Atmospheric Chemistry and Physics
Atmospheric Chemistry and Physics
ACP
Articles | Volume 25, issue 22
Articles | Volume 25, issue 22
https://doi.org/10.5194/acp-25-15819-2025
© Author(s) 2025. This work is distributed under
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-25-15819-2025
© Author(s) 2025. This work is distributed under
the Creative Commons Attribution 4.0 License.
Articles | Volume 25, issue 22
Research article
 | 
18 Nov 2025
Research article |  | 18 Nov 2025

Speciated measurement of bicyclic peroxy radicals via iodide-CIMS and its implication on OH-initiated aromatic oxidation

Yi Liu, Xin Li, Ying Liu, Shuyu He, Yuqing Qiu, Mengdi Song, Jiarong Ye, Shengrong Lou, Sihua Lu, Limin Zeng, and Yuanhang Zhang

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Short summary
We developed a method for speciated and quantitative measurement of peroxy radicals formed during the breakdown of aromatic hydrocarbons. These measurements revealed missing reaction pathways in current chemical mechanisms. Our findings help improve predictions of air quality and deepen understanding of chemical processes in the atmosphere.
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