Articles | Volume 14, issue 1
https://doi.org/10.5194/acp-14-255-2014
© Author(s) 2014. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-14-255-2014
© Author(s) 2014. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
09 Jan 2014
Research article |
| 09 Jan 2014
Direct estimation of the rate constant of the reaction ClO + HO2 → HOCl + O2 from SMILES atmospheric observations
K. Kuribayashi
Tokyo Institute of Technology, 4259 Nagatsuta-cho, Midori-ku, Yokohama, Kanagawa 226-8503, Japan
National Institute of Information and Communications Technology (NICT), Nukui-kita, Koganei, Tokyo, 184-8795, Japan
H. Sagawa
National Institute of Information and Communications Technology (NICT), Nukui-kita, Koganei, Tokyo, 184-8795, Japan
R. Lehmann
Alfred Wegener Institute for Polar and Marine Research, Potsdam, Germany
T. O. Sato
Tokyo Institute of Technology, 4259 Nagatsuta-cho, Midori-ku, Yokohama, Kanagawa 226-8503, Japan
National Institute of Information and Communications Technology (NICT), Nukui-kita, Koganei, Tokyo, 184-8795, Japan
Y. Kasai
Tokyo Institute of Technology, 4259 Nagatsuta-cho, Midori-ku, Yokohama, Kanagawa 226-8503, Japan
National Institute of Information and Communications Technology (NICT), Nukui-kita, Koganei, Tokyo, 184-8795, Japan
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Seidai Nara, Tomohiro O. Sato, Takayoshi Yamada, Tamaki Fujinawa, Kota Kuribayashi, Takeshi Manabe, Lucien Froidevaux, Nathaniel J. Livesey, Kaley A. Walker, Jian Xu, Franz Schreier, Yvan J. Orsolini, Varavut Limpasuvan, Nario Kuno, and Yasuko Kasai
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Richard Larsson, Yasuko Kasai, Takeshi Kuroda, Shigeru Sato, Takayoshi Yamada, Hiroyuki Maezawa, Yutaka Hasegawa, Toshiyuki Nishibori, Shinichi Nakasuka, and Paul Hartogh
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We are planning a Mars mission. The mission will carry an instrument capable of measuring and mapping molecular oxygen and water in the Martian atmosphere, as well as the temperature, wind, and magnetic field. Water and oxygen are vital parts of the Martian atmospheric chemistry and must be better understood. Using computer simulation results, the paper gives a description of how the measurements will work, some problems we expect to encounter, and the sensitivity of the measurements.
Philippe Baron, Donal Murtagh, Patrick Eriksson, Jana Mendrok, Satoshi Ochiai, Kristell Pérot, Hideo Sagawa, and Makoto Suzuki
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Farahnaz Khosrawi, Stefan Lossow, Gabriele P. Stiller, Karen H. Rosenlof, Joachim Urban, John P. Burrows, Robert P. Damadeo, Patrick Eriksson, Maya García-Comas, John C. Gille, Yasuko Kasai, Michael Kiefer, Gerald E. Nedoluha, Stefan Noël, Piera Raspollini, William G. Read, Alexei Rozanov, Christopher E. Sioris, Kaley A. Walker, and Katja Weigel
Atmos. Meas. Tech., 11, 4435–4463, https://doi.org/10.5194/amt-11-4435-2018, https://doi.org/10.5194/amt-11-4435-2018, 2018
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Time series of stratospheric and lower mesospheric water vapour using 33 data sets from 15 satellite instruments were compared in the framework of the second SPARC water vapour assessment. We find that most data sets can be considered in observational and modelling studies addressing, e.g. stratospheric and lower mesospheric water vapour variability and trends if data-set-specific characteristics (e.g. a drift) and restrictions (e.g. temporal and spatial coverage) are taken into account.
Tomohiro O. Sato, Takao M. Sato, Hideo Sagawa, Katsuyuki Noguchi, Naoko Saitoh, Hitoshi Irie, Kazuyuki Kita, Mona E. Mahani, Koji Zettsu, Ryoichi Imasu, Sachiko Hayashida, and Yasuko Kasai
Atmos. Meas. Tech., 11, 1653–1668, https://doi.org/10.5194/amt-11-1653-2018, https://doi.org/10.5194/amt-11-1653-2018, 2018
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Air pollution is one of the world's greatest environmental health risks. Ozone adversely affects human health and agricultural production, and the tropospheric ozone has been increasing globally over the past few decades. We report an advanced method to derive the ozone amount in the lowermost troposphere using multi-spectral measurements (UV, thermal infrared and microwave). Combining the MW measurement with the UV and thermal infrared measurements certainly increased the sensitivity.
Daniel Kreyling, Ingo Wohltmann, Ralph Lehmann, and Markus Rex
Geosci. Model Dev., 11, 753–769, https://doi.org/10.5194/gmd-11-753-2018, https://doi.org/10.5194/gmd-11-753-2018, 2018
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Rolf Müller, Jens-Uwe Grooß, Abdul Mannan Zafar, Sabine Robrecht, and Ralph Lehmann
Atmos. Chem. Phys., 18, 2985–2997, https://doi.org/10.5194/acp-18-2985-2018, https://doi.org/10.5194/acp-18-2985-2018, 2018
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This paper revisits the chemistry leading to strong ozone depletion in the Antarctic. We focus on the heart of the ozone layer in the lowermost stratosphere in the core of the vortex. We argue that chemical cycles (referred to as HCl null cycles) that have hitherto been largely neglected counteract the deactivation of chlorine and are therefore key to ozone depletion in the core of the Antarctic vortex. The key process to full activation of chlorine is the photolysis of formaldehyde.
Ingo Wohltmann, Ralph Lehmann, and Markus Rex
Atmos. Chem. Phys., 17, 10535–10563, https://doi.org/10.5194/acp-17-10535-2017, https://doi.org/10.5194/acp-17-10535-2017, 2017
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We present a quantitative analysis of the chemical reactions involved in polar ozone depletion in the stratosphere, and of the relevant reaction pathways and cycles. We show time series of reaction rates averaged over the core of the polar vortex in winter and spring for all relevant reactions. An emphasis is put on the partitioning of the relevant chemical families (nitrogen, hydrogen, chlorine, bromine and odd oxygen) and activation and deactivation of chlorine.
Ingo Wohltmann, Ralph Lehmann, and Markus Rex
Geosci. Model Dev., 10, 2671–2689, https://doi.org/10.5194/gmd-10-2671-2017, https://doi.org/10.5194/gmd-10-2671-2017, 2017
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The Polar SWIFT model is a fast scheme for calculating the chemistry of stratospheric ozone depletion in polar winter. It is intended for use in global climate models (GCMs) and Earth system models (ESMs) to enable the simulation of mutual interactions between the ozone layer and climate.
Richard Larsson, Mathias Milz, Patrick Eriksson, Jana Mendrok, Yasuko Kasai, Stefan Alexander Buehler, Catherine Diéval, David Brain, and Paul Hartogh
Geosci. Instrum. Method. Data Syst., 6, 27–37, https://doi.org/10.5194/gi-6-27-2017, https://doi.org/10.5194/gi-6-27-2017, 2017
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By computer simulations, we explore and quantify how to use radiation emitted by molecular oxygen in the Martian atmosphere to measure the magnetic field from the crust of the planet. This crustal magnetic field is important to understand the past evolution of Mars. Our method can measure the magnetic field at lower altitudes than has so far been done, which could give important information on the characteristics of the crustal sources if a mission with the required instrument is launched.
Hideaki Nakajima, Ingo Wohltmann, Tobias Wegner, Masanori Takeda, Michael C. Pitts, Lamont R. Poole, Ralph Lehmann, Michelle L. Santee, and Markus Rex
Atmos. Chem. Phys., 16, 3311–3325, https://doi.org/10.5194/acp-16-3311-2016, https://doi.org/10.5194/acp-16-3311-2016, 2016
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This paper presents the first trial of analyzing amount of chlorine activation on different PSC compositions by using match analysis on trajectories initiated from PSC locations identified by CALIPSO/CALIOP measurements. The measured minor species such as HCl and ClO by MLS are compared with ATLAS chemistry-transport model (CTM) results. PSC growth to NAT, NAT/STS mixture, and ice were identified by different temperature decrease histories on trajectories.
L. Di Liberto, R. Lehmann, I. Tritscher, F. Fierli, J. L. Mercer, M. Snels, G. Di Donfrancesco, T. Deshler, B. P. Luo, J-U. Grooß, E. Arnone, B. M. Dinelli, and F. Cairo
Atmos. Chem. Phys., 15, 6651–6665, https://doi.org/10.5194/acp-15-6651-2015, https://doi.org/10.5194/acp-15-6651-2015, 2015
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We investigated chemical and microphysical processes in the late winter Antarctic stratosphere, for the first time (to our knowledge) coupling a detailed microphysical box model to a chemistry model.
Model results have been compared with in situ and remote sensing measurements of particles along trajectories.
Our goal is to contribute to the most recent discussion of the relative role of PSC and liquid (background) aerosol in the ozone depletion.
L. Millán, S. Wang, N. Livesey, D. Kinnison, H. Sagawa, and Y. Kasai
Atmos. Chem. Phys., 15, 2889–2902, https://doi.org/10.5194/acp-15-2889-2015, https://doi.org/10.5194/acp-15-2889-2015, 2015
A. Schanz, K. Hocke, N. Kämpfer, S. Chabrillat, A. Inness, M. Palm, J. Notholt, I. Boyd, A. Parrish, and Y. Kasai
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acpd-14-32667-2014, https://doi.org/10.5194/acpd-14-32667-2014, 2014
Revised manuscript not accepted
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The manuscript describes novel findings in the diurnal variation of stratospheric ozone by means of the MACC reanalysis, the ERA-Interim reanalysis and the WACCM model. The diurnal variation in ozone has dynamical and photochemical origins which lead to substantial amplitudes especially in the polar, stratospheric regions. The unprecedented, global view on diurnal ozone variation strengthens the implication to correct diurnally sampled satellite observations used for ozone trend estimates.
K. Sagi, D. Murtagh, J. Urban, H. Sagawa, and Y. Kasai
Atmos. Chem. Phys., 14, 12855–12869, https://doi.org/10.5194/acp-14-12855-2014, https://doi.org/10.5194/acp-14-12855-2014, 2014
P. Eriksson, B. Rydberg, H. Sagawa, M. S. Johnston, and Y. Kasai
Atmos. Chem. Phys., 14, 12613–12629, https://doi.org/10.5194/acp-14-12613-2014, https://doi.org/10.5194/acp-14-12613-2014, 2014
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The sub-millimetre wavelength region has been identified as very useful for measurements of cloud ice mass. The only satellite sensors operating in this wavelength region are so far limb sounders, and results from two such instruments are presented and sample applications are demonstrated. The results have high intrinsic value, but serve also as a practical preparation for planned dedicated sub-millimetre cloud missions.
A. Laeng, U. Grabowski, T. von Clarmann, G. Stiller, N. Glatthor, M. Höpfner, S. Kellmann, M. Kiefer, A. Linden, S. Lossow, V. Sofieva, I. Petropavlovskikh, D. Hubert, T. Bathgate, P. Bernath, C. D. Boone, C. Clerbaux, P. Coheur, R. Damadeo, D. Degenstein, S. Frith, L. Froidevaux, J. Gille, K. Hoppel, M. McHugh, Y. Kasai, J. Lumpe, N. Rahpoe, G. Toon, T. Sano, M. Suzuki, J. Tamminen, J. Urban, K. Walker, M. Weber, and J. Zawodny
Atmos. Meas. Tech., 7, 3971–3987, https://doi.org/10.5194/amt-7-3971-2014, https://doi.org/10.5194/amt-7-3971-2014, 2014
B. Hassler, I. Petropavlovskikh, J. Staehelin, T. August, P. K. Bhartia, C. Clerbaux, D. Degenstein, M. De Mazière, B. M. Dinelli, A. Dudhia, G. Dufour, S. M. Frith, L. Froidevaux, S. Godin-Beekmann, J. Granville, N. R. P. Harris, K. Hoppel, D. Hubert, Y. Kasai, M. J. Kurylo, E. Kyrölä, J.-C. Lambert, P. F. Levelt, C. T. McElroy, R. D. McPeters, R. Munro, H. Nakajima, A. Parrish, P. Raspollini, E. E. Remsberg, K. H. Rosenlof, A. Rozanov, T. Sano, Y. Sasano, M. Shiotani, H. G. J. Smit, G. Stiller, J. Tamminen, D. W. Tarasick, J. Urban, R. J. van der A, J. P. Veefkind, C. Vigouroux, T. von Clarmann, C. von Savigny, K. A. Walker, M. Weber, J. Wild, and J. M. Zawodny
Atmos. Meas. Tech., 7, 1395–1427, https://doi.org/10.5194/amt-7-1395-2014, https://doi.org/10.5194/amt-7-1395-2014, 2014
M. Rex, I. Wohltmann, T. Ridder, R. Lehmann, K. Rosenlof, P. Wennberg, D. Weisenstein, J. Notholt, K. Krüger, V. Mohr, and S. Tegtmeier
Atmos. Chem. Phys., 14, 4827–4841, https://doi.org/10.5194/acp-14-4827-2014, https://doi.org/10.5194/acp-14-4827-2014, 2014
T. O. Sato, H. Sagawa, N. Yoshida, and Y. Kasai
Atmos. Meas. Tech., 7, 941–958, https://doi.org/10.5194/amt-7-941-2014, https://doi.org/10.5194/amt-7-941-2014, 2014
H. Sagawa, T. O. Sato, P. Baron, E. Dupuy, N. Livesey, J. Urban, T. von Clarmann, A. de Lange, G. Wetzel, B. J. Connor, A. Kagawa, D. Murtagh, and Y. Kasai
Atmos. Meas. Tech., 6, 3325–3347, https://doi.org/10.5194/amt-6-3325-2013, https://doi.org/10.5194/amt-6-3325-2013, 2013
T. Sugita, Y. Kasai, Y. Terao, S. Hayashida, G. L. Manney, W. H. Daffer, H. Sagawa, M. Suzuki, M. Shiotani, K. A. Walker, C. D. Boone, and P. F. Bernath
Atmos. Meas. Tech., 6, 3099–3113, https://doi.org/10.5194/amt-6-3099-2013, https://doi.org/10.5194/amt-6-3099-2013, 2013
M. von Hobe, S. Bekki, S. Borrmann, F. Cairo, F. D'Amato, G. Di Donfrancesco, A. Dörnbrack, A. Ebersoldt, M. Ebert, C. Emde, I. Engel, M. Ern, W. Frey, S. Genco, S. Griessbach, J.-U. Grooß, T. Gulde, G. Günther, E. Hösen, L. Hoffmann, V. Homonnai, C. R. Hoyle, I. S. A. Isaksen, D. R. Jackson, I. M. Jánosi, R. L. Jones, K. Kandler, C. Kalicinsky, A. Keil, S. M. Khaykin, F. Khosrawi, R. Kivi, J. Kuttippurath, J. C. Laube, F. Lefèvre, R. Lehmann, S. Ludmann, B. P. Luo, M. Marchand, J. Meyer, V. Mitev, S. Molleker, R. Müller, H. Oelhaf, F. Olschewski, Y. Orsolini, T. Peter, K. Pfeilsticker, C. Piesch, M. C. Pitts, L. R. Poole, F. D. Pope, F. Ravegnani, M. Rex, M. Riese, T. Röckmann, B. Rognerud, A. Roiger, C. Rolf, M. L. Santee, M. Scheibe, C. Schiller, H. Schlager, M. Siciliani de Cumis, N. Sitnikov, O. A. Søvde, R. Spang, N. Spelten, F. Stordal, O. Sumińska-Ebersoldt, A. Ulanovski, J. Ungermann, S. Viciani, C. M. Volk, M. vom Scheidt, P. von der Gathen, K. Walker, T. Wegner, R. Weigel, S. Weinbruch, G. Wetzel, F. G. Wienhold, I. Wohltmann, W. Woiwode, I. A. K. Young, V. Yushkov, B. Zobrist, and F. Stroh
Atmos. Chem. Phys., 13, 9233–9268, https://doi.org/10.5194/acp-13-9233-2013, https://doi.org/10.5194/acp-13-9233-2013, 2013
Y. Kasai, H. Sagawa, D. Kreyling, E. Dupuy, P. Baron, J. Mendrok, K. Suzuki, T. O. Sato, T. Nishibori, S. Mizobuchi, K. Kikuchi, T. Manabe, H. Ozeki, T. Sugita, M. Fujiwara, Y. Irimajiri, K. A. Walker, P. F. Bernath, C. Boone, G. Stiller, T. von Clarmann, J. Orphal, J. Urban, D. Murtagh, E. J. Llewellyn, D. Degenstein, A. E. Bourassa, N. D. Lloyd, L. Froidevaux, M. Birk, G. Wagner, F. Schreier, J. Xu, P. Vogt, T. Trautmann, and M. Yasui
Atmos. Meas. Tech., 6, 2311–2338, https://doi.org/10.5194/amt-6-2311-2013, https://doi.org/10.5194/amt-6-2311-2013, 2013
M. Khosravi, P. Baron, J. Urban, L. Froidevaux, A. I. Jonsson, Y. Kasai, K. Kuribayashi, C. Mitsuda, D. P. Murtagh, H. Sagawa, M. L. Santee, T. O. Sato, M. Shiotani, M. Suzuki, T. von Clarmann, K. A. Walker, and S. Wang
Atmos. Chem. Phys., 13, 7587–7606, https://doi.org/10.5194/acp-13-7587-2013, https://doi.org/10.5194/acp-13-7587-2013, 2013
P. Baron, D. P. Murtagh, J. Urban, H. Sagawa, S. Ochiai, Y. Kasai, K. Kikuchi, F. Khosrawi, H. Körnich, S. Mizobuchi, K. Sagi, and M. Yasui
Atmos. Chem. Phys., 13, 6049–6064, https://doi.org/10.5194/acp-13-6049-2013, https://doi.org/10.5194/acp-13-6049-2013, 2013
P. T. Verronen and R. Lehmann
Ann. Geophys., 31, 909–956, https://doi.org/10.5194/angeo-31-909-2013, https://doi.org/10.5194/angeo-31-909-2013, 2013
R. A. Stachnik, L. Millán, R. Jarnot, R. Monroe, C. McLinden, S. Kühl, J. Puķīte, M. Shiotani, M. Suzuki, Y. Kasai, F. Goutail, J. P. Pommereau, M. Dorf, and K. Pfeilsticker
Atmos. Chem. Phys., 13, 3307–3319, https://doi.org/10.5194/acp-13-3307-2013, https://doi.org/10.5194/acp-13-3307-2013, 2013
Related subject area
Subject: Gases | Research Activity: Remote Sensing | Altitude Range: Mesosphere | Science Focus: Chemistry (chemical composition and reactions)
Structure, variability, and origin of the low-latitude nightglow continuum between 300 and 1800 nm: evidence for HO2 emission in the near-infrared
Comparison of mesospheric sodium profile retrievals from OSIRIS and SCIAMACHY nightglow measurements
Local impact of solar variation on NO2 in the lower mesosphere and upper stratosphere from 2007 to 2012
On the quality of MIPAS kinetic temperature in the middle atmosphere
Signature of the 27-day solar rotation cycle in mesospheric OH and H2O observed by the Aura Microwave Limb Sounder
Polar-night O3, NO2 and NO3 distributions during sudden stratospheric warmings in 2003–2008 as seen by GOMOS/Envisat
Variability of the nighttime OH layer and mesospheric ozone at high latitudes during northern winter: influence of meteorology
A global climatology of the mesospheric sodium layer from GOMOS data during the 2002–2008 period
First multi-year occultation observations of CO2 in the MLT by ACE satellite: observations and analysis using the extended CMAM
Spatio-temporal observations of the tertiary ozone maximum
Stefan Noll, John M. C. Plane, Wuhu Feng, Konstantinos S. Kalogerakis, Wolfgang Kausch, Carsten Schmidt, Michael Bittner, and Stefan Kimeswenger
Atmos. Chem. Phys., 24, 1143–1176, https://doi.org/10.5194/acp-24-1143-2024, https://doi.org/10.5194/acp-24-1143-2024, 2024
Short summary
Short summary
The Earth's nighttime radiation in the range from the near-UV to the near-IR mainly originates between 75 and 105 km and consists of lines of different species, which are important indicators of the chemistry and dynamics at these altitudes. Based on astronomical spectra, we have characterised the structure and variability of a pseudo-continuum of a high number of faint lines and discovered a new emission process in the near-IR. By means of simulations, we identified HO2 as the likely emitter.
Julia Koch, Adam Bourassa, Nick Lloyd, Chris Roth, and Christian von Savigny
Atmos. Chem. Phys., 22, 3191–3202, https://doi.org/10.5194/acp-22-3191-2022, https://doi.org/10.5194/acp-22-3191-2022, 2022
Short summary
Short summary
The mesopause, the region of the earth's atmosphere between 85 and 100 km, is hard to access by direct measurements. Therefore we look for parameters that can be measured using satellite or ground-based measurements. In this study we researched sodium airglow, a phenomenon that occurs when sodium atoms are excited by chemical reactions. We compared satellite measurements of the airglow and resulting sodium concentration profiles to gain a better understanding of the sodium in that region.
F. Friederich, M. Sinnhuber, B. Funke, T. von Clarmann, and J. Orphal
Atmos. Chem. Phys., 14, 4055–4064, https://doi.org/10.5194/acp-14-4055-2014, https://doi.org/10.5194/acp-14-4055-2014, 2014
M. García-Comas, B. Funke, M. López-Puertas, D. Bermejo-Pantaleón, N. Glatthor, T. von Clarmann, G. Stiller, U. Grabowski, C. D. Boone, W. J. R. French, T. Leblanc, M. J. López-González, and M. J. Schwartz
Atmos. Chem. Phys., 12, 6009–6039, https://doi.org/10.5194/acp-12-6009-2012, https://doi.org/10.5194/acp-12-6009-2012, 2012
A. V. Shapiro, E. Rozanov, A. I. Shapiro, S. Wang, T. Egorova, W. Schmutz, and Th. Peter
Atmos. Chem. Phys., 12, 3181–3188, https://doi.org/10.5194/acp-12-3181-2012, https://doi.org/10.5194/acp-12-3181-2012, 2012
V. F. Sofieva, N. Kalakoski, P. T. Verronen, S.-M. Päivärinta, E. Kyrölä, L. Backman, and J. Tamminen
Atmos. Chem. Phys., 12, 1051–1066, https://doi.org/10.5194/acp-12-1051-2012, https://doi.org/10.5194/acp-12-1051-2012, 2012
A. Damiani, M. Storini, M. L. Santee, and S. Wang
Atmos. Chem. Phys., 10, 10291–10303, https://doi.org/10.5194/acp-10-10291-2010, https://doi.org/10.5194/acp-10-10291-2010, 2010
D. Fussen, F. Vanhellemont, C. Tétard, N. Mateshvili, E. Dekemper, N. Loodts, C. Bingen, E. Kyrölä, J. Tamminen, V. Sofieva, A. Hauchecorne, F. Dalaudier, J.-L. Bertaux, G. Barrot, L. Blanot, O. Fanton d'Andon, T. Fehr, L. Saavedra, T. Yuan, and C.-Y. She
Atmos. Chem. Phys., 10, 9225–9236, https://doi.org/10.5194/acp-10-9225-2010, https://doi.org/10.5194/acp-10-9225-2010, 2010
S. R. Beagley, C. D. Boone, V. I. Fomichev, J. J. Jin, K. Semeniuk, J. C. McConnell, and P. F. Bernath
Atmos. Chem. Phys., 10, 1133–1153, https://doi.org/10.5194/acp-10-1133-2010, https://doi.org/10.5194/acp-10-1133-2010, 2010
V. F. Sofieva, E. Kyrölä, P. T. Verronen, A. Seppälä, J. Tamminen, D. R. Marsh, A. K. Smith, J.-L. Bertaux, A. Hauchecorne, F. Dalaudier, D. Fussen, F. Vanhellemont, O. Fanton d'Andon, G. Barrot, M. Guirlet, T. Fehr, and L. Saavedra
Atmos. Chem. Phys., 9, 4439–4445, https://doi.org/10.5194/acp-9-4439-2009, https://doi.org/10.5194/acp-9-4439-2009, 2009
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