Solbrig, Jennifer Bukowski, Susan C. van den Heever, Yi Wang, Xiaoguang Xu, Jun Wang, Annette L. Walker, Ting-Chi Wu, Milija Zupanski, Christine Chiu, and Jeffrey S. Reid
Atmos. Meas. Tech., 12, 5101–5118, https://doi.org/10.5194/amt-12-5101-2019, https://doi.org/10.5194/amt-12-5101-2019, 2019
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Satellite–based detection of lofted mineral via infrared–window channels, well established in the literature, faces significant challenges in the presence of atmospheric moisture. Here, we consider a case featuring the juxtaposition of two dust plumes embedded within dry and moist air masses. The case is considered from the vantage points of numerical modeling, multi–sensor observations, and radiative transfer theory arriving at a new method for mitigating the water vapor masking effect.
Da-Eun Kim and Seon Ki Park
The Cryosphere Discuss., https://doi.org/10.5194/tc-2019-15, https://doi.org/10.5194/tc-2019-15, 2019
Preprint withdrawn
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An accurate prediction of the Eurasian snow is essentially important in predicting the climate and weather phenomena in Asia. Regional climate models are mostly coupled with several land surface models (LSMs) in which the land surface process parameters are calculated under their own physical principles and parameterization schemes. We show that prediction of the Eurasian snow cover is sensitive to the choice of LSMs coupled to regional climate models, and hence the future climate projections.
Milija Zupanski, Anton Kliewer, Ting-Chi Wu, Karina Apodaca, Qijing Bian, Sam Atwood, Yi Wang, Jun Wang, and Steven D. Miller
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2019-2, https://doi.org/10.5194/acp-2019-2, 2019
Revised manuscript not accepted
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The problem of under-observed aerosol observations and in particular the vertical distribution of aerosols is addressed using a strongly coupled atmosphere-aerosol data assimilation system. In the strongly coupled system the atmospheric observations, which are more numerous in general, can impact the aerosol initial conditions. In an application over a coastal zone, results indicate that atmospheric observations have a positive impact on aerosols.
Ting-Chi Wu, Milija Zupanski, Stephen Saleeby, Anton Kliewer, Lewis Grasso, Qijing Bian, Samuel A. Atwood, Yi Wang, and Jun Wang
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2018-1249, https://doi.org/10.5194/acp-2018-1249, 2018
Revised manuscript not accepted
Anton Kliewer, Milija Zupanski, Qijing Bian, Sam Atwood, Yi Wang, and Jun Wang
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2018-1156, https://doi.org/10.5194/acp-2018-1156, 2018
Revised manuscript not accepted
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This research is focused on improving numerical weather prediction by including data regarding aerosols in the atmosphere. Using weather prediction models along with data assimilation (the process of marrying observations with a model prediction), a better representation of the atmosphere can be described. As no model or observational platform is ever perfect, the aerosol observations have to be de-biased (adjusting for systematic error). Here we look at two such methods.
Sojung Park, Seon Ki Park, Jeung Whan Lee, and Yunho Park
Hydrol. Earth Syst. Sci., 22, 3435–3452, https://doi.org/10.5194/hess-22-3435-2018, https://doi.org/10.5194/hess-22-3435-2018, 2018
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Understanding the precipitation characteristics is essential to design an optimal observation network. We studied the spatial and temporal characteristics of summertime precipitation systems in Korea via geostatistical analyses on the ground-based precipitation and satellite water vapor data. We found that, under a strict standard, an observation network with higher resolution is required in local areas with frequent heavy rainfalls, depending on directional features of precipitation systems.
Claudio Cassardo, Seon Ki Park, Marco Galli, and Sungmin O
Hydrol. Earth Syst. Sci., 22, 3331–3350, https://doi.org/10.5194/hess-22-3331-2018, https://doi.org/10.5194/hess-22-3331-2018, 2018
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Temperature and precipitation can have abnormal states due to climate change and exert a significant impact on the regional hydrologic cycle. We assess the hydrologic component changes in the Alps and northern Italy, on the basis of regional future climate (FC) conditions, using the UTOPIA land surface model. The annual mean number of dry (wet) days increase remarkably (slightly) in FCs, thus increasing the risk of severe droughts and slightly increasing the risk of floods coincidently.
Sojung Park and Seon Ki Park
Geosci. Model Dev., 9, 1073–1085, https://doi.org/10.5194/gmd-9-1073-2016, https://doi.org/10.5194/gmd-9-1073-2016, 2016
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Snow albedo varies with snow grain size, snow cover thickness, etc. It also depends on the spatial characteristics of land cover and on the canopy density and structure. The Noah-MP model shows a bias error of albedo in winter due to no proper reflection of the vegetation effect. We developed new parameters, called leaf index and stem index, which reflect the vegetation effect on winter albedo. The Noah-MP's performance in albedo has prominently improved with about 69 % decrease in the RMSE.
J. Kim and S. K. Park
Hydrol. Earth Syst. Sci., 20, 651–658, https://doi.org/10.5194/hess-20-651-2016, https://doi.org/10.5194/hess-20-651-2016, 2016
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This study examined the uncertainty in climatological precipitation in East Asia, calculated from five gridded analysis data sets based on in situ rain gauge observations from 1980 to 2007. It is found that the regions of large uncertainties are typically lightly populated and are characterized by severe terrain and/or very high elevations. Thus, care must be taken in using long-term trends calculated from gridded precipitation analysis data for climate studies over such regions in East Asia.
S. K. Park, S. Lim, and M. Zupanski
Geosci. Model Dev., 8, 1315–1320, https://doi.org/10.5194/gmd-8-1315-2015, https://doi.org/10.5194/gmd-8-1315-2015, 2015
Short summary
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The structure of an ensemble-based coupled atmosphere-chemistry forecast error covariance is examined using the WRF-Chem, a coupled atmosphere-chemistry model. It is found that the coupled error covariance has important cross-variable components that allow a physically meaningful adjustment of all control variables. Additional benefit of the coupled error covariance is that a cross-component impact is allowed; e.g., atmospheric observations can exert impact on chemistry analysis, and vice versa.
S. Hong, X. Yu, S. K. Park, Y.-S. Choi, and B. Myoung
Geosci. Model Dev., 7, 2517–2529, https://doi.org/10.5194/gmd-7-2517-2014, https://doi.org/10.5194/gmd-7-2517-2014, 2014
K. Apodaca, M. Zupanski, M. DeMaria, J. A. Knaff, and L. D. Grasso
Nonlin. Processes Geophys., 21, 1027–1041, https://doi.org/10.5194/npg-21-1027-2014, https://doi.org/10.5194/npg-21-1027-2014, 2014
Related subject area
Subject: Gases | Research Activity: Atmospheric Modelling and Data Analysis | Altitude Range: Troposphere | Science Focus: Chemistry (chemical composition and reactions)
Estimating the variability in NOx emissions from Wuhan with TROPOMI NO2 data during 2018 to 2023
Enhanced understanding of atmospheric blocking modulation on ozone dynamics within a high-resolution Earth system model
Natural emissions of VOC and NOx over Africa constrained by TROPOMI HCHO and NO2 data using the MAGRITTEv1.1 model
Anthropogenic emission controls reduce summertime ozone–temperature sensitivity in the United States
Investigating the response of China's surface ozone concentration to the future changes of multiple factors
Assessing the relative impacts of satellite ozone and its precursor observations to improve global tropospheric ozone analysis using multiple chemical reanalysis systems
Evaluating present-day and future impacts of agricultural ammonia emissions on atmospheric chemistry and climate
Air-pollution-satellite-based CO2 emission inversion: system evaluation, sensitivity analysis, and future research direction
Insights into ozone pollution control in urban areas by decoupling meteorological factors based on machine learning
Quantification of regional net CO2 flux errors in the Orbiting Carbon Observatory-2 (OCO-2) v10 model intercomparison project (MIP) ensemble using airborne measurements
Reactive nitrogen in and around the northeastern and mid-Atlantic US: sources, sinks, and connections with ozone
Preindustrial-to-present-day changes in atmospheric carbon monoxide: agreement and gaps between ice archives and global model reconstructions
Investigating processes influencing simulation of local Arctic wintertime anthropogenic pollution in Fairbanks, Alaska, during ALPACA-2022
Urban ozone formation and sensitivities to volatile chemical products, cooking emissions, and NOx upwind of and within two Los Angeles Basin cities
Causes of growing middle-to-upper tropospheric ozone over the northwest Pacific region
Impact of introducing electric vehicles on ground-level O3 and PM2.5 in the Greater Tokyo Area: yearly trends and the importance of changes in the urban heat island effect
A CO2–Δ14CO2 inversion setup for estimating European fossil CO2 emissions
Maximum ozone concentrations in the southwestern US and Texas: implications of the growing predominance of the background contribution
Derivation of atmospheric reaction mechanisms for volatile organic compounds by the SAPRC mechanism generation system (MechGen)
Seasonal, regional, and vertical characteristics of high-carbon-monoxide plumes along with their associated ozone anomalies, as seen by IAGOS between 2002 and 2019
The potential of drone observations to improve air quality predictions by 4D-Var
Process analysis of elevated concentrations of organic acids at Whiteface Mountain, New York
Sensitivity of climate-chemistry model simulated atmospheric composition to lightning-produced NOx parameterizations based on lightning frequency
Ozone source attribution in polluted European areas during summer 2017 as simulated with MECO(n)
Surface ozone trend variability across the United States and the impact of heatwaves (1990–2023)
Opinion: Challenges and needs of tropospheric chemical mechanism development
Decrease of the European NOx anthropogenic emissions between 2005 and 2019 as seen from the OMI and TROPOMI NO2 satellite observations
Tracking daily NOx emissions from an urban agglomeration based on TROPOMI NO2 and a local ensemble transform Kalman filter
The atmospheric oxidizing capacity in China – Part 2: Sensitivity to emissions of primary pollutants
Role of chemical production and depositional losses on formaldehyde in the Community Regional Atmospheric Chemistry Multiphase Mechanism (CRACMM)
Review of source analyses of ambient volatile organic compounds considering reactive losses: methods of reducing loss effects, impacts of losses, and sources
Interpreting summertime hourly variation of NO2 columns with implications for geostationary satellite applications
An investigation into atmospheric nitrous acid (HONO) processes in South Korea
Performance evaluation of UKESM1 for surface ozone across the pan-tropics
Constraining light dependency in modeled emissions through comparison to observed biogenic volatile organic compound (BVOC) concentrations in a southeastern US forest
A global re-analysis of regionally resolved emissions and atmospheric mole fractions of SF6 for the period 2005–2021
Monoterpene oxidation pathways initiated by acyl peroxy radical addition
Tropospheric ozone precursors: global and regional distributions, trends, and variability
Sensitivity of climate effects of hydrogen to leakage size, location, and chemical background
The contribution of transport emissions to ozone mixing ratios and methane lifetime in 2015 and 2050 in the Shared Socioeconomic Pathways (SSPs)
Local and transboundary contributions to nitrogen loadings across East Asia using CMAQ-ISAM and GEMS-informed emissions inventory during the winter-spring transition
Ether and ester formation from peroxy radical recombination: a qualitative reaction channel analysis
ACEIC: a comprehensive anthropogenic chlorine emission inventory for China
Impact of methane and other precursor emission reductions on surface ozone in Europe: scenario analysis using the European Monitoring and Evaluation Programme (EMEP) Meteorological Synthesizing Centre – West (MSC-W) model
High-resolution mapping of on-road vehicle emissions with real-time traffic datasets based on big data
Chemistry-climate feedback of atmospheric methane in a methane emission flux driven chemistry-climate model
Verifying national inventory-based combustion emissions of CO2 across the UK and mainland Europe using satellite observations of atmospheric CO and CO2
Revisiting the high tropospheric ozone over Southern Africa: overestimated biomass burning and underestimated anthropogenic emissions
Source contribution to ozone pollution during June 2021 in Arizona: Insights from WRF-Chem tagged O3 and CO
An improved estimate of inorganic iodine emissions from the ocean using a coupled surface microlayer box model
Qianqian Zhang, K. Folkert Boersma, Chiel van der Laan, Alba Mols, Bin Zhao, Shengyue Li, and Yuepeng Pan
Atmos. Chem. Phys., 25, 3313–3326, https://doi.org/10.5194/acp-25-3313-2025, https://doi.org/10.5194/acp-25-3313-2025, 2025
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Accurate NOx emission estimates are required to better understand air pollution. This study investigates and demonstrates the ability of the superposition column model in combination with TROPOMI tropospheric NO2 column data to estimate city-scale NOx emissions and lifetimes and their variabilities. The results of this work nevertheless confirm the strength of the superposition column model in estimating urban NOx emissions with reasonable accuracy.
Wenbin Kou, Yang Gao, Dan Tong, Xiaojie Guo, Xiadong An, Wenyu Liu, Mengshi Cui, Xiuwen Guo, Shaoqing Zhang, Huiwang Gao, and Lixin Wu
Atmos. Chem. Phys., 25, 3029–3048, https://doi.org/10.5194/acp-25-3029-2025, https://doi.org/10.5194/acp-25-3029-2025, 2025
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Unlike traditional numerical studies, we apply a high-resolution Earth system model, improving simulations of surface ozone and large-scale circulations such as atmospheric blocking. Besides local heat waves, we quantify the impact of atmospheric blocking on downstream ozone concentrations, which is closely associated with the blocking position. We identify three major pathways of Rossby wave propagation, stressing the critical role of large-scale circulation in regional air quality.
Beata Opacka, Trissevgeni Stavrakou, Jean-François Müller, Isabelle De Smedt, Jos van Geffen, Eloise A. Marais, Rebekah P. Horner, Dylan B. Millet, Kelly C. Wells, and Alex B. Guenther
Atmos. Chem. Phys., 25, 2863–2894, https://doi.org/10.5194/acp-25-2863-2025, https://doi.org/10.5194/acp-25-2863-2025, 2025
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Vegetation releases biogenic volatile organic compounds, while soils and lightning contribute to the natural emissions of nitrogen oxides into the atmosphere. These gases interact in complex ways. Using satellite data and models, we developed a new method to simultaneously optimize these natural emissions over Africa in 2019. Our approach resulted in an increase in natural emissions, supported by independent data indicating that current estimates are underestimated.
Shuai Li, Haolin Wang, and Xiao Lu
Atmos. Chem. Phys., 25, 2725–2743, https://doi.org/10.5194/acp-25-2725-2025, https://doi.org/10.5194/acp-25-2725-2025, 2025
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Summertime ozone–temperature sensitivity has decreased by 50 % from 3.0 ppbv per K in 1990 to 1.5 ppb per K in 2021 in the US. GEOS-Chem simulations show that anthropogenic nitrogen oxide emission reduction is the dominant driver of ozone–temperature sensitivity decline by influencing both temperature direct and temperature indirect processes. Reduced ozone–temperature sensitivity has decreased ozone enhancement from low to high temperatures by an average of 6.8 ppbv across the US.
Jinya Yang, Yutong Wang, Lei Zhang, and Yu Zhao
Atmos. Chem. Phys., 25, 2649–2666, https://doi.org/10.5194/acp-25-2649-2025, https://doi.org/10.5194/acp-25-2649-2025, 2025
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We develop a modeling framework to predict future ozone concentrations (till the 2060s) in China following an IPCC scenario. We evaluate the contributions of climatic, anthropogenic, and biogenic factors by season and region. We find persistent emission controls will alter the nonlinear response of ozone to its precursors and dominate the declining ozone level. The outcomes highlight the importance of human actions, even with a climate penalty on air quality.
Takashi Sekiya, Emanuele Emili, Kazuyuki Miyazaki, Antje Inness, Zhen Qu, R. Bradley Pierce, Dylan Jones, Helen Worden, William Y. Y. Cheng, Vincent Huijnen, and Gerbrand Koren
Atmos. Chem. Phys., 25, 2243–2268, https://doi.org/10.5194/acp-25-2243-2025, https://doi.org/10.5194/acp-25-2243-2025, 2025
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Five global chemical reanalysis datasets were used to assess the relative impacts of assimilating satellite ozone and its precursor measurements on tropospheric ozone analyses for 2010. The multiple reanalysis system comparison allows an evaluation of the dependency of the impacts on different reanalysis systems. The results suggested the importance of satellite ozone and its precursor measurements for improving ozone analysis in the whole troposphere, with varying magnitudes among the systems.
Maureen Beaudor, Didier Hauglustaine, Juliette Lathière, Martin Van Damme, Lieven Clarisse, and Nicolas Vuichard
Atmos. Chem. Phys., 25, 2017–2046, https://doi.org/10.5194/acp-25-2017-2025, https://doi.org/10.5194/acp-25-2017-2025, 2025
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Agriculture is the biggest ammonia (NH3) source, impacting air quality, climate, and ecosystems. Because of food demand, NH3 emissions are projected to rise by 2100. Using a global model, we analyzed the impact of present and future NH3 emissions generated from a land model. Our results show improved ammonia patterns compared to a reference inventory. Future scenarios predict up to 70 % increase in global NH3 burden, with significant changes in radiative forcing that can greatly elevate N2O.
Hui Li, Jiaxin Qiu, and Bo Zheng
Atmos. Chem. Phys., 25, 1949–1963, https://doi.org/10.5194/acp-25-1949-2025, https://doi.org/10.5194/acp-25-1949-2025, 2025
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We conduct a sensitivity analysis with 31 tests on various factors including prior emissions, model resolution, satellite constraint, and other system configurations to assess the vulnerability of emission estimates across temporal, sectoral, and regional dimensions. This reveals the robustness of emissions estimated by this air-pollution-satellite-based CO2 emission inversion system, with relative change between tests and base inversion below 4.0 % for national annual NOx and CO2 emissions.
Yuqing Qiu, Xin Li, Wenxuan Chai, Yi Liu, Mengdi Song, Xudong Tian, Qiaoli Zou, Wenjun Lou, Wangyao Zhang, Juan Li, and Yuanhang Zhang
Atmos. Chem. Phys., 25, 1749–1763, https://doi.org/10.5194/acp-25-1749-2025, https://doi.org/10.5194/acp-25-1749-2025, 2025
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The chemical reactions of ozone (O3) formation are related to meteorology and local emissions. Here, a random forest approach was used to eliminate the effects of meteorological factors (dispersion or transport) on O3 and its precursors. Variations in the sensitivity of O3 formation and the apportionment of emission sources were revealed after meteorological normalization. Our results suggest that meteorological variations should be considered when diagnosing O3 formation.
Jeongmin Yun, Junjie Liu, Brendan Byrne, Brad Weir, Lesley E. Ott, Kathryn McKain, Bianca C. Baier, Luciana V. Gatti, and Sebastien C. Biraud
Atmos. Chem. Phys., 25, 1725–1748, https://doi.org/10.5194/acp-25-1725-2025, https://doi.org/10.5194/acp-25-1725-2025, 2025
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This study quantifies errors in regional net surface–atmosphere CO2 flux estimates from an inverse model ensemble using airborne CO2 measurements. Our results show that flux error estimates based on observations significantly exceed those computed from the ensemble spread of flux estimates in regions with high fossil fuel emissions. This finding suggests the presence of systematic biases in the inversion estimates, associated with errors in the fossil fuel emissions common to all models.
Min Huang, Gregory R. Carmichael, Kevin W. Bowman, Isabelle De Smedt, Andreas Colliander, Michael H. Cosh, Sujay V. Kumar, Alex B. Guenther, Scott J. Janz, Ryan M. Stauffer, Anne M. Thompson, Niko M. Fedkin, Robert J. Swap, John D. Bolten, and Alicia T. Joseph
Atmos. Chem. Phys., 25, 1449–1476, https://doi.org/10.5194/acp-25-1449-2025, https://doi.org/10.5194/acp-25-1449-2025, 2025
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We use model simulations along with multiplatform, multidisciplinary observations and a range of analysis methods to estimate and understand the distributions, temporal changes, and impacts of reactive nitrogen and ozone over the most populous US region that has undergone significant environmental changes. Deposition, biogenic emissions, and extra-regional sources have been playing increasingly important roles in controlling pollutant budgets in this area as local anthropogenic emissions drop.
Xavier Faïn, Sophie Szopa, Vaishali Naïk, Patricia Martinerie, David M. Etheridge, Rachael H. Rhodes, Cathy M. Trudinger, Vasilii V. Petrenko, Kévin Fourteau, and Philip Place
Atmos. Chem. Phys., 25, 1105–1119, https://doi.org/10.5194/acp-25-1105-2025, https://doi.org/10.5194/acp-25-1105-2025, 2025
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Carbon monoxide (CO) plays a crucial role in the atmosphere's oxidizing capacity. In this study, we analyse how historical (1850–2014) [CO] outputs from state-of-the-art global chemistry–climate models over Greenland and Antarctica are able to capture both absolute values and trends recorded in multi-site ice archives. A disparity in [CO] growth rates emerges in the Northern Hemisphere between models and observations from 1920–1975 CE, possibly linked to uncertainties in CO emission factors.
Natalie Brett, Kathy S. Law, Steve R. Arnold, Javier G. Fochesatto, Jean-Christophe Raut, Tatsuo Onishi, Robert Gilliam, Kathleen Fahey, Deanna Huff, George Pouliot, Brice Barret, Elsa Dieudonné, Roman Pohorsky, Julia Schmale, Andrea Baccarini, Slimane Bekki, Gianluca Pappaccogli, Federico Scoto, Stefano Decesari, Antonio Donateo, Meeta Cesler-Maloney, William Simpson, Patrice Medina, Barbara D'Anna, Brice Temime-Roussel, Joel Savarino, Sarah Albertin, Jingqiu Mao, Becky Alexander, Allison Moon, Peter F. DeCarlo, Vanessa Selimovic, Robert Yokelson, and Ellis S. Robinson
Atmos. Chem. Phys., 25, 1063–1104, https://doi.org/10.5194/acp-25-1063-2025, https://doi.org/10.5194/acp-25-1063-2025, 2025
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Processes influencing dispersion of local anthropogenic pollution in Arctic wintertime are investigated with Lagrangian dispersion modelling. Simulated power plant plume rise that considers temperature inversion layers improves results compared to observations (interior Alaska). Modelled surface concentrations are improved by representation of vertical mixing and emission estimates. Large increases in diesel vehicle emissions at temperatures reaching −35°C are required to reproduce observed NOx.
Chelsea E. Stockwell, Matthew M. Coggon, Rebecca H. Schwantes, Colin Harkins, Bert Verreyken, Congmeng Lyu, Qindan Zhu, Lu Xu, Jessica B. Gilman, Aaron Lamplugh, Jeff Peischl, Michael A. Robinson, Patrick R. Veres, Meng Li, Andrew W. Rollins, Kristen Zuraski, Sunil Baidar, Shang Liu, Toshihiro Kuwayama, Steven S. Brown, Brian C. McDonald, and Carsten Warneke
Atmos. Chem. Phys., 25, 1121–1143, https://doi.org/10.5194/acp-25-1121-2025, https://doi.org/10.5194/acp-25-1121-2025, 2025
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In urban areas, emissions from everyday products like paints, cleaners, and personal care products, along with non-traditional sources such as cooking, are increasingly important and impact air quality. This study uses a box model to evaluate how these emissions impact ozone in the Los Angeles Basin and quantifies the impact of gaseous cooking emissions. Accurate representation of these and other anthropogenic sources in inventories is crucial for informing effective air quality policies.
Xiaodan Ma, Jianping Huang, Michaela I. Hegglin, Patrick Jöckel, and Tianliang Zhao
Atmos. Chem. Phys., 25, 943–958, https://doi.org/10.5194/acp-25-943-2025, https://doi.org/10.5194/acp-25-943-2025, 2025
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Our research explored changes in ozone levels in the northwest Pacific region over 30 years, revealing a significant increase in the middle-to-upper troposphere, especially during spring and summer. This rise is influenced by both stratospheric and tropospheric sources, which affect climate and air quality in East Asia. This work underscores the need for continued study to understand underlying mechanisms.
Hiroo Hata, Norifumi Mizushima, and Tomohiko Ihara
Atmos. Chem. Phys., 25, 1037–1061, https://doi.org/10.5194/acp-25-1037-2025, https://doi.org/10.5194/acp-25-1037-2025, 2025
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The introduction of battery electric vehicles (BEVs) is expected to reduce the primary air pollutants from vehicular exhaust and evaporative emissions while reducing the anthropogenic heat produced by vehicles, ultimately mitigating the urban heat island (UHI) effect. This study revealed the impact of introducing BEVs on the decrease in the UHI effect and the impact of BEVs on the formation of tropospheric ozone and fine particulate matter in the Greater Tokyo Area of Japan.
Carlos Gómez-Ortiz, Guillaume Monteil, Sourish Basu, and Marko Scholze
Atmos. Chem. Phys., 25, 397–424, https://doi.org/10.5194/acp-25-397-2025, https://doi.org/10.5194/acp-25-397-2025, 2025
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In this paper, we test new implementations of our inverse modeling tool to estimate the weekly and regional CO2 emissions from fossil fuels in Europe. We use synthetic atmospheric observations of CO2 and radiocarbon (14CO2) to trace emissions to their sources, while separating the natural and fossil CO2. Our tool accurately estimates fossil CO2 emissions in densely monitored regions like western/central Europe. This approach aids in developing strategies for reducing CO2 emissions.
David D. Parrish, Ian C. Faloona, and Richard G. Derwent
Atmos. Chem. Phys., 25, 263–289, https://doi.org/10.5194/acp-25-263-2025, https://doi.org/10.5194/acp-25-263-2025, 2025
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Observation-based estimates of contributions to maximum ozone (O3) concentrations show that background O3 can exceed the air quality standard of 70 ppb in the southwestern US, precluding standard attainment. Over the past 4 decades, US anthropogenic O3 has decreased by a factor of ~ 6.3, while wildfire contributions have increased, so that the background now dominates maximum concentrations, even in Los Angeles, and the occurrence of maximum O3 has shifted from the eastern to the western US.
William P. L. Carter, Jia Jiang, John J. Orlando, and Kelley C. Barsanti
Atmos. Chem. Phys., 25, 199–242, https://doi.org/10.5194/acp-25-199-2025, https://doi.org/10.5194/acp-25-199-2025, 2025
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This paper describes the scientific basis for gas-phase atmospheric chemical mechanisms derived using the SAPRC mechanism generation system, MechGen. It can derive mechanisms for most organic compounds with C, H, O, or N atoms, including initial reactions of organics with OH, O3, NO3, and O3P or by photolysis, as well as the reactions of the various types of intermediates that are formed. The paper includes a description of areas of uncertainty where additional research and updates are needed.
Thibaut Lebourgeois, Bastien Sauvage, Pawel Wolff, Béatrice Josse, Virginie Marécal, Yasmine Bennouna, Romain Blot, Damien Boulanger, Hannah Clark, Jean-Marc Cousin, Philippe Nedelec, and Valérie Thouret
Atmos. Chem. Phys., 24, 13975–14004, https://doi.org/10.5194/acp-24-13975-2024, https://doi.org/10.5194/acp-24-13975-2024, 2024
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Our study examines intense-carbon-monoxide (CO) pollution events measured by commercial aircraft from the In-service Aircraft for a Global Observing System (IAGOS) research infrastructure. We combine these measurements with the SOFT-IO model to trace the origin of the observed CO. A comprehensive analysis of the geographical origin, source type, seasonal variation, and ozone levels of these pollution events is provided.
Hassnae Erraji, Philipp Franke, Astrid Lampert, Tobias Schuldt, Ralf Tillmann, Andreas Wahner, and Anne Caroline Lange
Atmos. Chem. Phys., 24, 13913–13934, https://doi.org/10.5194/acp-24-13913-2024, https://doi.org/10.5194/acp-24-13913-2024, 2024
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Four-dimensional variational data assimilation allows for the simultaneous optimisation of initial values and emission rates by using trace-gas profiles from drone observations in a regional air quality model. Assimilated profiles positively impact the representation of air pollutants in the model by improving their vertical distribution and ground-level concentrations. This case study highlights the potential of drone data to enhance air quality analyses including local emission evaluation.
Christopher Lawrence, Mary Barth, John Orlando, Paul Casson, Richard Brandt, Daniel Kelting, Elizabeth Yerger, and Sara Lance
Atmos. Chem. Phys., 24, 13693–13713, https://doi.org/10.5194/acp-24-13693-2024, https://doi.org/10.5194/acp-24-13693-2024, 2024
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This work uses chemical transport and box modeling to study the gas- and aqueous-phase production of organic acid concentrations measured in cloud water at the summit of Whiteface Mountain on 1 July 2018. Isoprene was the major source of formic, acetic, and oxalic acid. Gas-phase chemistry greatly underestimated formic and acetic acid, indicating missing sources, while cloud chemistry was a key source of oxalic acid. More studies of organic acids are required to better constrain their sources.
Francisco J. Pérez-Invernón, Francisco J. Gordillo-Vázquez, Heidi Huntrieser, Patrick Jöckel, and Eric J. Bucsela
EGUsphere, https://doi.org/10.5194/egusphere-2024-3348, https://doi.org/10.5194/egusphere-2024-3348, 2024
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Lightning plays a significant role in tropospheric chemistry by producing substantial amounts of nitrogen oxides. According to recent estimates, thunderstorms that produce a higher lightning frequency rate also produce less nitrogen oxide per flash. We implemented the dependency of nitrogen oxide production per flash on lightning flash frequency in a chemical atmospheric model.
Markus Kilian, Volker Grewe, Patrick Jöckel, Astrid Kerkweg, Mariano Mertens, Andreas Zahn, and Helmut Ziereis
Atmos. Chem. Phys., 24, 13503–13523, https://doi.org/10.5194/acp-24-13503-2024, https://doi.org/10.5194/acp-24-13503-2024, 2024
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Anthropogenic emissions are a major source of precursors of tropospheric ozone. As ozone formation is highly non-linear, we apply a global–regional chemistry–climate model with a source attribution method (tagging) to quantify the contribution of anthropogenic emissions to ozone. Our analysis shows that the contribution of European anthropogenic emissions largely increases during large ozone periods, indicating that emissions from these sectors drive ozone values.
Kai-Lan Chang, Brian C. McDonald, and Owen R. Cooper
EGUsphere, https://doi.org/10.5194/egusphere-2024-3674, https://doi.org/10.5194/egusphere-2024-3674, 2024
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Exposure to high levels of ozone can be harmful to human health. This study shows consistent and robust evidence of decreasing ozone extremes across much of the United States over 1990–2023, previously attributed to ozone precursor emission controls. Nevertheless, we also show that the increasing heatwave frequencies are likely to contribute to additional ozone exceedances, slowing the progress of decreasing the frequency of ozone exceedances.
Barbara Ervens, Andrew Rickard, Bernard Aumont, William P. L. Carter, Max McGillen, Abdelwahid Mellouki, John Orlando, Bénédicte Picquet-Varrault, Paul Seakins, William R. Stockwell, Luc Vereecken, and Timothy J. Wallington
Atmos. Chem. Phys., 24, 13317–13339, https://doi.org/10.5194/acp-24-13317-2024, https://doi.org/10.5194/acp-24-13317-2024, 2024
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Chemical mechanisms describe the chemical processes in atmospheric models that are used to describe the changes in the atmospheric composition. Therefore, accurate chemical mechanisms are necessary to predict the evolution of air pollution and climate change. The article describes all steps that are needed to build chemical mechanisms and discusses the advances and needs of experimental and theoretical research activities needed to build reliable chemical mechanisms.
Audrey Fortems-Cheiney, Grégoire Broquet, Robin Plauchu, Elise Potier, Antoine Berchet, Isabelle Pison, Adrien Martinez, Rimal Abeed, Gaelle Dufour, Adriana Coman, Dilek Savas, Guillaume Siour, Henk Eskes, Hugo A. C. Denier van der Gon, and Stijn N. C. Dellaert
EGUsphere, https://doi.org/10.5194/egusphere-2024-3679, https://doi.org/10.5194/egusphere-2024-3679, 2024
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This study assesses the potential of the OMI and TROPOMI satellite observations to inform about the evolution of NOx anthropogenic emissions between year 2005 and year 2019 at the regional to national scales in Europe. Both the OMI and TROPOMI inversions show decreases in European NOx anthropogenic emission budgets between 2005 and 2019, but with different magnitudes.
Yawen Kong, Bo Zheng, and Yuxi Liu
EGUsphere, https://doi.org/10.5194/egusphere-2024-2996, https://doi.org/10.5194/egusphere-2024-2996, 2024
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Current high-resolution satellite remote sensing technologies provide a unique opportunity to derive timely, high-resolution emission data. We developed an emission inversion system to assimilate satellite NO2 data to obtain daily, kilometer-scale NOx emission inventories. Our results enhance inventory accuracy, allowing us to capture the effects of pollution control policies on daily emissions (e.g., during COVID-19 lockdown) and improve fine-scale air quality modeling.
Jianing Dai, Guy P. Brasseur, Mihalis Vrekoussis, Maria Kanakidou, Kun Qu, Yijuan Zhang, Hongliang Zhang, and Tao Wang
Atmos. Chem. Phys., 24, 12943–12962, https://doi.org/10.5194/acp-24-12943-2024, https://doi.org/10.5194/acp-24-12943-2024, 2024
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This paper employs a regional chemical transport model to quantify the sensitivity of air pollutants and photochemical parameters to specified emission reductions in China for representative winter and summer conditions. The study provides insights into further air quality control in China with reduced primary emissions.
T. Nash Skipper, Emma L. D'Ambro, Forwood C. Wiser, V. Faye McNeill, Rebecca H. Schwantes, Barron H. Henderson, Ivan R. Piletic, Colleen B. Baublitz, Jesse O. Bash, Andrew R. Whitehill, Lukas C. Valin, Asher P. Mouat, Jennifer Kaiser, Glenn M. Wolfe, Jason M. St. Clair, Thomas F. Hanisco, Alan Fried, Bryan K. Place, and Havala O.T. Pye
Atmos. Chem. Phys., 24, 12903–12924, https://doi.org/10.5194/acp-24-12903-2024, https://doi.org/10.5194/acp-24-12903-2024, 2024
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We develop the Community Regional Atmospheric Chemistry Multiphase Mechanism (CRACMM) version 2 to improve predictions of formaldehyde in ambient air compared to satellite-, aircraft-, and ground-based observations. With the updated chemistry, we estimate the cancer risk from inhalation exposure to ambient formaldehyde across the contiguous USA and predict that 40 % of this risk is controllable through reductions in anthropogenic emissions of nitrogen oxides and reactive organic carbon.
Baoshuang Liu, Yao Gu, Yutong Wu, Qili Dai, Shaojie Song, Yinchang Feng, and Philip K. Hopke
Atmos. Chem. Phys., 24, 12861–12879, https://doi.org/10.5194/acp-24-12861-2024, https://doi.org/10.5194/acp-24-12861-2024, 2024
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Reactive loss of volatile organic compounds (VOCs) is a long-term issue yet to be resolved in VOC source analyses. We assess common methods of, and existing issues in, reducing losses, impacts of losses, and sources in current source analyses. We offer a potential supporting role for solving issues of VOC conversion. Source analyses of consumed VOCs that reacted to produce ozone and secondary organic aerosols can play an important role in the effective control of secondary pollution in air.
Deepangsu Chatterjee, Randall V. Martin, Chi Li, Dandan Zhang, Haihui Zhu, Daven K. Henze, James H. Crawford, Ronald C. Cohen, Lok N. Lamsal, and Alexander M. Cede
Atmos. Chem. Phys., 24, 12687–12706, https://doi.org/10.5194/acp-24-12687-2024, https://doi.org/10.5194/acp-24-12687-2024, 2024
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We investigate the hourly variation of NO2 columns and surface concentrations by applying the GEOS-Chem model to interpret aircraft and ground-based measurements over the US and Pandora sun photometer measurements over the US, Europe, and Asia. Corrections to the Pandora columns and finer model resolution improve the modeled representation of the summertime hourly variation of total NO2 columns to explain the weaker hourly variation in NO2 columns than at the surface.
Kiyeon Kim, Kyung Man Han, Chul Han Song, Hyojun Lee, Ross Beardsley, Jinhyeok Yu, Greg Yarwood, Bonyoung Koo, Jasper Madalipay, Jung-Hun Woo, and Seogju Cho
Atmos. Chem. Phys., 24, 12575–12593, https://doi.org/10.5194/acp-24-12575-2024, https://doi.org/10.5194/acp-24-12575-2024, 2024
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We incorporated each HONO process into the current CMAQ modeling framework to enhance the accuracy of HONO mixing ratio predictions. These results expand our understanding of HONO photochemistry and identify crucial sources of HONO that impact the total HONO budget in Seoul, South Korea. Through this investigation, we contribute to resolving discrepancies in understanding chemical transport models, with implications for better air quality management and environmental protection in the region.
Flossie Brown, Gerd Folberth, Stephen Sitch, Paulo Artaxo, Marijn Bauters, Pascal Boeckx, Alexander W. Cheesman, Matteo Detto, Ninong Komala, Luciana Rizzo, Nestor Rojas, Ines dos Santos Vieira, Steven Turnock, Hans Verbeeck, and Alfonso Zambrano
Atmos. Chem. Phys., 24, 12537–12555, https://doi.org/10.5194/acp-24-12537-2024, https://doi.org/10.5194/acp-24-12537-2024, 2024
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Ozone is a pollutant that is detrimental to human and plant health. Ozone monitoring sites in the tropics are limited, so models are often used to understand ozone exposure. We use measurements from the tropics to evaluate ozone from the UK Earth system model, UKESM1. UKESM1 is able to capture the pattern of ozone in the tropics, except in southeast Asia, although it systematically overestimates it at all sites. This work highlights that UKESM1 can capture seasonal and hourly variability.
Namrata Shanmukh Panji, Deborah F. McGlynn, Laura E. R. Barry, Todd M. Scanlon, Manuel T. Lerdau, Sally E. Pusede, and Gabriel Isaacman-VanWertz
Atmos. Chem. Phys., 24, 12495–12507, https://doi.org/10.5194/acp-24-12495-2024, https://doi.org/10.5194/acp-24-12495-2024, 2024
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Climate change will bring about changes in parameters that are currently used in global-scale models to calculate biogenic emissions. This study seeks to understand the factors driving these models by comparing long-term datasets of biogenic compounds to modeled emissions. We note that the light-dependent fractions currently used in models do not accurately represent regional observations. We provide evidence for the time-dependent variation in this parameter for future modifications to models.
Martin Vojta, Andreas Plach, Saurabh Annadate, Sunyoung Park, Gawon Lee, Pallav Purohit, Florian Lindl, Xin Lan, Jens Mühle, Rona L. Thompson, and Andreas Stohl
Atmos. Chem. Phys., 24, 12465–12493, https://doi.org/10.5194/acp-24-12465-2024, https://doi.org/10.5194/acp-24-12465-2024, 2024
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We constrain the global emissions of the very potent greenhouse gas sulfur hexafluoride (SF6) between 2005 and 2021. We show that SF6 emissions are decreasing in the USA and in the EU, while they are substantially growing in China, leading overall to an increasing global emission trend. The national reports for the USA, EU, and China all underestimated their SF6 emissions. However, stringent mitigation measures can successfully reduce SF6 emissions, as can be seen in the EU emission trend.
Dominika Pasik, Thomas Golin Almeida, Emelda Ahongshangbam, Siddharth Iyer, and Nanna Myllys
EGUsphere, https://doi.org/10.5194/egusphere-2024-3464, https://doi.org/10.5194/egusphere-2024-3464, 2024
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We used quantum chemistry methods to investigate the oxidation mechanisms of acyl peroxy radicals (APRs) with various monoterpenes. Our findings reveal unique oxidation pathways for different monoterpenes, leading to either chain-terminating products or highly reactive intermediates that can contribute to particle formation in the atmosphere. This research highlights APRs as potentially significant but underexplored atmospheric oxidants, which may influence future approaches to modeling climate.
Yasin Elshorbany, Jerald R. Ziemke, Sarah Strode, Hervé Petetin, Kazuyuki Miyazaki, Isabelle De Smedt, Kenneth Pickering, Rodrigo J. Seguel, Helen Worden, Tamara Emmerichs, Domenico Taraborrelli, Maria Cazorla, Suvarna Fadnavis, Rebecca R. Buchholz, Benjamin Gaubert, Néstor Y. Rojas, Thiago Nogueira, Thérèse Salameh, and Min Huang
Atmos. Chem. Phys., 24, 12225–12257, https://doi.org/10.5194/acp-24-12225-2024, https://doi.org/10.5194/acp-24-12225-2024, 2024
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We investigated tropospheric ozone spatial variability and trends from 2005 to 2019 and related those to ozone precursors on global and regional scales. We also investigate the spatiotemporal characteristics of the ozone formation regime in relation to ozone chemical sources and sinks. Our analysis is based on remote sensing products of the tropospheric column of ozone and its precursors, nitrogen dioxide, formaldehyde, and total column CO, as well as ozonesonde data and model simulations.
Ragnhild Bieltvedt Skeie, Marit Sandstad, Srinath Krishnan, Gunnar Myhre, and Maria Sand
EGUsphere, https://doi.org/10.5194/egusphere-2024-3079, https://doi.org/10.5194/egusphere-2024-3079, 2024
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Hydrogen leakages can alter the amount of climate gases in the atmosphere and hence have a climate impact. In this study we investigate, using an atmospheric chemistry model, how this indirect climate effect differs for different amounts of leakages, where the hydrogen leaks and if this effect changes in the future. The effect is largest for emissions far from areas where hydrogen is removed from the atmosphere by the soil, but these are not relevant locations for a future hydrogen economy.
Mariano Mertens, Sabine Brinkop, Phoebe Graf, Volker Grewe, Johannes Hendricks, Patrick Jöckel, Anna Lanteri, Sigrun Matthes, Vanessa S. Rieger, Mattia Righi, and Robin N. Thor
Atmos. Chem. Phys., 24, 12079–12106, https://doi.org/10.5194/acp-24-12079-2024, https://doi.org/10.5194/acp-24-12079-2024, 2024
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We quantified the contributions of land transport, shipping, and aviation emissions to tropospheric ozone; its radiative forcing; and the reductions of the methane lifetime using chemistry-climate model simulations. The contributions were analysed for the conditions of 2015 and for three projections for the year 2050. The results highlight the challenges of mitigating ozone formed by emissions of the transport sector, caused by the non-linearitiy of the ozone chemistry and the long lifetime.
Jincheol Park, Yunsoo Choi, and Sagun Kayastha
EGUsphere, https://doi.org/10.5194/egusphere-2024-3312, https://doi.org/10.5194/egusphere-2024-3312, 2024
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We investigated NOx emissions’ contributions to nitrogen loadings across five regions of East Asia during the 2022 winter-spring transition through chemical transport modeling informed by satellite data. As seasons progress, local contributions within each region to its NOy budget decreased from 32 %–43 % to 23 %–30 %, while transboundary contributions increased from 16 %–33 % to 27 %–37 %, driven by a shift in synoptic settings that allowed pollutants to spread more broadly across the regions.
Lauri Franzon, Marie Camredon, Richard Valorso, Bernard Aumont, and Theo Kurtén
Atmos. Chem. Phys., 24, 11679–11699, https://doi.org/10.5194/acp-24-11679-2024, https://doi.org/10.5194/acp-24-11679-2024, 2024
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In this article we investigate the formation of large, sticky molecules from various organic compounds entering the atmosphere as primary emissions and the degree to which these processes may contribute to organic aerosol particle mass. More specifically, we qualitatively investigate a recently discovered chemical reaction channel for one of the most important short-lived radical compounds, peroxy radicals, and discover which of these reactions are most atmospherically important.
Siting Li, Yiming Liu, Yuqi Zhu, Yinbao Jin, Yingying Hong, Ao Shen, Yifei Xu, Haofan Wang, Haichao Wang, Xiao Lu, Shaojia Fan, and Qi Fan
Atmos. Chem. Phys., 24, 11521–11544, https://doi.org/10.5194/acp-24-11521-2024, https://doi.org/10.5194/acp-24-11521-2024, 2024
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This study establishes an inventory of anthropogenic chlorine emissions in China in 2019 with expanded species (HCl, Cl-, Cl2, HOCl) and sources (41 specific sources). The inventory is validated by a modeling study against the observations. This study enhances the understanding of anthropogenic chlorine emissions in the atmosphere, identifies key sources, and provides scientific support for pollution control and climate change.
Willem E. van Caspel, Zbigniew Klimont, Chris Heyes, and Hilde Fagerli
Atmos. Chem. Phys., 24, 11545–11563, https://doi.org/10.5194/acp-24-11545-2024, https://doi.org/10.5194/acp-24-11545-2024, 2024
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Methane in the atmosphere contributes to the production of ozone gas – an air pollutant and greenhouse gas. Our results highlight that simultaneous reductions in methane emissions help avoid offsetting the air pollution benefits already achieved by the already-approved precursor emission reductions by 2050 in the European Monitoring and Evaluation Programme region, while also playing an important role in bringing air pollution further down towards World Health Organization guideline limits.
Yujia Wang, Hongbin Wang, Bo Zhang, Peng Liu, Xinfeng Wang, Shuchun Si, Likun Xue, Qingzhu Zhang, and Qiao Wang
EGUsphere, https://doi.org/10.5194/egusphere-2024-2791, https://doi.org/10.5194/egusphere-2024-2791, 2024
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This study established a bottom-up approach that employs real-time traffic flows and interpolation to obtain a spatially continuous on-road vehicle emission mapping for the main urban area of Jinan. The diurnal variation, spatial distribution, and emission hotspots were analyzed with clustering and hotspot analysis, showing unique fine-scale variation characteristics of on-road vehicle emissions. Future scenario analysis demonstrates remarkable benefits of electrification on emission reduction.
Laura Stecher, Franziska Winterstein, Patrick Jöckel, Michael Ponater, Mariano Mertens, and Martin Dameris
EGUsphere, https://doi.org/10.5194/egusphere-2024-2938, https://doi.org/10.5194/egusphere-2024-2938, 2024
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Methane, the second most important anthropogenic greenhouse gas, is chemically decomposed in the atmosphere. The chemical sink of atmospheric methane is not constant, but depends on the temperature and on the abundance of its reaction partners. In this study, we use a global chemistry-climate model to assess the feedback of atmospheric methane induced by changes of the chemical sink in a warming climate, and its implications for the chemical composition and the surface air temperature change.
Tia R. Scarpelli, Paul I. Palmer, Mark Lunt, Ingrid Super, and Arjan Droste
Atmos. Chem. Phys., 24, 10773–10791, https://doi.org/10.5194/acp-24-10773-2024, https://doi.org/10.5194/acp-24-10773-2024, 2024
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Under the Paris Agreement, countries must track their anthropogenic greenhouse gas emissions. This study describes a method to determine self-consistent estimates for combustion emissions and natural fluxes of CO2 from atmospheric data. We report consistent estimates inferred using this approach from satellite data and ground-based data over Europe, suggesting that satellite data can be used to determine national anthropogenic CO2 emissions for countries where ground-based CO2 data are absent.
Yufen Wang, Ke Li, Xi Chen, Zhenjiang Yang, Minglong Tang, Pascoal M. D. Campos, Yang Yang, Xu Yue, and Hong Liao
EGUsphere, https://doi.org/10.5194/egusphere-2024-2576, https://doi.org/10.5194/egusphere-2024-2576, 2024
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The impact of biomass burning and anthropogenic emissions on high tropospheric ozone was not well studied in Southern Africa. We combined the model simulation with recent observations at the surface and from space to quantify tropospheric ozone and its main drivers in Southern Africa. Our work focuses on the impact of emissions from different sources at different spatial scales, contributing to a comprehensive understanding of air pollution drivers and their uncertainties in Southern Africa.
Yafang Guo, Mohammad Amin Mirrezaei, Armin Sorooshian, and Avelino F. Arellano
EGUsphere, https://doi.org/10.5194/egusphere-2024-2617, https://doi.org/10.5194/egusphere-2024-2617, 2024
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We assess the contributions of fire and anthropogenic emissions to O3 levels in Phoenix Arizona during a period of intense heat and drought conditions. We find that fire exacerbates O3 pollution and that interactions between weather, climate, and air chemistry are important to consider. This has implications to activities related to formulating emission reduction strategies in areas that are currently under-studied yet becoming relevant due to reports of increasing global aridity.
Ryan J. Pound, Lucy V. Brown, Mat J. Evans, and Lucy J. Carpenter
Atmos. Chem. Phys., 24, 9899–9921, https://doi.org/10.5194/acp-24-9899-2024, https://doi.org/10.5194/acp-24-9899-2024, 2024
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Iodine-mediated loss of ozone to the ocean surface and the subsequent emission of iodine species has a large effect on the troposphere. Here we combine recent experimental insights to develop a box model of the process, which we then parameterize and incorporate into the GEOS-Chem transport model. We find that these new insights have a small impact on the total emission of iodine but significantly change its distribution.
Cited articles
Apodaca, K., Zupanski, M., DeMaria, M., Knaff, J. A., and Grasso, L. D.: Development of a hybrid variational-ensemble data assimilation technique for observed lightning tested in a mesoscale model, Nonlin. Processes Geophys., 21, 1027–1041, https://doi.org/10.5194/npg-21-1027-2014, 2014.
Buehner, M.: Ensemble-derived stationary and flow-dependent background-error covariances, Q. J. Roy. Meteor. Soc., 131, 1013–1043, 2005.
Carmichael, G. R., Sandu, A., Chai, T., Daescu, D. N., Constantinescu, E. M., and Tang, Y.: Predicting air quality: improvements through advanced methods to integrate models and measurements, J. Comput. Phys., 227, 3540–3571, 2008.
Carsey, T. P. and Willoughby, H. E.: Ozone measurements from eyewall transects of two Atlantic tropical cyclones, Mon. Weather Rev., 133, 166–174, 2005.
Chapman, E. G., Gustafson Jr., W. I., Easter, R. C., Barnard, J. C., Ghan, S. J., Pekour, M. S., and Fast, J. D.: Coupling aerosol-cloud-radiative processes in the WRF-Chem model: Investigating the radiative impact of elevated point sources, Atmos. Chem. Phys., 9, 945–964, https://doi.org/10.5194/acp-9-945-2009, 2009.
Elbern, H. and Schmidt, H.: A four-dimensional variational chemistry data assimilation scheme for Eulerian chemistry transport modeling, J. Geophys. Res., 104, 18583–18598, 1999.
Evensen, G.: The ensemble Kalman filter: theoretical formulation and practical implementation, Ocean Dynam., 53, 343–367, 2003.
Fast, J. D., Gustafson Jr., W. I., Easter, R. C., Zaveri, R. A., Barnard, J. C., Chapman, E. G., Grell, G. A., and Peckham, S. E.: Evolution of ozone, particulates, and aerosol direct radiative forcing in the vicinity of Houston using a fully coupled meteorology-chemistry-aerosol model, J. Geophys. Res., 111, D21305, https://doi.org/10.1029/2005JD006721, 2006.
Fletcher, S. J. and Zupanski, M.: A data assimilation method for log-normally distributed observational errors, Q. J. Roy. Meteor. Soc., 132, 2505–2519, 2006.
Grell, G. A., Peckham, S. E., Schmitz, R., McKeen, S. A., Frost, G., Skamarock, W. C., and Eder, B.: Fully coupled "online" chemistry within the WRF model, Atmos. Environ., 39, 6957–6975, 2005.
Houtekamer, P. L. and Mitchell, H. L.: Data assimilation using an ensemble Kalman filter technique, Mon. Weather Rev., 126, 796–811, 1998.
Jang, K. I., Zou, X., De Pondeca, M. S. F. V., Shapiro, M., Davis, C., and Krueger, A.: Incorporating TOMS ozone measurements into the prediction of the Washington, DC, winter storm during 24–25 January 2000, J. Appl. Meteorol., 42, 797–812, 2003.
Kalnay, E.: Atmospheric Modeling, Data Assimilation and Predictability, Cambridge University Press, New York, USA, 364 pp., 2002.
Kim, H. H., Park, S. K., Zupanski, D., and Zupanski, M.: 2010: Uncertainty analysis using the maximum likelihood ensemble filter and WRF and comparison with dropwindsonde observations in Typhoon Sinlaku (2008), Asia-Pac. J. Atmos. Sci., 46, 317–325, 2010.
Lahoz, W. A., Errera, Q., Swinbank, R., and Fonteyn, D.: Data assimilation of stratospheric constituents: a review, Atmos. Chem. Phys., 7, 5745–5773, https://doi.org/10.5194/acp-7-5745-2007, 2007.
Lokupitiya, R. S., Zupanski, D., Denning, A. S., Kawa, S. R., Gurney, K. R., and Zupanski, M.: Estimation of global CO2 fluxes at regional scale using the maximum likelihood ensemble filter, J. Geophys. Res., 113, D20110, https://doi.org/10.1029/2007JD009679, 2008.
Meena, G. S., Bhosale, C. S., and Jadhav, D. B.: Retrieval of stratospheric O3 and NO2 vertical profiles using zenith scattered light observations, J. Earth Syst. Sci., 115, 333–347, 2006.
Navon, I. M.: Data assimilation for numerical weather prediction: a review, in: Data Assimilation for Atmospheric, Oceanic and Hydrologic Applications, edited by: Park, S. K. and Xu, L., Springer, Berlin, Heidelberg, Germany, 21–65, 2009.
Ohara, T., Akimoto, H., Kurokawa, J., Horii, N., Yamaji, K., Yan, X., and Hayasaka, T.: An Asian emission inventory of anthropogenic emission sources for the period 1980–2020, Atmos. Chem. Phys., 7, 4419–4444, https://doi.org/10.5194/acp-7-4419-2007, 2007.
OMI Team: Ozone Monitoring Instrument (OMI) Data User's Guide, NASA, Greenbelt, USA, 62, 2012.
Park, S. K. and Zupanski, D.: Four-dimensional variational data assimilation for mesoscale and storm-scale applications, Meteorol. Atmos. Phys., 82, 173–208, 2003.
Park, S. K., Lim, S., and Zupanski, M.: Structure of forecast error covariance in coupled atmosphere–chemistry data assimilation, Geosci. Model Dev., 8, 1315–1320, https://doi.org/10.5194/gmd-8-1315-2015, 2015.
Richter, A., Burrows, J. P., Nüß, H., Granier, C., and Niemeier, U.: Increase in tropospheric nitrogen dioxide over China observed from space, Nature, 437, 129–132, 2005.
Rodgers, C. D.: Inverse Methods for Atmospheric Sounding: theory and Practice, World Scientific, Singapore, 256 pp., 2000.
Rodgers, E. B., Stout, J., Steranka, J., and Chang, S.: Tropical cyclone-upper atmospheric interaction as inferred from satellite total ozone observations, J. Appl. Meteorol., 29, 934–954, 1990.
Silver, J. D., Brandt, J., Hvidberg, M., Frydendall, J., and Christensen, J. H.: Assimilation of OMI NO2 retrievals into the limited-area chemistry-transport model DEHM (V2009.0) with a 3-D OI algorithm, Geosci. Model Dev., 6, 1–16, https://doi.org/10.5194/gmd-6-1-2013, 2013.
Skamarock, W. C., Klemp, J. B., Dudhia, J., Gill, D. O., Barker, D. M., Duda, M. G., Huang, X.-Y., Wang, W., and Powers, J. G.: A description of the Advanced Research WRF version 3. NCAR/TN-475+ STR, National Center For Atmospheric Research, Boulder, CO, USA, 113 pp., 2008.
Stout, J. and Rodgers, E. B.: Nimbus-7 total ozone observations of western North Pacific tropical cyclones, J. Appl. Meteorol., 31, 758–783, 1992.
Tran, A. P., Vanclooster, M., Zupanski, M., and Lambot, S.: Joint estimation of soil moisture profile and hydraulic parameters by ground-penetrating radar data assimilation with maximum likelihood ensemble filter, Water Resour. Res., 50, 3131–3146, https://doi.org/10.1002/2013WR014583, 2014.
Wang, K.-Y., Lary, D. J., Shallcross, D. E., Hall, S. M., and Pyle, J. A.: A review on the use of the adjoint method in four-dimensional atmospheric–chemistry data assimilation, Q. J. Roy. Meteor. Soc., 127, 2181–2204, 2001.
Wu, Y. and Zou, X.: Numerical test of a simple approach for using TOMS total ozone data in hurricane environment, Q. J. Roy. Meteor. Soc., 134, 1397–1408, 2008.
Yang, Q., W. I. Gustafson Jr., Fast, J. D., Wang, H., Easter, R. C., Morrison, H., Lee, Y.-N., Chapman, E. G., Spak, S. N., and Mena-Carrasco, M. A.: Assessing regional scale predictions of aerosols, marine stratocumulus, and their interactions during VOCALS-REx using WRF-Chem, Atmos. Chem. Phys., 11, 11951–11975, https://doi.org/10.5194/acp-11-11951-2011, 2011.
Zhang, R., Sanger, N. T., Orville, R. E., Tie, X., Randel, W., and Williams, E. R.: Enhanced NOx by lightning in the upper troposphere and lower stratosphere inferred from the UARS global NO2 measurements, Geophys. Res. Lett., 27, 685–688, 2000.
Zhang, S. Q., Zupanski, M., Hou, A. Y., Lin, X., and Cheung, S. H.: Assimilation of precipitation-affected radiances in a cloud-resolving WRF ensemble data assimilation system, Mon. Weather Rev., 141, 754–772, 2013.
Zou, X. and Wu, Y.: On the relationship between Total Ozone Mapping Spectrometer (TOMS) ozone and hurricanes, J. Geophys. Res.–Atmos., 110, D06109, https://doi.org/10.1029/2004JD005019, 2005.
Zupanski, D. and Zupanski, M.: Model error estimation employing an ensemble data assimilation approach, Mon. Weather Rev., 134, 1337–1354, 2006.
Zupanski, D., Denning, A. S., Uliasz, M., Zupanski, M., Schuh, A. E., Rayner, P. J., Peters, W., and Corbin, K. D.: Carbon flux bias estimation employing Maximum Likelihood Ensemble Filter (MLEF), J. Geophys. Res., 112, D17107, https://doi.org/10.1029/2006JD008371, 2007a.
Zupanski, D., Hou, A. Y., Zhang, S. Q., Zupanski, M., Kummerow, C. D., and Cheung, S. H.: Applications of information theory in ensemble data assimilation, Q. J. Roy. Meteor. Soc., 133, 1533–1545, 2007b.
Zupanski, M.: Maximum likelihood ensemble filter: theoretical aspects, Mon. Weather Rev., 133, 1710–1726, 2005.
Zupanski, M.: Theoretical and practical issues of ensemble data assimilation in weather and climate, in: Data Assimilation for Atmospheric, Oceanic and Hydrologic Applications, edited by: Park, S. K. and Xu, L., Springer, Berlin, Heidelberg, Germany, 67–84, 2009.
Zupanski, M., Navon, I. M., and Zupanski, D.: The Maximum Likelihood Ensemble Filter as a non-differentiable minimization algorithm, Q. J. Roy. Meteor. Soc., 134, 1039–1050, 2008.
Short summary
In this study, the impact of O3 observations on the tropical cyclone (TC) structure is examined using the WRF-Chem with an ensemble-based data assimilation (DA) system. For a TC case that occurred over East Asia, the ensemble forecast is reasonable and the O3 assimilation affects both chemical and atmospheric variables near the TC area. All measures indicate a positive impact of DA on the analysis – the cost function and root mean square error have decreased by 16.9% and 8.87%, respectively.
In this study, the impact of O3 observations on the tropical cyclone (TC) structure is examined...
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