Articles | Volume 23, issue 12
https://doi.org/10.5194/acp-23-7103-2023
https://doi.org/10.5194/acp-23-7103-2023
Research article
 | 
28 Jun 2023
Research article |  | 28 Jun 2023

Photoaging of phenolic secondary organic aerosol in the aqueous phase: evolution of chemical and optical properties and effects of oxidants

Wenqing Jiang, Christopher Niedek, Cort Anastasio, and Qi Zhang

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Short summary
We studied how aqueous-phase secondary organic aerosol (aqSOA) form and evolve from a phenolic carbonyl commonly present in biomass burning smoke. The composition and optical properties of the aqSOA are significantly affected by photochemical reactions and are dependent on the oxidants' concentration and identity in water. During photoaging, the aqSOA initially becomes darker, but prolonged aging leads to the formation of volatile products, resulting in significant mass loss and photobleaching.
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