Articles | Volume 8, issue 16
https://doi.org/10.5194/acp-8-4855-2008
© Author(s) 2008. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-8-4855-2008
© Author(s) 2008. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Multiphase modeling of nitrate photochemistry in the quasi-liquid layer (QLL): implications for NOx release from the Arctic and coastal Antarctic snowpack
C. S. Boxe
Earth and Space Science Div., NASA Jet Propulsion Laboratory, California Inst. of Technology, Pasadena, CA 91109, USA
A. Saiz-Lopez
Earth and Space Science Div., NASA Jet Propulsion Laboratory, California Inst. of Technology, Pasadena, CA 91109, USA
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Cited
62 citations as recorded by crossref.
- Nitrate Concentration near the Surface of Frozen Aqueous Solutions H. Marrocco & R. Michelsen 10.1021/jp508244u
- Exclusion of Nitrate to the Air–Ice Interface During Freezing S. Wren & D. Donaldson 10.1021/jz2007484
- Calculations of in-snow NO2and OH radical photochemical production and photolysis rates: A field and radiative-transfer study of the optical properties of Arctic (Ny-Ålesund, Svalbard) snow J. France et al. 10.1029/2011JF002019
- Atmospheric nitric oxide and ozone at the WAIS Divide deep coring site: a discussion of local sources and transport in West Antarctica S. Masclin et al. 10.5194/acp-13-8857-2013
- The influence of snow grain size and impurities on the vertical profiles of actinic flux and associated NO<sub>x</sub> emissions on the Antarctic and Greenland ice sheets M. Zatko et al. 10.5194/acp-13-3547-2013
- Freezing-enhanced reduction of chromate by nitrite K. Kim et al. 10.1016/j.scitotenv.2017.02.176
- Air–snow exchange of nitrate: a modelling approach to investigate physicochemical processes in surface snow at Dome C, Antarctica J. Bock et al. 10.5194/acp-16-12531-2016
- Modeling chemistry in and above snow at Summit, Greenland – Part 1: Model description and results J. Thomas et al. 10.5194/acp-11-4899-2011
- Arctic halogens reduce ozone in the northern mid-latitudes R. Fernandez et al. 10.1073/pnas.2401975121
- Nitrate Photolysis in Salty Snow K. Morenz et al. 10.1021/acs.jpca.6b06685
- Nitrate Photochemistry in NaY Zeolite: Product Formation and Product Stability under Different Environmental Conditions A. Gankanda & V. Grassian 10.1021/jp312247m
- The quasi-liquid layer of ice revisited: the role of temperature gradients and tip chemistry in AFM studies J. Gelman Constantin et al. 10.5194/acp-18-14965-2018
- Role of Nitrite in the Photochemical Formation of Radicals in the Snow H. Jacobi et al. 10.1021/es404002c
- Photolysis of frozen iodate salts as a source of active iodine in the polar environment Ó. Gálvez et al. 10.5194/acp-16-12703-2016
- The effect of the novel HO2 + NO → HNO3 reaction channel at South Pole, Antarctica C. Boxe et al. 10.1017/S0954102012000144
- Influence of thin liquid films on polar ice chemistry: Implications for Earth and planetary science C. Boxe & A. Saiz-Lopez 10.1016/j.polar.2009.01.001
- Using Singlet Molecular Oxygen to Probe the Solute and Temperature Dependence of Liquid-Like Regions in/on Ice J. Bower & C. Anastasio 10.1021/jp404071y
- Air–snow transfer of nitrate on the East Antarctic Plateau – Part 2: An isotopic model for the interpretation of deep ice-core records J. Erbland et al. 10.5194/acp-15-12079-2015
- Cryoprotective Polyol-Induced Ice Microstructure Development and Enhanced Chromium(VI) Reduction in Polycrystalline Structures B. Kim & K. Kim 10.1021/acs.cgd.4c01067
- Production of Molecular Iodine and Tri-iodide in the Frozen Solution of Iodide: Implication for Polar Atmosphere K. Kim et al. 10.1021/acs.est.5b05148
- Investigating the photo-oxidative and heterogeneous chemical production of HCHO in the snowpack at the South Pole, Antarctica P. Hamer et al. 10.1071/EN13227
- Development of a Mechanism for Nitrate Photochemistry in Snow J. Bock & H. Jacobi 10.1021/jp909205e
- Accelerated dissolution of iron oxides in ice D. Jeong et al. 10.5194/acp-12-11125-2012
- Appearance and Disappearance of Quasi-Liquid Layers on Ice Crystals in the Presence of Nitric Acid Gas K. Nagashima et al. 10.3390/cryst10020072
- Accumulation of dissolved organic matter in the transition from fresh to aged seasonal snow in an industrial city in NE China Z. Mu et al. 10.1016/j.scitotenv.2022.159337
- Observation of gas-phase peroxynitrous and peroxynitric acid during the photolysis of nitrate in acidified frozen solutions O. Abida et al. 10.1016/j.cplett.2011.06.055
- The Effect of Freezing on Reactions with Environmental Impact R. O’Concubhair & J. Sodeau 10.1021/ar400114e
- A mechanism for biologically induced iodine emissions from sea ice A. Saiz-Lopez et al. 10.5194/acp-15-9731-2015
- Coupling of HO<sub>x</sub>, NO<sub>x</sub> and halogen chemistry in the antarctic boundary layer W. Bloss et al. 10.5194/acp-10-10187-2010
- On the pH dependence of photo-induced volatilization of nitrogen oxides from frozen solutions containing nitrate O. Abida & H. Osthoff 10.1029/2011GL048517
- Nitrate Ion Photolysis in Thin Water Films in the Presence of Bromide Ions N. Richards et al. 10.1021/jp109560j
- Effect of Ionic Strength on Solvation Geometries in Aqueous Nitrate Ion Solutions K. Jones et al. 10.1021/acs.jpca.6b12102
- Nitric acid-induced surface disordering on ice S. Moussa et al. 10.1039/c3cp50487e
- Modeling interfacial liquid layers on environmental ices M. Kuo et al. 10.5194/acp-11-9971-2011
- Photolysis imprint in the nitrate stable isotope signal in snow and atmosphere of East Antarctica and implications for reactive nitrogen cycling M. Frey et al. 10.5194/acp-9-8681-2009
- Enabling Forbidden Processes: Quantum and Solvation Enhancement of Nitrate Anion UV Absorption O. Svoboda et al. 10.1021/jp4098777
- Isotope Fractionation of Nitrate During Volatilization in Snow: A Field Investigation in Antarctica G. Shi et al. 10.1029/2019GL081968
- Advances in Cryochemistry: Mechanisms, Reactions and Applications L. An et al. 10.3390/molecules26030750
- Nitrate Photochemistry at the Air–Ice Interface and in Other Ice Reservoirs A. McFall et al. 10.1021/acs.est.8b00095
- Quantum Yields of Nitrite (NO2–) from the Photolysis of Nitrate (NO3–) in Ice at 313 nm K. Benedict & C. Anastasio 10.1021/acs.jpca.7b08839
- Adsorbed water and thin liquid films on Mars C. Boxe et al. 10.1017/S1473550412000080
- Nitrate postdeposition processes in Svalbard surface snow M. Björkman et al. 10.1002/2013JD021234
- HONO, Particulate Nitrite, and Snow Nitrite at a Midlatitude Urban Site during Wintertime Q. Chen et al. 10.1021/acsearthspacechem.9b00023
- Dynamics of ozone and nitrogen oxides at Summit, Greenland. II. Simulating snowpack chemistry during a spring high ozone event with a 1-D process-scale model K. Murray et al. 10.1016/j.atmosenv.2015.07.004
- Production of gas phase NO2 and halogens from the photolysis of thin water films containing nitrate, chloride and bromide ions at room temperature N. Richards-Henderson et al. 10.1039/c3cp52956h
- Nitrate photolysis in ice and snow: A critical review of its multiphase chemistry C. Blaszczak-Boxe & A. Saiz-Lopez 10.1016/j.atmosenv.2018.09.002
- Ground-State Intermolecular Proton Transfer of N2O4 and H2O: An Important Source of Atmospheric Hydroxyl Radical? G. Luo & X. Chen 10.1021/jz300336s
- Enhanced Removal of Hexavalent Chromium in the Presence of H2O2 in Frozen Aqueous Solutions K. Kim et al. 10.1021/acs.est.5b02702
- Modelling the physical multiphase interactions of HNO<sub>3</sub> between snow and air on the Antarctic Plateau (Dome C) and coast (Halley) H. Chan et al. 10.5194/acp-18-1507-2018
- Modeling the Sources and Chemistry of Polar Tropospheric Halogens (Cl, Br, and I) Using the CAM‐Chem Global Chemistry‐Climate Model R. Fernandez et al. 10.1029/2019MS001655
- Nitrate Photolysis at the Air–Ice Interface of Nature-Identical Snow T. Hullar et al. 10.1021/acsearthspacechem.3c00166
- Hydration of ions and salt crystallization in liquid phase coexistent with ice at temperature below eutectic point M. Harada et al. 10.1039/C1RA00801C
- Reactions at surfaces in the atmosphere: integration of experiments and theory as necessary (but not necessarily sufficient) for predicting the physical chemistry of aerosols B. Finlayson-Pitts 10.1039/b906540g
- Numerical analysis of the chemical kinetic mechanisms of ozone depletion and halogen release in the polar troposphere L. Cao et al. 10.5194/acp-14-3771-2014
- Protonated Nitrosamide and Its Potential Role in the Release of HONO from Snow and Ice in the Dark S. Hellebust et al. 10.1021/jp104327a
- Can We Model Snow Photochemistry? Problems with the Current Approaches F. Domine et al. 10.1021/jp3123314
- A review of air–ice chemical and physical interactions (AICI): liquids, quasi-liquids, and solids in snow T. Bartels-Rausch et al. 10.5194/acp-14-1587-2014
- An isotopic view on the connection between photolytic emissions of NOx from the Arctic snowpack and its oxidation by reactive halogens S. Morin et al. 10.1029/2011JD016618
- Contrasting atmospheric boundary layer chemistry of methylhydroperoxide (CH<sub>3</sub>OOH) and hydrogen peroxide (H<sub>2</sub>O<sub>2</sub>) above polar snow M. Frey et al. 10.5194/acp-9-3261-2009
- An active nitrogen cycle on Mars sufficient to support a subsurface biosphere C. Boxe et al. 10.1017/S1473550411000401
- Impacts of cryogenic sampling processes on iron mineral coatings in contaminated sediment H. Hua et al. 10.1016/j.scitotenv.2020.142796
- Hydroxyl radical and NOxproduction rates, black carbon concentrations and light-absorbing impurities in snow from field measurements of light penetration and nadir reflectivity of onshore and offshore coastal Alaskan snow J. France et al. 10.1029/2011JD016639
61 citations as recorded by crossref.
- Nitrate Concentration near the Surface of Frozen Aqueous Solutions H. Marrocco & R. Michelsen 10.1021/jp508244u
- Exclusion of Nitrate to the Air–Ice Interface During Freezing S. Wren & D. Donaldson 10.1021/jz2007484
- Calculations of in-snow NO2and OH radical photochemical production and photolysis rates: A field and radiative-transfer study of the optical properties of Arctic (Ny-Ålesund, Svalbard) snow J. France et al. 10.1029/2011JF002019
- Atmospheric nitric oxide and ozone at the WAIS Divide deep coring site: a discussion of local sources and transport in West Antarctica S. Masclin et al. 10.5194/acp-13-8857-2013
- The influence of snow grain size and impurities on the vertical profiles of actinic flux and associated NO<sub>x</sub> emissions on the Antarctic and Greenland ice sheets M. Zatko et al. 10.5194/acp-13-3547-2013
- Freezing-enhanced reduction of chromate by nitrite K. Kim et al. 10.1016/j.scitotenv.2017.02.176
- Air–snow exchange of nitrate: a modelling approach to investigate physicochemical processes in surface snow at Dome C, Antarctica J. Bock et al. 10.5194/acp-16-12531-2016
- Modeling chemistry in and above snow at Summit, Greenland – Part 1: Model description and results J. Thomas et al. 10.5194/acp-11-4899-2011
- Arctic halogens reduce ozone in the northern mid-latitudes R. Fernandez et al. 10.1073/pnas.2401975121
- Nitrate Photolysis in Salty Snow K. Morenz et al. 10.1021/acs.jpca.6b06685
- Nitrate Photochemistry in NaY Zeolite: Product Formation and Product Stability under Different Environmental Conditions A. Gankanda & V. Grassian 10.1021/jp312247m
- The quasi-liquid layer of ice revisited: the role of temperature gradients and tip chemistry in AFM studies J. Gelman Constantin et al. 10.5194/acp-18-14965-2018
- Role of Nitrite in the Photochemical Formation of Radicals in the Snow H. Jacobi et al. 10.1021/es404002c
- Photolysis of frozen iodate salts as a source of active iodine in the polar environment Ó. Gálvez et al. 10.5194/acp-16-12703-2016
- The effect of the novel HO2 + NO → HNO3 reaction channel at South Pole, Antarctica C. Boxe et al. 10.1017/S0954102012000144
- Influence of thin liquid films on polar ice chemistry: Implications for Earth and planetary science C. Boxe & A. Saiz-Lopez 10.1016/j.polar.2009.01.001
- Using Singlet Molecular Oxygen to Probe the Solute and Temperature Dependence of Liquid-Like Regions in/on Ice J. Bower & C. Anastasio 10.1021/jp404071y
- Air–snow transfer of nitrate on the East Antarctic Plateau – Part 2: An isotopic model for the interpretation of deep ice-core records J. Erbland et al. 10.5194/acp-15-12079-2015
- Cryoprotective Polyol-Induced Ice Microstructure Development and Enhanced Chromium(VI) Reduction in Polycrystalline Structures B. Kim & K. Kim 10.1021/acs.cgd.4c01067
- Production of Molecular Iodine and Tri-iodide in the Frozen Solution of Iodide: Implication for Polar Atmosphere K. Kim et al. 10.1021/acs.est.5b05148
- Investigating the photo-oxidative and heterogeneous chemical production of HCHO in the snowpack at the South Pole, Antarctica P. Hamer et al. 10.1071/EN13227
- Development of a Mechanism for Nitrate Photochemistry in Snow J. Bock & H. Jacobi 10.1021/jp909205e
- Accelerated dissolution of iron oxides in ice D. Jeong et al. 10.5194/acp-12-11125-2012
- Appearance and Disappearance of Quasi-Liquid Layers on Ice Crystals in the Presence of Nitric Acid Gas K. Nagashima et al. 10.3390/cryst10020072
- Accumulation of dissolved organic matter in the transition from fresh to aged seasonal snow in an industrial city in NE China Z. Mu et al. 10.1016/j.scitotenv.2022.159337
- Observation of gas-phase peroxynitrous and peroxynitric acid during the photolysis of nitrate in acidified frozen solutions O. Abida et al. 10.1016/j.cplett.2011.06.055
- The Effect of Freezing on Reactions with Environmental Impact R. O’Concubhair & J. Sodeau 10.1021/ar400114e
- A mechanism for biologically induced iodine emissions from sea ice A. Saiz-Lopez et al. 10.5194/acp-15-9731-2015
- Coupling of HO<sub>x</sub>, NO<sub>x</sub> and halogen chemistry in the antarctic boundary layer W. Bloss et al. 10.5194/acp-10-10187-2010
- On the pH dependence of photo-induced volatilization of nitrogen oxides from frozen solutions containing nitrate O. Abida & H. Osthoff 10.1029/2011GL048517
- Nitrate Ion Photolysis in Thin Water Films in the Presence of Bromide Ions N. Richards et al. 10.1021/jp109560j
- Effect of Ionic Strength on Solvation Geometries in Aqueous Nitrate Ion Solutions K. Jones et al. 10.1021/acs.jpca.6b12102
- Nitric acid-induced surface disordering on ice S. Moussa et al. 10.1039/c3cp50487e
- Modeling interfacial liquid layers on environmental ices M. Kuo et al. 10.5194/acp-11-9971-2011
- Photolysis imprint in the nitrate stable isotope signal in snow and atmosphere of East Antarctica and implications for reactive nitrogen cycling M. Frey et al. 10.5194/acp-9-8681-2009
- Enabling Forbidden Processes: Quantum and Solvation Enhancement of Nitrate Anion UV Absorption O. Svoboda et al. 10.1021/jp4098777
- Isotope Fractionation of Nitrate During Volatilization in Snow: A Field Investigation in Antarctica G. Shi et al. 10.1029/2019GL081968
- Advances in Cryochemistry: Mechanisms, Reactions and Applications L. An et al. 10.3390/molecules26030750
- Nitrate Photochemistry at the Air–Ice Interface and in Other Ice Reservoirs A. McFall et al. 10.1021/acs.est.8b00095
- Quantum Yields of Nitrite (NO2–) from the Photolysis of Nitrate (NO3–) in Ice at 313 nm K. Benedict & C. Anastasio 10.1021/acs.jpca.7b08839
- Adsorbed water and thin liquid films on Mars C. Boxe et al. 10.1017/S1473550412000080
- Nitrate postdeposition processes in Svalbard surface snow M. Björkman et al. 10.1002/2013JD021234
- HONO, Particulate Nitrite, and Snow Nitrite at a Midlatitude Urban Site during Wintertime Q. Chen et al. 10.1021/acsearthspacechem.9b00023
- Dynamics of ozone and nitrogen oxides at Summit, Greenland. II. Simulating snowpack chemistry during a spring high ozone event with a 1-D process-scale model K. Murray et al. 10.1016/j.atmosenv.2015.07.004
- Production of gas phase NO2 and halogens from the photolysis of thin water films containing nitrate, chloride and bromide ions at room temperature N. Richards-Henderson et al. 10.1039/c3cp52956h
- Nitrate photolysis in ice and snow: A critical review of its multiphase chemistry C. Blaszczak-Boxe & A. Saiz-Lopez 10.1016/j.atmosenv.2018.09.002
- Ground-State Intermolecular Proton Transfer of N2O4 and H2O: An Important Source of Atmospheric Hydroxyl Radical? G. Luo & X. Chen 10.1021/jz300336s
- Enhanced Removal of Hexavalent Chromium in the Presence of H2O2 in Frozen Aqueous Solutions K. Kim et al. 10.1021/acs.est.5b02702
- Modelling the physical multiphase interactions of HNO<sub>3</sub> between snow and air on the Antarctic Plateau (Dome C) and coast (Halley) H. Chan et al. 10.5194/acp-18-1507-2018
- Modeling the Sources and Chemistry of Polar Tropospheric Halogens (Cl, Br, and I) Using the CAM‐Chem Global Chemistry‐Climate Model R. Fernandez et al. 10.1029/2019MS001655
- Nitrate Photolysis at the Air–Ice Interface of Nature-Identical Snow T. Hullar et al. 10.1021/acsearthspacechem.3c00166
- Hydration of ions and salt crystallization in liquid phase coexistent with ice at temperature below eutectic point M. Harada et al. 10.1039/C1RA00801C
- Reactions at surfaces in the atmosphere: integration of experiments and theory as necessary (but not necessarily sufficient) for predicting the physical chemistry of aerosols B. Finlayson-Pitts 10.1039/b906540g
- Numerical analysis of the chemical kinetic mechanisms of ozone depletion and halogen release in the polar troposphere L. Cao et al. 10.5194/acp-14-3771-2014
- Protonated Nitrosamide and Its Potential Role in the Release of HONO from Snow and Ice in the Dark S. Hellebust et al. 10.1021/jp104327a
- Can We Model Snow Photochemistry? Problems with the Current Approaches F. Domine et al. 10.1021/jp3123314
- A review of air–ice chemical and physical interactions (AICI): liquids, quasi-liquids, and solids in snow T. Bartels-Rausch et al. 10.5194/acp-14-1587-2014
- An isotopic view on the connection between photolytic emissions of NOx from the Arctic snowpack and its oxidation by reactive halogens S. Morin et al. 10.1029/2011JD016618
- Contrasting atmospheric boundary layer chemistry of methylhydroperoxide (CH<sub>3</sub>OOH) and hydrogen peroxide (H<sub>2</sub>O<sub>2</sub>) above polar snow M. Frey et al. 10.5194/acp-9-3261-2009
- An active nitrogen cycle on Mars sufficient to support a subsurface biosphere C. Boxe et al. 10.1017/S1473550411000401
- Impacts of cryogenic sampling processes on iron mineral coatings in contaminated sediment H. Hua et al. 10.1016/j.scitotenv.2020.142796
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