Atmospheric Chemistry and Physics
Atmospheric Chemistry and Physics
ACP
Articles | Volume 22, issue 2
Articles | Volume 22, issue 2
https://doi.org/10.5194/acp-22-1467-2022
© Author(s) 2022. This work is distributed under
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-22-1467-2022
© Author(s) 2022. This work is distributed under
the Creative Commons Attribution 4.0 License.
Articles | Volume 22, issue 2
Research article
 | 
31 Jan 2022
Research article |  | 31 Jan 2022

Secondary organic aerosol and organic nitrogen yields from the nitrate radical (NO3) oxidation of alpha-pinene from various RO2 fates

Kelvin H. Bates, Guy J. P. Burke, James D. Cope, and Tran B. Nguyen

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Ayres, B. R., Allen, H. M., Draper, D. C., Brown, S. S., Wild, R. J., Jimenez, J. L., Day, D. A., Campuzano-Jost, P., Hu, W., de Gouw, J., Koss, A., Cohen, R. C., Duffey, K. C., Romer, P., Baumann, K., Edgerton, E., Takahama, S., Thornton, J. A., Lee, B. H., Lopez-Hilfiker, F. D., Mohr, C., Wennberg, P. O., Nguyen, T. B., Teng, A., Goldstein, A. H., Olson, K., and Fry, J. L.: Organic nitrate aerosol formation via NO3 + biogenic volatile organic compounds in the southeastern United States, Atmos. Chem. Phys., 15, 13377–13392, https://doi.org/10.5194/acp-15-13377-2015, 2015. 
Bates, K. H.: Experiment Set: a-pinene nighttime chemistry, ICARUS [data set], available at: https://icarus.ucdavis.edu/experimentset/214 (last accessed: 24 January 2022), 2021. 
Bell, D. M., Wu, C., Bertrand, A., Graham, E., Schoonbaert, J., Giannoukos, S., Baltensperger, U., Prevot, A. S. H., Riipinen, I., El Haddad, I., and Mohr, C.: Particle-phase processing of α-pinene NO3 secondary organic aerosol in the dark, Atmos. Chem. Phys. Discuss. [preprint], https://doi.org/10.5194/acp-2021-379, in review, 2021. 
Berndt, T., Scholz, W., Mentler, B., Fischer, L., Herrmann, H., Kulmala, M., and Hansel, A.: Accretion product formation from self- and cross-reactions of RO2 radicals in the atmosphere, Angew. Chem. Int. Ed., 57, 3820–3824, https://doi.org/10.1002/anie.201710989, 2018a. 
Berndt, T., Mentler, B., Scholz, W., Fischer, L., Herrmann, H., Kulmala, M., and Hansel, A.: Accretion Product Formation from Ozonolysis and OH Radical Reaction of α-Pinene: Mechanistic Insight and the Influence of Isoprene and Ethylene, Environ. Sci. Technol., 52, 11069–11077, https://doi.org/10.1021/acs.est.8b02210, 2018b. 
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The main nighttime sink of α-pinene, a hydrocarbon abundantly emitted by plants, is reaction with NO3 to form nitrooxy peroxy radicals (nRO2). Using uniquely designed chamber experiments, we show that this reaction is a major source of organic aerosol when nRO2 reacts with other nRO2 and forms a nitrooxy hydroperoxide when nRO2 reacts with HO2. Under ambient conditions these pathways are key loss processes of atmospheric reactive nitrogen in areas with mixed biogenic and anthropogenic influence.
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