Articles | Volume 22, issue 22
https://doi.org/10.5194/acp-22-14783-2022
© Author(s) 2022. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-22-14783-2022
© Author(s) 2022. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
21 Nov 2022
Research article |
| 21 Nov 2022
| 21 Nov 2022
Evaluation of isoprene nitrate chemistry in detailed chemical mechanisms
Alfred W. Mayhew
Wolfson Atmospheric Chemistry Laboratories, Department of Chemistry, University of York, Heslington, York, UK
Ben H. Lee
Department of Atmospheric Sciences, University of Washington, Seattle, Washington 98195, USA
Joel A. Thornton
Department of Atmospheric Sciences, University of Washington, Seattle, Washington 98195, USA
Thomas J. Bannan
School of Earth and Environmental Sciences, University of Manchester, Manchester, UK
James Brean
School of Geography, Earth and Environmental Sciences, University of Birmingham, Birmingham, UK
James R. Hopkins
Wolfson Atmospheric Chemistry Laboratories, Department of Chemistry, University of York, Heslington, York, UK
National Centre for Atmospheric Science, University of York, York, UK
James D. Lee
Wolfson Atmospheric Chemistry Laboratories, Department of Chemistry, University of York, Heslington, York, UK
National Centre for Atmospheric Science, University of York, York, UK
Beth S. Nelson
Wolfson Atmospheric Chemistry Laboratories, Department of Chemistry, University of York, Heslington, York, UK
Carl Percival
School of Earth and Environmental Sciences, University of Manchester, Manchester, UK
Andrew R. Rickard
Wolfson Atmospheric Chemistry Laboratories, Department of Chemistry, University of York, Heslington, York, UK
National Centre for Atmospheric Science, University of York, York, UK
Marvin D. Shaw
Wolfson Atmospheric Chemistry Laboratories, Department of Chemistry, University of York, Heslington, York, UK
National Centre for Atmospheric Science, University of York, York, UK
Peter M. Edwards
Wolfson Atmospheric Chemistry Laboratories, Department of Chemistry, University of York, Heslington, York, UK
Jaqueline F. Hamilton
CORRESPONDING AUTHOR
Wolfson Atmospheric Chemistry Laboratories, Department of Chemistry, University of York, Heslington, York, UK
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Cited
9 citations as recorded by crossref.
- Characterization and Seasonal Variation of PM2.5 Composition in Xi’an, Northwest China: Oxygenated and Nitrogenous Organic Aerosol Y. Shang et al. 10.1021/acsearthspacechem.4c00042
- Comparison of isoprene chemical mechanisms under atmospheric night-time conditions in chamber experiments: evidence of hydroperoxy aldehydes and epoxy products from NO3 oxidation P. Carlsson et al. 10.5194/acp-23-3147-2023
- Online Calibration of a Chemical Ionization Mass Spectrometer for Multifunctional Biogenic Organic Nitrates M. Robinson et al. 10.1021/acsestair.4c00056
- The important contribution of secondary formation and biomass burning to oxidized organic nitrogen (OON) in a polluted urban area: insights from in situ measurements of a chemical ionization mass spectrometer (CIMS) Y. Cai et al. 10.5194/acp-23-8855-2023
- Kinetics for the Reactions of Ar+, O2+, and NO+ with Isoprene (2-Methyl-1,3-butadiene) as a Function of Temperature (300–500 K) T. Lewis et al. 10.1021/acs.jpca.3c03914
- Measuring Biogenic Volatile Organic Compounds from Leaves Exposed to Submicron Black Carbon Using Portable Sensor Q. Liu & Y. Liu 10.3390/pollutants4020012
- Source apportionment of gaseous Nitrophenols and their contribution to HONO formation in an urban area M. Ahmed et al. 10.1016/j.chemosphere.2023.139499
- Daytime isoprene nitrates under changing NOx and O3 A. Mayhew et al. 10.5194/acp-23-8473-2023
- OH, HO2, and RO2 radical chemistry in a rural forest environment: measurements, model comparisons, and evidence of a missing radical sink B. Bottorff et al. 10.5194/acp-23-10287-2023
9 citations as recorded by crossref.
- Characterization and Seasonal Variation of PM2.5 Composition in Xi’an, Northwest China: Oxygenated and Nitrogenous Organic Aerosol Y. Shang et al. 10.1021/acsearthspacechem.4c00042
- Comparison of isoprene chemical mechanisms under atmospheric night-time conditions in chamber experiments: evidence of hydroperoxy aldehydes and epoxy products from NO3 oxidation P. Carlsson et al. 10.5194/acp-23-3147-2023
- Online Calibration of a Chemical Ionization Mass Spectrometer for Multifunctional Biogenic Organic Nitrates M. Robinson et al. 10.1021/acsestair.4c00056
- The important contribution of secondary formation and biomass burning to oxidized organic nitrogen (OON) in a polluted urban area: insights from in situ measurements of a chemical ionization mass spectrometer (CIMS) Y. Cai et al. 10.5194/acp-23-8855-2023
- Kinetics for the Reactions of Ar+, O2+, and NO+ with Isoprene (2-Methyl-1,3-butadiene) as a Function of Temperature (300–500 K) T. Lewis et al. 10.1021/acs.jpca.3c03914
- Measuring Biogenic Volatile Organic Compounds from Leaves Exposed to Submicron Black Carbon Using Portable Sensor Q. Liu & Y. Liu 10.3390/pollutants4020012
- Source apportionment of gaseous Nitrophenols and their contribution to HONO formation in an urban area M. Ahmed et al. 10.1016/j.chemosphere.2023.139499
- Daytime isoprene nitrates under changing NOx and O3 A. Mayhew et al. 10.5194/acp-23-8473-2023
- OH, HO2, and RO2 radical chemistry in a rural forest environment: measurements, model comparisons, and evidence of a missing radical sink B. Bottorff et al. 10.5194/acp-23-10287-2023
Latest update: 21 Feb 2025
Short summary
Isoprene nitrates are chemical species commonly found in the atmosphere that are important for their impacts on air quality and climate. This paper compares 3 different representations of the chemistry of isoprene nitrates in computational models highlighting cases where the choice of chemistry included has significant impacts on the concentration and composition of the modelled nitrates. Calibration of mass spectrometers is also shown to be an important factor when analysing isoprene nitrates.
Isoprene nitrates are chemical species commonly found in the atmosphere that are important for...
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