Articles | Volume 22, issue 10
https://doi.org/10.5194/acp-22-6411-2022
https://doi.org/10.5194/acp-22-6411-2022
Research article
 | 
18 May 2022
Research article |  | 18 May 2022

An experimental study of the reactivity of terpinolene and β-caryophyllene with the nitrate radical

Axel Fouqueau, Manuela Cirtog, Mathieu Cazaunau, Edouard Pangui, Jean-François Doussin, and Bénédicte Picquet-Varrault

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Short summary
Biogenic volatile organic compounds are intensely emitted by forests and crops and react with the nitrate radical during the nighttime to form functionalized products. The purpose of this study is to furnish kinetic and mechanistic data for terpinolene and β-caryophyllene, using simulation chamber experiments. Rate constants have been measured using both relative and absolute methods, and mechanistic studies have been conducted in order to identify and quantify the main reaction products.
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