Articles | Volume 22, issue 22
https://doi.org/10.5194/acp-22-14837-2022
© Author(s) 2022. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-22-14837-2022
© Author(s) 2022. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
22 Nov 2022
Research article |
| 22 Nov 2022
| 22 Nov 2022
Formation and impacts of nitryl chloride in Pearl River Delta
Haichao Wang
School of Atmospheric Sciences, Sun Yat-sen University, Zhuhai, 519082, China
Guangdong Provincial Observation and Research Station for Climate Environment and Air Quality Change in the Pearl River Estuary, Key Laboratory of Tropical Atmosphere-Ocean System, Ministry of Education, Southern Marine Science and Engineering Guangdong Laboratory (Zhuhai), Zhuhai, 519082, China
Institute for Environmental and Climate Research, Jinan University, Guangzhou, 511443, China
Guangdong–Hong Kong–Macau Joint Laboratory of Collaborative Innovation for Environmental Quality, Guangzhou, 511443, China
E Zheng
Institute for Environmental and Climate Research, Jinan University, Guangzhou, 511443, China
Guangdong–Hong Kong–Macau Joint Laboratory of Collaborative Innovation for Environmental Quality, Guangzhou, 511443, China
Xiaoxiao Zhang
Institute for Environmental and Climate Research, Jinan University, Guangzhou, 511443, China
Guangdong–Hong Kong–Macau Joint Laboratory of Collaborative Innovation for Environmental Quality, Guangzhou, 511443, China
Jie Wang
School of Atmospheric Sciences, Sun Yat-sen University, Zhuhai, 519082, China
Keding Lu
State Key Joint Laboratory of Environmental Simulation and Pollution Control, College of Environmental Sciences and Engineering, Peking University, Beijing, 100871, China
The State Environmental Protection Key Laboratory of Atmospheric Ozone Pollution Control, College of Environmental Sciences and Engineering, Peking University, Beijing, 100871, China
Chenshuo Ye
Institute for Environmental and Climate Research, Jinan University, Guangzhou, 511443, China
Guangdong–Hong Kong–Macau Joint Laboratory of Collaborative Innovation for Environmental Quality, Guangzhou, 511443, China
Lei Yang
Institute for Environmental and Climate Research, Jinan University, Guangzhou, 511443, China
Guangdong–Hong Kong–Macau Joint Laboratory of Collaborative Innovation for Environmental Quality, Guangzhou, 511443, China
Shan Huang
Institute for Environmental and Climate Research, Jinan University, Guangzhou, 511443, China
Guangdong–Hong Kong–Macau Joint Laboratory of Collaborative Innovation for Environmental Quality, Guangzhou, 511443, China
Weiwei Hu
State Key Laboratory of Organic Geochemistry and Guangdong Key Laboratory of Environmental Protection and Resources Utilization, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640, China
Suxia Yang
Institute for Environmental and Climate Research, Jinan University, Guangzhou, 511443, China
Guangdong–Hong Kong–Macau Joint Laboratory of Collaborative Innovation for Environmental Quality, Guangzhou, 511443, China
Yuwen Peng
Institute for Environmental and Climate Research, Jinan University, Guangzhou, 511443, China
Guangdong–Hong Kong–Macau Joint Laboratory of Collaborative Innovation for Environmental Quality, Guangzhou, 511443, China
Jipeng Qi
Institute for Environmental and Climate Research, Jinan University, Guangzhou, 511443, China
Guangdong–Hong Kong–Macau Joint Laboratory of Collaborative Innovation for Environmental Quality, Guangzhou, 511443, China
Sihang Wang
Institute for Environmental and Climate Research, Jinan University, Guangzhou, 511443, China
Guangdong–Hong Kong–Macau Joint Laboratory of Collaborative Innovation for Environmental Quality, Guangzhou, 511443, China
Xianjun He
Institute for Environmental and Climate Research, Jinan University, Guangzhou, 511443, China
Guangdong–Hong Kong–Macau Joint Laboratory of Collaborative Innovation for Environmental Quality, Guangzhou, 511443, China
Yubin Chen
Institute for Environmental and Climate Research, Jinan University, Guangzhou, 511443, China
Guangdong–Hong Kong–Macau Joint Laboratory of Collaborative Innovation for Environmental Quality, Guangzhou, 511443, China
Tiange Li
Institute for Environmental and Climate Research, Jinan University, Guangzhou, 511443, China
Guangdong–Hong Kong–Macau Joint Laboratory of Collaborative Innovation for Environmental Quality, Guangzhou, 511443, China
Wenjie Wang
Institute for Environmental and Climate Research, Jinan University, Guangzhou, 511443, China
Multiphase Chemistry Department, Max Planck Institute for Chemistry, Mainz 55128, Germany
Yibo Huangfu
Institute for Environmental and Climate Research, Jinan University, Guangzhou, 511443, China
Guangdong–Hong Kong–Macau Joint Laboratory of Collaborative Innovation for Environmental Quality, Guangzhou, 511443, China
Xiaobing Li
Institute for Environmental and Climate Research, Jinan University, Guangzhou, 511443, China
Guangdong–Hong Kong–Macau Joint Laboratory of Collaborative Innovation for Environmental Quality, Guangzhou, 511443, China
Mingfu Cai
Institute for Environmental and Climate Research, Jinan University, Guangzhou, 511443, China
Guangdong–Hong Kong–Macau Joint Laboratory of Collaborative Innovation for Environmental Quality, Guangzhou, 511443, China
Xuemei Wang
Institute for Environmental and Climate Research, Jinan University, Guangzhou, 511443, China
Guangdong–Hong Kong–Macau Joint Laboratory of Collaborative Innovation for Environmental Quality, Guangzhou, 511443, China
Min Shao
Institute for Environmental and Climate Research, Jinan University, Guangzhou, 511443, China
Guangdong–Hong Kong–Macau Joint Laboratory of Collaborative Innovation for Environmental Quality, Guangzhou, 511443, China
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Cited
19 citations as recorded by crossref.
- Enhanced oxidation capacity driven by pollution-induced chlorine chemistry in the coastal atmosphere G. Chen et al.
- HOCl Formation Driven by Photochemical Processes Enhanced Atmospheric Oxidation Capacity in a Coastal Atmosphere G. Chen et al.
- The primary sources of RO radicals in atmosphere: Oxidative capacity and self-purifying effect G. Chen et al.
- Chloride Loss in Fine Aerosols over the Atmosphere of Pearl River Estuary Y. Gao et al.
- Unclassical Radical Generation Mechanisms in the Troposphere: A Review X. Yang et al.
- Driving factors and photochemical impacts of Cl2 in coastal atmosphere of Southeast China G. Chen et al.
- Direct measurement of N2O5 heterogeneous uptake coefficients on atmospheric aerosols in southwestern China and evaluation of current parameterizations J. Li et al.
- Measurement report: High contribution of N2O5 uptake to particulate nitrate formation in NO2-limited urban areas Z. Lin et al.
- Nocturnal N2O5 and NO3 chemistry and its impact on wintertime HNO3 in Seoul during ASIA-AQ campaign J. Kim et al.
- Carbonyl Compound Reduction Mitigates Ozone Pollution: Lessons from Pollution Control during the 19th Asian Games in Hangzhou, China G. Guo et al.
- Significant contributions of sea spray aerosol to vertical ClNO2 formation over coastal South China Y. Zhu et al.
- Anthropogenic Oxygenated Volatile Organic Compounds Dominate Atmospheric Oxidation Capacity and Ozone Production via Secondary Formation of Formaldehyde in the Urban Atmosphere H. Qian et al.
- Measurement report: Atmospheric nitrate radical chemistry in the South China Sea influenced by the urban outflow of the Pearl River Delta J. Wang et al.
- Formation drivers and photochemical effects of ClNO2 in a coastal city of Southeast China G. Chen et al.
- The determination of ClNO2 via thermal dissociation–tunable infrared laser direct absorption spectroscopy J. Halfacre et al.
- Increasing Contribution of Chlorine Chemistry to Wintertime Ozone Formation Promoted by Enhanced Nitrogen Chemistry G. Chen et al.
- A systematic review of reactive nitrogen simulations with chemical transport models in China H. Zhang et al.
- Prolonged daytime presence and oxidative impact of nitryl chloride, ClNO2, in winter urban environment W. Nam et al.
- Vertical Gradient of Nitryl Chloride and Implications for Atmospheric Photochemistry in Pearl River Delta, China, during Wintertime H. Wang et al.
19 citations as recorded by crossref.
- Enhanced oxidation capacity driven by pollution-induced chlorine chemistry in the coastal atmosphere G. Chen et al.
- HOCl Formation Driven by Photochemical Processes Enhanced Atmospheric Oxidation Capacity in a Coastal Atmosphere G. Chen et al.
- The primary sources of RO radicals in atmosphere: Oxidative capacity and self-purifying effect G. Chen et al.
- Chloride Loss in Fine Aerosols over the Atmosphere of Pearl River Estuary Y. Gao et al.
- Unclassical Radical Generation Mechanisms in the Troposphere: A Review X. Yang et al.
- Driving factors and photochemical impacts of Cl2 in coastal atmosphere of Southeast China G. Chen et al.
- Direct measurement of N2O5 heterogeneous uptake coefficients on atmospheric aerosols in southwestern China and evaluation of current parameterizations J. Li et al.
- Measurement report: High contribution of N2O5 uptake to particulate nitrate formation in NO2-limited urban areas Z. Lin et al.
- Nocturnal N2O5 and NO3 chemistry and its impact on wintertime HNO3 in Seoul during ASIA-AQ campaign J. Kim et al.
- Carbonyl Compound Reduction Mitigates Ozone Pollution: Lessons from Pollution Control during the 19th Asian Games in Hangzhou, China G. Guo et al.
- Significant contributions of sea spray aerosol to vertical ClNO2 formation over coastal South China Y. Zhu et al.
- Anthropogenic Oxygenated Volatile Organic Compounds Dominate Atmospheric Oxidation Capacity and Ozone Production via Secondary Formation of Formaldehyde in the Urban Atmosphere H. Qian et al.
- Measurement report: Atmospheric nitrate radical chemistry in the South China Sea influenced by the urban outflow of the Pearl River Delta J. Wang et al.
- Formation drivers and photochemical effects of ClNO2 in a coastal city of Southeast China G. Chen et al.
- The determination of ClNO2 via thermal dissociation–tunable infrared laser direct absorption spectroscopy J. Halfacre et al.
- Increasing Contribution of Chlorine Chemistry to Wintertime Ozone Formation Promoted by Enhanced Nitrogen Chemistry G. Chen et al.
- A systematic review of reactive nitrogen simulations with chemical transport models in China H. Zhang et al.
- Prolonged daytime presence and oxidative impact of nitryl chloride, ClNO2, in winter urban environment W. Nam et al.
- Vertical Gradient of Nitryl Chloride and Implications for Atmospheric Photochemistry in Pearl River Delta, China, during Wintertime H. Wang et al.
Saved (final revised paper)
Latest update: 04 May 2026
Short summary
We present intensive field measurement of ClNO2 in the Pearl River Delta in 2019. Large variation in the level, formation, and atmospheric impacts of ClNO2 was found in different air masses. ClNO2 formation was limited by the particulate chloride (Cl−) and aerosol surface area. Our results reveal that Cl− originated from various anthropogenic emissions rather than sea sources and show minor contribution to the O3 pollution and photochemistry.
We present intensive field measurement of ClNO2 in the Pearl River Delta in 2019. Large...
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