Articles | Volume 24, issue 19
https://doi.org/10.5194/acp-24-11365-2024
© Author(s) 2024. This work is distributed under
the Creative Commons Attribution 4.0 License.Global modeling of aerosol nucleation with a semi-explicit chemical mechanism for highly oxygenated organic molecules (HOMs)
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- Final revised paper (published on 11 Oct 2024)
- Supplement to the final revised paper
- Preprint (discussion started on 13 Feb 2024)
- Supplement to the preprint
Interactive discussion
Status: closed
Comment types: AC – author | RC – referee | CC – community | EC – editor | CEC – chief editor
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RC1: 'Comment on egusphere-2024-401', Anonymous Referee #1, 12 Mar 2024
- AC1: 'Reply on RC1', Xinyue Shao, 24 Jun 2024
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RC2: 'Comment on egusphere-2024-401', Anonymous Referee #2, 31 Mar 2024
- AC2: 'Reply on RC2', Xinyue Shao, 24 Jun 2024
Peer review completion
AR: Author's response | RR: Referee report | ED: Editor decision | EF: Editorial file upload
AR by Xinyue Shao on behalf of the Authors (28 Jun 2024)
Author's response
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ED: Referee Nomination & Report Request started (04 Jul 2024) by Manabu Shiraiwa
RR by Anonymous Referee #1 (19 Jul 2024)
RR by Anonymous Referee #2 (26 Jul 2024)

ED: Publish subject to minor revisions (review by editor) (02 Aug 2024) by Manabu Shiraiwa

AR by Xinyue Shao on behalf of the Authors (11 Aug 2024)
Author's response
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ED: Publish as is (14 Aug 2024) by Manabu Shiraiwa
AR by Xinyue Shao on behalf of the Authors (20 Aug 2024)
This paper details work on implementing a HOM chemistry scheme into a large-scale model and comparing the results with an updated inorganic-only nucleation scheme. The inclusion of organic nucleation and growth at small particle sizes due to HOM formation leads to better agreement overall with measurements of high altitude CCN and frequency of NPF events globally. This work provides an interesting look into incorporating HOM chemistry into global models. The results seem reasonable and fit within the scope of ACP. My main concern stems from a lack sensitivity studies surrounding many of the uncertainties in the mechanism as well as a lack of discussion of the limitations of the mechanism. Given HOM chemistry is an active area of research, it makes these results incredibly significant to the community, but also means communicating clearly the limitations of the work given the present understanding of HOM chemistry is all the more important. Overall, I think this paper presents an important contribution to the field and I would support publication if the following comments are addressed.
Major comments:
Minor comments
References
Liu, Y. et al., A Modeling Study of Global Distribution and Formation Pathways of Highly Oxygenated Organic Molecules Derived Secondary Organic Aerosols (HOMs-SOA) from Monoterpenes, J. Geophys. Res.-Atmos., (under review), 2024
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