Articles | Volume 25, issue 14
https://doi.org/10.5194/acp-25-8147-2025
https://doi.org/10.5194/acp-25-8147-2025
Research article
 | 
30 Jul 2025
Research article |  | 30 Jul 2025

Observation and modeling of atmospheric OH and HO2 radicals at a subtropical rural site and implications for secondary pollutants

Zhouxing Zou, Tianshu Chen, Qianjie Chen, Weihang Sun, Shichun Han, Zhuoyue Ren, Xinyi Li, Wei Song, Aoqi Ge, Qi Wang, Xiao Tian, Chenglei Pei, Xinming Wang, Yanli Zhang, and Tao Wang

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Interactive discussion

Status: closed

Comment types: AC – author | RC – referee | CC – community | EC – editor | CEC – chief editor | : Report abuse
  • RC1: 'Comment on egusphere-2024-3210', Anonymous Referee #1, 08 Nov 2024
  • RC2: 'Comment on egusphere-2024-3210', Anonymous Referee #2, 09 Nov 2024
  • RC3: 'Comment on egusphere-2024-3210', Anonymous Referee #3, 11 Nov 2024

Peer review completion

AR: Author's response | RR: Referee report | ED: Editor decision | EF: Editorial file upload
AR by Tao Wang on behalf of the Authors (23 Jan 2025)  Author's response   Author's tracked changes   Manuscript 
ED: Referee Nomination & Report Request started (23 Jan 2025) by Kelvin Bates
RR by Anonymous Referee #3 (03 Feb 2025)
RR by Anonymous Referee #2 (10 Feb 2025)
RR by Anonymous Referee #1 (12 Feb 2025)
ED: Reconsider after major revisions (13 Feb 2025) by Kelvin Bates
AR by Tao Wang on behalf of the Authors (26 Mar 2025)  Author's response   Author's tracked changes   Manuscript 
ED: Referee Nomination & Report Request started (12 Apr 2025) by Kelvin Bates
RR by Anonymous Referee #3 (24 Apr 2025)
ED: Publish subject to minor revisions (review by editor) (24 Apr 2025) by Kelvin Bates
AR by Tao Wang on behalf of the Authors (03 May 2025)  Author's response   Author's tracked changes   Manuscript 
ED: Publish as is (05 May 2025) by Kelvin Bates
AR by Tao Wang on behalf of the Authors (08 May 2025)  Manuscript 
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Short summary
We measured ambient OH and HO2* (HO2 and contribution from RO2, organic peroxyl radicals) concentrations at a subtropical rural site and compared our observations with model results. During warm periods, the model overestimated concentrations of OH and HO2, leading to overestimation of ozone and nitric acid production. Our findings highlight the need to better understand how OH and HO2 are formed and removed, which is important for accurate air quality and climate predictions.
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