Articles | Volume 22, issue 9
https://doi.org/10.5194/acp-22-6001-2022
© Author(s) 2022. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-22-6001-2022
© Author(s) 2022. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
06 May 2022
Research article |
| 06 May 2022
| 06 May 2022
Kinetics, SOA yields, and chemical composition of secondary organic aerosol from β-caryophyllene ozonolysis with and without nitrogen oxides between 213 and 313 K
Institute of Meteorology and Climate Research, Karlsruhe Institute of
Technology, Karlsruhe, Germany
Working Group for
Environmental Mineralogy and Environmental System Analysis, Institute of Geography and Geoecology, Karlsruhe
Institute of Technology, Karlsruhe, Germany
Junwei Song
Institute of Meteorology and Climate Research, Karlsruhe Institute of
Technology, Karlsruhe, Germany
Working Group for
Environmental Mineralogy and Environmental System Analysis, Institute of Geography and Geoecology, Karlsruhe
Institute of Technology, Karlsruhe, Germany
Claudia Mohr
Department of Environmental Science, Stockholm University, Stockholm,
Sweden
Wei Huang
Institute for Atmospheric and Earth System Research/Physics,
Faculty of Science, University of Helsinki, Helsinki, Finland
Magdalena Vallon
Institute of Meteorology and Climate Research, Karlsruhe Institute of
Technology, Karlsruhe, Germany
Feng Jiang
Institute of Meteorology and Climate Research, Karlsruhe Institute of
Technology, Karlsruhe, Germany
Working Group for
Environmental Mineralogy and Environmental System Analysis, Institute of Geography and Geoecology, Karlsruhe
Institute of Technology, Karlsruhe, Germany
Thomas Leisner
Institute of Meteorology and Climate Research, Karlsruhe Institute of
Technology, Karlsruhe, Germany
Institute of Environmental Physics, Heidelberg University, Heidelberg,
Germany
Institute of Meteorology and Climate Research, Karlsruhe Institute of
Technology, Karlsruhe, Germany
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Cited
28 citations as recorded by crossref.
- Development and validation of a NOx+ ratio method for the quantitative separation of inorganic and organic nitrate aerosol using a unit-mass-resolution time-of-flight aerosol chemical speciation monitor equipped with a capture vaporizer (CV-UMR-ToF-ACSM) F. Nursanto et al.
- Impact of temperature on the role of Criegee intermediates and peroxy radicals in dimer formation from β-pinene ozonolysis Y. Gong et al.
- NH3 Weakens the Enhancing Effect of SO2 on Biogenic Secondary Organic Aerosol Formation L. Du et al.
- Bidirectional emission of organic compounds by decaying leaf litter of a number of forest-forming tree species in the northern hemisphere V. Isidorov et al.
- Comprehensive non-targeted molecular characterization of organic aerosols in the Amazon rainforest D. Leppla et al.
- Estimation of secondary organic aerosol formation parameters for the volatility basis set combining thermodenuder, isothermal dilution, and yield measurements P. Uruci et al.
- A comprehensive evaluation of enhanced temperature influence on gas and aerosol chemistry in the lamp-enclosed oxidation flow reactor (OFR) system T. Pan et al.
- Measurement of Atmospheric Volatile and Intermediate Volatility Organic Compounds: Development of a New Time-of-Flight Mass Spectrometer C. Kaltsonoudis et al.
- AIDA Arctic transport experiment – Part 1: Simulation of northward transport and aging effect on fundamental black carbon properties M. Zanatta et al.
- Sources of organic gases and aerosol particles and their roles in nighttime particle growth at a rural forested site in southwest Germany J. Song et al.
- Organic Solar Radiation Modification M. Kulmala et al.
- Role of sesquiterpenes in biogenic new particle formation L. Dada et al.
- Photo-Oxidation of α-Pinene Oxidation Products in Atmospheric Waters – pH- and Temperature-Dependent Kinetic Studies A. Błaziak et al.
- Assessing the Difference in the Effects of NOx on the Photooxidation Mechanisms of Isomeric Compounds of α-Pinene and Δ3-Carene Z. Zhang et al.
- Atmospheric Temperature Dependence of β-Caryophyllene Ozonolysis Kinetics Is Governed by Stabilized Prereactive Complexes H. Ou & K. Chen
- Unveiling the formation of atmospheric oxygenated organic molecules under anthropogenic–biogenic interactions: insights from binned positive matrix factorization on multi-subrange mass spectra J. Yin et al.
- Applications of environmental mass spectrometry in atmospheric haze chemistry T. Chen et al.
- Volatility of Secondary Organic Aerosol from β-Caryophyllene Ozonolysis over a Wide Tropospheric Temperature Range L. Gao et al.
- Temperature effects on SOA formation of n-dodecane reaction initiated by Cl atoms C. Fan et al.
- The AquaVIT-4 intercomparison of atmospheric hygrometers S. Brunamonti et al.
- Formation and kinetics of terpenoic acids from α-pinene and δ-3-carene-derived SOA components via aqueous-phase OH radicals K. Pawlak et al.
- Development of the low-temperature hygroscopicity tandem differential mobility analyzer (Low-T HTDMA) and its application to (NH4)2SO4 and NaCl particles M. Cheng & M. Kuwata
- Molecular analysis of secondary organic aerosol and brown carbon from the oxidation of indole F. Jiang et al.
- Dependence of Reactive Oxygen Species Formation on the Oxidation State of Biogenic Secondary Organic Aerosols K. Edwards et al.
- Review of Smog Chamber Research Trends J. Kim et al.
- Controlled particle coating from β -caryophyllene photo-oxidation: An aerosol dynamics modeling–assisted chamber method M. Olin et al.
- Modeling secondary organic aerosols from β-caryophyllene: role of extremely low-volatile organic compounds on new particle formation and evaluation of the SOA composition Y. Shi et al.
- Unaccounted impacts of diterpene emissions on atmospheric aerosol loadings A. Yáñez-Serrano et al.
28 citations as recorded by crossref.
- Development and validation of a NOx+ ratio method for the quantitative separation of inorganic and organic nitrate aerosol using a unit-mass-resolution time-of-flight aerosol chemical speciation monitor equipped with a capture vaporizer (CV-UMR-ToF-ACSM) F. Nursanto et al.
- Impact of temperature on the role of Criegee intermediates and peroxy radicals in dimer formation from β-pinene ozonolysis Y. Gong et al.
- NH3 Weakens the Enhancing Effect of SO2 on Biogenic Secondary Organic Aerosol Formation L. Du et al.
- Bidirectional emission of organic compounds by decaying leaf litter of a number of forest-forming tree species in the northern hemisphere V. Isidorov et al.
- Comprehensive non-targeted molecular characterization of organic aerosols in the Amazon rainforest D. Leppla et al.
- Estimation of secondary organic aerosol formation parameters for the volatility basis set combining thermodenuder, isothermal dilution, and yield measurements P. Uruci et al.
- A comprehensive evaluation of enhanced temperature influence on gas and aerosol chemistry in the lamp-enclosed oxidation flow reactor (OFR) system T. Pan et al.
- Measurement of Atmospheric Volatile and Intermediate Volatility Organic Compounds: Development of a New Time-of-Flight Mass Spectrometer C. Kaltsonoudis et al.
- AIDA Arctic transport experiment – Part 1: Simulation of northward transport and aging effect on fundamental black carbon properties M. Zanatta et al.
- Sources of organic gases and aerosol particles and their roles in nighttime particle growth at a rural forested site in southwest Germany J. Song et al.
- Organic Solar Radiation Modification M. Kulmala et al.
- Role of sesquiterpenes in biogenic new particle formation L. Dada et al.
- Photo-Oxidation of α-Pinene Oxidation Products in Atmospheric Waters – pH- and Temperature-Dependent Kinetic Studies A. Błaziak et al.
- Assessing the Difference in the Effects of NOx on the Photooxidation Mechanisms of Isomeric Compounds of α-Pinene and Δ3-Carene Z. Zhang et al.
- Atmospheric Temperature Dependence of β-Caryophyllene Ozonolysis Kinetics Is Governed by Stabilized Prereactive Complexes H. Ou & K. Chen
- Unveiling the formation of atmospheric oxygenated organic molecules under anthropogenic–biogenic interactions: insights from binned positive matrix factorization on multi-subrange mass spectra J. Yin et al.
- Applications of environmental mass spectrometry in atmospheric haze chemistry T. Chen et al.
- Volatility of Secondary Organic Aerosol from β-Caryophyllene Ozonolysis over a Wide Tropospheric Temperature Range L. Gao et al.
- Temperature effects on SOA formation of n-dodecane reaction initiated by Cl atoms C. Fan et al.
- The AquaVIT-4 intercomparison of atmospheric hygrometers S. Brunamonti et al.
- Formation and kinetics of terpenoic acids from α-pinene and δ-3-carene-derived SOA components via aqueous-phase OH radicals K. Pawlak et al.
- Development of the low-temperature hygroscopicity tandem differential mobility analyzer (Low-T HTDMA) and its application to (NH4)2SO4 and NaCl particles M. Cheng & M. Kuwata
- Molecular analysis of secondary organic aerosol and brown carbon from the oxidation of indole F. Jiang et al.
- Dependence of Reactive Oxygen Species Formation on the Oxidation State of Biogenic Secondary Organic Aerosols K. Edwards et al.
- Review of Smog Chamber Research Trends J. Kim et al.
- Controlled particle coating from β -caryophyllene photo-oxidation: An aerosol dynamics modeling–assisted chamber method M. Olin et al.
- Modeling secondary organic aerosols from β-caryophyllene: role of extremely low-volatile organic compounds on new particle formation and evaluation of the SOA composition Y. Shi et al.
- Unaccounted impacts of diterpene emissions on atmospheric aerosol loadings A. Yáñez-Serrano et al.
Saved (final revised paper)
Latest update: 28 Apr 2026
Short summary
We study secondary organic aerosol (SOA) from β-caryophyllene (BCP) ozonolysis with and without nitrogen oxides over 213–313 K in the simulation chamber. The yields and the rate constants were determined at 243–313 K. Chemical compositions varied at different temperatures, indicating a strong impact on the BCP ozonolysis pathways. This work helps to better understand the SOA from BCP ozonolysis for conditions representative of the real atmosphere from the boundary layer to the upper troposphere.
We study secondary organic aerosol (SOA) from β-caryophyllene (BCP) ozonolysis with and without...
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