Atmospheric Chemistry and Physics
Atmospheric Chemistry and Physics
ACP
Articles | Volume 26, issue 3
Articles | Volume 26, issue 3
https://doi.org/10.5194/acp-26-2103-2026
© Author(s) 2026. This work is distributed under
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-26-2103-2026
© Author(s) 2026. This work is distributed under
the Creative Commons Attribution 4.0 License.
Articles | Volume 26, issue 3
Research article
 | 
10 Feb 2026
Research article |  | 10 Feb 2026

Elucidation of the myrcene ozonolysis mechanism from a Criegee Chemistry perspective

Meifang Chen, Shengrui Tong, Shanshan Yu, Xiaofan Lv, Yanyong Xu, Hailiang Zhang, and Maofa Ge

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Short summary
The critical role of Criegee intermediates (CIs) in the myrcene ozonolysis was elucidated through the combined approach of matrix isolation Fourier transform infrared spectroscopy and smog chamber experiments. Distinct mechanisms of different-sized CIs in secondary organic aerosol formation were proposed, and a synergistic effect between RO2 autoxidation and CIs oligomerization was identified. This study provided new insights into the ozonolysis process from the Criegee chemistry perspective.
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