Articles | Volume 22, issue 7
https://doi.org/10.5194/acp-22-4895-2022
© Author(s) 2022. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-22-4895-2022
© Author(s) 2022. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
12 Apr 2022
Research article |
| 12 Apr 2022
| 12 Apr 2022
The impact of molecular self-organisation on the atmospheric fate of a cooking aerosol proxy
Adam Milsom
School of Geography, Earth and Environmental Sciences, University of Birmingham, Edgbaston, Birmingham, UK
Adam M. Squires
Department of Chemistry, University of Bath, South Building, Soldier Down Ln, Claverton Down, Bath, UK
Andrew D. Ward
STFC Rutherford Appleton Laboratory, Central Laser Facility, Didcot OX11 0FA, UK
School of Geography, Earth and Environmental Sciences, University of Birmingham, Edgbaston, Birmingham, UK
Department of Meteorology, University of Reading, Whiteknights, Earley Gate, Reading, UK
Viewed
Total article views: 4,906 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 25 Nov 2021)
| HTML | XML | Total | Supplement | BibTeX | EndNote | |
|---|---|---|---|---|---|---|
| 3,694 | 1,078 | 134 | 4,906 | 306 | 119 | 154 |
- HTML: 3,694
- PDF: 1,078
- XML: 134
- Total: 4,906
- Supplement: 306
- BibTeX: 119
- EndNote: 154
Total article views: 3,869 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 12 Apr 2022)
| HTML | XML | Total | Supplement | BibTeX | EndNote | |
|---|---|---|---|---|---|---|
| 3,105 | 665 | 99 | 3,869 | 164 | 106 | 140 |
- HTML: 3,105
- PDF: 665
- XML: 99
- Total: 3,869
- Supplement: 164
- BibTeX: 106
- EndNote: 140
Total article views: 1,037 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 25 Nov 2021)
| HTML | XML | Total | Supplement | BibTeX | EndNote | |
|---|---|---|---|---|---|---|
| 589 | 413 | 35 | 1,037 | 142 | 13 | 14 |
- HTML: 589
- PDF: 413
- XML: 35
- Total: 1,037
- Supplement: 142
- BibTeX: 13
- EndNote: 14
Viewed (geographical distribution)
Total article views: 4,906 (including HTML, PDF, and XML)
Thereof 4,850 with geography defined
and 56 with unknown origin.
Total article views: 3,869 (including HTML, PDF, and XML)
Thereof 3,819 with geography defined
and 50 with unknown origin.
Total article views: 1,037 (including HTML, PDF, and XML)
Thereof 1,031 with geography defined
and 6 with unknown origin.
| Country | # | Views | % |
|---|
| Country | # | Views | % |
|---|
| Country | # | Views | % |
|---|
| Total: | 0 |
| HTML: | 0 |
| PDF: | 0 |
| XML: | 0 |
- 1
1
| Total: | 0 |
| HTML: | 0 |
| PDF: | 0 |
| XML: | 0 |
- 1
1
| Total: | 0 |
| HTML: | 0 |
| PDF: | 0 |
| XML: | 0 |
- 1
1
Cited
20 citations as recorded by crossref.
- Surface Nitrate Enrichment and Enhanced HONO Production from Ionic Surfactant Aggregation at the Aqueous-Air Interface Q. Li et al. https://doi.org/10.1021/acs.est.4c05967
- Exploring the Nanostructures Accessible to an Organic Surfactant Atmospheric Aerosol Proxy A. Milsom et al. https://doi.org/10.1021/acs.jpca.2c04611
- Surface functionality of sub- to full-monolayer organic coverage of water aerosols determined by molecular dynamics simulations A. Stewart et al. https://doi.org/10.1039/D2EA00148A
- Surface Crust Formation Controls Evaporation Kinetics of Secondary Organic Aerosols M. Schervish et al. https://doi.org/10.1021/acs.est.5c11018
- Experimental observation of the impact of nanostructure on hygroscopicity and reactivity of fatty acid atmospheric aerosol proxies A. Milsom et al. https://doi.org/10.5194/acp-24-13571-2024
- Does gas-phase sulfur dioxide remove films of atmosphere-extracted organic material from the aqueous aerosol air–water interface? E. Stuckey et al. https://doi.org/10.1039/D4EA00098F
- The influence of saturation on the surface structure of mixed fatty acid-on-water aerosol: a molecular dynamics study A. Stewart et al. https://doi.org/10.1039/D2EA00089J
- Electrodynamic balance–mass spectrometry reveals impact of oxidant concentration on product composition in the ozonolysis of oleic acid M. Müller et al. https://doi.org/10.1039/D2CP03289A
- Exploring the influence of particle phase in the ozonolysis of oleic and elaidic acid R. Kaur Kohli et al. https://doi.org/10.1080/02786826.2023.2226183
- Technical note: In situ measurements and modelling of the oxidation kinetics in films of a cooking aerosol proxy using a quartz crystal microbalance with dissipation monitoring (QCM-D) A. Milsom et al. https://doi.org/10.5194/acp-23-10835-2023
- Accelerating models for multiphase chemical kinetics through machine learning with polynomial chaos expansion and neural networks T. Berkemeier et al. https://doi.org/10.5194/gmd-16-2037-2023
- MultilayerPy (v1.0): a Python-based framework for building, running and optimising kinetic multi-layer models of aerosols and films A. Milsom et al. https://doi.org/10.5194/gmd-15-7139-2022
- Molecular Self-Organization in Surfactant Atmospheric Aerosol Proxies A. Milsom et al. https://doi.org/10.1021/acs.accounts.3c00194
- Acoustic levitation with polarising optical microscopy (AL-POM): water uptake in a nanostructured atmospheric aerosol proxy A. Milsom et al. https://doi.org/10.1039/D3EA00083D
- A numerical compass for experiment design in chemical kinetics and molecular property estimation M. Krüger et al. https://doi.org/10.1186/s13321-024-00825-0
- Night-time oxidation at the air–water interface: co-surfactant effects in binary mixtures F. Sebastiani et al. https://doi.org/10.1039/D2EA00056C
- Impact of Bulk-Phase Self-Assembly on Growth and Activation of Aqueous Surfactant Aerosol S. Vepsäläinen & N. Prisle https://doi.org/10.1021/acs.est.4c11584
- Use of Humidity Controlled Quartz Crystal Microbalance with Simultaneous Grazing Incidence Small Angle X-ray Scattering to Investigate the Self-assembly and Energetics of Lipid Thin Films J. Macklin et al. https://doi.org/10.1021/acs.langmuir.4c05158
- A Breath of Fresh Air: Perspectives on Inhaled Nutrients and Bacteria to Improve Human Health F. Fayet-Moore & S. Robinson https://doi.org/10.1016/j.advnut.2024.100333
- The evolution of surface structure during simulated atmospheric ageing of nano-scale coatings of an organic surfactant aerosol proxy A. Milsom et al. https://doi.org/10.1039/D2EA00011C
20 citations as recorded by crossref.
- Surface Nitrate Enrichment and Enhanced HONO Production from Ionic Surfactant Aggregation at the Aqueous-Air Interface Q. Li et al. https://doi.org/10.1021/acs.est.4c05967
- Exploring the Nanostructures Accessible to an Organic Surfactant Atmospheric Aerosol Proxy A. Milsom et al. https://doi.org/10.1021/acs.jpca.2c04611
- Surface functionality of sub- to full-monolayer organic coverage of water aerosols determined by molecular dynamics simulations A. Stewart et al. https://doi.org/10.1039/D2EA00148A
- Surface Crust Formation Controls Evaporation Kinetics of Secondary Organic Aerosols M. Schervish et al. https://doi.org/10.1021/acs.est.5c11018
- Experimental observation of the impact of nanostructure on hygroscopicity and reactivity of fatty acid atmospheric aerosol proxies A. Milsom et al. https://doi.org/10.5194/acp-24-13571-2024
- Does gas-phase sulfur dioxide remove films of atmosphere-extracted organic material from the aqueous aerosol air–water interface? E. Stuckey et al. https://doi.org/10.1039/D4EA00098F
- The influence of saturation on the surface structure of mixed fatty acid-on-water aerosol: a molecular dynamics study A. Stewart et al. https://doi.org/10.1039/D2EA00089J
- Electrodynamic balance–mass spectrometry reveals impact of oxidant concentration on product composition in the ozonolysis of oleic acid M. Müller et al. https://doi.org/10.1039/D2CP03289A
- Exploring the influence of particle phase in the ozonolysis of oleic and elaidic acid R. Kaur Kohli et al. https://doi.org/10.1080/02786826.2023.2226183
- Technical note: In situ measurements and modelling of the oxidation kinetics in films of a cooking aerosol proxy using a quartz crystal microbalance with dissipation monitoring (QCM-D) A. Milsom et al. https://doi.org/10.5194/acp-23-10835-2023
- Accelerating models for multiphase chemical kinetics through machine learning with polynomial chaos expansion and neural networks T. Berkemeier et al. https://doi.org/10.5194/gmd-16-2037-2023
- MultilayerPy (v1.0): a Python-based framework for building, running and optimising kinetic multi-layer models of aerosols and films A. Milsom et al. https://doi.org/10.5194/gmd-15-7139-2022
- Molecular Self-Organization in Surfactant Atmospheric Aerosol Proxies A. Milsom et al. https://doi.org/10.1021/acs.accounts.3c00194
- Acoustic levitation with polarising optical microscopy (AL-POM): water uptake in a nanostructured atmospheric aerosol proxy A. Milsom et al. https://doi.org/10.1039/D3EA00083D
- A numerical compass for experiment design in chemical kinetics and molecular property estimation M. Krüger et al. https://doi.org/10.1186/s13321-024-00825-0
- Night-time oxidation at the air–water interface: co-surfactant effects in binary mixtures F. Sebastiani et al. https://doi.org/10.1039/D2EA00056C
- Impact of Bulk-Phase Self-Assembly on Growth and Activation of Aqueous Surfactant Aerosol S. Vepsäläinen & N. Prisle https://doi.org/10.1021/acs.est.4c11584
- Use of Humidity Controlled Quartz Crystal Microbalance with Simultaneous Grazing Incidence Small Angle X-ray Scattering to Investigate the Self-assembly and Energetics of Lipid Thin Films J. Macklin et al. https://doi.org/10.1021/acs.langmuir.4c05158
- A Breath of Fresh Air: Perspectives on Inhaled Nutrients and Bacteria to Improve Human Health F. Fayet-Moore & S. Robinson https://doi.org/10.1016/j.advnut.2024.100333
- The evolution of surface structure during simulated atmospheric ageing of nano-scale coatings of an organic surfactant aerosol proxy A. Milsom et al. https://doi.org/10.1039/D2EA00011C
Saved (final revised paper)
Latest update: 12 Aug 2026
Short summary
Cooking emissions can self-organise into nanostructured lamellar bilayers, and this can influence reaction kinetics. We developed a kinetic multi-layer model-based description of decay data we obtained from laboratory experiments of the ozonolysis of coated films of such a self-organised system, demonstrating a decreased diffusivity for both oleic acid and ozone. Nanostructure formation can thus increase the reactive half-life of oleic acid by days under typical indoor and outdoor conditions.
Cooking emissions can self-organise into nanostructured lamellar bilayers, and this can...
Altmetrics
Final-revised paper
Preprint