Articles | Volume 22, issue 5
https://doi.org/10.5194/acp-22-3131-2022
© Author(s) 2022. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-22-3131-2022
© Author(s) 2022. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Secondary organic aerosol formation from camphene oxidation: measurements and modeling
Qi Li
Department of Chemical and Environmental Engineering, University of
California Riverside, Riverside, California 92521, United States
The Bourns College of Engineering, Center for Environmental Research
and Technology, University of California Riverside, Riverside, California
92507, United States
Jia Jiang
Department of Chemical and Environmental Engineering, University of
California Riverside, Riverside, California 92521, United States
The Bourns College of Engineering, Center for Environmental Research
and Technology, University of California Riverside, Riverside, California
92507, United States
Isaac K. Afreh
Department of Chemical and Environmental Engineering, University of
California Riverside, Riverside, California 92521, United States
The Bourns College of Engineering, Center for Environmental Research
and Technology, University of California Riverside, Riverside, California
92507, United States
Kelley C. Barsanti
CORRESPONDING AUTHOR
Department of Chemical and Environmental Engineering, University of
California Riverside, Riverside, California 92521, United States
The Bourns College of Engineering, Center for Environmental Research
and Technology, University of California Riverside, Riverside, California
92507, United States
David R. Cocker III
CORRESPONDING AUTHOR
Department of Chemical and Environmental Engineering, University of
California Riverside, Riverside, California 92521, United States
The Bourns College of Engineering, Center for Environmental Research
and Technology, University of California Riverside, Riverside, California
92507, United States
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Cited
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- Derivation of atmospheric reaction mechanisms for volatile organic compounds by the SAPRC mechanism generation system (MechGen) W. Carter et al. 10.5194/acp-25-199-2025
- Furan-based fluorescent probe free radical capture membrane: Analysis of RO2 radical composition and transformation mechanism in urban atmosphere X. Li et al. 10.1016/j.chemosphere.2023.140916
- Development of a multiphase chemical mechanism to improve secondary organic aerosol formation in CAABA/MECCA (version 4.7.0) F. Wieser et al. 10.5194/gmd-17-4311-2024
- New insights into black carbon light absorption enhancement: A comprehensive analysis of two differential behaviors R. Fan et al. 10.1016/j.envpol.2024.124175
- Emerging investigator series: secondary organic aerosol formation from photooxidation of acyclic terpenes in an oxidation flow reactor S. Gu et al. 10.1039/D4EM00063C
- Highly Effective and Broad-Spectrum Antimicrobial Quaternary Ammonium Salts Containing Camphene Structure: Preparation, Surface-Active Properties, and Bioassay Y. Huang et al. 10.1021/acsomega.3c03599
- Ring-Opening Competes with Peroxidation in Fenchone Low-Temperature Autoignition D. Vassetti et al. 10.1021/acs.jpca.4c08396
- Effects of NO2 and RH on secondary organic aerosol formation and light absorption from OH oxidation of ο-xylene S. Liu et al. 10.1016/j.chemosphere.2022.136541
- Review of Smog Chamber Research Trends J. Kim et al. 10.5572/KOSAE.2023.39.5.866
- Implementation of a parallel reduction algorithm in the GENerator of reduced Organic Aerosol mechanisms (GENOA v2.0): Application to multiple monoterpene aerosol precursors Z. Wang et al. 10.1016/j.jaerosci.2023.106248
10 citations as recorded by crossref.
- Derivation of atmospheric reaction mechanisms for volatile organic compounds by the SAPRC mechanism generation system (MechGen) W. Carter et al. 10.5194/acp-25-199-2025
- Furan-based fluorescent probe free radical capture membrane: Analysis of RO2 radical composition and transformation mechanism in urban atmosphere X. Li et al. 10.1016/j.chemosphere.2023.140916
- Development of a multiphase chemical mechanism to improve secondary organic aerosol formation in CAABA/MECCA (version 4.7.0) F. Wieser et al. 10.5194/gmd-17-4311-2024
- New insights into black carbon light absorption enhancement: A comprehensive analysis of two differential behaviors R. Fan et al. 10.1016/j.envpol.2024.124175
- Emerging investigator series: secondary organic aerosol formation from photooxidation of acyclic terpenes in an oxidation flow reactor S. Gu et al. 10.1039/D4EM00063C
- Highly Effective and Broad-Spectrum Antimicrobial Quaternary Ammonium Salts Containing Camphene Structure: Preparation, Surface-Active Properties, and Bioassay Y. Huang et al. 10.1021/acsomega.3c03599
- Ring-Opening Competes with Peroxidation in Fenchone Low-Temperature Autoignition D. Vassetti et al. 10.1021/acs.jpca.4c08396
- Effects of NO2 and RH on secondary organic aerosol formation and light absorption from OH oxidation of ο-xylene S. Liu et al. 10.1016/j.chemosphere.2022.136541
- Review of Smog Chamber Research Trends J. Kim et al. 10.5572/KOSAE.2023.39.5.866
- Implementation of a parallel reduction algorithm in the GENerator of reduced Organic Aerosol mechanisms (GENOA v2.0): Application to multiple monoterpene aerosol precursors Z. Wang et al. 10.1016/j.jaerosci.2023.106248
Latest update: 23 Apr 2025
Short summary
Chamber-derived secondary organic aerosol (SOA) yields from camphene are reported for the first time. The role of peroxy radicals (RO2) was investigated using chemically detailed box models. We observed higher SOA yields (up to 64 %) in the experiments with added NOx than without due to the formation of highly oxygenated organic molecules (HOMs) when
NOx is present. This work can improve the representation of camphene in air quality models and provide insights into other monoterpene studies.
Chamber-derived secondary organic aerosol (SOA) yields from camphene are reported for the first...
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