Articles | Volume 23, issue 13
https://doi.org/10.5194/acp-23-7569-2023
© Author(s) 2023. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-23-7569-2023
© Author(s) 2023. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
11 Jul 2023
Research article |
| 11 Jul 2023
| 11 Jul 2023
Arctic observations of hydroperoxymethyl thioformate (HPMTF) – seasonal behavior and relationship to other oxidation products of dimethyl sulfide at the Zeppelin Observatory, Svalbard
Karolina Siegel
Department of Environmental Science, Stockholm University, Stockholm, 10691, Sweden
Department of Meteorology, Stockholm University, Stockholm, 10691,
Sweden
Bolin Centre for Climate Research, Stockholm University, Stockholm,
10691, Sweden
Yvette Gramlich
Department of Environmental Science, Stockholm University, Stockholm, 10691, Sweden
Bolin Centre for Climate Research, Stockholm University, Stockholm,
10691, Sweden
Sophie L. Haslett
Department of Environmental Science, Stockholm University, Stockholm, 10691, Sweden
Bolin Centre for Climate Research, Stockholm University, Stockholm,
10691, Sweden
Gabriel Freitas
Department of Environmental Science, Stockholm University, Stockholm, 10691, Sweden
Bolin Centre for Climate Research, Stockholm University, Stockholm,
10691, Sweden
Radovan Krejci
Department of Environmental Science, Stockholm University, Stockholm, 10691, Sweden
Bolin Centre for Climate Research, Stockholm University, Stockholm,
10691, Sweden
Paul Zieger
Department of Environmental Science, Stockholm University, Stockholm, 10691, Sweden
Bolin Centre for Climate Research, Stockholm University, Stockholm,
10691, Sweden
Department of Environmental Science, Stockholm University, Stockholm, 10691, Sweden
Bolin Centre for Climate Research, Stockholm University, Stockholm,
10691, Sweden
now at: Laboratory of Atmospheric Chemistry, Paul Scherrer Institute, Villigen, Switzerland
now at: Department of Environmental Systems Science, ETH Zurich, Zurich, Switzerland
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Cited
11 citations as recorded by crossref.
- The annual cycle and sources of relevant aerosol precursor vapors in the central Arctic during the MOSAiC expedition M. Boyer et al. https://doi.org/10.5194/acp-24-12595-2024
- Cloud processing of dimethyl sulfide (DMS) oxidation products limits sulfur dioxide (SO2) and carbonyl sulfide (OCS) production in the eastern North Atlantic marine boundary layer D. Kilgour et al. https://doi.org/10.5194/acp-25-1931-2025
- The biogenic sulfur cycle in the coupled ocean–sea ice–atmosphere system S. Ishino et al. https://doi.org/10.1525/elementa.2025.00067
- Role of Selenium in Production of Reactive Oxygen Species from Aqueous Processing of Dimethyl Selenide-Derived Secondary Aerosols M. Lum et al. https://doi.org/10.1021/acs.est.5c13687
- Reaction of Carbonyl Oxide with Hydroperoxymethyl Thioformate: Quantitative Kinetics and Atmospheric Implications B. Long et al. https://doi.org/10.34133/research.0525
- Synergistic effects of oceanic dimethyl sulfide emissions and atmospheric oxidants on new particle formation in the Arctic E. Jang et al. https://doi.org/10.1016/j.envres.2025.122024
- A Machine Learning Approach to Understand Thermal Desorption Profiles of Levoglucosan from FIGAERO–CIMS Y. Gramlich et al. https://doi.org/10.1021/acs.est.5c18488
- Impact of Biomass Burning on Arctic Aerosol Composition Y. Gramlich et al. https://doi.org/10.1021/acsearthspacechem.3c00187
- Treatment of Key Aerosol and Cloud Processes in Earth System Models – Recommendations from the FORCeS Project I. Riipinen et al. https://doi.org/10.16993/tellusb.1883
- Dimethyl sulfide chemistry over the industrial era: comparison of key oxidation mechanisms and long-term observations U. Jongebloed et al. https://doi.org/10.5194/acp-25-4083-2025
- How to trace the origins of short-lived atmospheric species: an Arctic example A. Da Silva et al. https://doi.org/10.5194/acp-25-5331-2025
11 citations as recorded by crossref.
- The annual cycle and sources of relevant aerosol precursor vapors in the central Arctic during the MOSAiC expedition M. Boyer et al. https://doi.org/10.5194/acp-24-12595-2024
- Cloud processing of dimethyl sulfide (DMS) oxidation products limits sulfur dioxide (SO2) and carbonyl sulfide (OCS) production in the eastern North Atlantic marine boundary layer D. Kilgour et al. https://doi.org/10.5194/acp-25-1931-2025
- The biogenic sulfur cycle in the coupled ocean–sea ice–atmosphere system S. Ishino et al. https://doi.org/10.1525/elementa.2025.00067
- Role of Selenium in Production of Reactive Oxygen Species from Aqueous Processing of Dimethyl Selenide-Derived Secondary Aerosols M. Lum et al. https://doi.org/10.1021/acs.est.5c13687
- Reaction of Carbonyl Oxide with Hydroperoxymethyl Thioformate: Quantitative Kinetics and Atmospheric Implications B. Long et al. https://doi.org/10.34133/research.0525
- Synergistic effects of oceanic dimethyl sulfide emissions and atmospheric oxidants on new particle formation in the Arctic E. Jang et al. https://doi.org/10.1016/j.envres.2025.122024
- A Machine Learning Approach to Understand Thermal Desorption Profiles of Levoglucosan from FIGAERO–CIMS Y. Gramlich et al. https://doi.org/10.1021/acs.est.5c18488
- Impact of Biomass Burning on Arctic Aerosol Composition Y. Gramlich et al. https://doi.org/10.1021/acsearthspacechem.3c00187
- Treatment of Key Aerosol and Cloud Processes in Earth System Models – Recommendations from the FORCeS Project I. Riipinen et al. https://doi.org/10.16993/tellusb.1883
- Dimethyl sulfide chemistry over the industrial era: comparison of key oxidation mechanisms and long-term observations U. Jongebloed et al. https://doi.org/10.5194/acp-25-4083-2025
- How to trace the origins of short-lived atmospheric species: an Arctic example A. Da Silva et al. https://doi.org/10.5194/acp-25-5331-2025
Saved (final revised paper)
Latest update: 03 Jun 2026
Short summary
Hydroperoxymethyl thioformate (HPMTF) is a recently discovered oxidation product of dimethyl sulfide (DMS). We present a full year of concurrent gas- and particle-phase observations of HPMTF and other DMS oxidation products from the Arctic. We did not observe significant amounts of HPMTF in the particle phase but a good agreement between gas-phase HMPTF and methanesulfonic acid in the summer. Our study provides information about the relationship between HPMTF and other DMS oxidation products.
Hydroperoxymethyl thioformate (HPMTF) is a recently discovered oxidation product of dimethyl...
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