Articles | Volume 22, issue 14
https://doi.org/10.5194/acp-22-9283-2022
© Author(s) 2022. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-22-9283-2022
© Author(s) 2022. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
19 Jul 2022
Research article |
| 19 Jul 2022
| 19 Jul 2022
Volatility parameterization of ambient organic aerosols at a rural site of the North China Plain
Siman Ren
Shanghai Key Laboratory of Atmospheric Particle Pollution and
Prevention (LAP), Department of Environmental Science &
Engineering, Jiangwan Campus, Fudan University, Shanghai 200438, China
Shanghai Key Laboratory of Atmospheric Particle Pollution and
Prevention (LAP), Department of Environmental Science &
Engineering, Jiangwan Campus, Fudan University, Shanghai 200438, China
Yuwei Wang
Shanghai Key Laboratory of Atmospheric Particle Pollution and
Prevention (LAP), Department of Environmental Science &
Engineering, Jiangwan Campus, Fudan University, Shanghai 200438, China
Gan Yang
Shanghai Key Laboratory of Atmospheric Particle Pollution and
Prevention (LAP), Department of Environmental Science &
Engineering, Jiangwan Campus, Fudan University, Shanghai 200438, China
Yiliang Liu
Shanghai Key Laboratory of Atmospheric Particle Pollution and
Prevention (LAP), Department of Environmental Science &
Engineering, Jiangwan Campus, Fudan University, Shanghai 200438, China
Yueyang Li
Shanghai Key Laboratory of Atmospheric Particle Pollution and
Prevention (LAP), Department of Environmental Science &
Engineering, Jiangwan Campus, Fudan University, Shanghai 200438, China
Shanghai Key Laboratory of Atmospheric Particle Pollution and
Prevention (LAP), Department of Environmental Science &
Engineering, Jiangwan Campus, Fudan University, Shanghai 200438, China
Lihong Wang
Shanghai Key Laboratory of Atmospheric Particle Pollution and
Prevention (LAP), Department of Environmental Science &
Engineering, Jiangwan Campus, Fudan University, Shanghai 200438, China
Shanghai Key Laboratory of Atmospheric Particle Pollution and
Prevention (LAP), Department of Environmental Science &
Engineering, Jiangwan Campus, Fudan University, Shanghai 200438, China
Collaborative Innovation Center of Climate Change, Nanjing 210023,
China
Shanghai Institute of Pollution Control and Ecological Security,
Shanghai 200092, China
IRDR International Center of Excellence on Risk Interconnectivity
and Governance on Weather/ Climate Extremes Impact and Public Health, Fudan
University, Shanghai 200438, China
National Observations and Research Station for Wetland Ecosystems of
the Yangtze Estuary, Shanghai, China
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Cited
14 citations as recorded by crossref.
- Influencing factors of the gas–particle distribution of oxygenated organic molecules in the urban atmosphere and deviation from equilibrium partitioning: a random forest model study X. Wang et al. https://doi.org/10.5194/acp-25-9601-2025
- Volatility Parametrization of Atmospheric Organic Compounds Based on Molecular Formula X. Zhang et al. https://doi.org/10.1021/acsestair.5c00167
- Chemical ionization mass spectrometry: Developments and applications for on-line characterization of atmospheric aerosols and trace gases Y. Zhang et al. https://doi.org/10.1016/j.trac.2023.117353
- Characteristics and Sources of Organic Aerosol in PM2.5 at Yangbajing in Tibetan Plateau Y. Xiang et al. https://doi.org/10.1016/j.atmosenv.2024.120662
- Predicting Liquid–Liquid Phase Separation of Submicrometer Proxies for Atmospheric Secondary Aerosol Q. Huang et al. https://doi.org/10.1021/acsestair.4c00254
- New insight into the formation and aging processes of organic aerosol from positive matrix factorization (PMF) analysis of ambient FIGAERO-CIMS thermograms M. Cai et al. https://doi.org/10.5194/acp-26-769-2026
- Advances in analysis of atmospheric ultrafine particles and application in air quality, climate, and health research T. Lei et al. https://doi.org/10.1016/j.scitotenv.2024.175045
- Chemical Characterization of Rural Organic Aerosol in the North China Plain Using Ultrahigh-Resolution Mass Spectrometry Y. Zhang et al. https://doi.org/10.3390/atmos14111636
- Characterization of the Vaporization Inlet for Aerosols (VIA) for online measurements of particulate highly oxygenated organic molecules (HOMs) J. Zhao et al. https://doi.org/10.5194/amt-17-1527-2024
- Characterization and Seasonal Variation of PM2.5 Composition in Xi’an, Northwest China: Oxygenated and Nitrogenous Organic Aerosol Y. Shang et al. https://doi.org/10.1021/acsearthspacechem.4c00042
- Volatility Parametrization of Low-Volatile Components of Ambient Organic Aerosols Based on Molecular Formulas X. Yang et al. https://doi.org/10.1021/acs.est.3c02073
- Unexpected Gas-Phase Formation of Glycolic Acid Sulfate in the Atmosphere H. Sun et al. https://doi.org/10.1021/acs.est.5c07888
- Variation in chemical composition and volatility of oxygenated organic aerosol in different rural, urban, and mountain environments W. Huang et al. https://doi.org/10.5194/acp-24-2607-2024
- Enhanced daytime secondary aerosol formation driven by gas–particle partitioning in downwind urban plumes M. Cai et al. https://doi.org/10.5194/acp-24-13065-2024
14 citations as recorded by crossref.
- Influencing factors of the gas–particle distribution of oxygenated organic molecules in the urban atmosphere and deviation from equilibrium partitioning: a random forest model study X. Wang et al. https://doi.org/10.5194/acp-25-9601-2025
- Volatility Parametrization of Atmospheric Organic Compounds Based on Molecular Formula X. Zhang et al. https://doi.org/10.1021/acsestair.5c00167
- Chemical ionization mass spectrometry: Developments and applications for on-line characterization of atmospheric aerosols and trace gases Y. Zhang et al. https://doi.org/10.1016/j.trac.2023.117353
- Characteristics and Sources of Organic Aerosol in PM2.5 at Yangbajing in Tibetan Plateau Y. Xiang et al. https://doi.org/10.1016/j.atmosenv.2024.120662
- Predicting Liquid–Liquid Phase Separation of Submicrometer Proxies for Atmospheric Secondary Aerosol Q. Huang et al. https://doi.org/10.1021/acsestair.4c00254
- New insight into the formation and aging processes of organic aerosol from positive matrix factorization (PMF) analysis of ambient FIGAERO-CIMS thermograms M. Cai et al. https://doi.org/10.5194/acp-26-769-2026
- Advances in analysis of atmospheric ultrafine particles and application in air quality, climate, and health research T. Lei et al. https://doi.org/10.1016/j.scitotenv.2024.175045
- Chemical Characterization of Rural Organic Aerosol in the North China Plain Using Ultrahigh-Resolution Mass Spectrometry Y. Zhang et al. https://doi.org/10.3390/atmos14111636
- Characterization of the Vaporization Inlet for Aerosols (VIA) for online measurements of particulate highly oxygenated organic molecules (HOMs) J. Zhao et al. https://doi.org/10.5194/amt-17-1527-2024
- Characterization and Seasonal Variation of PM2.5 Composition in Xi’an, Northwest China: Oxygenated and Nitrogenous Organic Aerosol Y. Shang et al. https://doi.org/10.1021/acsearthspacechem.4c00042
- Volatility Parametrization of Low-Volatile Components of Ambient Organic Aerosols Based on Molecular Formulas X. Yang et al. https://doi.org/10.1021/acs.est.3c02073
- Unexpected Gas-Phase Formation of Glycolic Acid Sulfate in the Atmosphere H. Sun et al. https://doi.org/10.1021/acs.est.5c07888
- Variation in chemical composition and volatility of oxygenated organic aerosol in different rural, urban, and mountain environments W. Huang et al. https://doi.org/10.5194/acp-24-2607-2024
- Enhanced daytime secondary aerosol formation driven by gas–particle partitioning in downwind urban plumes M. Cai et al. https://doi.org/10.5194/acp-24-13065-2024
Saved (final revised paper)
Latest update: 13 Jun 2026
Short summary
We improved the empirical functions between volatility and chemical formulas of organic aerosols based on lab experiments and field observations. It was found that organic compounds in ambient aerosols can be divided into two groups according to their O / C ratios and that there should be specialized volatility parameterizations for different O / C organic compounds.
We improved the empirical functions between volatility and chemical formulas of organic aerosols...
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