Articles | Volume 22, issue 3
https://doi.org/10.5194/acp-22-1761-2022
© Author(s) 2022. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-22-1761-2022
© Author(s) 2022. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
04 Feb 2022
Research article |
| 04 Feb 2022
| 04 Feb 2022
NO3 chemistry of wildfire emissions: a kinetic study of the gas-phase reactions of furans with the NO3 radical
Mike J. Newland
CORRESPONDING AUTHOR
ICARE-CNRS, 1C, avenue de la Recherche Scientifique, 45071 Orléans CEDEX 2,
France
Yangang Ren
ICARE-CNRS, 1C, avenue de la Recherche Scientifique, 45071 Orléans CEDEX 2,
France
now at: Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085, China
now at: University of Chinese Academy of Sciences, Beijing 100049, China
Max R. McGillen
ICARE-CNRS, 1C, avenue de la Recherche Scientifique, 45071 Orléans CEDEX 2,
France
Lisa Michelat
ICARE-CNRS, 1C, avenue de la Recherche Scientifique, 45071 Orléans CEDEX 2,
France
Véronique Daële
ICARE-CNRS, 1C, avenue de la Recherche Scientifique, 45071 Orléans CEDEX 2,
France
Abdelwahid Mellouki
CORRESPONDING AUTHOR
ICARE-CNRS, 1C, avenue de la Recherche Scientifique, 45071 Orléans CEDEX 2,
France
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Cited
15 citations as recorded by crossref.
- Rate coefficients for the gas‐phase OH + furan (C4H4O) reaction between 273 and 353 K M. Angelaki et al. 10.1002/kin.21697
- Reacting flow field simulation of Hg<sup>0</sup> oxidation in flue gas by ozone injection Z. Wen et al. 10.4491/eer.2022.681
- Rate Coefficients for the Gas-Phase Reactions of Nitrate Radicals with a Series of Furan Compounds F. Al Ali et al. 10.1021/acs.jpca.2c03828
- O3 chemistry of 2,5-dimethylfuran: mechanism development N. Illmann & V. Rösgen 10.1039/D4EA00045E
- Chirped-pulse Fourier-transform millimeter-wave rotational spectroscopy of furan in its v10 and v13 excited vibrational states P. Mishra et al. 10.1016/j.jms.2022.111686
- Nighttime chemistry of furanoids and terpenes: Temperature dependent kinetics with NO3 radicals and insights into the reaction mechanism F. Al Ali et al. 10.1016/j.atmosenv.2024.120898
- Simulated temperatures of forest fires affect water solubility in soil and litter K. Miotliński et al. 10.1016/j.ecolind.2023.110236
- Insights into secondary organic aerosol formation from the day- and nighttime oxidation of polycyclic aromatic hydrocarbons and furans in an oxidation flow reactor A. El Mais et al. 10.5194/acp-23-15077-2023
- Effects of Nitrate Radical Levels and Pre-Existing Particles on Secondary Brown Carbon Formation from Nighttime Oxidation of Furan K. Chen et al. 10.1021/acsearthspacechem.2c00244
- Products and yields for the NO3 radical initiated atmospheric degradation of 2-methylfuran (2-MF, CH3–C4H3O) F. Al Ali et al. 10.1016/j.atmosenv.2023.120276
- Emissions and Atmospheric Chemistry of Furanoids from Biomass Burning: Insights from Laboratory to Atmospheric Observations M. Romanias et al. 10.1021/acsearthspacechem.3c00226
- An experimental study of the reactivity of terpinolene and <i>β</i>-caryophyllene with the nitrate radical A. Fouqueau et al. 10.5194/acp-22-6411-2022
- Millimeter-Wave Spectroscopy of Methylfuran Isomers: Local vs. Global Treatments of the Internal Rotation J. Bruckhuisen et al. 10.3390/molecules27113591
- Furoyl peroxynitrate (fur-PAN), a product of VOC–NOxphotochemistry from biomass burning emissions: photochemical synthesis, calibration, chemical characterization, and first atmospheric observations J. Roberts et al. 10.1039/D2EA00068G
- Characterization and dark oxidation of the emissions of a pellet stove K. Florou et al. 10.1039/D3EA00070B
15 citations as recorded by crossref.
- Rate coefficients for the gas‐phase OH + furan (C4H4O) reaction between 273 and 353 K M. Angelaki et al. 10.1002/kin.21697
- Reacting flow field simulation of Hg<sup>0</sup> oxidation in flue gas by ozone injection Z. Wen et al. 10.4491/eer.2022.681
- Rate Coefficients for the Gas-Phase Reactions of Nitrate Radicals with a Series of Furan Compounds F. Al Ali et al. 10.1021/acs.jpca.2c03828
- O3 chemistry of 2,5-dimethylfuran: mechanism development N. Illmann & V. Rösgen 10.1039/D4EA00045E
- Chirped-pulse Fourier-transform millimeter-wave rotational spectroscopy of furan in its v10 and v13 excited vibrational states P. Mishra et al. 10.1016/j.jms.2022.111686
- Nighttime chemistry of furanoids and terpenes: Temperature dependent kinetics with NO3 radicals and insights into the reaction mechanism F. Al Ali et al. 10.1016/j.atmosenv.2024.120898
- Simulated temperatures of forest fires affect water solubility in soil and litter K. Miotliński et al. 10.1016/j.ecolind.2023.110236
- Insights into secondary organic aerosol formation from the day- and nighttime oxidation of polycyclic aromatic hydrocarbons and furans in an oxidation flow reactor A. El Mais et al. 10.5194/acp-23-15077-2023
- Effects of Nitrate Radical Levels and Pre-Existing Particles on Secondary Brown Carbon Formation from Nighttime Oxidation of Furan K. Chen et al. 10.1021/acsearthspacechem.2c00244
- Products and yields for the NO3 radical initiated atmospheric degradation of 2-methylfuran (2-MF, CH3–C4H3O) F. Al Ali et al. 10.1016/j.atmosenv.2023.120276
- Emissions and Atmospheric Chemistry of Furanoids from Biomass Burning: Insights from Laboratory to Atmospheric Observations M. Romanias et al. 10.1021/acsearthspacechem.3c00226
- An experimental study of the reactivity of terpinolene and <i>β</i>-caryophyllene with the nitrate radical A. Fouqueau et al. 10.5194/acp-22-6411-2022
- Millimeter-Wave Spectroscopy of Methylfuran Isomers: Local vs. Global Treatments of the Internal Rotation J. Bruckhuisen et al. 10.3390/molecules27113591
- Furoyl peroxynitrate (fur-PAN), a product of VOC–NOxphotochemistry from biomass burning emissions: photochemical synthesis, calibration, chemical characterization, and first atmospheric observations J. Roberts et al. 10.1039/D2EA00068G
- Characterization and dark oxidation of the emissions of a pellet stove K. Florou et al. 10.1039/D3EA00070B
Latest update: 13 Dec 2024
Short summary
Wildfires are increasing in extent and severity, driven by climate change. Such fires emit large amounts of volatile organic compounds (VOCs) to the atmosphere. Many of these, such as the furans studied here, are very reactive and are rapidly converted to other VOCs, which are expected to have negative health effects and to further impact the climate. Here, we establish the importance of the nitrate radical for removing these compounds both during the night and during the day.
Wildfires are increasing in extent and severity, driven by climate change. Such fires emit large...
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