Articles | Volume 25, issue 19
https://doi.org/10.5194/acp-25-12615-2025
https://doi.org/10.5194/acp-25-12615-2025
Research article
 | 
10 Oct 2025
Research article |  | 10 Oct 2025

Acid-catalyzed hydrolysis kinetics of organic hydroperoxides: computational strategy and structure–activity relationship

Qiaojing Zhao, Fangfang Ma, Hui Zhao, Qian Xu, Rujing Yin, Hong-Bin Xie, Xin Wang, and Jingwen Chen

Viewed

Total article views: 941 (including HTML, PDF, and XML)
HTML PDF XML Total Supplement BibTeX EndNote
832 85 24 941 39 18 41
  • HTML: 832
  • PDF: 85
  • XML: 24
  • Total: 941
  • Supplement: 39
  • BibTeX: 18
  • EndNote: 41
Views and downloads (calculated since 25 Apr 2025)
Cumulative views and downloads (calculated since 25 Apr 2025)

Viewed (geographical distribution)

Total article views: 941 (including HTML, PDF, and XML) Thereof 941 with geography defined and 0 with unknown origin.
Country # Views %
  • 1
1
 
 
 
 
Latest update: 10 Oct 2025
Download
Short summary
The scarcity of kinetic data for key aerosol aqueous-phase reactions contributes to large uncertainties in atmospheric models. We establish a computational strategy to rapidly predict acid-catalyzed hydrolysis kinetics of organic hydroperoxides, an aerosol constituent with high abundance. The kinetic parameters can be integrated into atmospheric models to improve simulations of the global hydrogen peroxide budget and secondary organic aerosol production.
Share
Altmetrics
Final-revised paper
Preprint