Articles | Volume 14, issue 18
https://doi.org/10.5194/acp-14-10211-2014
© Author(s) 2014. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-14-10211-2014
© Author(s) 2014. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
25 Sep 2014
Research article |
| 25 Sep 2014
Horizontal distributions of aerosol constituents and their mixing states in Antarctica during the JASE traverse
Department of Earth System Science, Faculty of Science, Fukuoka University, Fukuoka, Japan
F. Nakazawa
National Institute of Polar Research, Tokyo, Japan
S. Fujita
National Institute of Polar Research, Tokyo, Japan
K. Fukui
National Institute of Polar Research, Tokyo, Japan
now at: Tateyama Caldera Sabo Museum, Toyama, Japan
H. Enomoto
Kitami Institute of Technology, Kitami, Japan
now at: National Institute of Polar Research, Tokyo, Japan
S. Sugiyama
Institute of Low temperature Science, Hokkaido University, Sapporo, Japan
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Shun Tsutaki, Koji Fujita, Takayuki Nuimura, Akiko Sakai, Shin Sugiyama, Jiro Komori, and Phuntsho Tshering
The Cryosphere, 13, 2733–2750, https://doi.org/10.5194/tc-13-2733-2019, https://doi.org/10.5194/tc-13-2733-2019, 2019
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Atmos. Chem. Phys., 19, 7817–7837, https://doi.org/10.5194/acp-19-7817-2019, https://doi.org/10.5194/acp-19-7817-2019, 2019
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We measured equivalent black carbon (EBC) concentrations at Syowa Station, Antarctica, from February 2005. EBC might be transported directly to Syowa Station from mid-latitudes mainly via the boundary layer and the lower free troposphere. Some BC was transported to Antarctic regions via the upper free troposphere. Biomass burning in South America and southern Africa is the most dominant source. Fossil fuel combustion in South America and southern Africa also have important contributions.
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Atmos. Chem. Phys., 18, 9207–9224, https://doi.org/10.5194/acp-18-9207-2018, https://doi.org/10.5194/acp-18-9207-2018, 2018
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Keiichiro Hara, Sumito Matoba, Motohiro Hirabayashi, and Tetsuhide Yamasaki
Atmos. Chem. Phys., 17, 8577–8598, https://doi.org/10.5194/acp-17-8577-2017, https://doi.org/10.5194/acp-17-8577-2017, 2017
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Guillaume Jouvet, Yvo Weidmann, Julien Seguinot, Martin Funk, Takahiro Abe, Daiki Sakakibara, Hakime Seddik, and Shin Sugiyama
The Cryosphere, 11, 911–921, https://doi.org/10.5194/tc-11-911-2017, https://doi.org/10.5194/tc-11-911-2017, 2017
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In this study, we combine UAV (unmanned aerial vehicles) images taken over the Bowdoin Glacier, north-western Greenland, and a model describing the viscous motion of ice to track the propagation of crevasses responsible for the collapse of large icebergs at the glacier-ocean front (calving). This new technique allows us to explain the systematic calving pattern observed in spring and summer of 2015 and anticipate a possible rapid retreat in the future.
Alexandra Touzeau, Amaëlle Landais, Barbara Stenni, Ryu Uemura, Kotaro Fukui, Shuji Fujita, Sarah Guilbaud, Alexey Ekaykin, Mathieu Casado, Eugeni Barkan, Boaz Luz, Olivier Magand, Grégory Teste, Emmanuel Le Meur, Mélanie Baroni, Joël Savarino, Ilann Bourgeois, and Camille Risi
The Cryosphere, 10, 837–852, https://doi.org/10.5194/tc-10-837-2016, https://doi.org/10.5194/tc-10-837-2016, 2016
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The relationship between water isotope ratios and temperature is investigated in precipitation snow at Vostok and Dome C, as well as in surface snow along traverses. The temporal slope of the linear regression for the precipitation is smaller than the geographical slope. Thus, using the latter could lead to an underestimation of past temperature changes. The processes active at remote sites (best glacial analogs) are explored through a combination of water isotopes in short snow pits.
S. Fujita, F. Parrenin, M. Severi, H. Motoyama, and E. W. Wolff
Clim. Past, 11, 1395–1416, https://doi.org/10.5194/cp-11-1395-2015, https://doi.org/10.5194/cp-11-1395-2015, 2015
A. Svensson, S. Fujita, M. Bigler, M. Braun, R. Dallmayr, V. Gkinis, K. Goto-Azuma, M. Hirabayashi, K. Kawamura, S. Kipfstuhl, H. A. Kjær, T. Popp, M. Simonsen, J. P. Steffensen, P. Vallelonga, and B. M. Vinther
Clim. Past, 11, 1127–1137, https://doi.org/10.5194/cp-11-1127-2015, https://doi.org/10.5194/cp-11-1127-2015, 2015
F. Parrenin, S. Fujita, A. Abe-Ouchi, K. Kawamura, V. Masson-Delmotte, H. Motoyama, F. Saito, M. Severi, B. Stenni, R. Uemura, and E. Wolff
Clim. Past Discuss., https://doi.org/10.5194/cpd-11-377-2015, https://doi.org/10.5194/cpd-11-377-2015, 2015
Revised manuscript has not been submitted
M. Montagnat, N. Azuma, D. Dahl-Jensen, J. Eichler, S. Fujita, F. Gillet-Chaulet, S. Kipfstuhl, D. Samyn, A. Svensson, and I. Weikusat
The Cryosphere, 8, 1129–1138, https://doi.org/10.5194/tc-8-1129-2014, https://doi.org/10.5194/tc-8-1129-2014, 2014
K. Hara, M. Hayashi, M. Yabuki, M. Shiobara, and C. Nishita-Hara
Atmos. Chem. Phys., 14, 4169–4183, https://doi.org/10.5194/acp-14-4169-2014, https://doi.org/10.5194/acp-14-4169-2014, 2014
K. Hara, K. Osada, and T. Yamanouchi
Atmos. Chem. Phys., 13, 9119–9139, https://doi.org/10.5194/acp-13-9119-2013, https://doi.org/10.5194/acp-13-9119-2013, 2013
A. Svensson, M. Bigler, T. Blunier, H. B. Clausen, D. Dahl-Jensen, H. Fischer, S. Fujita, K. Goto-Azuma, S. J. Johnsen, K. Kawamura, S. Kipfstuhl, M. Kohno, F. Parrenin, T. Popp, S. O. Rasmussen, J. Schwander, I. Seierstad, M. Severi, J. P. Steffensen, R. Udisti, R. Uemura, P. Vallelonga, B. M. Vinther, A. Wegner, F. Wilhelms, and M. Winstrup
Clim. Past, 9, 749–766, https://doi.org/10.5194/cp-9-749-2013, https://doi.org/10.5194/cp-9-749-2013, 2013
P. Fretwell, H. D. Pritchard, D. G. Vaughan, J. L. Bamber, N. E. Barrand, R. Bell, C. Bianchi, R. G. Bingham, D. D. Blankenship, G. Casassa, G. Catania, D. Callens, H. Conway, A. J. Cook, H. F. J. Corr, D. Damaske, V. Damm, F. Ferraccioli, R. Forsberg, S. Fujita, Y. Gim, P. Gogineni, J. A. Griggs, R. C. A. Hindmarsh, P. Holmlund, J. W. Holt, R. W. Jacobel, A. Jenkins, W. Jokat, T. Jordan, E. C. King, J. Kohler, W. Krabill, M. Riger-Kusk, K. A. Langley, G. Leitchenkov, C. Leuschen, B. P. Luyendyk, K. Matsuoka, J. Mouginot, F. O. Nitsche, Y. Nogi, O. A. Nost, S. V. Popov, E. Rignot, D. M. Rippin, A. Rivera, J. Roberts, N. Ross, M. J. Siegert, A. M. Smith, D. Steinhage, M. Studinger, B. Sun, B. K. Tinto, B. C. Welch, D. Wilson, D. A. Young, C. Xiangbin, and A. Zirizzotti
The Cryosphere, 7, 375–393, https://doi.org/10.5194/tc-7-375-2013, https://doi.org/10.5194/tc-7-375-2013, 2013
Related subject area
Subject: Aerosols | Research Activity: Field Measurements | Altitude Range: Troposphere | Science Focus: Chemistry (chemical composition and reactions)
High-altitude aerosol chemical characterization and source identification: insights from the CALISHTO campaign
Measurement report: Impact of emission control measures on environmental persistent free radicals and reactive oxygen species – a short-term case study in Beijing
Characterizing water solubility of fresh and aged secondary organic aerosol in PM2.5 with the stable carbon isotope technique
Measurement report: Impact of cloud processes on secondary organic aerosols at a forested mountain site in southeastern China
Critical contribution of chemically diverse carbonyl molecules to the oxidative potential of atmospheric aerosols
Measurement report: Vanadium-containing ship exhaust particles detected in and above the marine boundary layer in the remote atmosphere
Diverging trends in aerosol sulfate and nitrate measured in the remote North Atlantic in Barbados are attributed to clean air policies, African smoke, and anthropogenic emissions
Diverse sources and aging change the mixing state and ice nucleation properties of aerosol particles over the western Pacific and Southern Ocean
The water-insoluble organic carbon in PM2.5 of typical Chinese urban areas: light-absorbing properties, potential sources, radiative forcing effects, and a possible light-absorbing continuum
Measurement report: Size-resolved secondary organic aerosol formation modulated by aerosol water uptake in wintertime haze
In situ measurement of organic aerosol molecular markers in urban Hong Kong during a summer period: temporal variations and source apportionment
Technical note: Determining chemical composition of atmospheric single particles by a standard-free mass calibration algorithm
Different formation pathways of nitrogen-containing organic compounds in aerosols and fog water in northern China
Automated compound speciation, cluster analysis, and quantification of organic vapours and aerosols using comprehensive two-dimensional gas chromatography and mass spectrometry
Atmospheric evolution of environmentally persistent free radicals in rural North China Plain: insights into water solubility and effects on PM2.5 oxidative potential
Impact of weather patterns and meteorological factors on PM2.5 and O3 responses to the COVID-19 lockdown in China
Daytime and nighttime aerosol soluble iron formation in clean and slightly polluted moist air in a coastal city in eastern China
Non-negligible secondary contribution to brown carbon in autumn and winter: inspiration from particulate nitrated and oxygenated aromatic compounds in urban Beijing
Simultaneous organic aerosol source apportionment at two Antarctic sites reveals large-scale and ecoregion-specific components
Two distinct ship emission profiles for organic-sulfate source apportionment of PM in sulfur emission control areas
Measurement report: Optical characterization, seasonality, and sources of brown carbon in fine aerosols from Tianjin, North China: year-round observations
Bayesian inference-based estimation of hourly primary and secondary organic carbon in suburban Hong Kong: multi-temporal-scale variations and evolution characteristics during PM2.5 episodes
Exploring the sources of light-absorbing carbonaceous aerosols by integrating observational and modeling results: insights from Northeast China
Vertical variability of aerosol properties and trace gases over a remote marine region: A case study over Bermuda
Measurement report: Characteristics of aminiums in PM2.5 during winter clean and polluted episodes in China: aminium outbreak and its constraint
Hygroscopic Growth and Activation Changed Submicron Aerosol Composition and Properties in North China Plain
Assessing the influence of long-range transport of aerosols on the PM2.5 chemical composition and concentration in the Aburrá Valley
Bridging Gas and Aerosol Properties between Northeast U.S. and Bermuda: Analysis of Eight Transit Flights
Measurement report: Characteristics of nitrogen-containing organics in PM2.5 in Ürümqi, northwestern China – differential impacts of combustion of fresh and aged biomass materials
Measurement report: Formation of tropospheric brown carbon in a lifting air mass
Measurement report: Bio-physicochemistry of tropical clouds at Maïdo (Réunion, Indian Ocean): overview of results from the BIO-MAÏDO campaign
Impacts of elevated anthropogenic emissions on physicochemical characteristics of BC-containing particles over the Tibetan Plateau
Chemical properties and single-particle mixing state of soot aerosol in Houston during the TRACER campaign
The behaviour of charged particles (ions) during new particle formation events in urban Leipzig (Germany)
Measurement report: Evaluation of the TOF-ACSM-CV for PM1.0 and PM2.5 measurements during the RITA-2021 field campaign
Sea salt reactivity over the northwest Atlantic: an in-depth look using the airborne ACTIVATE dataset
Measurement report: Atmospheric ice nuclei in the Changbai Mountains (2623 m a.s.l.) in northeastern Asia
Morphological and optical properties of carbonaceous aerosol particles from ship emissions and biomass burning during a summer cruise measurement in the South China Sea
Tropical tropospheric aerosol sources and chemical composition observed at high altitude in the Bolivian Andes
Chemical composition, sources and formation mechanism of urban PM2.5 in Southwest China: a case study at the beginning of 2023
Chemical characterization of atmospheric aerosols at a high-altitude mountain site: a study of source apportionment
Composition and sources of carbonaceous aerosol in the European Arctic at Zeppelin Observatory, Svalbard (2017 to 2020)
Variation in chemical composition and volatility of oxygenated organic aerosol in different rural, urban, and mountain environments
Elucidating the mechanisms of atmospheric new particle formation in the highly polluted Po Valley, Italy
Differences in aerosol and cloud properties along the central California coast when winds change from northerly to southerly
Local ship speed reduction effect on black carbon emissions measured at remote marine station
Roles of marine biota in the formation of atmospheric bioaerosols, cloud condensation nuclei, and ice-nucleating particles over the North Pacific Ocean, Bering Sea, and Arctic Ocean
Evolution of nucleophilic high molecular-weight organic compounds in ambient aerosols: a case study
Fractional solubility of iron in mineral dust aerosols over coastal Namibia: a link to marine biogenic emissions?
Real-world observations of reduced nitrogen and ultrafine particles in commercial cooking organic aerosol emissions
Olga Zografou, Maria Gini, Prodromos Fetfatzis, Konstantinos Granakis, Romanos Foskinis, Manousos Ioannis Manousakas, Fotios Tsopelas, Evangelia Diapouli, Eleni Dovrou, Christina N. Vasilakopoulou, Alexandros Papayannis, Spyros N. Pandis, Athanasios Nenes, and Konstantinos Eleftheriadis
Atmos. Chem. Phys., 24, 8911–8926, https://doi.org/10.5194/acp-24-8911-2024, https://doi.org/10.5194/acp-24-8911-2024, 2024
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Characterization of PM1 and positive matrix factorization (PMF) source apportionment of organic and inorganic fractions were conducted at the high-altitude station (HAC)2. Cloud presence reduced PM1, affecting sulfate more than organics. Free-troposphere (FT) conditions showed more black carbon (eBC) than planetary boundary layer (PBL) conditions.
Yuanyuan Qin, Xinghua Zhang, Wei Huang, Juanjuan Qin, Xiaoyu Hu, Yuxuan Cao, Tianyi Zhao, Yang Zhang, Jihua Tan, Ziyin Zhang, Xinming Wang, and Zhenzhen Wang
Atmos. Chem. Phys., 24, 8737–8750, https://doi.org/10.5194/acp-24-8737-2024, https://doi.org/10.5194/acp-24-8737-2024, 2024
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Environmental persistent free radicals (EPFRs) and reactive oxygen species (ROSs) play an active role in the atmosphere. Despite control measures having effectively reduced their emissions, reductions were less than in PM2.5. Emission control measures performed well in achieving Parade Blue, but reducing the impact of the atmosphere on human health remains challenging. Thus, there is a need to reassess emission control measures to better address the challenges posed by EPFRs and ROSs.
Fenghua Wei, Xing Peng, Liming Cao, Mengxue Tang, Ning Feng, Xiaofeng Huang, and Lingyan He
Atmos. Chem. Phys., 24, 8507–8518, https://doi.org/10.5194/acp-24-8507-2024, https://doi.org/10.5194/acp-24-8507-2024, 2024
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The water solubility of secondary organic aerosols (SOAs) is a crucial factor in determining their hygroscopicity and climatic impact. Stable carbon isotope and mass spectrometry techniques were combined to assess the water solubility of SOAs with different aging degrees in a coastal megacity in China. This work revealed a much higher water-soluble fraction of aged SOA compared to fresh SOA, indicating that the aging degree of SOA has considerable impacts on its water solubility.
Zijun Zhang, Weiqi Xu, Yi Zhang, Wei Zhou, Xiangyu Xu, Aodong Du, Yinzhou Zhang, Hongqin Qiao, Ye Kuang, Xiaole Pan, Zifa Wang, Xueling Cheng, Lanzhong Liu, Qingyan Fu, Douglas R. Worsnop, Jie Li, and Yele Sun
Atmos. Chem. Phys., 24, 8473–8488, https://doi.org/10.5194/acp-24-8473-2024, https://doi.org/10.5194/acp-24-8473-2024, 2024
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We investigated aerosol composition and sources and the interaction between secondary organic aerosol (SOA) and clouds at a regional mountain site in southeastern China. Clouds efficiently scavenge more oxidized SOA; however, cloud evaporation leads to the production of less oxidized SOA. The unexpectedly high presence of nitrate in aerosol particles indicates that nitrate formed in polluted areas has undergone interactions with clouds, significantly influencing the regional background site.
Feifei Li, Shanshan Tang, Jitao Lv, Shiyang Yu, Xu Sun, Dong Cao, Yawei Wang, and Guibin Jiang
Atmos. Chem. Phys., 24, 8397–8411, https://doi.org/10.5194/acp-24-8397-2024, https://doi.org/10.5194/acp-24-8397-2024, 2024
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Targeted derivatization and non-targeted analysis with Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS) were used to reveal the molecular composition of carbonyl molecules in PM2.5, and the important role of carbonyls in increasing the oxidative potential of organic aerosol was found in real samples.
Maya Abou-Ghanem, Daniel M. Murphy, Gregory P. Schill, Michael J. Lawler, and Karl D. Froyd
Atmos. Chem. Phys., 24, 8263–8275, https://doi.org/10.5194/acp-24-8263-2024, https://doi.org/10.5194/acp-24-8263-2024, 2024
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Using particle analysis by laser mass spectrometry, we examine vanadium-containing ship exhaust particles measured on NASA's DC-8 during the Atmospheric Tomography Mission (ATom). Our results reveal ship exhaust particles are sufficiently widespread in the marine atmosphere and experience atmospheric aging. Finally, we use laboratory calibrations to determine the vanadium, sulfate, and organic single-particle mass fractions of vanadium-containing ship exhaust particles.
Cassandra J. Gaston, Joseph M. Prospero, Kristen Foley, Havala O. T. Pye, Lillian Custals, Edmund Blades, Peter Sealy, and James A. Christie
Atmos. Chem. Phys., 24, 8049–8066, https://doi.org/10.5194/acp-24-8049-2024, https://doi.org/10.5194/acp-24-8049-2024, 2024
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To understand how changing emissions have impacted aerosols in remote regions, we measured nitrate and sulfate in Barbados and compared them to model predictions from EPA’s Air QUAlity TimE Series (EQUATES). Nitrate was stable, except for spikes in 2008 and 2010 due to transported smoke. Sulfate decreased in the 1990s due to reductions in sulfur dioxide (SO2) in the US and Europe; then it increased in the 2000s, likely due to anthropogenic emissions from Africa.
Jiao Xue, Tian Zhang, Keyhong Park, Jinpei Yan, Young Jun Yoon, Jiyeon Park, and Bingbing Wang
Atmos. Chem. Phys., 24, 7731–7754, https://doi.org/10.5194/acp-24-7731-2024, https://doi.org/10.5194/acp-24-7731-2024, 2024
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Ice formation by particles is an important way of making mixed-phase and ice clouds. We found that particles collected in the marine atmosphere exhibit diverse ice nucleation abilities and mixing states. Sea salt mixed-sulfate particles were enriched in ice-nucleating particles. Selective aging on sea salt particles made particle populations more externally mixed. Characterizations of particles and their mixing state are needed for a better understanding of aerosol–cloud interactions.
Yangzhi Mo, Jun Li, Guangcai Zhong, Sanyuan Zhu, Shizhen Zhao, Jiao Tang, Hongxing Jiang, Zhineng Cheng, Chongguo Tian, Yingjun Chen, and Gan Zhang
Atmos. Chem. Phys., 24, 7755–7772, https://doi.org/10.5194/acp-24-7755-2024, https://doi.org/10.5194/acp-24-7755-2024, 2024
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In this study, we found that biomass burning (31.0 %) and coal combustion (31.1 %) were the dominant sources of water-insoluble organic carbon in China, with coal combustion sources exhibiting the strongest light-absorbing capacity. Additionally, we propose a light-absorbing carbonaceous continuum, revealing that components enriched with fossil sources tend to have stronger light-absorbing capacity, higher aromaticity, higher molecular weights, and greater recalcitrance in the atmosphere.
Jing Duan, Ru-Jin Huang, Ying Wang, Wei Xu, Haobin Zhong, Chunshui Lin, Wei Huang, Yifang Gu, Jurgita Ovadnevaite, Darius Ceburnis, and Colin O'Dowd
Atmos. Chem. Phys., 24, 7687–7698, https://doi.org/10.5194/acp-24-7687-2024, https://doi.org/10.5194/acp-24-7687-2024, 2024
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The chemical composition of atmospheric particles has shown significant changes in recent years. We investigated the potential effects of changes in inorganics on aerosol water uptake and, thus, secondary organic aerosol formation in wintertime haze based on the size-resolved measurements of non-refractory fine particulate matter (NR-PM2.5) in Xi’an, northwestern China. We highlight the key role of aerosol water as a medium to link inorganics and organics in their multiphase processes.
Hongyong Li, Xiaopu Lyu, Likun Xue, Yunxi Huo, Dawen Yao, Haoxian Lu, and Hai Guo
Atmos. Chem. Phys., 24, 7085–7100, https://doi.org/10.5194/acp-24-7085-2024, https://doi.org/10.5194/acp-24-7085-2024, 2024
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Organic aerosol is ubiquitous in the atmosphere and largely explains the gap between current levels of fine particulate matter in many cities and the World Health Organization guideline values. This study highlights the dominant contributions of cooking emissions to organic aerosol when marine air prevailed in Hong Kong, which were occasionally overwhelmed by aromatics-derived secondary organic aerosol in continental ouflows.
Shao Shi, Jinghao Zhai, Xin Yang, Yechun Ruan, Yuanlong Huang, Xujian Chen, Antai Zhang, Jianhuai Ye, Guomao Zheng, Baohua Cai, Yaling Zeng, Yixiang Wang, Chunbo Xing, Yujie Zhang, Tzung-May Fu, Lei Zhu, Huizhong Shen, and Chen Wang
Atmos. Chem. Phys., 24, 7001–7012, https://doi.org/10.5194/acp-24-7001-2024, https://doi.org/10.5194/acp-24-7001-2024, 2024
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The determination of ions in the mass spectra of individual particles remains uncertain. We have developed a standard-free mass calibration algorithm applicable to more than 98 % of ambient particles. With our algorithm, ions with ~ 0.05 Th mass difference could be determined. Therefore, many more atmospheric species could be determined and involved in the source apportionment of aerosols, the study of chemical reaction mechanisms, and the analysis of single-particle mixing states.
Wei Sun, Xiaodong Hu, Yuzhen Fu, Guohua Zhang, Yujiao Zhu, Xinfeng Wang, Caiqing Yan, Likun Xue, He Meng, Bin Jiang, Yuhong Liao, Xinming Wang, Ping'an Peng, and Xinhui Bi
Atmos. Chem. Phys., 24, 6987–6999, https://doi.org/10.5194/acp-24-6987-2024, https://doi.org/10.5194/acp-24-6987-2024, 2024
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The formation pathways of nitrogen-containing compounds (NOCs) in the atmosphere remain unclear. We investigated the composition of aerosols and fog water by state-of-the-art mass spectrometry and compared the formation pathways of NOCs. We found that NOCs in aerosols were mainly formed through nitration reaction, while ammonia addition played a more important role in fog water. The results deepen our understanding of the processes of organic particulate pollution.
Xiao He, Xuan Zheng, Shuwen Guo, Lewei Zeng, Ting Chen, Bohan Yang, Shupei Xiao, Qiongqiong Wang, Zhiyuan Li, Yan You, Shaojun Zhang, and Ye Wu
EGUsphere, https://doi.org/10.5194/egusphere-2024-1671, https://doi.org/10.5194/egusphere-2024-1671, 2024
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This study introduces an innovative method for identifying and quantifying complex organic vapors and aerosols. By combining advanced analytical techniques and new algorithms, we categorized thousands of compounds from heavy-duty diesel vehicles and ambient air and highlighted specific tracers for emission sources. The innovative approach enhances peak identification, reduces quantification uncertainties, and offers new insights for air quality management and atmospheric chemistry.
Xu Yang, Fobang Liu, Shuqi Yang, Yuling Yang, Yanan Wang, Jingjing Li, Mingyu Zhao, Zhao Wang, Kai Wang, Chi He, and Haijie Tong
EGUsphere, https://doi.org/10.5194/egusphere-2024-1622, https://doi.org/10.5194/egusphere-2024-1622, 2024
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A study in rural North China Plain revealed Environmental persistent free radicals (EPFRs) in atmospheric particulate matter (PM), with a notable water-soluble fraction likely from atmospheric oxidation during transport. Significant positive correlations between EPFRs and the water-soluble oxidative potential of PM2.5 were found, primarily attributable to the water-soluble fractions of EPFRs. These findings emphasize understanding EPFRs’ atmospheric evolution for climate and health impacts.
Fuzhen Shen, Michaela I. Hegglin, and Yue Yuan
Atmos. Chem. Phys., 24, 6539–6553, https://doi.org/10.5194/acp-24-6539-2024, https://doi.org/10.5194/acp-24-6539-2024, 2024
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We attempt to use a novel structural self-organising map and machine learning models to identify a weather system and quantify the importance of each meteorological factor in driving the unexpected PM2.5 and O3 changes under the specific weather system during the COVID-19 lockdown in China. The result highlights that temperature under the double-centre high-pressure system plays the most crucial role in abnormal events.
Wenshuai Li, Yuxuan Qi, Yingchen Liu, Guanru Wu, Yanjing Zhang, Jinhui Shi, Wenjun Qu, Lifang Sheng, Wencai Wang, Daizhou Zhang, and Yang Zhou
Atmos. Chem. Phys., 24, 6495–6508, https://doi.org/10.5194/acp-24-6495-2024, https://doi.org/10.5194/acp-24-6495-2024, 2024
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Aerosol particles from mainland can transport to oceans and deposit, providing soluble Fe and affecting phytoplankton growth. Thus, we studied the dissolution process of aerosol Fe and found that photochemistry played a key role in promoting Fe dissolution in clean conditions. RH-dependent reactions were more influential in slightly polluted conditions. These results highlight the distinct roles of two weather-related parameters (radiation and RH) in influencing geochemical cycles related to Fe.
Yanqin Ren, Zhenhai Wu, Yuanyuan Ji, Fang Bi, Junling Li, Haijie Zhang, Hao Zhang, Hong Li, and Gehui Wang
Atmos. Chem. Phys., 24, 6525–6538, https://doi.org/10.5194/acp-24-6525-2024, https://doi.org/10.5194/acp-24-6525-2024, 2024
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Nitrated aromatic compounds (NACs) and oxygenated derivatives of polycyclic aromatic hydrocarbons (OPAHs) in PM2.5 were examined from an urban area in Beijing during the autumn and winter. The OPAH and NAC concentrations were much higher during heating than before heating. They majorly originated from the combustion of biomass and automobile emissions, and the secondary generation was the major contributor throughout the whole sampling period.
Marco Paglione, David C. S. Beddows, Anna Jones, Thomas Lachlan-Cope, Matteo Rinaldi, Stefano Decesari, Francesco Manarini, Mara Russo, Karam Mansour, Roy M. Harrison, Andrea Mazzanti, Emilio Tagliavini, and Manuel Dall'Osto
Atmos. Chem. Phys., 24, 6305–6322, https://doi.org/10.5194/acp-24-6305-2024, https://doi.org/10.5194/acp-24-6305-2024, 2024
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Applying factor analysis techniques to H-NMR spectra, we present the organic aerosol (OA) source apportionment of PM1 samples collected in parallel at two Antarctic stations, namely Signy and Halley, allowing investigation of aerosol–climate interactions in an unperturbed atmosphere. Our results show remarkable differences between pelagic (open-ocean) and sympagic (sea-ice-influenced) air masses and indicate that various sources and processes are controlling Antarctic aerosols.
Kirsten N. Fossum, Chunshui Lin, Niall O'Sullivan, Lu Lei, Stig Hellebust, Darius Ceburnis, Aqeel Afzal, Anja Tremper, David Green, Srishti Jain, Steigvilė Byčenkienė, Colin O'Dowd, John Wenger, and Jurgita Ovadnevaite
EGUsphere, https://doi.org/10.5194/egusphere-2024-1262, https://doi.org/10.5194/egusphere-2024-1262, 2024
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The chemical composition and sources of submicron aerosol in the Dublin Port area were investigated over a month-long campaign. Two distinct types of ship emissions were identified and characterized: sulfate-rich plumes from use of heavy fuel oil with scrubbers and organic-rich plumes from use of low sulfur fuels. The latter were more frequent, emitting double the particle number, and having atypical V/Ni ratio for ship emission.
Zhichao Dong, Chandra Mouli Pavuluri, Peisen Li, Zhanjie Xu, Junjun Deng, Xueyan Zhao, Xiaomai Zhao, Pingqing Fu, and Cong-Qiang Liu
Atmos. Chem. Phys., 24, 5887–5905, https://doi.org/10.5194/acp-24-5887-2024, https://doi.org/10.5194/acp-24-5887-2024, 2024
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Comprehensive study of optical properties of brown carbon (BrC) in fine aerosols from Tianjin, China, implied that biological emissions are major sources of BrC in summer, whereas fossil fuel combustion and biomass burning emissions are in cold periods. The direct radiation absorption caused by BrC in short wavelengths contributed about 40 % to that caused by BrC in 300–700 nm. Water-insoluble but methanol-soluble BrC contains more protein-like chromophores (PLOM) than that of water-soluble BrC.
Shan Wang, Kezheng Liao, Zijing Zhang, Yuk Ying Cheng, Qiongqiong Wang, Hanzhe Chen, and Jian Zhen Yu
Atmos. Chem. Phys., 24, 5803–5821, https://doi.org/10.5194/acp-24-5803-2024, https://doi.org/10.5194/acp-24-5803-2024, 2024
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In this work, hourly primary and secondary organic carbon were estimated by a novel Bayesian inference approach in suburban Hong Kong. Their multi-temporal-scale variations and evolution characteristics during PM2.5 episodes were examined. The methodology could serve as a guide for other locations with similar monitoring capabilities. The observation-based results are helpful for understanding the evolving nature of secondary organic aerosols and refining the accuracy of model simulations.
Yuan Cheng, Xu-bing Cao, Sheng-qiang Zhu, Zhi-qing Zhang, Jiu-meng Liu, Hong-liang Zhang, Qiang Zhang, and Ke-bin He
EGUsphere, https://doi.org/10.5194/egusphere-2024-1260, https://doi.org/10.5194/egusphere-2024-1260, 2024
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An agreement between observational and modeling results is essential for the development of efficient air pollution control strategies. Here we constrained the modeling results of carbonaceous aerosols by field observation in Northeast China, a historically overlooked but recently targeted region of national clean air actions. Our results suggested that the estimation of agricultural fire emission and prediction of secondary organic aerosol remain challenging.
Taiwo Adedayo Ajayi, Yonghoon Choi, Ewan C. Crosbie, Joshua P. DiGangi, Glenn S. Diskin, Marta A. Fenn, Richard A. Ferrare, Johnathan W. Hair, Miguel Ricardo A. Hilario, Chris A. Hostetler, Simon Kirschler, Richard H. Moore, Taylor J. Shingler, Michael A. Shook, Cassidy Soloff, Kenneth L. Thornhill, Christiane Voigt, Edward L. Winstead, Luke Ziemba, and Armin Sorooshian
EGUsphere, https://doi.org/10.5194/egusphere-2024-1065, https://doi.org/10.5194/egusphere-2024-1065, 2024
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This study uses airborne data to examine vertical profiles of trace gases, aerosol particles, and meteorological variables over a remote marine area (Bermuda). Results show distinct differences based on both air mass source region (North America, Ocean, Caribbean/North Africa) and altitude for a given air mass type. This work highlights the sensitivity of remote marine areas to long-range transport and the importance of considering vertical dependence of trace gas and aerosol properties.
Yu Xu, Tang Liu, Yi-Jia Ma, Qi-Bin Sun, Hong-Wei Xiao, Hao Xiao, and Hua-Yun Xiao
EGUsphere, https://doi.org/10.5194/egusphere-2024-975, https://doi.org/10.5194/egusphere-2024-975, 2024
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This study has explored the characteristics of aminiums, ammonium, and PM2.5 from the clean days to the polluted days according to the observational data from 11 different Chinese cities, highlighting the possibility of the competitive uptake of ammonia versus amines on acidic aerosols, or the displacement of aminiums by ammonia under a high ammonia condition. The overall results deepen the understanding of the spatiotemporal differences in aminium characteristic and formation in China.
Weiqi Xu, Ye Kuang, Wanyun Xu, Zhiqiang Zhang, Biao Luo, Xiaoyi Zhang, Jiangchuang Tao, Hongqin Qiao, Li Liu, and Yele Sun
EGUsphere, https://doi.org/10.5194/egusphere-2024-998, https://doi.org/10.5194/egusphere-2024-998, 2024
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We deployed an advanced aerosol-fog sampling system at a rural site in the North China Plain to investigate the impact of aerosol hygroscopic growth and activation on the physicochemical properties of submicron aerosols. Observed results highlighted remarkably different aqueous processing of primary and secondary submicron aerosol components under distinct ambient RH conditions, and RH levels would impact significantly on aerosol sampling through aerosol swelling effect.
Maria P. Velásquez-García, K. Santiago Hernández, James A. Vergara-Correa, Richard J. Pope, Miriam Gómez-Marín, and Angela M. Rendón
EGUsphere, https://doi.org/10.5194/egusphere-2024-695, https://doi.org/10.5194/egusphere-2024-695, 2024
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For the Aburrá Valley, Colombia, local emissions dominate aerosol concentrations, which degrade air quality (AQ) and impact human health. However, this can be exacerbated by the influx of external emissions from sources such as regional fires, Saharan dust, and volcanic degassing. While substantially increasing city-wide aerosols, these external sources can also degrade the aerosol chemical composition (i.e. their toxicity) and impact AQ, which we investigate in this study.
Cassidy Soloff, Taiwo Ajayi, Yonghoon Choi, Ewan C. Crosbie, Joshua P. DiGangi, Glenn S. Diskin, Marta A. Fenn, Richard A. Ferrare, Francesca Gallo, Johnathan W. Hair, Miguel Ricardo A. Hilario, Simon Kirschler, Richard H. Moore, Taylor J. Shingler, Michael A. Shook, Kenneth L. Thornhill, Christiane Voigt, Edward L. Winstead, Luke D. Ziemba, and Armin Sorooshian
EGUsphere, https://doi.org/10.5194/egusphere-2024-926, https://doi.org/10.5194/egusphere-2024-926, 2024
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Using aircraft measurements over the northwest Atlantic between the U.S. East Coast and Bermuda and trajectory modeling of continental outflow, we identify trace gas and particle properties that exhibit gradients with offshore distance and quantify these changes with high resolution measurements of concentrations as well as particle chemistry, size, and scattering properties. This work furthers our understanding of the complex interactions between continental and marine environments.
Yi-Jia Ma, Yu Xu, Ting Yang, Hong-Wei Xiao, and Hua-Yun Xiao
Atmos. Chem. Phys., 24, 4331–4346, https://doi.org/10.5194/acp-24-4331-2024, https://doi.org/10.5194/acp-24-4331-2024, 2024
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This study provides field-based evidence about the differential impacts of combustion of fresh and aged biomass materials on aerosol nitrogen-containing organic compounds (NOCs) in different seasons in Ürümqi, bridging the linkages between the observations and previous laboratory studies showing the formation mechanisms of NOCs.
Can Wu, Xiaodi Liu, Ke Zhang, Si Zhang, Cong Cao, Jianjun Li, Rui Li, Fan Zhang, and Gehui Wang
EGUsphere, https://doi.org/10.5194/egusphere-2024-891, https://doi.org/10.5194/egusphere-2024-891, 2024
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Brown carbon (BrC) is prevalent in the troposphere, and can efficiently absorb solar and terrestrial radiation. Our observations manifested that the enhanced light-absorption of BrC relative to black carbon at the tropopause can be attributed to the formation of nitrogen-containing organic compounds through the aqueous-phase reactions of carbonyls with ammonium.
Maud Leriche, Pierre Tulet, Laurent Deguillaume, Frédéric Burnet, Aurélie Colomb, Agnès Borbon, Corinne Jambert, Valentin Duflot, Stéphan Houdier, Jean-Luc Jaffrezo, Mickaël Vaïtilingom, Pamela Dominutti, Manon Rocco, Camille Mouchel-Vallon, Samira El Gdachi, Maxence Brissy, Maroua Fathalli, Nicolas Maury, Bert Verreyken, Crist Amelynck, Niels Schoon, Valérie Gros, Jean-Marc Pichon, Mickael Ribeiro, Eric Pique, Emmanuel Leclerc, Thierry Bourrianne, Axel Roy, Eric Moulin, Joël Barrie, Jean-Marc Metzger, Guillaume Péris, Christian Guadagno, Chatrapatty Bhugwant, Jean-Mathieu Tibere, Arnaud Tournigand, Evelyn Freney, Karine Sellegri, Anne-Marie Delort, Pierre Amato, Muriel Joly, Jean-Luc Baray, Pascal Renard, Angelica Bianco, Anne Réchou, and Guillaume Payen
Atmos. Chem. Phys., 24, 4129–4155, https://doi.org/10.5194/acp-24-4129-2024, https://doi.org/10.5194/acp-24-4129-2024, 2024
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Aerosol particles in the atmosphere play a key role in climate change and air pollution. A large number of aerosol particles are formed from the oxidation of volatile organic compounds (VOCs and secondary organic aerosols – SOA). An important field campaign was organized on Réunion in March–April 2019 to understand the formation of SOA in a tropical atmosphere mostly influenced by VOCs emitted by forest and in the presence of clouds. This work synthesizes the results of this campaign.
Jinbo Wang, Jiaping Wang, Yuxuan Zhang, Tengyu Liu, Xuguang Chi, Xin Huang, Dafeng Ge, Shiyi Lai, Caijun Zhu, Lei Wang, Qiaozhi Zha, Ximeng Qi, Wei Nie, Congbin Fu, and Aijun Ding
EGUsphere, https://doi.org/10.5194/egusphere-2024-879, https://doi.org/10.5194/egusphere-2024-879, 2024
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In this study, we found large spatial discrepancies in the physical and chemical properties of black carbon over the Tibetan Plateau (TP). Elevated anthropogenic emissions from low-altitude regions can significantly change the mass concentration, mixing state and chemical composition of black carbon -containing aerosol in TP region, further altering its light absorption ability. Our study emphasizes the vulnerability of remote plateau regions to intense anthropogenic influences.
Ryan N. Farley, James E. Lee, Laura-Hélèna Rivellini, Alex K. Y. Lee, Rachael Dal Porto, Christopher D. Cappa, Kyle Gorkowski, Abu Sayeed Md Shawon, Katherine B. Benedict, Allison C. Aiken, Manvendra K. Dubey, and Qi Zhang
Atmos. Chem. Phys., 24, 3953–3971, https://doi.org/10.5194/acp-24-3953-2024, https://doi.org/10.5194/acp-24-3953-2024, 2024
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The black carbon aerosol composition and mixing state were characterized using a soot particle aerosol mass spectrometer. Single-particle measurements revealed the major role of atmospheric processing in modulating the black carbon mixing state. A significant fraction of soot particles were internally mixed with oxidized organic aerosol and sulfate, with implications for activation as cloud nuclei.
Alex Rowell, James Brean, David C. S. Beddows, Zongbo Shi, Avinash Kumar, Matti Rissanen, Miikka Dal Maso, Peter Mettke, Kay Weinhold, Maik Merkel, and Roy M. Harrison
EGUsphere, https://doi.org/10.5194/egusphere-2024-742, https://doi.org/10.5194/egusphere-2024-742, 2024
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Ions enhance the formation and growth rates of new particles, affecting the earths radiation budget. Despite these effects, there is little published data exploring the sources of ions in the urban environment and their role in new particle formation (NPF). Here we show that natural ion sources dominate in urban environments, while traffic is a secondary source. Ions contribute up to 12.7 % of the formation rate of particles, indicating that they are important for forming urban PM.
Xinya Liu, Bas Henzing, Arjan Hensen, Jan Mulder, Peng Yao, Danielle van Dinther, Jerry van Bronckhorst, Rujin Huang, and Ulrike Dusek
Atmos. Chem. Phys., 24, 3405–3420, https://doi.org/10.5194/acp-24-3405-2024, https://doi.org/10.5194/acp-24-3405-2024, 2024
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We evaluated the time-of-flight aerosol chemical speciation monitor (TOF-ACSM) following the implementation of the PM2.5 aerodynamic lens and a capture vaporizer (CV). The results showed that it significantly improved the accuracy and precision of ACSM in the field observations. The paper elucidates the measurement outcomes of various instruments and provides an analysis of their biases. This comprehensive evaluation is expected to benefit the ACSM community and other aerosol field measurements.
Eva-Lou Edwards, Yonghoon Choi, Ewan C. Crosbie, Joshua P. DiGangi, Glenn S. Diskin, Claire E. Robinson, Michael A. Shook, Edward L. Winstead, Luke D. Ziemba, and Armin Sorooshian
Atmos. Chem. Phys., 24, 3349–3378, https://doi.org/10.5194/acp-24-3349-2024, https://doi.org/10.5194/acp-24-3349-2024, 2024
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We investigate Cl− depletion in sea salt particles over the northwest Atlantic from December 2021 to June 2022 using an airborne dataset. Losses of Cl− are greatest in May and least in December–February and March. Inorganic acidic species can account for all depletion observed for December–February, March, and June near Bermuda but none in May. Quantifying Cl− depletion as a percentage captures seasonal trends in depletion but fails to convey the effects it may have on atmospheric oxidation.
Yue Sun, Yujiao Zhu, Yanbin Qi, Lanxiadi Chen, Jiangshan Mu, Ye Shan, Yu Yang, Yanqiu Nie, Ping Liu, Can Cui, Ji Zhang, Mingxuan Liu, Lingli Zhang, Yufei Wang, Xinfeng Wang, Mingjin Tang, Wenxing Wang, and Likun Xue
Atmos. Chem. Phys., 24, 3241–3256, https://doi.org/10.5194/acp-24-3241-2024, https://doi.org/10.5194/acp-24-3241-2024, 2024
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Field observations were conducted at the summit of Changbai Mountain in northeast Asia. The cumulative number concentration of ice-nucleating particles (INPs) varied from 1.6 × 10−3 to 78.3 L−1 over the temperature range of −5.5 to −29.0 ℃. Biological INPs (bio-INPs) accounted for the majority of INPs, and the proportion exceeded 90% above −13.0 ℃. Planetary boundary layer height, valley breezes, and long-distance transport of air mass influence the abundance of bio-INPs.
Cuizhi Sun, Yongyun Zhang, Baoling Liang, Min Gao, Xi Sun, Fei Li, Xue Ni, Qibin Sun, Hengjia Ou, Dexian Chen, Shengzhen Zhou, and Jun Zhao
Atmos. Chem. Phys., 24, 3043–3063, https://doi.org/10.5194/acp-24-3043-2024, https://doi.org/10.5194/acp-24-3043-2024, 2024
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In a May–June 2021 expedition in the South China Sea, we analyzed black and brown carbon in marine aerosols, key to light absorption and climate impact. Using advanced in situ and microscope techniques, we observed particle size, structure, and tar balls mixed with various elements. Results showed biomass burning and fossil fuels majorly influence light absorption, especially during significant burning events. This research aids the understanding of carbonaceous aerosols' role in marine climate.
C. Isabel Moreno, Radovan Krejci, Jean-Luc Jaffrezo, Gaëlle Uzu, Andrés Alastuey, Marcos F. Andrade, Valeria Mardóñez, Alkuin Maximilian Koenig, Diego Aliaga, Claudia Mohr, Laura Ticona, Fernando Velarde, Luis Blacutt, Ricardo Forno, David N. Whiteman, Alfred Wiedensohler, Patrick Ginot, and Paolo Laj
Atmos. Chem. Phys., 24, 2837–2860, https://doi.org/10.5194/acp-24-2837-2024, https://doi.org/10.5194/acp-24-2837-2024, 2024
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Aerosol chemical composition (ions, sugars, carbonaceous matter) from 2011 to 2020 was studied at Mt. Chacaltaya (5380 m a.s.l., Bolivian Andes). Minimum concentrations occur in the rainy season with maxima in the dry and transition seasons. The origins of the aerosol are located in a radius of hundreds of kilometers: nearby urban and rural areas, natural biogenic emissions, vegetation burning from Amazonia and Chaco, Pacific Ocean emissions, soil dust, and Peruvian volcanism.
Junke Zhang, Yunfei Su, Chunying Chen, Wenkai Guo, Qinwen Tan, Miao Feng, Danlin Song, Tao Jiang, Qiang Chen, Yuan Li, Wei Li, Yizhi Wang, Xiaojuan Huang, Lin Han, Wanqing Wu, and Gehui Wang
Atmos. Chem. Phys., 24, 2803–2820, https://doi.org/10.5194/acp-24-2803-2024, https://doi.org/10.5194/acp-24-2803-2024, 2024
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Typical haze events in Chengdu at the beginning of 2023 were investigated with bulk-chemical and single-particle analyses along with numerical model simulations. By integrating the obtained chemical composition, source, mixing state and numerical simulation results, we infer that Haze-1 was mainly caused by pollutants related to fossil fuel combustion, especially local mobile sources, while Haze-2 was triggered by the secondary pollutants, which mainly came from regional transmission.
Elena Barbaro, Matteo Feltracco, Fabrizio De Blasi, Clara Turetta, Marta Radaelli, Warren Cairns, Giulio Cozzi, Giovanna Mazzi, Marco Casula, Jacopo Gabrieli, Carlo Barbante, and Andrea Gambaro
Atmos. Chem. Phys., 24, 2821–2835, https://doi.org/10.5194/acp-24-2821-2024, https://doi.org/10.5194/acp-24-2821-2024, 2024
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The study analyzed a year of atmospheric aerosol composition at Col Margherita in the Italian Alps. Over 100 chemical markers were identified, including major ions, organic compounds, and trace elements. It revealed sources of aerosol, highlighted impacts of Saharan dust events, and showed anthropogenic pollution's influence despite the site's remoteness. Enrichment factors emphasized non-natural sources of trace elements. Source apportionment identified four key factors affecting the area.
Karl Espen Yttri, Are Bäcklund, Franz Conen, Sabine Eckhardt, Nikolaos Evangeliou, Markus Fiebig, Anne Kasper-Giebl, Avram Gold, Hans Gundersen, Cathrine Lund Myhre, Stephen Matthew Platt, David Simpson, Jason D. Surratt, Sönke Szidat, Martin Rauber, Kjetil Tørseth, Martin Album Ytre-Eide, Zhenfa Zhang, and Wenche Aas
Atmos. Chem. Phys., 24, 2731–2758, https://doi.org/10.5194/acp-24-2731-2024, https://doi.org/10.5194/acp-24-2731-2024, 2024
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We discuss carbonaceous aerosol (CA) observed at the high Arctic Zeppelin Observatory (2017 to 2020). We find that organic aerosol is a significant fraction of the Arctic aerosol, though less than sea salt aerosol and mineral dust, as well as non-sea-salt sulfate, originating mainly from anthropogenic sources in winter and from natural sources in summer, emphasizing the importance of wildfires for biogenic secondary organic aerosol and primary biological aerosol particles observed in the Arctic.
Wei Huang, Cheng Wu, Linyu Gao, Yvette Gramlich, Sophie L. Haslett, Joel Thornton, Felipe D. Lopez-Hilfiker, Ben H. Lee, Junwei Song, Harald Saathoff, Xiaoli Shen, Ramakrishna Ramisetty, Sachchida N. Tripathi, Dilip Ganguly, Feng Jiang, Magdalena Vallon, Siegfried Schobesberger, Taina Yli-Juuti, and Claudia Mohr
Atmos. Chem. Phys., 24, 2607–2624, https://doi.org/10.5194/acp-24-2607-2024, https://doi.org/10.5194/acp-24-2607-2024, 2024
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We present distinct molecular composition and volatility of oxygenated organic aerosol particles in different rural, urban, and mountain environments. We do a comprehensive investigation of the relationship between the chemical composition and volatility of oxygenated organic aerosol particles across different systems and environments. This study provides implications for volatility descriptions of oxygenated organic aerosol particles in different model frameworks.
Jing Cai, Juha Sulo, Yifang Gu, Sebastian Holm, Runlong Cai, Steven Thomas, Almuth Neuberger, Fredrik Mattsson, Marco Paglione, Stefano Decesari, Matteo Rinaldi, Rujing Yin, Diego Aliaga, Wei Huang, Yuanyuan Li, Yvette Gramlich, Giancarlo Ciarelli, Lauriane Quéléver, Nina Sarnela, Katrianne Lehtipalo, Nora Zannoni, Cheng Wu, Wei Nie, Juha Kangasluoma, Claudia Mohr, Markku Kulmala, Qiaozhi Zha, Dominik Stolzenburg, and Federico Bianchi
Atmos. Chem. Phys., 24, 2423–2441, https://doi.org/10.5194/acp-24-2423-2024, https://doi.org/10.5194/acp-24-2423-2024, 2024
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By combining field measurements, simulations and recent chamber experiments, we investigate new particle formation (NPF) and growth in the Po Valley, where both haze and frequent NPF occur. Our results show that sulfuric acid, ammonia and amines are the dominant NPF precursors there. A high NPF rate and a lower condensation sink lead to a greater survival probability for newly formed particles, highlighting the importance of gas-to-particle conversion for aerosol concentrations.
Kira Zeider, Grace Betito, Anthony Bucholtz, Peng Xian, Annette Walker, and Armin Sorooshian
EGUsphere, https://doi.org/10.5194/egusphere-2024-392, https://doi.org/10.5194/egusphere-2024-392, 2024
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The predominant wind direction along the California coast (northerly) reverses several times during the summer (to southerly). The effects of these wind reversals on aerosol and cloud characteristics are not well understood. Using data from multiple datasets we found that southerly flow periods had enhanced signatures of anthropogenic emissions due to shipping/continental sources, and clouds had more but smaller droplets.
Mikko Heikkilä, Krista Luoma, Timo Mäkelä, and Tiia Grönholm
EGUsphere, https://doi.org/10.5194/egusphere-2023-2823, https://doi.org/10.5194/egusphere-2023-2823, 2024
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Black carbon (BC) concentration was measured from 211 ship exhaust gas plumes at a remote marine station. Emission factors of BC were calculated in grams/kilograms fuel. Ships using exhaust gas cleaning systems (EGCS) were found to emit 80 % less BC than ships without EGCS. Emission factors were used to model BC emissions as a function of speed to define the effect of speed reduction. BC emissions increased with a decrease in speed from the ship’s service speed.
Kaori Kawana, Fumikazu Taketani, Kazuhiko Matsumoto, Yutaka Tobo, Yoko Iwamoto, Takuma Miyakawa, Akinori Ito, and Yugo Kanaya
Atmos. Chem. Phys., 24, 1777–1799, https://doi.org/10.5194/acp-24-1777-2024, https://doi.org/10.5194/acp-24-1777-2024, 2024
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Based on comprehensive shipborne observations, we found strong links between sea-surface biological materials and the formation of atmospheric fluorescent bioaerosols, cloud condensation nuclei, and ice-nucleating particles over the Arctic Ocean and Bering Sea during autumn 2019. Taking the wind-speed effect into account, we propose equations to approximate the links for this cruise, which can be used as a guide for modeling as well as for systematic comparisons with other observations.
Chen He, Hanxiong Che, Zier Bao, Yiliang Liu, Qing Li, Miao Hu, Jiawei Zhou, Shumin Zhang, Xiaojiang Yao, Quan Shi, Chunmao Chen, Yan Han, Lingshuo Meng, Xin Long, Fumo Yang, and Yang Chen
Atmos. Chem. Phys., 24, 1627–1639, https://doi.org/10.5194/acp-24-1627-2024, https://doi.org/10.5194/acp-24-1627-2024, 2024
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We examined the daily evolution of high molecular-weight organic compounds with a molecular weight of up to 1000 Da in order to comprehend their behaviors in the atmosphere under actual conditions. These compounds were proven to undergo multi-generation oxidation, carboxylation, and nitrification via both day- and nighttime chemistry.
Karine Desboeufs, Paola Formenti, Raquel Torres-Sánchez, Kerstin Schepanski, Jean-Pierre Chaboureau, Hendrik Andersen, Jan Cermak, Stefanie Feuerstein, Benoit Laurent, Danitza Klopper, Andreas Namwoonde, Mathieu Cazaunau, Servanne Chevaillier, Anaïs Feron, Cécile Mirande-Bret, Sylvain Triquet, and Stuart J. Piketh
Atmos. Chem. Phys., 24, 1525–1541, https://doi.org/10.5194/acp-24-1525-2024, https://doi.org/10.5194/acp-24-1525-2024, 2024
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This study investigates the fractional solubility of iron (Fe) in dust particles along the coast of Namibia, a critical region for the atmospheric Fe supply of the South Atlantic Ocean. Our results suggest a possible two-way interplay whereby marine biogenic emissions from the coastal marine ecosystems into the atmosphere would increase the solubility of Fe-bearing dust by photo-reduction processes. The subsequent deposition of soluble Fe could act to further enhance marine biogenic emissions.
Sunhye Kim, Jo Machesky, Drew R. Gentner, and Albert A. Presto
Atmos. Chem. Phys., 24, 1281–1298, https://doi.org/10.5194/acp-24-1281-2024, https://doi.org/10.5194/acp-24-1281-2024, 2024
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Cooking emissions are often an overlooked source of air pollution. We used a mobile lab to measure the characteristics of particles emitted from cooking sites in two cities. Our findings showed that cooking releases a substantial number of fine particles. While most emissions were similar, a bakery site showed distinctive chemical compositions with higher nitrogen compound levels. Thus, understanding the particle emissions from different cooking activities is crucial.
Cited articles
Allison, I.: Surface climate of the interior of the Lambert Glacier basin, Antarctica, from automatic weather station data, Ann. Glaciol., 27, 515–520, 1998.
Artaxo, P., Rabello, M. L. C., Maenhaut, W., and van Grieken, R.: Trace elements and individual particle analysis of atmospheric aerosols from the Antarctic Peninsula, Tellus, 44, 318–334, 1992.
Bodhaine, B. A.: Aerosol absorption measurements at Barrow, Mauna Loa and the South Pole, J. Geophys. Res., 100, 8967–8975, 1995.
Davis, D., Nowak, J. B., Chen, G., Buhr, M., Arimoto, R., Hogan, A., Eisele, F., Mauldin, L., Tanner, D., Shetter, R., Lefer, B., and McMurry, P.: Unexpected high levels of NO observed at South Pole, Geophys. Res. Lett., 28, 3625–3628, 2001.
Davis, D., Chen, G., Buhr, M., Crawford, J., Lenschow, D., Lefer, B., Shetter, R., Eisele, F., Mauldin, L., and Hogan, A.: South Pole NOx chemistry: an assessment of factors controlling variability and absolute levels, Atmos. Environ., 38, 5375–5388, 2004.
Delmonte, B., Petit, J. R., Andersen, K. K., Basile-Doelsch, I., Maggi, V., and Ya Lipenkov, V.: Dust size evidence for opposite regional atmospheric circulation changes over east Antarctica during the last climatic transition, Clim. Dynam., 23, 427–438, https://doi.org/10.1007/s00382-004-0450-9, 2004.
Delmonte, B., Petit, J. R., Basile-Doelsch, I., Jagoutz, E., and Maggi, V.: Late quaternary interglacials in East Antarctica from ice-core dust records, in: Developments in Quaternary Sciences, edited by: Sirocko, F., Claussen, M., Sánchez Goñi, M. F., and Litt, T., Elsevier, 7, 53–73, ISSN 1571-0866, ISBN 9780444529558, 2007.
Dibb, J., Huey, L., Slusher, D., and Tanner, D.: Soluble reactive nitrogen oxides at South Pole during isCAT 2000, Atmos. Environ., 38, 5399–5409, https://doi.org/10.1016/j.atmosenv.2003.01.001, 2004.
Ding, Z. J., Li, Y. G., Zeng, R. G., Mao, S. F., Zhang, P., and Zhang, Z. M.: Depth distribution functions of secondary electron production and emission, J. Surface Anal., 15, 249–253, 2009.
Draxler, R. R. and Rolph, G. D.: HYSPLIT (HYbrid Single-Particle Lagrangian Integrated Trajectory) Model access via NOAA ARL READY Website (http://ready.arl.noaa.gov/HYSPLIT.php), NOAA Air Resources Laboratory, Silver Spring, MD, 2013.
Eisele, F., Davis, D. D., Helmig, D., Oltmans, S. J., Neff, W., Huey, G., Tanner, D., Chen, G., Crawford, J., Arimoto, R., Buhr, M., Mauldin, L., Hutterli, M., Dibb, J., Blake, D., Brooks, S. B., Johnson, B., Roberts, J. M., Wang, Y., Tan, D., and Flocke, F.: Antarctic Tropospheric Chemistry Investigation (ANTCI) 2003 overview, Atmos. Environ., 42, 2749–2761, https://doi.org/10.1016/j.atmosenv.2007.04.013, 2008.
Frey, M. M., Savarino, J., Morin, S., Erbland, J., and Martins, J. M. F.: Photolysis imprint in the nitrate stable isotope signal in snow and atmosphere of East Antarctica and implications for reactive nitrogen cycling, Atmos. Chem. Phys., 9, 8681–8696, https://doi.org/10.5194/acp-9-8681-2009, 2009.
Fujita, S., Holmlund, P., Andersson, I., Brown, I., Enomoto, H., Fujii, Y., Fujita, K., Fukui, K., Furukawa, T., Hansson, M., Hara, K., Hoshina, Y., Igarashi, M., Iizuka, Y., Imura, S., Ingvander, S., Karlin, T., Motoyama, H., Nakazawa, F., Oerter, H., Sjöberg, L. E., Sugiyama, S., Surdyk, S., Ström, J., Uemura, R., and Wilhelms, F.: Spatial and temporal variability of snow accumulation rate on the East Antarctic ice divide between Dome Fuji and EPICA DML, The Cryosphere, 5, 1057–1081, https://doi.org/10.5194/tc-5-1057-2011, 2011.
Fujita, S., Fukui, K., Nakazawa, F., Enomoto, H., and Sugiyama, S.: Report of the Japanese-Swedish joint Antarctic traverse: II, Report of field expedition in 2007/2008 season, Submitted to Antarctic record, 2014 (in Japanese with English abstract).
Ge, Z., Wexler, A. S., and Johnston, M. V.: Deliquescence Behavior of Multicomponent Aerosols, J. Phys. Chem. A, 102, 173–180, 1998.
Geilfus, N.-X., Galley, R. J., Cooper, M., Halden, N., Hare, A., Wang, F., Søgaard, D. H., and Rysgaard, S.: Gypsum crystals observed in experimental and natural sea ice, Geophys. Res. Lett., 40, 6362–-6367, https://doi.org/10.1002/2013GL058479, 2013.
Goldstein, J. I., Newbury, D. E., Joy, D. C., Lyman, C. E., Echlin, P., Lifshin, E., Sawyer, L., and Michael, J.: Chapter 6 Generation of X-rays in the SEM specimen, in: Scanning Electron Microscopy and X-ray Micronalysis, 3, 271–296, Plenum Press, New York, 2003.
Hara, K., Kikuchi, T., Furuya, K., Hayashi, M., and Fujii, Y.: Characterization of Antarctic aerosol particles using laser microprobe mass spectrometry, Environ. Sci. Technol., 30, 385–391, 1995.
Hara, K., Osada, K., Hayashi, M., Matsunaga, K., Shibata, T., Iwasaka, Y., and Furuya, K.: Fractionation of inorganic nitrates in winter Arctic troposphere: Coarse aerosol particles containing inorganic nitrates, J. Geophy. Res., 104, 23671–23679, https://doi.org/10.1029/1999JD900348, 1999.
Hara, K., Osada, K., Nishita, C., Yamagata, S., Yamanouchi, T., Herber, A., Matsunaga, K., Iwasaka, Y., Nagatani, M., and Nakata, H.: Vertical variations of sea-salt modification in the boundary layer of spring Arctic during the ASTAR 2000 campaign, Tellus, 54B, 361–376, 2002.
Hara, K., Osada, K., Kido, M., Hayashi, M., Matsunaga, K., Iwasaka, Y., Yamanouchi, T., Hashida, G., and Fukatsu, T.: Chemistry of sea-salt particles and inorganic halogen species in the Antarctic regions: Compositional differences between coastal and inland stations, J. Geophys. Res., 109, D20208, https://doi.org/10.1029/2004JD004713, 2004.
Hara, K., Osada, K., Kido, M., Matsunaga, K., Iwasaka, Y., and Hashida, G.: Seasonal variations of sea-salt constituents and sea-salt modification at Syowa station, Antarctica, Tellus, 57B, 230–246, 2005.
Hara, K., Osada, K., Yabuki, M., Hashida, G., Yamanouchi, T., Hayashi, M., Shiobara, M., Nishita-Hara, C., and Wada, M.: Haze episodes at Syowa Station, coastal Antarctica: Where did they come from?, J. Geophys. Res., 115, D14205, https://doi.org/10.1029/2009JD012582, 2010a.
Hara, K., Hirasawa, N., Yamanouchi, T., Wada, M., Herber, A., and ANTSYO-II members: Spatial distributions and mixing states of aerosol particles in the summer Antarctic troposphere, Antarctic Record, 54, 704–730, 2010b (in Japanese with English abstract).
Hara, K., Osada, K., Nishita-Hara, C., Yabuki, M., Hayashi, M., Yamanouchi, T., Wada, M., and Shiobara, M.: Seasonal features of ultrafine particle volatility in the coastal Antarctic troposphere, Atmos. Chem. Phys., 11, 9803–9812, https://doi.org/10.5194/acp-11-9803-2011, 2011a.
Hara, K., Osada, K., Nishita-Hara, C., and Yamanouchi, T.: Seasonal variations and vertical features of aerosol particles in the Antarctic troposphere, Atmos. Chem. Phys., 11, 5471–5484, https://doi.org/10.5194/acp-11-5471-2011, 2011b.
Hara, K., Osada, K., Yabuki, M., and Yamanouchi, T.: Seasonal variation of fractionated sea-salt particles on the Antarctic coast, Geophys. Res. Lett., 39, L18801, https://doi.org/10.1029/2012GL052761, 2012.
Hara, K., Osada, K., and Yamanouchi, T.: Tethered balloon-borne aerosol measurements: seasonal and vertical variations of aerosol constituents over Syowa Station, Antarctica, Atmos. Chem. Phys., 13, 9119–9139, https://doi.org/10.5194/acp-13-9119-2013, 2013.
Helmig, D., Johnson, B., Warshawsky, M., Morse, T., Neff, W., Eisele, F., and Davis, D. D.: Nitric Oxide in the Boundary-Layer at South Pole during the Antarctic Tropospheric Chemistry Investigation (ANTCI), Atmos. Environ., 42, 2817–2830, 2008.
Hirasawa, N., Nakamura, H., Motoyama, H., Hayashi, M., and Yamanouchi, T.: The role of synoptic-scale features and advection in prolonged warming and generation of different forms of precipitation at Dome Fuji station, Antarctica, following a prominent blocking event, J. Geophys. Res.-Atmos., 118, 6916–6928, https://doi.org/10.1002/jgrd.50532, 2013.
Huey, L. G., Tanner, D. J., Slusher, D. L., Dibb, J. E., Arimoto, R., Chen, G., Davis, D., Buhr, M. P., Nowak, J. B., Mauldin III, R. L., Eisele, F. L., and Kosciuch, E.: CIMS measurements of HNO3 and SO2 at the South Pole during ISCAT 2000, Atmos. Environ., 38, 5411–5421, https://doi.org/10.1016/j.atmosenv.2004.04.037, 2004.
Iizuka, Y., Tsuchimoto, A., Hoshina, Y., Sakurai, T., Hansson, M., Karlin, T., Fujita, K., Nakazawa, F., Motoyama, H., and Fujita, S.: The rates of sea salt sulfatization in the atmosphere and surface snow of inland Antarctica, J. Geophys. Res., 117, D04308, https://doi.org/10.1029/2011JD016378, 2012.
Jones, A. E., Wolff, E. W., Ames, D., Bauguitte, S. J.-B., Clemitshaw, K. C., Fleming, Z., Mills, G. P., Saiz-Lopez, A., Salmon, R. A., Sturges, W. T., and Worton, D. R.: The multi-seasonal NOy budget in coastal Antarctica and its link with surface snow and ice core nitrate: results from the CHABLIS campaign, Atmos. Chem. Phys., 11, 9271–9285, https://doi.org/10.5194/acp-11-9271-2011, 2011.
Jourdain, B. and Legrand, M.: Seasonal variations of atmospheric dimethylsulfide, dimethylsulfoxide, sulfur dioxide, methanesulfonate, and non-sea-salt sulfate aerosols at Dumont d'Urville (coastal Antarctica) (December 1998 to July 1999), J. Geophys. Res., 106, 14391–14408, 2001.
Jourdain, B. and Legrand, M.: Year-round records of bulk and size-segregated aerosol composition and HCl and HNO3 levels in the Dumont d'Urville (coastal Antarctica) atmosphere: Implications for sea-salt aerosol fractionation in the winter and summer, J. Geophys. Res., 107, 4645, https://doi.org/10.1029/2002JD002471, 2002.
Jourdain, B., Preunkert, S., Cerri, O., Castebrunet, H., Udisti, R., and Legrand, M.: Year-round record of size-segregated aerosol composition in central Antarctica (Concordia station): Implications for the degree of fractionation of sea-salt particles, J. Geophys. Res., 113, D14308, https://doi.org/10.1029/2007JD009584, 2008.
Junge, C. E.: Aerosols in "Air chemistry and radioactivity", Academic Press, 111–208, 1963.
Kahl, J., Harris, J., Herbert, G., and Olson, M.: Intercomparison of three long-range trajectory models applied to Arctic haze, Tellus B, 41B, 418, 524–536, 1989.
Kameda, T., Azuma, N., Furukawa, T., Ageta, Y., and Takahashi, S.: Surface mass balance, sublimation and snow temperatures at Dome Fuji Station, Antarctica, in 1995, Proc. NIPR Symp. Polar Meteorol. Glaciol., 11, 24–34, 1997.
Kelly, J. T. and Wexler, A. S.: Thermodynamics of carbonates and hydrates related to heterogeneous reactions involving mineral aerosol, J. Geophys. Res., 110, D11201, https://doi.org/10.1029/2004JD005583, 2005.
Kerminen, V. M., Teinilä, K., and Hillamo, R.: Chemistry of sea-salt particles in the summer Antarctic atmosphere, Atmos. Environ., 34, 2817–2825, 2000.
King, J. C., Argentini, S. A., and Anderson, P. S.: Contrasts between the summertime surface energy balance and boundary layer structure at Dome C and Halley stations, Antarctica, J. Geophys. Res., 111, D02105, https://doi.org/10.1029/2005JD006130, 2006.
Laskin, A., Moffet, R. C., Gilles, M. K., Fast, J. D., Zaveri, R. A., Wang, B., Nigge, P., and Shutthanandan, J.: Tropospheric chemistry of internally mixed sea salt and organic particles: Surprising reactivity of NaCl with weak organic acids, J. Geophys. Res., 117, D15302, https://doi.org/10.1029/2012JD017743, 2012.
Legrand, M., Sciare, J., Jourdain, B., and Genthon, C.: Subdaily variations of atmospheric dimethylsulfide, dimethylsulfoxide, methanesulfonate, and non-sea-salt sulfate aerosols in the atmospheric boundary layer at Dumont d'Urville (coastal Antarctica) during summer, J. Geophys. Res., 106, 409–14, 2001.
Legrand, M., Preunkert, S., Jourdain, B., and Aumont, B.: Year-round records of gas and particulate formic and acetic acids in the boundary layer at Dumont d'Urville, coastal Antarctica. J. Geophys. Res., 109, D06313, https://doi.org/10.1029/2003JD003786, 2004.
Marion, G. M. and Farren, R. E.: Mineral solubilities in the Na-K-Mg-Ca-Cl-SO4-H2O system: a re-evaluation of the sulfate chemistry in the Spencer-Møller-Weare model, Geochim. Cosmochim. Acta, 63, 1305–1318, https://doi.org/10.1016/S0016-7037(99)00102-7, 1999.
Minikin, A., Legrand, M., Hall, J., Wagenbach, D., Kleefeld, C., Wolff, E., Pasteur, E., and Ducroz, F.: Sulfur-containing species (sulfate and methanesulfonate) in coastal Antarctic aerosol and precipitation, J. Geophys. Res., 103, 10975–10990, 1998.
Motoyama, H., Hirasawa, N., Satow, K., and Watanabe, O.: Seasonal variations in oxygen isotope ratios of daily collected precipitation and wind drift samples and in the final snow cover at Dome Fuji Station, Antarctica, J. Geophys. Res., 110, D11106, https://doi.org/10.1029/2004JD004953, 2005.
Mouri, H., Nagao, I., Okada, K., Koga, S., and Tanaka, H.: Individual-particle analyses of coastal Antarctic aerosols, Tellus, 51B, 603–611, 1999.
Neff, W., Helmig, D., Grachev, A., and Davis, D.: A study of boundary layer behavior associated with high NO concentrations at the South Pole using a minisodar, tethered balloon, and sonic anemometer, Atmos. Environ., 42, 2762-2779, https://doi.org/10.1016/j.atmosenv.2007.01.033, 2008.
Niemi, J., Tervahattu, H., Virkkula, A., Hillamo, R., Teinilä, K., Koponen, I., and Kulmala, M.: Continental Impact on Marine Boundary Layer Coarse Particles over the Atlantic Ocean between Europe and Antarctica, Atmos. Res , 75, 301–321, 2005.
Okada, K., Ikegami, M., Zaizen, Y., Makino, Y., Jensen, J. and Gras, J.: The mixture state of individual aerosol particles in the 1997 Indonesian haze episode, J. Aerosol Sci., 32, 1269–1279, https://doi.org/10.1016/S0021-8502(01)00062-3, 2001.
Okada, K., Ikegami, M., Zaizen, Y., Tsutsumi, Y., Makino, Y., Jensen, J., and Gras, J. L.: Submicrometer Sulfur-Rich Particles in the Middle Troposphere: Aircraft Observations from Australia to Japan, Atmos. Res., 88, 185–198, 2008.
Parungo, F., Ackerman, E., Caldwell, W., and Weickmann, H.: Individual Particle Analysis of Antarctic Aerosols, Tellus, 31, 521–529, 1979.
Preunkert, S., Jourdain, B., Legrand, M., Udisti, R., Becagli, S., and Cerri, O.: Seasonality of sulfur species (dimethylsulfide, sulfate, and methanesulfonate) in Antarctica: Inland versus coastal regions, J. Geophys. Res., 113, D15302, https://doi.org/10.1029/2008JD009937, 2008.
Ram, M., Gayley, R., and Petit, J.-R.: Insoluble particles in Antarctic ice – Background aerosol size distribution and diatom concentration, J. Geophys. Res., 93, 8378–8382, https://doi.org/10.1029/JD093iD07p08378, 1988.
Rankin, A. M., Auld, V., and Wolff, E. W.: Frost flowers as a source of fractionated sea salt aerosol in the polar regions, Geophys. Res. Lett., 27, 3469–3472, https://doi.org/10.1029/2000GL011771, 2000.
Rankin, A. M., Wolff, E. W., and Martin, S.: Frost flowers: Implications for tropospheric chemistry and ice core interpretation, J. Geophys. Res., 107, 4683, https://doi.org/10.1029/2002JD002492, 2002.
Rankin, A. M. and Wolff, E. W.: A year-long record of size-segregated aerosol composition at Halley, Antarctica, J. Geophys. Res., 108, 4775, https://doi.org/10.1029/2003JD003993, 2003.
Read, K. A., Lewis, A. C., Bauguitte, S., Rankin, A. M., Salmon, R. A., Wolff, E. W., Saiz-Lopez, A., Bloss, W. J., Heard, D. E., Lee, J. D., and Plane, J. M. C.: DMS and MSA measurements in the Antarctic Boundary Layer: impact of BrO on MSA production, Atmos. Chem. Phys., 8, 2985–2997, https://doi.org/10.5194/acp-8-2985-2008, 2008.
Reijmer, C. H. and van den Broeke, M. R.: Moisture source of precipitation in Western Dronning Maud Land, Antarctica, Antarct. Sci., 13, 210–220, https://doi.org/10.1017/S0954102001000293, 2001.
Reijmer, C. H., van den Broeke, M. R., and Scheele, M. P.: Air parcel trajectories and snowfall related to five deep drilling locations in Antarctica based on the ERA-15 dataset, J. Climate, 15, 1957–1968, https://doi.org/10.1175/1520-0442(2002)015<1957:APTASR>2.0.CO;2, 2002.
Sato, K. and Hirasawa, N.: Statistics of Antarctic surface meteorology based on hourly data in 1957–2007 at Syowa Station, Polar Sci., 1, 1–15, 2007.
Savoie, D. L., Prospero, J. M., Larsen, R. J., and Saltzman, E. S.: Nitrogen and sulfur species in aerosols at Mawson, Antarctica, and their relationship to natural radionuclides, J. Atmos. Chem., 14, 181–204, 1992.
Savoie, D. L., Prospero, J. M., Larsen, R. J., Huang, F., Izaguirre, M. A., Huang, T., Snowdon, T. H., Custals, L., and Sanderson, C. G.: Nitrogen and sulfur species in Antarctic aerosols at Mawson, Palmer Station, and Marsh (King George Island), J. Atmos. Chem., 17, 95–122, 1993.
Stohl, A., Wotawa, G., and Seibert, P.: Interpolation errors in wind fields as a function of spatial and temporal resolution and their impact on different types of kinematic trajectories, J. Appl. Meteorol., 34, 2149–2165, 1995.
Suzuki, K., Yamanouchi, T., and Motoyama, H.: Moisture transport to Syowa and Dome Fuji stations in Antarctica, J. Geophys. Res., 113, https://doi.org/10.1029/2008JD009794, 2008.
Suzuki, K., Yamanouchi, T., Kawamura, K., and Motoyama, H.: The spatial and seasonal distributions of air-transport origins to the Antarctic based on 5-day backward trajectory analysis, Polar Sci., 7, 205–213, 2013.
Tang, I. N.: Deliquescence properties and particle size change of hygroscopic aerosols, in "Generation of aerosols and facilities for exposure experiments", edited by: K. Willeke, Chapter 7, 153–167, Butterworth, Stoneham, Mass., 1980.
Tang, I. N. and Munkelwitz, H. R.: Composition and temperature dependence of the deliquescence properties of hygroscopic aerosols, Atmos. Environ, 27, 467–473, 1993.
Tang, I. N. and Munkelwitz, H. R.: Water activities, densities, and refractive indices of aqueous sulfates and sodium nitrate droplets of atmospheric importance, J. Geophys. Res., 99, 2156–2202, https://doi.org/10.1029/94JD01345, 1994.
Teinilä, K., Kerminen, V.-M., and Hillamo, R.: A study of size-segregated aerosol chemistry in the Antarctic atmosphere, J. Geophys. Res., 105, 3893–3904, https://doi.org/10.1029/1999JD901033, 2000.
Udisti, R., Dayan, U., Becagli, S., Busetto, M., Frosini, D., Legrand, M., Lucarelli, F., Preunkert, S., Severi, M., Traversi, R., and Vitale, V.: Sea spray aerosol in central Antarctica. Present atmospheric behaviour and implications for paleoclimatic reconstructions, Atmos. Environ., 52, 109–120, 2012.
Van As, D., Van Den Broeke, M., and Van De Wal, R.: Daily cycle of the surface layer and energy balance on the high Antarctic Plateau, Antarct. Sci., 17, 121–133, 2005.
Wagenbach, D., Ducroz, F., Mulvaney, R., Keck, L., Minikin, A., Legrand, M. J., Hall, S., and Wolff, E. W.: Sea-salt aerosol in coastal Antarctic regions, J. Geophys. Res., 103, 10961–10974, 1998.
Wang, L.-Y., Ding, F., Zhang, Y.-H., Zhao, L.-J., and Hu, Y.-A.: Anomalous hygroscopic growth of fine particles of MgSO4 aerosols investigated by FTIR/ATR spectroscopy, Spectrochimica Acta Part A, 71, 682–687, https://doi.org/10.1016/j.saa.2008.01.027, 2008.
Weller, R. and Wagenbach, D.: Year-round chemical aerosol records in continental Antarctica obtained by automatic samplings, Tellus, 59B, 755–765, 2007.
Weller, R., Jones, A. E., Wille, A., Jacobi, H.-W., McIntyre, H. P., Sturges, W. T., Huke, M., and Wagenbach, D.: Seasonality of reactive nitrogen oxides (NOy) at Neumayer Station, Antarctica, J. Geophys. Res., 107, 4673, https://doi.org/10.1029/2002JD002495, 2002.
Weller, R., Minikin, A., Wagenbach, D., and Dreiling, V.: Characterization of the inter-annual, seasonal, and diurnal variations of condensation particle concentrations at Neumayer, Antarctica, Atmos. Chem. Phys., 11, 13243–13257, https://doi.org/10.5194/acp-11-13243-2011, 2011.
Wilson, T. R.: Salinity and the major elements of sea-water, in: Chemical Oceanography, edited by: Riley, J. P. and Skirrow, G., 365–413, Academic Press, San Diego, Calif., 1975.
Wise, M. E., Freney, E. J., Tyree, C. A., Allen, J. O., Martin, S. T., Russell, L. M., and Buseck P. R.: Hygroscopic behavior and liquid-layer composition of aerosol particles generated from natural and artificial seawater, J. Geophys. Res., 114, D03201, https://doi.org/10.1029/2008JD010449, 2009.
Woods, E., Chung, D., Lanney, H. M., and Ashwell, B. A.: Surface morphology and phase transitions in mixed NaCl/MgSO4 aerosol particles, J. Phys. Chem. A, 114, 2837–2844, 2010.
Wouters, L., Artaxo, P., and van Grieken, R.: Laser Microprobe Mass Analysis of Individual Antarctic Aerosol Particles, Int. J. Environ. Anal. Chem., 38, 427–438, 1990.
Yamato, M., Iwasaka, Y., Ono, A., and Yoshida, M.: On the sulfate particles in the submicron size range collected at Mizuho Station and in east Queen Maud Land, Antarctica, Polar Meteorol. Glaciol., 1, 82–90, 1987a.
Yamato, M., Iwasaka, Y., Okada, K., Ono, A., Nishio, F., and Fukabori, M.: Evidence for the presence of submicron sulfuric acid particles in summer Antarctic atmosphere: Preliminary results, Proc. NIPR Symp. Polar Meteorol. Glaciol., 1, 74–81, 1987b.
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