Articles | Volume 24, issue 14
https://doi.org/10.5194/acp-24-8397-2024
© Author(s) 2024. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-24-8397-2024
© Author(s) 2024. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Critical contribution of chemically diverse carbonyl molecules to the oxidative potential of atmospheric aerosols
Feifei Li
State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research Center for Eco-environmental Sciences, Chinese Academy of Sciences, Beijing 100085, China
College of Resources and Environment, University of Chinese Academy of Sciences, Beijing 100049, China
Shanshan Tang
Hangzhou International Innovation Institute, Beihang University, Hangzhou 311115, China
Jitao Lv
CORRESPONDING AUTHOR
State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research Center for Eco-environmental Sciences, Chinese Academy of Sciences, Beijing 100085, China
College of Resources and Environment, University of Chinese Academy of Sciences, Beijing 100049, China
Shiyang Yu
State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research Center for Eco-environmental Sciences, Chinese Academy of Sciences, Beijing 100085, China
College of Resources and Environment, University of Chinese Academy of Sciences, Beijing 100049, China
Xu Sun
State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research Center for Eco-environmental Sciences, Chinese Academy of Sciences, Beijing 100085, China
Beijing Urban Ecosystem Research Station, State Key Laboratory of Urban and Regional Ecology, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085, China
Dong Cao
State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research Center for Eco-environmental Sciences, Chinese Academy of Sciences, Beijing 100085, China
Yawei Wang
CORRESPONDING AUTHOR
State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research Center for Eco-environmental Sciences, Chinese Academy of Sciences, Beijing 100085, China
College of Resources and Environment, University of Chinese Academy of Sciences, Beijing 100049, China
School of Environment, Hangzhou Institute for Advanced Study, University of Chinese Academy of Sciences, Hangzhou 310024, China
Hubei Key Laboratory of Environmental and Health Effects of Persistent Toxic Substances, Institute of Environment and Health, Jianghan University, Wuhan 430056, China
Guibin Jiang
State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research Center for Eco-environmental Sciences, Chinese Academy of Sciences, Beijing 100085, China
College of Resources and Environment, University of Chinese Academy of Sciences, Beijing 100049, China
School of Environment, Hangzhou Institute for Advanced Study, University of Chinese Academy of Sciences, Hangzhou 310024, China
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Cited
9 citations as recorded by crossref.
- The Promotion Effect of Dust on Oxidative Potential of PM2.5 via Photochemical Aging J. Li et al. https://doi.org/10.1021/acs.est.6c02168
- Investigation of the Mechanism of Oxidative Potential Increase in Atmospheric Particulate Matter during Photoaging: Important Role of Aromatic Nitrogenous Compounds Q. Wang et al. https://doi.org/10.1021/acs.est.4c03199
- Reactions of carbonyl oxide with aldehydes: accurate electronic structure methods, kinetic insights, and atmospheric implications C. Xie & B. Long https://doi.org/10.5194/acp-26-6973-2026
- PTR-QMS observation of OVOCs in an urban suburb of Guangzhou: seasonal characterization, source apportionment and regional transport X. Ma et al. https://doi.org/10.1016/j.atmosenv.2025.121589
- Photochemical Aging of China VI Gasoline Vehicle Exhaust Drives Nonlinear Secondary Aerosol Formation J. Li et al. https://doi.org/10.1021/acs.est.6c00964
- Atmospheric Chemistry of Hydroxypinonaldehydes: Their Reactions with Hydroperoxy Radicals in the Atmosphere G. Zhao et al. https://doi.org/10.1021/acs.jpca.5c01933
- Impact of Molecular Structure on Secondary Organic Aerosol Formation from Aliphatic Carbonyls C. Liang et al. https://doi.org/10.1021/acs.est.5c00793
- Seasonal dependence of oxidative toxicity of atmospheric fine particulate matter: A case study of Xi’an, a megacity in Northwest China B. Wang et al. https://doi.org/10.1016/j.jhazmat.2026.141878
- Revealing the sources of water-soluble PM2.5 oxidative potential with explainable machine learning L. Zhang et al. https://doi.org/10.1016/j.envpol.2025.127278
9 citations as recorded by crossref.
- The Promotion Effect of Dust on Oxidative Potential of PM2.5 via Photochemical Aging J. Li et al. https://doi.org/10.1021/acs.est.6c02168
- Investigation of the Mechanism of Oxidative Potential Increase in Atmospheric Particulate Matter during Photoaging: Important Role of Aromatic Nitrogenous Compounds Q. Wang et al. https://doi.org/10.1021/acs.est.4c03199
- Reactions of carbonyl oxide with aldehydes: accurate electronic structure methods, kinetic insights, and atmospheric implications C. Xie & B. Long https://doi.org/10.5194/acp-26-6973-2026
- PTR-QMS observation of OVOCs in an urban suburb of Guangzhou: seasonal characterization, source apportionment and regional transport X. Ma et al. https://doi.org/10.1016/j.atmosenv.2025.121589
- Photochemical Aging of China VI Gasoline Vehicle Exhaust Drives Nonlinear Secondary Aerosol Formation J. Li et al. https://doi.org/10.1021/acs.est.6c00964
- Atmospheric Chemistry of Hydroxypinonaldehydes: Their Reactions with Hydroperoxy Radicals in the Atmosphere G. Zhao et al. https://doi.org/10.1021/acs.jpca.5c01933
- Impact of Molecular Structure on Secondary Organic Aerosol Formation from Aliphatic Carbonyls C. Liang et al. https://doi.org/10.1021/acs.est.5c00793
- Seasonal dependence of oxidative toxicity of atmospheric fine particulate matter: A case study of Xi’an, a megacity in Northwest China B. Wang et al. https://doi.org/10.1016/j.jhazmat.2026.141878
- Revealing the sources of water-soluble PM2.5 oxidative potential with explainable machine learning L. Zhang et al. https://doi.org/10.1016/j.envpol.2025.127278
Saved (final revised paper)
Latest update: 09 Jun 2026
Short summary
Targeted derivatization and non-targeted analysis with Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS) were used to reveal the molecular composition of carbonyl molecules in PM2.5, and the important role of carbonyls in increasing the oxidative potential of organic aerosol was found in real samples.
Targeted derivatization and non-targeted analysis with Fourier transform ion cyclotron resonance...
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