Articles | Volume 23, issue 10
https://doi.org/10.5194/acp-23-5851-2023
© Author(s) 2023. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-23-5851-2023
© Author(s) 2023. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
On the importance of multiphase photolysis of organic nitrates on their global atmospheric removal
Juan Miguel González-Sánchez
CORRESPONDING AUTHOR
Aix Marseille
Univ, CNRS, LCE, Marseille, France
Aix Marseille
Univ, CNRS, ICR, Marseille, France
Nicolas Brun
Aix Marseille
Univ, CNRS, LCE, Marseille, France
Aix Marseille
Univ, CNRS, ICR, Marseille, France
Junteng Wu
Aix Marseille
Univ, CNRS, LCE, Marseille, France
Sylvain Ravier
Aix Marseille
Univ, CNRS, LCE, Marseille, France
Jean-Louis Clément
Aix Marseille
Univ, CNRS, ICR, Marseille, France
Anne Monod
CORRESPONDING AUTHOR
Aix Marseille
Univ, CNRS, LCE, Marseille, France
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Cited
13 citations as recorded by crossref.
- Enhanced organic aerosol formation induced by inorganic aerosol formed in laboratory photochemical experiments A. Ali et al. https://doi.org/10.1016/j.jaerosci.2024.106481
- Gas-particle partitioning, molecular weight, and yield of organic nitrate under different urban VOC, NOx, and oxidation conditions during SAPHIR-CHANEL campaign F. Nursanto et al. https://doi.org/10.5194/acp-26-8425-2026
- Effects of Relative Humidity on Time-Resolved Molecular Characterization of Secondary Organic Aerosols from the OH-Initiated Oxidation of Cresol in the Presence of NOx C. Carstens et al. https://doi.org/10.1021/acs.est.4c08215
- Measurement of octanol–air and air–water partition coefficients of isopropyl and isobutyl nitrate A. Buss et al. https://doi.org/10.1039/D5EM00940E
- Using observed urban NOx sinks to constrain VOC reactivity and the ozone and radical budget in the Seoul Metropolitan Area B. Nault et al. https://doi.org/10.5194/acp-24-9573-2024
- Direct formation of HONO through aqueous-phase photolysis of organic nitrates J. González-Sánchez et al. https://doi.org/10.5194/acp-23-15135-2023
- Gas-Phase Photolysis and Photo-Oxidation of Isoprene-Derived Atmospherically Relevant Hydroxy Nitrates R. Verma et al. https://doi.org/10.1021/acsestair.4c00010
- Rapid Photolysis of Gaseous Organic Nitrates Formed from Hydroxyl and Nitrate Radical Oxidation of α-Pinene and β-Pinene M. Takeuchi et al. https://doi.org/10.1021/acsestair.5c00183
- Revealing severely underestimated hydrolysis in liquid-phase degradation of alkyl nitrates W. Zhang et al. https://doi.org/10.1016/j.atmosenv.2025.121482
- Chloramine chemistry as a missing link in atmospheric chlorine cycling Y. Chen et al. https://doi.org/10.1126/sciadv.adv4298
- Resolving the overlooked photochemical nitrophenol transformation mechanism induced by nonradical species under visible light S. Liu et al. https://doi.org/10.1073/pnas.2401452121
- Aqueous Reaction Mechanisms and Kinetics of Atmospherically Relevant Carbonyl Organonitrates and Organosulfates M. Foley et al. https://doi.org/10.1021/acsestair.5c00058
- Aqueous‐Phase Secondary Processes and Meteorological Change Promote the Brown Carbon Formation and Transformation During Haze Events H. Jiang et al. https://doi.org/10.1029/2023JD038735
13 citations as recorded by crossref.
- Enhanced organic aerosol formation induced by inorganic aerosol formed in laboratory photochemical experiments A. Ali et al. https://doi.org/10.1016/j.jaerosci.2024.106481
- Gas-particle partitioning, molecular weight, and yield of organic nitrate under different urban VOC, NOx, and oxidation conditions during SAPHIR-CHANEL campaign F. Nursanto et al. https://doi.org/10.5194/acp-26-8425-2026
- Effects of Relative Humidity on Time-Resolved Molecular Characterization of Secondary Organic Aerosols from the OH-Initiated Oxidation of Cresol in the Presence of NOx C. Carstens et al. https://doi.org/10.1021/acs.est.4c08215
- Measurement of octanol–air and air–water partition coefficients of isopropyl and isobutyl nitrate A. Buss et al. https://doi.org/10.1039/D5EM00940E
- Using observed urban NOx sinks to constrain VOC reactivity and the ozone and radical budget in the Seoul Metropolitan Area B. Nault et al. https://doi.org/10.5194/acp-24-9573-2024
- Direct formation of HONO through aqueous-phase photolysis of organic nitrates J. González-Sánchez et al. https://doi.org/10.5194/acp-23-15135-2023
- Gas-Phase Photolysis and Photo-Oxidation of Isoprene-Derived Atmospherically Relevant Hydroxy Nitrates R. Verma et al. https://doi.org/10.1021/acsestair.4c00010
- Rapid Photolysis of Gaseous Organic Nitrates Formed from Hydroxyl and Nitrate Radical Oxidation of α-Pinene and β-Pinene M. Takeuchi et al. https://doi.org/10.1021/acsestair.5c00183
- Revealing severely underestimated hydrolysis in liquid-phase degradation of alkyl nitrates W. Zhang et al. https://doi.org/10.1016/j.atmosenv.2025.121482
- Chloramine chemistry as a missing link in atmospheric chlorine cycling Y. Chen et al. https://doi.org/10.1126/sciadv.adv4298
- Resolving the overlooked photochemical nitrophenol transformation mechanism induced by nonradical species under visible light S. Liu et al. https://doi.org/10.1073/pnas.2401452121
- Aqueous Reaction Mechanisms and Kinetics of Atmospherically Relevant Carbonyl Organonitrates and Organosulfates M. Foley et al. https://doi.org/10.1021/acsestair.5c00058
- Aqueous‐Phase Secondary Processes and Meteorological Change Promote the Brown Carbon Formation and Transformation During Haze Events H. Jiang et al. https://doi.org/10.1029/2023JD038735
Saved (final revised paper)
Latest update: 03 Jul 2026
Short summary
Organic nitrates play a crucial role in air pollution, as they are NOx reservoirs. This work investigated for the first time their reactivity with light in the aqueous phase (cloud and fog and wet aerosol), proving it slower than in the gas phase. Therefore, our findings reveal that partitioning of organic nitrates in the aqueous phase leads to longer atmospheric lifetimes of these compounds and thus a broader spatial distribution of their related pollution.
Organic nitrates play a crucial role in air pollution, as they are NOx reservoirs. This work...
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