Articles | Volume 26, issue 9
https://doi.org/10.5194/acp-26-6083-2026
https://doi.org/10.5194/acp-26-6083-2026
Research article
 | 
06 May 2026
Research article |  | 06 May 2026

Thin organic films unexpectedly enhance alcohol uptake on soot analogs: critical implications for aerosol aging

Xiangrui Kong, Yongjian Lian, Shuai Jiang, and Jan B. C. Pettersson

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This preprint is open for discussion and under review for Atmospheric Chemistry and Physics (ACP).
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Cited articles

Ahern, A. T., Subramanian, R., Saliba, G., Lipsky, E. M., Donahue, N. M., and Sullivan, R. C.: Effect of secondary organic aerosol coating thickness on the real-time detection and characterization of biomass-burning soot by two particle mass spectrometers, Atmos. Meas. Tech., 9, 6117–6137, https://doi.org/10.5194/amt-9-6117-2016, 2016. 
Andersson, P. U., Tomsic, A., Andersson, M. B., and Petterson, J. B. C.: Emission of small fragments during water cluster collisions with a graphite surface, Chem. Phys. Lett., 279, 100–106, https://doi.org/10.1016/S0009-2614(97)00990-1, 1997. 
Arumainayagam, C. R. and Madix, R. J.: Molecular Beam Studies of Gas-Surface Collision Dynamics, Prog. Surf. Sci., 38, 1–102, 1991. 
Bayly, C. I., Cieplak, P., Cornell, W., and Kollman, P. A.: A well-behaved electrostatic potential based method using charge restraints for deriving atomic charges: the RESP model, J. Phys. Chem., 97, 10269–10280, https://doi.org/10.1021/j100142a004, 1993. 
Beeler, P., Corbin, J. C., Sipkens, T. A., and Fierce, L.: A Framework for Quantifying the Size and Fractal Dimension of Compacting Soot Particles, Environ. Sci. Technol., 59, 5994–6003, https://doi.org/10.1021/acs.est.4c11100, 2025. 
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This study examines how organic films on soot particles influence how alcohol vapors are taken up and released. Laboratory measurements and computer simulations show that very thin organic coatings unexpectedly trap alcohols by forming stable surface layers, while thicker coatings favor faster release. The results reveal that particle surface structure strongly controls pollutant aging in the atmosphere, with important implications for air quality, cloud formation, and climate.
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