Reactive chlorine-, sulfur-, and nitrogen-containing volatile organic compounds impact atmospheric chemistry in the megacity of Delhi during both clean and extremely polluted seasons
Sachin Mishra,Vinayak Sinha,Haseeb Hakkim,Arpit Awasthi,Sachin D. Ghude,Vijay Kumar Soni,Narendra Nigam,Baerbel Sinha,and Madhavan N. Rajeevan
Sachin Mishra
Department of Earth and Environmental Sciences, Indian Institute of Science Education and Research Mohali, Sector 81, S.A.S Nagar, Manauli PO, Punjab 140306, India
Department of Earth and Environmental Sciences, Indian Institute of Science Education and Research Mohali, Sector 81, S.A.S Nagar, Manauli PO, Punjab 140306, India
Haseeb Hakkim
Department of Earth and Environmental Sciences, Indian Institute of Science Education and Research Mohali, Sector 81, S.A.S Nagar, Manauli PO, Punjab 140306, India
Department of Earth and Environmental Sciences, Indian Institute of Science Education and Research Mohali, Sector 81, S.A.S Nagar, Manauli PO, Punjab 140306, India
Sachin D. Ghude
Indian Institute of Tropical Meteorology, Ministry of Earth Sciences, Pashan, Pune 411 008, India
Department of Earth and Environmental Sciences, Indian Institute of Science Education and Research Mohali, Sector 81, S.A.S Nagar, Manauli PO, Punjab 140306, India
Madhavan N. Rajeevan
Ministry of Earth Sciences, Government of India, New Delhi 110 003, India
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We quantified 111 gases using mass spectrometry to understand how seasonal and emission changes lead from clean air in the monsoon season to extremely polluted air in the post-monsoon season in Delhi. Averaged total mass concentrations (260 µg m-3) were > 4 times in polluted periods, driven by biomass burning emissions and reduced atmospheric ventilation. Reactive gaseous nitrogen, chlorine, and sulfur compounds hitherto unreported from such a polluted environment were discovered.
We quantified 111 gases using mass spectrometry to understand how seasonal and emission changes...