Articles | Volume 22, issue 10
https://doi.org/10.5194/acp-22-6919-2022
© Author(s) 2022. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-22-6919-2022
© Author(s) 2022. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Molecular characteristics, sources, and formation pathways of organosulfur compounds in ambient aerosol in Guangzhou, South China
Hongxing Jiang
State Key Laboratory of Organic Geochemistry, Guangdong province Key
Laboratory of Environmental Protection and Resources Utilization, and
Guangdong-Hong Kong-Macao Joint Laboratory for Environmental Pollution and
Control, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences,
Guangzhou, 510640, China
Shanghai Key Laboratory of Atmospheric Particle Pollution and
Prevention (LAP3), Department of Environmental Science and Engineering,
Fudan University, Shanghai 200433, China
CAS Center for Excellence in Deep Earth Science, Guangzhou, 510640,
China
University of Chinese Academy of Sciences, Beijing, 100049, China
State Key Laboratory of Organic Geochemistry, Guangdong province Key
Laboratory of Environmental Protection and Resources Utilization, and
Guangdong-Hong Kong-Macao Joint Laboratory for Environmental Pollution and
Control, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences,
Guangzhou, 510640, China
CAS Center for Excellence in Deep Earth Science, Guangzhou, 510640,
China
Jiao Tang
State Key Laboratory of Organic Geochemistry, Guangdong province Key
Laboratory of Environmental Protection and Resources Utilization, and
Guangdong-Hong Kong-Macao Joint Laboratory for Environmental Pollution and
Control, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences,
Guangzhou, 510640, China
CAS Center for Excellence in Deep Earth Science, Guangzhou, 510640,
China
Min Cui
College of Environmental Science and Engineering, Yangzhou University,
225009, Yangzhou, China
Shizhen Zhao
State Key Laboratory of Organic Geochemistry, Guangdong province Key
Laboratory of Environmental Protection and Resources Utilization, and
Guangdong-Hong Kong-Macao Joint Laboratory for Environmental Pollution and
Control, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences,
Guangzhou, 510640, China
CAS Center for Excellence in Deep Earth Science, Guangzhou, 510640,
China
Yangzhi Mo
State Key Laboratory of Organic Geochemistry, Guangdong province Key
Laboratory of Environmental Protection and Resources Utilization, and
Guangdong-Hong Kong-Macao Joint Laboratory for Environmental Pollution and
Control, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences,
Guangzhou, 510640, China
CAS Center for Excellence in Deep Earth Science, Guangzhou, 510640,
China
Chongguo Tian
Key Laboratory of Coastal Environmental Processes and Ecological
Remediation, Yantai Institute of Coastal Zone Research, Chinese Academy of
Sciences, Yantai, 264003, China
Xiangyun Zhang
State Key Laboratory of Organic Geochemistry, Guangdong province Key
Laboratory of Environmental Protection and Resources Utilization, and
Guangdong-Hong Kong-Macao Joint Laboratory for Environmental Pollution and
Control, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences,
Guangzhou, 510640, China
CAS Center for Excellence in Deep Earth Science, Guangzhou, 510640,
China
Bin Jiang
State Key Laboratory of Organic Geochemistry, Guangdong province Key
Laboratory of Environmental Protection and Resources Utilization, and
Guangdong-Hong Kong-Macao Joint Laboratory for Environmental Pollution and
Control, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences,
Guangzhou, 510640, China
CAS Center for Excellence in Deep Earth Science, Guangzhou, 510640,
China
Yuhong Liao
State Key Laboratory of Organic Geochemistry, Guangdong province Key
Laboratory of Environmental Protection and Resources Utilization, and
Guangdong-Hong Kong-Macao Joint Laboratory for Environmental Pollution and
Control, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences,
Guangzhou, 510640, China
CAS Center for Excellence in Deep Earth Science, Guangzhou, 510640,
China
Yingjun Chen
Shanghai Key Laboratory of Atmospheric Particle Pollution and
Prevention (LAP3), Department of Environmental Science and Engineering,
Fudan University, Shanghai 200433, China
Gan Zhang
State Key Laboratory of Organic Geochemistry, Guangdong province Key
Laboratory of Environmental Protection and Resources Utilization, and
Guangdong-Hong Kong-Macao Joint Laboratory for Environmental Pollution and
Control, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences,
Guangzhou, 510640, China
CAS Center for Excellence in Deep Earth Science, Guangzhou, 510640,
China
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Short summary
We conducted field observation employing Fourier transform ion cyclotron resonance mass spectrometry to characterize the molecular composition and major formation pathways or sources of organosulfur compounds in Guangzhou, where is heavily influenced by biogenic–anthropogenic interactions and has high relative humidity and temperature. We suggested that heterogeneous reactions such as SO2 uptake and heterogeneous oxidations are important to the molecular variations of organosulfur compounds.
We conducted field observation employing Fourier transform ion cyclotron resonance mass...
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