Articles | Volume 23, issue 1
https://doi.org/10.5194/acp-23-221-2023
© Author(s) 2023. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-23-221-2023
© Author(s) 2023. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Impact of phase state and non-ideal mixing on equilibration timescales of secondary organic aerosol partitioning
Meredith Schervish
Department of Chemistry, University of California, Irvine, CA 92697, USA
Department of Chemistry, University of California, Irvine, CA 92697, USA
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Cited
16 citations as recorded by crossref.
- Secondary organic aerosols from oxidation of 1-methylnaphthalene: Yield, composition, and volatility W. Xiang et al. 10.1016/j.scitotenv.2024.170379
- Global Simulations of Phase State and Equilibration Time Scales of Secondary Organic Aerosols with GEOS-Chem R. Luu et al. 10.1021/acsearthspacechem.4c00281
- Secondary organic aerosols derived from intermediate-volatility n-alkanes adopt low-viscous phase state T. Galeazzo et al. 10.5194/acp-24-5549-2024
- Secondary Organic Aerosol from OH-Initiated Oxidation of Mixtures of d-Limonene and β-Myrcene S. Liu et al. 10.1021/acs.est.4c04870
- Spectral Characteristics of Unsaturated and Supersaturated Inorganic Aerosols: Insights into Deliquescence Kinetics S. Ma et al. 10.1021/acs.jpca.4c03107
- Desorption lifetimes and activation energies influencing gas–surface interactions and multiphase chemical kinetics D. Knopf et al. 10.5194/acp-24-3445-2024
- An improved model on the evaporation kinetics of the single aerosol droplet and its application for the droplet composed of ammonium sulfate or sucrose solution C. Zhang et al. 10.1016/j.powtec.2025.120627
- Quantitative description of self-, Maxwell–Stefan, and Fick diffusion coefficients in sucrose and citric acid solution based on molecular dynamics simulations H. Bao et al. 10.1063/5.0268503
- Volatility and chemical composition of secondary organic aerosol derived from acenaphthylene and acenaphthene under various oxidant conditions W. Xiang et al. 10.1016/j.atmosenv.2024.120563
- Effects of volatility, viscosity, and non-ideality on particle–particle mixing timescales of secondary organic aerosols M. Schervish et al. 10.1080/02786826.2023.2256827
- Simulated phase state and viscosity of secondary organic aerosols over China Z. Zhang et al. 10.5194/acp-24-4809-2024
- Key Roles of Bulk Viscosity and Acidity on Liquid–Liquid Phase Separation of Atmospheric Organic–Inorganic Mixed Aerosols Y. Ye et al. 10.1021/acs.jpca.5c01182
- Geometric Analysis of Free and Accessible Volume in Atmospheric Nanoparticles P. Mermigkis et al. 10.1021/acsomega.3c03293
- Chemically Resolved Evaporation Dynamics of Dicarboxylic Acid Mixtures in Solid Particles R. Kaur Kohli et al. 10.1021/acs.analchem.3c02475
- Species-specific effect of particle viscosity and particle-phase reactions on the formation of secondary organic aerosol Z. Luo et al. 10.1016/j.scitotenv.2024.175207
- Vertical gradient in atmospheric particle phase state: a case study over the alaskan arctic oil fields N. Lata et al. 10.1039/D4EA00150H
16 citations as recorded by crossref.
- Secondary organic aerosols from oxidation of 1-methylnaphthalene: Yield, composition, and volatility W. Xiang et al. 10.1016/j.scitotenv.2024.170379
- Global Simulations of Phase State and Equilibration Time Scales of Secondary Organic Aerosols with GEOS-Chem R. Luu et al. 10.1021/acsearthspacechem.4c00281
- Secondary organic aerosols derived from intermediate-volatility n-alkanes adopt low-viscous phase state T. Galeazzo et al. 10.5194/acp-24-5549-2024
- Secondary Organic Aerosol from OH-Initiated Oxidation of Mixtures of d-Limonene and β-Myrcene S. Liu et al. 10.1021/acs.est.4c04870
- Spectral Characteristics of Unsaturated and Supersaturated Inorganic Aerosols: Insights into Deliquescence Kinetics S. Ma et al. 10.1021/acs.jpca.4c03107
- Desorption lifetimes and activation energies influencing gas–surface interactions and multiphase chemical kinetics D. Knopf et al. 10.5194/acp-24-3445-2024
- An improved model on the evaporation kinetics of the single aerosol droplet and its application for the droplet composed of ammonium sulfate or sucrose solution C. Zhang et al. 10.1016/j.powtec.2025.120627
- Quantitative description of self-, Maxwell–Stefan, and Fick diffusion coefficients in sucrose and citric acid solution based on molecular dynamics simulations H. Bao et al. 10.1063/5.0268503
- Volatility and chemical composition of secondary organic aerosol derived from acenaphthylene and acenaphthene under various oxidant conditions W. Xiang et al. 10.1016/j.atmosenv.2024.120563
- Effects of volatility, viscosity, and non-ideality on particle–particle mixing timescales of secondary organic aerosols M. Schervish et al. 10.1080/02786826.2023.2256827
- Simulated phase state and viscosity of secondary organic aerosols over China Z. Zhang et al. 10.5194/acp-24-4809-2024
- Key Roles of Bulk Viscosity and Acidity on Liquid–Liquid Phase Separation of Atmospheric Organic–Inorganic Mixed Aerosols Y. Ye et al. 10.1021/acs.jpca.5c01182
- Geometric Analysis of Free and Accessible Volume in Atmospheric Nanoparticles P. Mermigkis et al. 10.1021/acsomega.3c03293
- Chemically Resolved Evaporation Dynamics of Dicarboxylic Acid Mixtures in Solid Particles R. Kaur Kohli et al. 10.1021/acs.analchem.3c02475
- Species-specific effect of particle viscosity and particle-phase reactions on the formation of secondary organic aerosol Z. Luo et al. 10.1016/j.scitotenv.2024.175207
- Vertical gradient in atmospheric particle phase state: a case study over the alaskan arctic oil fields N. Lata et al. 10.1039/D4EA00150H
Latest update: 14 Jun 2025
Short summary
Secondary organic aerosols (SOAs) can exhibit complex non-ideal behavior and adopt an amorphous semisolid state. We simulate condensation of semi-volatile compounds into a phase-separated particle to investigate the effect of non-ideality and particle phase state on the equilibration timescale of SOA partitioning. Our results provide useful insights into the interpretation of experimental observations and the description and treatment of SOA in aerosol models.
Secondary organic aerosols (SOAs) can exhibit complex non-ideal behavior and adopt an amorphous...
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