Articles | Volume 22, issue 10
https://doi.org/10.5194/acp-22-7051-2022
© Author(s) 2022. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-22-7051-2022
© Author(s) 2022. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Fate of the nitrate radical at the summit of a semi-rural mountain site in Germany assessed with direct reactivity measurements
Patrick Dewald
Atmospheric Chemistry Department, Max-Planck-Institut für Chemie, 55128 Mainz, Germany
Clara M. Nussbaumer
Atmospheric Chemistry Department, Max-Planck-Institut für Chemie, 55128 Mainz, Germany
Jan Schuladen
Atmospheric Chemistry Department, Max-Planck-Institut für Chemie, 55128 Mainz, Germany
Akima Ringsdorf
Atmospheric Chemistry Department, Max-Planck-Institut für Chemie, 55128 Mainz, Germany
Achim Edtbauer
Atmospheric Chemistry Department, Max-Planck-Institut für Chemie, 55128 Mainz, Germany
Horst Fischer
Atmospheric Chemistry Department, Max-Planck-Institut für Chemie, 55128 Mainz, Germany
Jonathan Williams
Atmospheric Chemistry Department, Max-Planck-Institut für Chemie, 55128 Mainz, Germany
Jos Lelieveld
Atmospheric Chemistry Department, Max-Planck-Institut für Chemie, 55128 Mainz, Germany
Atmospheric Chemistry Department, Max-Planck-Institut für Chemie, 55128 Mainz, Germany
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Cited
10 citations as recorded by crossref.
- Quantitative analysis of temporal stability and instrument performance during field experiments of an airborne QCLAS via Allan–Werle-plots L. Röder et al. https://doi.org/10.1007/s00340-024-08254-5
- Measurement report: Sources, sinks, and lifetime of NOx in a suburban temperate forest at night S. Andersen et al. https://doi.org/10.5194/acp-24-11603-2024
- Data quality enhancement for field experiments in atmospheric chemistry via sequential Monte Carlo filters L. Röder et al. https://doi.org/10.5194/amt-16-1167-2023
- Vertical profiles of NO3 reactivity within the surface layer of a boreal forest P. Dewald et al. https://doi.org/10.1039/D5EA00153F
- Measurement report: Atmospheric nitrate radical chemistry in the South China Sea influenced by the urban outflow of the Pearl River Delta J. Wang et al. https://doi.org/10.5194/acp-24-977-2024
- Probing the Large Discrepancy of Highly Oxygenated Organic Molecules and Secondary Organic Aerosol Formation from Atmospheric Oxidation of Nerolidol by OH, NO3, and O3 W. Yang et al. https://doi.org/10.1021/acs.est.5c15989
- Elucidating key factors in regulating budgets of ozone and its precursors in atmospheric boundary layer X. Song et al. https://doi.org/10.1038/s41612-024-00818-8
- NO3 reactivity during a summer period in a temperate forest below and above the canopy P. Dewald et al. https://doi.org/10.5194/acp-24-8983-2024
- Influence of ambient NO and NO2 on the quantification of total peroxy nitrates (ΣPNs) and total alkyl nitrates (ΣANs) by thermal dissociation cavity ring-down spectroscopy (TD-CRDS) L. Wüst et al. https://doi.org/10.5194/amt-18-1943-2025
- NO3 reactivity measurements in an indoor environment: a pilot study P. Dewald et al. https://doi.org/10.1039/D3EA00137G
10 citations as recorded by crossref.
- Quantitative analysis of temporal stability and instrument performance during field experiments of an airborne QCLAS via Allan–Werle-plots L. Röder et al. https://doi.org/10.1007/s00340-024-08254-5
- Measurement report: Sources, sinks, and lifetime of NOx in a suburban temperate forest at night S. Andersen et al. https://doi.org/10.5194/acp-24-11603-2024
- Data quality enhancement for field experiments in atmospheric chemistry via sequential Monte Carlo filters L. Röder et al. https://doi.org/10.5194/amt-16-1167-2023
- Vertical profiles of NO3 reactivity within the surface layer of a boreal forest P. Dewald et al. https://doi.org/10.1039/D5EA00153F
- Measurement report: Atmospheric nitrate radical chemistry in the South China Sea influenced by the urban outflow of the Pearl River Delta J. Wang et al. https://doi.org/10.5194/acp-24-977-2024
- Probing the Large Discrepancy of Highly Oxygenated Organic Molecules and Secondary Organic Aerosol Formation from Atmospheric Oxidation of Nerolidol by OH, NO3, and O3 W. Yang et al. https://doi.org/10.1021/acs.est.5c15989
- Elucidating key factors in regulating budgets of ozone and its precursors in atmospheric boundary layer X. Song et al. https://doi.org/10.1038/s41612-024-00818-8
- NO3 reactivity during a summer period in a temperate forest below and above the canopy P. Dewald et al. https://doi.org/10.5194/acp-24-8983-2024
- Influence of ambient NO and NO2 on the quantification of total peroxy nitrates (ΣPNs) and total alkyl nitrates (ΣANs) by thermal dissociation cavity ring-down spectroscopy (TD-CRDS) L. Wüst et al. https://doi.org/10.5194/amt-18-1943-2025
- NO3 reactivity measurements in an indoor environment: a pilot study P. Dewald et al. https://doi.org/10.1039/D3EA00137G
Saved (final revised paper)
Latest update: 28 May 2026
Short summary
We measured the gas-phase reactivity of the NO3 radical on the summit (825 m a.s.l.) of a semi-rural mountain in southwestern Germany in July 2021. The impact of VOC-induced NO3 losses (mostly monoterpenes) competing with a loss by reaction with NO and photolysis throughout the diel cycle was estimated. Besides chemistry, boundary layer dynamics and plant-physiological processes presumably have a great impact on our observations, which were compared to previous NO3 measurements at the same site.
We measured the gas-phase reactivity of the NO3 radical on the summit (825 m a.s.l.) of a...
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