Articles | Volume 22, issue 2
https://doi.org/10.5194/acp-22-929-2022
© Author(s) 2022. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-22-929-2022
© Author(s) 2022. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
An assessment of the tropospherically accessible photo-initiated ground state chemistry of organic carbonyls
Keiran N. Rowell
School of Chemistry, University of Sydney, Sydney, Australia
School of Chemistry, University of New South Wales, Sydney, Australia
Scott H. Kable
School of Chemistry, University of New South Wales, Sydney, Australia
Meredith J. T. Jordan
CORRESPONDING AUTHOR
School of Chemistry, University of Sydney, Sydney, Australia
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Cited
17 citations as recorded by crossref.
- Tropospheric Photochemistry of 2-Butenedial: Role of the Triplet States, CO and Acrolein Formation, and the Experimentally Unidentified Carbonyl Compound—Theoretical Study A. Maranzana & G. Tonachini https://doi.org/10.3390/molecules29030575
- Real-Time Probing of the Multistep/Multichannel Photoisomerization and Dissociation of Propenal L. Sauer et al. https://doi.org/10.1021/jacs.6c08146
- Resolving emission factors and formation pathways of organic gaseous compounds from residential combustion of European brown coal A. Hartikainen et al. https://doi.org/10.1016/j.combustflame.2024.113485
- Evaluating the contribution of the unexplored photochemistry of aldehydes on the tropospheric levels of molecular hydrogen (H2) M. Pérez-Peña et al. https://doi.org/10.5194/acp-22-12367-2022
- Seaweed residue–derived carbon dots composite films for spoilage-responsive monitoring and preservation of large yellow croaker fillets Z. Zhan et al. https://doi.org/10.1016/j.fochx.2026.103626
- Probing soy protein-aldehyde binding by inverse liquid chromatography on protein-packed columns M. Liu et al. https://doi.org/10.1016/j.foodchem.2026.150473
- Acetylacetone Photolysis at 280 nm Studied by Velocity-Map Ion Imaging J. Rinaman & C. Murray https://doi.org/10.1021/acs.jpca.3c01653
- Photochemical transformation of weakly absorbing organics by visible light in microdroplets A. Logozzo & T. Preston https://doi.org/10.1039/D5CP03615A
- Mechanism of the Photochemical Isomerization and Oxidation of 2-Butenedial: A Theoretical Study A. Maranzana & G. Tonachini https://doi.org/10.3390/molecules28134994
- Primary and Secondary Dissociation Pathways in the UV Photochemistry of α-Dicarbonyls J. Rinaman & C. Murray https://doi.org/10.1021/acs.jpca.5c00715
- Structure–Activity Relationships for 1,3-Dipolar Cycloaddition Reactions of Criegee Intermediates with Carbonyls Z. Cornwell et al. https://doi.org/10.1021/acsearthspacechem.5c00398
- Polydimethylsiloxane-Based Composites with Photo-Autocatalytic Properties: Surface Photooxidation, Hydrophobicity, and Nanomechanical Properties M. Avadanei et al. https://doi.org/10.3390/polym18111334
- Unusually Chemoselective Photocyclization of 2-(Hydroxyimino)aldehydes to Cyclobutanol Oximes: Synthetic, Stereochemical, and Mechanistic Aspects A. Di Sabato et al. https://doi.org/10.1021/acs.joc.2c01503
- Rapid Photolysis of Gaseous Organic Nitrates Formed from Hydroxyl and Nitrate Radical Oxidation of α-Pinene and β-Pinene M. Takeuchi et al. https://doi.org/10.1021/acsestair.5c00183
- Unraveling the Primary Photochemistry of Pyruvic Acid: Direct Observation of Three Competing Channels L. Sauer & H. Davis https://doi.org/10.1021/acs.jpclett.5c00323
- Photophysical oxidation of HCHO produces HO2 radicals B. Welsh et al. https://doi.org/10.1038/s41557-023-01272-4
- The Effect of β-Hydrogens on the Tropospheric Photochemistry of Aldehydes: Norrish Type 1, Triple Fragmentation, and Methylketene Formation from Propanal A. Kharazmi et al. https://doi.org/10.1021/jacs.4c00877
17 citations as recorded by crossref.
- Tropospheric Photochemistry of 2-Butenedial: Role of the Triplet States, CO and Acrolein Formation, and the Experimentally Unidentified Carbonyl Compound—Theoretical Study A. Maranzana & G. Tonachini https://doi.org/10.3390/molecules29030575
- Real-Time Probing of the Multistep/Multichannel Photoisomerization and Dissociation of Propenal L. Sauer et al. https://doi.org/10.1021/jacs.6c08146
- Resolving emission factors and formation pathways of organic gaseous compounds from residential combustion of European brown coal A. Hartikainen et al. https://doi.org/10.1016/j.combustflame.2024.113485
- Evaluating the contribution of the unexplored photochemistry of aldehydes on the tropospheric levels of molecular hydrogen (H2) M. Pérez-Peña et al. https://doi.org/10.5194/acp-22-12367-2022
- Seaweed residue–derived carbon dots composite films for spoilage-responsive monitoring and preservation of large yellow croaker fillets Z. Zhan et al. https://doi.org/10.1016/j.fochx.2026.103626
- Probing soy protein-aldehyde binding by inverse liquid chromatography on protein-packed columns M. Liu et al. https://doi.org/10.1016/j.foodchem.2026.150473
- Acetylacetone Photolysis at 280 nm Studied by Velocity-Map Ion Imaging J. Rinaman & C. Murray https://doi.org/10.1021/acs.jpca.3c01653
- Photochemical transformation of weakly absorbing organics by visible light in microdroplets A. Logozzo & T. Preston https://doi.org/10.1039/D5CP03615A
- Mechanism of the Photochemical Isomerization and Oxidation of 2-Butenedial: A Theoretical Study A. Maranzana & G. Tonachini https://doi.org/10.3390/molecules28134994
- Primary and Secondary Dissociation Pathways in the UV Photochemistry of α-Dicarbonyls J. Rinaman & C. Murray https://doi.org/10.1021/acs.jpca.5c00715
- Structure–Activity Relationships for 1,3-Dipolar Cycloaddition Reactions of Criegee Intermediates with Carbonyls Z. Cornwell et al. https://doi.org/10.1021/acsearthspacechem.5c00398
- Polydimethylsiloxane-Based Composites with Photo-Autocatalytic Properties: Surface Photooxidation, Hydrophobicity, and Nanomechanical Properties M. Avadanei et al. https://doi.org/10.3390/polym18111334
- Unusually Chemoselective Photocyclization of 2-(Hydroxyimino)aldehydes to Cyclobutanol Oximes: Synthetic, Stereochemical, and Mechanistic Aspects A. Di Sabato et al. https://doi.org/10.1021/acs.joc.2c01503
- Rapid Photolysis of Gaseous Organic Nitrates Formed from Hydroxyl and Nitrate Radical Oxidation of α-Pinene and β-Pinene M. Takeuchi et al. https://doi.org/10.1021/acsestair.5c00183
- Unraveling the Primary Photochemistry of Pyruvic Acid: Direct Observation of Three Competing Channels L. Sauer & H. Davis https://doi.org/10.1021/acs.jpclett.5c00323
- Photophysical oxidation of HCHO produces HO2 radicals B. Welsh et al. https://doi.org/10.1038/s41557-023-01272-4
- The Effect of β-Hydrogens on the Tropospheric Photochemistry of Aldehydes: Norrish Type 1, Triple Fragmentation, and Methylketene Formation from Propanal A. Kharazmi et al. https://doi.org/10.1021/jacs.4c00877
Saved (final revised paper)
Latest update: 30 Jul 2026
Short summary
Sunlight drives chemical reactions in the atmosphere by breaking chemical bonds. Motivated by the knowledge that if we can better understand the fundamental chemistry, we will be better able to predict atmospheric composition and model any future changes, we use quantum chemistry to investigate new classes of atmospheric reactions. We identify several potentially important reaction classes that will have implications for the atmospheric production of organic acids and molecular hydrogen.
Sunlight drives chemical reactions in the atmosphere by breaking chemical bonds. Motivated by...
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