Articles | Volume 22, issue 19
https://doi.org/10.5194/acp-22-13219-2022
© Author(s) 2022. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-22-13219-2022
© Author(s) 2022. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
14 Oct 2022
Research article |
| 14 Oct 2022
| 14 Oct 2022
A single-parameter hygroscopicity model for functionalized insoluble aerosol surfaces
Chun-Ning Mao
Department of Chemical and Biomolecular Engineering, University of
Maryland, College Park, MD 20742, USA
Kanishk Gohil
Department of Chemical and Biomolecular Engineering, University of
Maryland, College Park, MD 20742, USA
Department of Chemical and Biomolecular Engineering, University of
Maryland, College Park, MD 20742, USA
Department of Chemistry and Biochemistry, University of Maryland,
College Park, MD 20742, USA
Related authors
Kanishk Gohil, Chun-Ning Mao, Dewansh Rastogi, Chao Peng, Mingjin Tang, and Akua Asa-Awuku
Atmos. Chem. Phys., 22, 12769–12787, https://doi.org/10.5194/acp-22-12769-2022, https://doi.org/10.5194/acp-22-12769-2022, 2022
Short summary
Short summary
The Hybrid Activity Model (HAM) is a promising new droplet growth model that can be potentially used for the analysis of any type of atmospheric compound. HAM may potentially improve the representation of hygroscopicity of organic aerosols in large-scale global climate models (GCMs), hence reducing the uncertainties in the climate forcing due to the aerosol indirect effect.
Nahin Ferdousi-Rokib, Stephanie Jacoby, N. Cazimir Armstrong, Alana Dodero, Martin Changman Ahn, Ergine Zephira Remy, Zhenfa Zhang, Avram Gold, Joseph L. Woo, Yue Zhang, Jason D. Surratt, and Akua A. Asa-Awuku
EGUsphere, https://doi.org/10.5194/egusphere-2025-1935, https://doi.org/10.5194/egusphere-2025-1935, 2025
Short summary
Short summary
This study looks at how natural compounds when mixed with salts in the air affect how clouds form. These compounds come from plants and are found all over the world. They are sticky, and this changes how water droplets and clouds form. Sometimes the compound spreads more easily when mixed with salt, while the other compound does not change. Depending on the condition, these mixtures can behave differently, which affects how we predict cloud formation.
Jie Zhang, Tianyu Zhu, Alexandra Catena, Yaowei Li, Margaret J. Schwab, Pengfei Liu, Akua Asa-Awuku, and James Schwab
Atmos. Chem. Phys., 24, 13445–13456, https://doi.org/10.5194/acp-24-13445-2024, https://doi.org/10.5194/acp-24-13445-2024, 2024
Short summary
Short summary
This study shows the derived organic aerosol hygroscopicity under high-humidity conditions based on a simple optical scatter monitor system, including two nephelometric monitors (pDR-1500), when the aerosol chemical composition is already known.
Kanishk Gohil, Chun-Ning Mao, Dewansh Rastogi, Chao Peng, Mingjin Tang, and Akua Asa-Awuku
Atmos. Chem. Phys., 22, 12769–12787, https://doi.org/10.5194/acp-22-12769-2022, https://doi.org/10.5194/acp-22-12769-2022, 2022
Short summary
Short summary
The Hybrid Activity Model (HAM) is a promising new droplet growth model that can be potentially used for the analysis of any type of atmospheric compound. HAM may potentially improve the representation of hygroscopicity of organic aerosols in large-scale global climate models (GCMs), hence reducing the uncertainties in the climate forcing due to the aerosol indirect effect.
Kanishk Gohil and Akua A. Asa-Awuku
Atmos. Meas. Tech., 15, 1007–1019, https://doi.org/10.5194/amt-15-1007-2022, https://doi.org/10.5194/amt-15-1007-2022, 2022
Short summary
Short summary
This work develops a methodology and software to study and analyze the cloud-droplet-forming ability of aerosols with an aerodynamic aerosol classifier (AAC). This work quantifies the uncertainties in size-resolved measurements and subsequent uncertainties propagated to cloud droplet parameterizations. Lastly, we present the best practices for AAC cloud droplet measurement.
Chao Peng, Patricia N. Razafindrambinina, Kotiba A. Malek, Lanxiadi Chen, Weigang Wang, Ru-Jin Huang, Yuqing Zhang, Xiang Ding, Maofa Ge, Xinming Wang, Akua A. Asa-Awuku, and Mingjin Tang
Atmos. Chem. Phys., 21, 7135–7148, https://doi.org/10.5194/acp-21-7135-2021, https://doi.org/10.5194/acp-21-7135-2021, 2021
Short summary
Short summary
Organosulfates are important constituents in tropospheric aerosol particles, but their hygroscopic properties and cloud condensation nuclei activities are not well understood. In our work, three complementary techniques were employed to investigate the interactions of 11 organosulfates with water vapor under sub- and supersaturated conditions.
Diep Vu, Shaokai Gao, Tyler Berte, Mary Kacarab, Qi Yao, Kambiz Vafai, and Akua Asa-Awuku
Atmos. Meas. Tech., 12, 4277–4289, https://doi.org/10.5194/amt-12-4277-2019, https://doi.org/10.5194/amt-12-4277-2019, 2019
Short summary
Short summary
Aerosol–cloud interactions contribute the greatest uncertainty to cloud formation. Aerosol composition is complex and can change quickly in the atmosphere. In this work, we recreate a transition in aerosol mixing state in the laboratory, which (to date) has only been observed in the ambient state. We then report the subsequent changes on cloud condensation nuclei (CCN) activation.
M. Giordano, C. Espinoza, and A. Asa-Awuku
Atmos. Chem. Phys., 15, 1807–1821, https://doi.org/10.5194/acp-15-1807-2015, https://doi.org/10.5194/acp-15-1807-2015, 2015
Related subject area
Subject: Clouds and Precipitation | Research Activity: Laboratory Studies | Altitude Range: Troposphere | Science Focus: Physics (physical properties and processes)
Ice-nucleating properties of glassy organic and organosulfate aerosol
Retention During Freezing of Raindrops, Part I: Investigation of Single and Binary Mixtures
Measurement Report: Influence of particle density on secondary ice production by graupel and ice pellet collisions
Stable and unstable fall motions of plate-like ice crystal analogues
Secondary ice production – no evidence of efficient rime-splintering mechanism
Fragmentation of ice particles: laboratory experiments on graupel–graupel and graupel–snowflake collisions
Molecular simulations reveal that heterogeneous ice nucleation occurs at higher temperatures in water under capillary tension
Measurement of the collision rate coefficients between atmospheric ions and multiply charged aerosol particles in the CERN CLOUD chamber
Re-evaluating cloud chamber constraints on depositional ice growth in cirrus clouds – Part 1: Model description and sensitivity tests
Ice nucleation by smectites: the role of the edges
Mexican agricultural soil dust as a source of ice nucleating particles
The impact of (bio-)organic substances on the ice nucleation activity of the K-feldspar microcline in aqueous solutions
Secondary ice production during the break-up of freezing water drops on impact with ice particles
High homogeneous freezing onsets of sulfuric acid aerosol at cirrus temperatures
Laboratory and field studies of ice-nucleating particles from open-lot livestock facilities in Texas
Comment on “Review of experimental studies of secondary ice production” by Korolev and Leisner (2020)
Effect of chemically induced fracturing on the ice nucleation activity of alkali feldspar
Ice nucleation ability of ammonium sulfate aerosol particles internally mixed with secondary organics
Ice-nucleating particles in precipitation samples from the Texas Panhandle
Comparative study on immersion freezing utilizing single-droplet levitation methods
Exploratory experiments on pre-activated freezing nucleation on mercuric iodide
Application of holography and automated image processing for laboratory experiments on mass and fall speed of small cloud ice crystals
Review of experimental studies of secondary ice production
The role of contact angle and pore width on pore condensation and freezing
Technical note: Equilibrium droplet size distributions in a turbulent cloud chamber with uniform supersaturation
Protein aggregates nucleate ice: the example of apoferritin
No anomalous supersaturation in ultracold cirrus laboratory experiments
Lateral facet growth of ice and snow – Part 1: Observations and applications to secondary habits
The ice-nucleating ability of quartz immersed in water and its atmospheric importance compared to K-feldspar
Ice nucleation properties of K-feldspar polymorphs and plagioclase feldspars
Enhanced ice nucleation activity of coal fly ash aerosol particles initiated by ice-filled pores
A comprehensive characterization of ice nucleation by three different types of cellulose particles immersed in water
Activation of intact bacteria and bacterial fragments mixed with agar as cloud droplets and ice crystals in cloud chamber experiments
Anomalous holiday precipitation over southern China
Coal fly ash: linking immersion freezing behavior and physicochemical particle properties
Surface roughness during depositional growth and sublimation of ice crystals
Ice nucleation abilities of soot particles determined with the Horizontal Ice Nucleation Chamber
The efficiency of secondary organic aerosol particles acting as ice-nucleating particles under mixed-phase cloud conditions
Uncertainty in counting ice nucleating particles with continuous flow diffusion chambers
Experimental evidence of the rear capture of aerosol particles by raindrops
Refreeze experiments with water droplets containing different types of ice nuclei interpreted by classical nucleation theory
Pre-activation of aerosol particles by ice preserved in pores
Heterogeneous ice nucleation on dust particles sourced from nine deserts worldwide – Part 1: Immersion freezing
A comparative study of K-rich and Na/Ca-rich feldspar ice-nucleating particles in a nanoliter droplet freezing assay
Ice nucleation efficiency of AgI: review and new insights
The adsorption of fungal ice-nucleating proteins on mineral dusts: a terrestrial reservoir of atmospheric ice-nucleating particles
Exploring an approximation for the homogeneous freezing temperature of water droplets
Cloud chamber experiments on the origin of ice crystal complexity in cirrus clouds
Phase transition observations and discrimination of small cloud particles by light polarization in expansion chamber experiments
Analysis of isothermal and cooling-rate-dependent immersion freezing by a unifying stochastic ice nucleation model
Christopher N. Rapp, Sining Niu, N. Cazimir Armstrong, Xiaoli Shen, Thomas Berkemeier, Jason D. Surratt, Yue Zhang, and Daniel J. Cziczo
Atmos. Chem. Phys., 25, 5519–5536, https://doi.org/10.5194/acp-25-5519-2025, https://doi.org/10.5194/acp-25-5519-2025, 2025
Short summary
Short summary
Atmospheric ice formation is initiated by particulate matter suspended in air and has profound impacts on Earth's climate. This study focuses on examining the effectiveness of ice formation by a subset of particles composed of organic matter and sulfate. We used experiments and computer modeling to obtain the result that these particles are not effective ice-nucleating particles, suggesting that molecular structure is important for ice formation on these types of particles.
Martanda Gautam, Alexander Theis, Jackson Seymore, Moritz Hey, Stephan Borrmann, Karoline Diehl, Subir K. Mitra, and Miklós Szakáll
EGUsphere, https://doi.org/10.5194/egusphere-2024-3917, https://doi.org/10.5194/egusphere-2024-3917, 2024
Short summary
Short summary
We investigated the retention of chemical species and their binary mixtures during freezing of raindrops via acoustic levitation. Our results reveal high retention-nearly all substances being fully retained during freezing. This could be attributed to faster freezing time compared to slower mass expulsion time, along with ice-shell formation during freezing. This result helps improve our understanding of interaction between ice microphysical processes and chemistry in deep convective clouds.
Sudha Yadav, Lilly Metten, Pierre Grzegorczyk, Alexander Theis, Subir Kumar Mitra, and Miklós Szakáll
EGUsphere, https://doi.org/10.5194/egusphere-2024-3222, https://doi.org/10.5194/egusphere-2024-3222, 2024
Short summary
Short summary
We conducted laboratory studies on the fragmentation of ice particles by collision. Graupels were created by riming at -7 and -15 °C simulating also rotation and tumbling. Ice pellets were generated by freezing water in 3D-printed spherical molds. The number of fragments generated by collision was between 1 and 20, and strongly dependent on the density of the graupel. We also showed that the number of fragments becomes zero when the particle suffers more than three collisions in a row.
Jennifer R. Stout, Christopher D. Westbrook, Thorwald H. M. Stein, and Mark W. McCorquodale
Atmos. Chem. Phys., 24, 11133–11155, https://doi.org/10.5194/acp-24-11133-2024, https://doi.org/10.5194/acp-24-11133-2024, 2024
Short summary
Short summary
This study uses 3D-printed ice crystal analogues falling in a water–glycerine mix and observed with multi-view cameras, simulating atmospheric conditions. Four types of motion are observed: stable, zigzag, transitional, and spiralling. Particle shape strongly influences motion; complex shapes have a wider range of conditions where they fall steadily compared to simple plates. The most common orientation of unstable particles is non-horizontal, contrary to prior assumptions of always horizontal.
Johanna S. Seidel, Alexei A. Kiselev, Alice Keinert, Frank Stratmann, Thomas Leisner, and Susan Hartmann
Atmos. Chem. Phys., 24, 5247–5263, https://doi.org/10.5194/acp-24-5247-2024, https://doi.org/10.5194/acp-24-5247-2024, 2024
Short summary
Short summary
Clouds often contain several thousand times more ice crystals than aerosol particles catalyzing ice formation. This phenomenon, commonly known as ice multiplication, is often explained by secondary ice formation due to the collisions between falling ice particles and droplets. In this study, we mimic this riming process. Contrary to earlier experiments, we found no efficient ice multiplication, which fundamentally questions the importance of the rime-splintering mechanism.
Pierre Grzegorczyk, Sudha Yadav, Florian Zanger, Alexander Theis, Subir K. Mitra, Stephan Borrmann, and Miklós Szakáll
Atmos. Chem. Phys., 23, 13505–13521, https://doi.org/10.5194/acp-23-13505-2023, https://doi.org/10.5194/acp-23-13505-2023, 2023
Short summary
Short summary
Secondary ice production generates high concentrations of ice crystals in clouds. These processes have been poorly understood. We conducted experiments at the wind tunnel laboratory of the Johannes Gutenberg University, Mainz, on graupel–graupel and graupel–snowflake collisions. From these experiments fragment number, size, cross-sectional area, and aspect ratio were determined.
Elise Rosky, Will Cantrell, Tianshu Li, Issei Nakamura, and Raymond A. Shaw
Atmos. Chem. Phys., 23, 10625–10642, https://doi.org/10.5194/acp-23-10625-2023, https://doi.org/10.5194/acp-23-10625-2023, 2023
Short summary
Short summary
Using computer simulations of water, we find that water under tension freezes more easily than under normal conditions. A linear equation describes how freezing temperature increases with tension. Accordingly, simulations show that naturally occurring tension in water capillary bridges leads to higher freezing temperatures. This work is an early step in determining if atmospheric cloud droplets freeze due to naturally occurring tension, for example, during processes such as droplet collisions.
Joschka Pfeifer, Naser G. A. Mahfouz, Benjamin C. Schulze, Serge Mathot, Dominik Stolzenburg, Rima Baalbaki, Zoé Brasseur, Lucia Caudillo, Lubna Dada, Manuel Granzin, Xu-Cheng He, Houssni Lamkaddam, Brandon Lopez, Vladimir Makhmutov, Ruby Marten, Bernhard Mentler, Tatjana Müller, Antti Onnela, Maxim Philippov, Ana A. Piedehierro, Birte Rörup, Meredith Schervish, Ping Tian, Nsikanabasi S. Umo, Dongyu S. Wang, Mingyi Wang, Stefan K. Weber, André Welti, Yusheng Wu, Marcel Zauner-Wieczorek, Antonio Amorim, Imad El Haddad, Markku Kulmala, Katrianne Lehtipalo, Tuukka Petäjä, António Tomé, Sander Mirme, Hanna E. Manninen, Neil M. Donahue, Richard C. Flagan, Andreas Kürten, Joachim Curtius, and Jasper Kirkby
Atmos. Chem. Phys., 23, 6703–6718, https://doi.org/10.5194/acp-23-6703-2023, https://doi.org/10.5194/acp-23-6703-2023, 2023
Short summary
Short summary
Attachment rate coefficients between ions and charged aerosol particles determine their lifetimes and may also influence cloud dynamics and aerosol processing. Here we present novel experiments that measure ion–aerosol attachment rate coefficients for multiply charged aerosol particles under atmospheric conditions in the CERN CLOUD chamber. Our results provide experimental discrimination between various theoretical models.
Kara D. Lamb, Jerry Y. Harrington, Benjamin W. Clouser, Elisabeth J. Moyer, Laszlo Sarkozy, Volker Ebert, Ottmar Möhler, and Harald Saathoff
Atmos. Chem. Phys., 23, 6043–6064, https://doi.org/10.5194/acp-23-6043-2023, https://doi.org/10.5194/acp-23-6043-2023, 2023
Short summary
Short summary
This study investigates how ice grows directly from vapor in cirrus clouds by comparing observations of populations of ice crystals growing in a cloud chamber against models developed in the context of single-crystal laboratory studies. We demonstrate that previous discrepancies between different experimental measurements do not necessarily point to different physical interpretations but are rather due to assumptions that were made in terms of how experiments were modeled in previous studies.
Anand Kumar, Kristian Klumpp, Chen Barak, Giora Rytwo, Michael Plötze, Thomas Peter, and Claudia Marcolli
Atmos. Chem. Phys., 23, 4881–4902, https://doi.org/10.5194/acp-23-4881-2023, https://doi.org/10.5194/acp-23-4881-2023, 2023
Short summary
Short summary
Smectites are a major class of clay minerals that are ice nucleation (IN) active. They form platelets that swell or even delaminate in water by intercalation of water between their layers. We hypothesize that at least three smectite layers need to be stacked together to host a critical ice embryo on clay mineral edges and that the larger the surface edge area is, the higher the freezing temperature. Edge sites on such clay particles play a crucial role in imparting IN ability to such particles.
Diana L. Pereira, Irma Gavilán, Consuelo Letechipía, Graciela B. Raga, Teresa Pi Puig, Violeta Mugica-Álvarez, Harry Alvarez-Ospina, Irma Rosas, Leticia Martinez, Eva Salinas, Erika T. Quintana, Daniel Rosas, and Luis A. Ladino
Atmos. Chem. Phys., 22, 6435–6447, https://doi.org/10.5194/acp-22-6435-2022, https://doi.org/10.5194/acp-22-6435-2022, 2022
Short summary
Short summary
Airborne particles were i) collected in an agricultural fields and ii) generated in the laboratory from agricultural soil samples to analyze their ice nucleating abilities. It was found that the size and chemical composition of the Mexican agricultural dust particles influence their ice nucleating behavior, where the organic components are likely responsible for their efficiency as INPs. The INP concentrations from the present study are comparable to those from higher latitudes.
Kristian Klumpp, Claudia Marcolli, and Thomas Peter
Atmos. Chem. Phys., 22, 3655–3673, https://doi.org/10.5194/acp-22-3655-2022, https://doi.org/10.5194/acp-22-3655-2022, 2022
Short summary
Short summary
Surface interactions with solutes can significantly alter the ice nucleation activity of mineral dust. Past studies revealed the sensitivity of microcline, one of the most ice-active types of dust in the atmosphere, to inorganic solutes. This study focuses on the interaction of microcline with bio-organic substances and the resulting effects on its ice nucleation activity. We observe strongly hampered ice nucleation activity due to the presence of carboxylic and amino acids but not for polyols.
Rachel L. James, Vaughan T. J. Phillips, and Paul J. Connolly
Atmos. Chem. Phys., 21, 18519–18530, https://doi.org/10.5194/acp-21-18519-2021, https://doi.org/10.5194/acp-21-18519-2021, 2021
Short summary
Short summary
Secondary ice production (SIP) plays an important role in ice formation within mixed-phase clouds. We present a laboratory investigation of a potentially new SIP mechanism involving the collisions of supercooled water drops with ice particles. At impact, the supercooled water drop fragments form smaller secondary drops. Approximately 30 % of the secondary drops formed during the retraction phase of the supercooled water drop impact freeze over a temperature range of −4 °C to −12 °C.
Julia Schneider, Kristina Höhler, Robert Wagner, Harald Saathoff, Martin Schnaiter, Tobias Schorr, Isabelle Steinke, Stefan Benz, Manuel Baumgartner, Christian Rolf, Martina Krämer, Thomas Leisner, and Ottmar Möhler
Atmos. Chem. Phys., 21, 14403–14425, https://doi.org/10.5194/acp-21-14403-2021, https://doi.org/10.5194/acp-21-14403-2021, 2021
Short summary
Short summary
Homogeneous freezing is a relevant mechanism for the formation of cirrus clouds in the upper troposphere. Based on an extensive set of homogeneous freezing experiments at the AIDA chamber with aqueous sulfuric acid aerosol, we provide a new fit line for homogeneous freezing onset conditions of sulfuric acid aerosol focusing on cirrus temperatures. In the atmosphere, homogeneous freezing thresholds have important implications on the cirrus cloud occurrence and related cloud radiative effects.
Naruki Hiranuma, Brent W. Auvermann, Franco Belosi, Jack Bush, Kimberly M. Cory, Dimitrios G. Georgakopoulos, Kristina Höhler, Yidi Hou, Larissa Lacher, Harald Saathoff, Gianni Santachiara, Xiaoli Shen, Isabelle Steinke, Romy Ullrich, Nsikanabasi S. Umo, Hemanth S. K. Vepuri, Franziska Vogel, and Ottmar Möhler
Atmos. Chem. Phys., 21, 14215–14234, https://doi.org/10.5194/acp-21-14215-2021, https://doi.org/10.5194/acp-21-14215-2021, 2021
Short summary
Short summary
We present laboratory and field studies showing that an open-lot livestock facility is a substantial source of atmospheric ice-nucleating particles (INPs). The ambient concentration of INPs from livestock facilities in Texas is very high. It is up to several thousand INPs per liter below –20 °C and may impact regional aerosol–cloud interactions. About 50% of feedlot INPs were supermicron in diameter. No notable amount of known ice-nucleating microorganisms was found in our feedlot samples.
Vaughan T. J. Phillips, Jun-Ichi Yano, Akash Deshmukh, and Deepak Waman
Atmos. Chem. Phys., 21, 11941–11953, https://doi.org/10.5194/acp-21-11941-2021, https://doi.org/10.5194/acp-21-11941-2021, 2021
Short summary
Short summary
For decades, high concentrations of ice observed in precipitating mixed-phase clouds have created an enigma. Such concentrations are higher than can be explained by the action of aerosols or by the spontaneous freezing of most cloud droplets. The controversy has partly persisted due to the lack of laboratory experimentation in ice microphysics, especially regarding fragmentation of ice, a topic reviewed by a recent paper. Our comment attempts to clarify some issues with regards to that review.
Alexei A. Kiselev, Alice Keinert, Tilia Gaedeke, Thomas Leisner, Christoph Sutter, Elena Petrishcheva, and Rainer Abart
Atmos. Chem. Phys., 21, 11801–11814, https://doi.org/10.5194/acp-21-11801-2021, https://doi.org/10.5194/acp-21-11801-2021, 2021
Short summary
Short summary
Alkali feldspar is the most abundant mineral in the Earth's crust and is often present in mineral dust aerosols that are responsible for the formation of rain and snow in clouds. However, the cloud droplets containing pure potassium-rich feldspar would not freeze unless cooled down to a very low temperature. Here we show that partly replacing potassium with sodium would induce fracturing of feldspar, exposing a crystalline surface that could initiate freezing at higher temperature.
Barbara Bertozzi, Robert Wagner, Junwei Song, Kristina Höhler, Joschka Pfeifer, Harald Saathoff, Thomas Leisner, and Ottmar Möhler
Atmos. Chem. Phys., 21, 10779–10798, https://doi.org/10.5194/acp-21-10779-2021, https://doi.org/10.5194/acp-21-10779-2021, 2021
Short summary
Short summary
Internally mixed particles composed of sulfate and organics are among the most abundant aerosol types. Their ice nucleation (IN) ability influences the formation of cirrus and, thus, the climate. We show that the presence of a thin organic coating suppresses the heterogeneous IN ability of crystalline ammonium sulfate particles. However, the IN ability of the same particle can substantially change if subjected to atmospheric processing, mainly due to differences in the resulting morphology.
Hemanth S. K. Vepuri, Cheyanne A. Rodriguez, Dimitrios G. Georgakopoulos, Dustin Hume, James Webb, Gregory D. Mayer, and Naruki Hiranuma
Atmos. Chem. Phys., 21, 4503–4520, https://doi.org/10.5194/acp-21-4503-2021, https://doi.org/10.5194/acp-21-4503-2021, 2021
Short summary
Short summary
Due to a high frequency of storm events, West Texas is an ideal location to study ice-nucleating particles (INPs) in severe precipitation. Our results present that cumulative INP concentration in our precipitation samples below −20 °C could be high in the samples collected while observing > 10 mm h−1 precipitation with notably large hydrometeor sizes and an implication of cattle feedyard bacteria inclusion. Marine bacteria were found in a subset of our precipitation and cattle feedyard samples.
Miklós Szakáll, Michael Debertshäuser, Christian Philipp Lackner, Amelie Mayer, Oliver Eppers, Karoline Diehl, Alexander Theis, Subir Kumar Mitra, and Stephan Borrmann
Atmos. Chem. Phys., 21, 3289–3316, https://doi.org/10.5194/acp-21-3289-2021, https://doi.org/10.5194/acp-21-3289-2021, 2021
Short summary
Short summary
The freezing of cloud drops is promoted by ice-nucleating particles immersed in the drops. This process is essential to understand ice and subsequent precipitation formation in clouds. We investigated the efficiency of several particle types to trigger immersion freezing with two single-drop levitation techniques: a wind tunnel and an acoustic levitator. The evaluation accounted for different conditions during our two series of experiments, which is also applicable to future comparison studies.
Gabor Vali
Atmos. Chem. Phys., 21, 2551–2568, https://doi.org/10.5194/acp-21-2551-2021, https://doi.org/10.5194/acp-21-2551-2021, 2021
Short summary
Short summary
The freezing of water drops in clouds is a prime example for the role of ice-nucleating particles (INPs). Mercuric iodide particles and a few other substances can be conditioned to become very effective INPs after previous ice formation and moderate heating to melt temperatures, opening a new pathway to ice formation in the atmosphere and in other systems like tissue preservation, artificial snow making, and more.
Maximilian Weitzel, Subir K. Mitra, Miklós Szakáll, Jacob P. Fugal, and Stephan Borrmann
Atmos. Chem. Phys., 20, 14889–14901, https://doi.org/10.5194/acp-20-14889-2020, https://doi.org/10.5194/acp-20-14889-2020, 2020
Short summary
Short summary
The properties of ice crystals smaller than 150 µm in diameter were investigated in a cold-room laboratory using digital holography and microscopy. Automated image processing has been used to determine the track of falling ice crystals, and collected crystals were melted and scanned under a microscope to infer particle mass. A parameterization relating particle size and mass was determined which describes ice crystals in this size range more accurately than existing relationships.
Alexei Korolev and Thomas Leisner
Atmos. Chem. Phys., 20, 11767–11797, https://doi.org/10.5194/acp-20-11767-2020, https://doi.org/10.5194/acp-20-11767-2020, 2020
Short summary
Short summary
Secondary ice production (SIP) plays a key role in the formation of ice particles in tropospheric clouds. This work presents a critical review of the laboratory studies related to secondary ice production. It aims to identify gaps in our knowledge of SIP as well as to stimulate further laboratory studies focused on obtaining a quantitative description of efficiencies for each SIP mechanism.
Robert O. David, Jonas Fahrni, Claudia Marcolli, Fabian Mahrt, Dominik Brühwiler, and Zamin A. Kanji
Atmos. Chem. Phys., 20, 9419–9440, https://doi.org/10.5194/acp-20-9419-2020, https://doi.org/10.5194/acp-20-9419-2020, 2020
Short summary
Short summary
Ice crystal formation plays an important role in controlling the Earth's climate. However, the mechanisms responsible for ice formation in the atmosphere are still uncertain. Here we use surrogates for atmospherically relevant porous particles to determine the role of pore diameter and wettability on the ability of porous particles to nucleate ice in the atmosphere. Our results are consistent with the pore condensation and freeing mechanism.
Steven K. Krueger
Atmos. Chem. Phys., 20, 7895–7909, https://doi.org/10.5194/acp-20-7895-2020, https://doi.org/10.5194/acp-20-7895-2020, 2020
Short summary
Short summary
When CCN are injected into a turbulent cloud chamber at a constant rate, and the rate of droplet activation is balanced by the rate of droplet fallout, a steady-state droplet size distribution (DSD) can be achieved. Analytic DSDs and PDFs of droplet radius were derived for such conditions when there is uniform supersaturation. Given the chamber height, the analytic PDF is determined by the supersaturation alone. This could allow one to infer the supersaturation that produced a measured PDF.
María Cascajo-Castresana, Robert O. David, Maiara A. Iriarte-Alonso, Alexander M. Bittner, and Claudia Marcolli
Atmos. Chem. Phys., 20, 3291–3315, https://doi.org/10.5194/acp-20-3291-2020, https://doi.org/10.5194/acp-20-3291-2020, 2020
Short summary
Short summary
Atmospheric ice-nucleating particles are rare but relevant for cloud glaciation. A source of particles that nucleate ice above −15 °C is biological material including some proteins. Here we show that proteins of very diverse functions and structures can nucleate ice. Among these, the iron storage protein apoferritin stands out, with activity up to −4 °C. We show that its activity does not stem from correctly assembled proteins but from misfolded protein monomers or oligomers and aggregates.
Benjamin W. Clouser, Kara D. Lamb, Laszlo C. Sarkozy, Jan Habig, Volker Ebert, Harald Saathoff, Ottmar Möhler, and Elisabeth J. Moyer
Atmos. Chem. Phys., 20, 1089–1103, https://doi.org/10.5194/acp-20-1089-2020, https://doi.org/10.5194/acp-20-1089-2020, 2020
Short summary
Short summary
Previous measurements of water vapor in the upper troposphere and lower stratosphere (UT/LS) have shown unexpectedly high concentrations of water vapor in ice clouds, which may be due to an incomplete understanding of the structure of ice and the behavior of ice growth in this part of the atmosphere. Water vapor measurements during the 2013 IsoCloud campaign at the AIDA cloud chamber show no evidence of this
anomalous supersaturationin conditions similar to the real atmosphere.
Jon Nelson and Brian D. Swanson
Atmos. Chem. Phys., 19, 15285–15320, https://doi.org/10.5194/acp-19-15285-2019, https://doi.org/10.5194/acp-19-15285-2019, 2019
Short summary
Short summary
Ice crystals in clouds have a wide variety. But many crystal forms are inexplicable using the common approach of modeling the growth rates normal to the crystal faces. Instead of using only this normal-growth approach, we suggest including lateral facet growth processes. Using such lateral processes, backed up by new experiments, we give explanations for some of these puzzling forms. The forms include the center droxtal in stellar crystals, scrolls, capped columns, sheath bundles, and trigonals.
Alexander D. Harrison, Katherine Lever, Alberto Sanchez-Marroquin, Mark A. Holden, Thomas F. Whale, Mark D. Tarn, James B. McQuaid, and Benjamin J. Murray
Atmos. Chem. Phys., 19, 11343–11361, https://doi.org/10.5194/acp-19-11343-2019, https://doi.org/10.5194/acp-19-11343-2019, 2019
Short summary
Short summary
Mineral dusts are a source of ice-nucleating particles (INPs) in the atmosphere. Here we present a comprehensive survey of the ice-nucleating ability of naturally occurring quartz. We show the ice-nucleating variability of quartz and its sensitivity to time spent in water and air. We propose four new parameterizations for the minerals quartz, K feldspar, albite and plagioclase to predict INP concentrations in the atmosphere and show that K-feldspar is the dominant INP type in mineral dusts.
André Welti, Ulrike Lohmann, and Zamin A. Kanji
Atmos. Chem. Phys., 19, 10901–10918, https://doi.org/10.5194/acp-19-10901-2019, https://doi.org/10.5194/acp-19-10901-2019, 2019
Short summary
Short summary
The ice nucleation ability of singly immersed feldspar particles in suspended water droplets relevant for ice crystal formation under mixed-phase cloud conditions is presented. The effects of particle size, crystal structure, trace metal and mineralogical composition are discussed by testing up to five different diameters in the submicron range and nine different feldspar samples at conditions relevant for ice nucleation in mixed-phase clouds.
Nsikanabasi Silas Umo, Robert Wagner, Romy Ullrich, Alexei Kiselev, Harald Saathoff, Peter G. Weidler, Daniel J. Cziczo, Thomas Leisner, and Ottmar Möhler
Atmos. Chem. Phys., 19, 8783–8800, https://doi.org/10.5194/acp-19-8783-2019, https://doi.org/10.5194/acp-19-8783-2019, 2019
Short summary
Short summary
Annually, over 600 Tg of coal fly ash (CFA) is produced; a significant proportion of this amount is injected into the atmosphere, which could significantly contribute to heterogeneous ice formation in clouds. This study presents an improved understanding of CFA particles' behaviour in forming ice in clouds, especially when exposed to lower temperatures before being re-circulated in the upper troposphere or entrained into the lower troposphere.
Naruki Hiranuma, Kouji Adachi, David M. Bell, Franco Belosi, Hassan Beydoun, Bhaskar Bhaduri, Heinz Bingemer, Carsten Budke, Hans-Christian Clemen, Franz Conen, Kimberly M. Cory, Joachim Curtius, Paul J. DeMott, Oliver Eppers, Sarah Grawe, Susan Hartmann, Nadine Hoffmann, Kristina Höhler, Evelyn Jantsch, Alexei Kiselev, Thomas Koop, Gourihar Kulkarni, Amelie Mayer, Masataka Murakami, Benjamin J. Murray, Alessia Nicosia, Markus D. Petters, Matteo Piazza, Michael Polen, Naama Reicher, Yinon Rudich, Atsushi Saito, Gianni Santachiara, Thea Schiebel, Gregg P. Schill, Johannes Schneider, Lior Segev, Emiliano Stopelli, Ryan C. Sullivan, Kaitlyn Suski, Miklós Szakáll, Takuya Tajiri, Hans Taylor, Yutaka Tobo, Romy Ullrich, Daniel Weber, Heike Wex, Thomas F. Whale, Craig L. Whiteside, Katsuya Yamashita, Alla Zelenyuk, and Ottmar Möhler
Atmos. Chem. Phys., 19, 4823–4849, https://doi.org/10.5194/acp-19-4823-2019, https://doi.org/10.5194/acp-19-4823-2019, 2019
Short summary
Short summary
A total of 20 ice nucleation measurement techniques contributed to investigate the immersion freezing behavior of cellulose particles – natural polymers. Our data showed several types of cellulose are able to nucleate ice as efficiently as some mineral dust samples and cellulose has the potential to be an important atmospheric ice-nucleating particle. Continued investigation/collaboration is necessary to obtain further insight into consistency or diversity of ice nucleation measurements.
Kaitlyn J. Suski, David M. Bell, Naruki Hiranuma, Ottmar Möhler, Dan Imre, and Alla Zelenyuk
Atmos. Chem. Phys., 18, 17497–17513, https://doi.org/10.5194/acp-18-17497-2018, https://doi.org/10.5194/acp-18-17497-2018, 2018
Short summary
Short summary
This work investigates the cloud condensation nuclei and ice nucleation activity of bacteria using cloud chamber data and a single particle mass spectrometer. The size and chemical composition of the cloud residuals show that bacterial fragments mixed with agar growth media activate preferentially over intact bacteria cells as cloud condensation nuclei. Intact bacteria cells do not make it into cloud droplets; they thus cannot serve as immersion-mode ice nucleating particles.
Jiahui Zhang, Dao-Yi Gong, Rui Mao, Jing Yang, Ziyin Zhang, and Yun Qian
Atmos. Chem. Phys., 18, 16775–16791, https://doi.org/10.5194/acp-18-16775-2018, https://doi.org/10.5194/acp-18-16775-2018, 2018
Short summary
Short summary
The Chinese Spring Festival (also known as the Chinese New Year or Lunar New Year) is the most important festival in China. This paper reports that during the Chinese Spring Festival, the precipitation over southern China has been significantly reduced. The precipitation reduction is due to anomalous northerly winds. We suppose that anomalous atmospheric circulation is likely related to the human activity during holidays. It is an interesting phenomenon.
Sarah Grawe, Stefanie Augustin-Bauditz, Hans-Christian Clemen, Martin Ebert, Stine Eriksen Hammer, Jasmin Lubitz, Naama Reicher, Yinon Rudich, Johannes Schneider, Robert Staacke, Frank Stratmann, André Welti, and Heike Wex
Atmos. Chem. Phys., 18, 13903–13923, https://doi.org/10.5194/acp-18-13903-2018, https://doi.org/10.5194/acp-18-13903-2018, 2018
Short summary
Short summary
In this study, coal fly ash particles immersed in supercooled cloud droplets were analyzed concerning their freezing behavior. Additionally, physico-chemical particle properties (morphology, chemical composition, crystallography) were investigated. In combining both aspects, components that potentially contribute to the observed freezing behavior of the ash could be identified. Interactions at the particle-water interface, that depend on suspension time and influence freezing, are discussed.
Jens Voigtländer, Cedric Chou, Henner Bieligk, Tina Clauss, Susan Hartmann, Paul Herenz, Dennis Niedermeier, Georg Ritter, Frank Stratmann, and Zbigniew Ulanowski
Atmos. Chem. Phys., 18, 13687–13702, https://doi.org/10.5194/acp-18-13687-2018, https://doi.org/10.5194/acp-18-13687-2018, 2018
Short summary
Short summary
Surface roughness of ice crystals has recently been acknowledged to strongly influence the radiative properties of cold clouds such as cirrus, but it is unclear how this roughness arises. The study investigates the origins of ice surface roughness under a variety of atmospherically relevant conditions, using a novel method to measure roughness quantitatively. It is found that faster growth leads to stronger roughness. Roughness also increases following repeated growth–sublimation cycles.
Fabian Mahrt, Claudia Marcolli, Robert O. David, Philippe Grönquist, Eszter J. Barthazy Meier, Ulrike Lohmann, and Zamin A. Kanji
Atmos. Chem. Phys., 18, 13363–13392, https://doi.org/10.5194/acp-18-13363-2018, https://doi.org/10.5194/acp-18-13363-2018, 2018
Short summary
Short summary
The ice nucleation ability of different soot particles in the cirrus and mixed-phase cloud temperature regime is presented. The impact of aerosol particle size, particle morphology, organic matter and hydrophilicity on ice nucleation is examined. We propose ice nucleation proceeds via a pore condensation freezing mechanism for soot particles with the necessary physicochemical properties that nucleated ice well below water saturation.
Wiebke Frey, Dawei Hu, James Dorsey, M. Rami Alfarra, Aki Pajunoja, Annele Virtanen, Paul Connolly, and Gordon McFiggans
Atmos. Chem. Phys., 18, 9393–9409, https://doi.org/10.5194/acp-18-9393-2018, https://doi.org/10.5194/acp-18-9393-2018, 2018
Short summary
Short summary
The coupled system of the Manchester Aerosol Chamber and Manchester Ice Cloud Chamber was used to study the ice-forming abilities of secondary
organic aerosol particles under mixed-phase cloud conditions. Given the vast abundance of secondary organic particles in the atmosphere, they
might present an important contribution to ice-nucleating particles. However, we find that in the studied temperature range (20 to 28 °C)
the secondary organic particles do not nucleate ice particles.
Sarvesh Garimella, Daniel A. Rothenberg, Martin J. Wolf, Robert O. David, Zamin A. Kanji, Chien Wang, Michael Rösch, and Daniel J. Cziczo
Atmos. Chem. Phys., 17, 10855–10864, https://doi.org/10.5194/acp-17-10855-2017, https://doi.org/10.5194/acp-17-10855-2017, 2017
Short summary
Short summary
This study investigates systematic and variable low bias in the measurement of ice nucleating particle concentration using continuous flow diffusion chambers. We find that non-ideal instrument behavior exposes particles to different humidities and/or temperatures than predicted from theory. We use a machine learning approach to quantify and minimize the uncertainty associated with this measurement bias.
Pascal Lemaitre, Arnaud Querel, Marie Monier, Thibault Menard, Emmanuel Porcheron, and Andrea I. Flossmann
Atmos. Chem. Phys., 17, 4159–4176, https://doi.org/10.5194/acp-17-4159-2017, https://doi.org/10.5194/acp-17-4159-2017, 2017
Short summary
Short summary
We present new measurements of the efficiency with which aerosol particles are collected by raindrops. These measurements provide the link to reconcile the scavenging coefficients obtained from theoretical approaches with those from experimental studies. We provide proof of the rear capture that is a fundamental effect on submicroscopic particles. Finally, we propose an expression to take into account this mechanism to calculate the collection efficiency for drops within the rain size range.
Lukas Kaufmann, Claudia Marcolli, Beiping Luo, and Thomas Peter
Atmos. Chem. Phys., 17, 3525–3552, https://doi.org/10.5194/acp-17-3525-2017, https://doi.org/10.5194/acp-17-3525-2017, 2017
Short summary
Short summary
To improve the understanding of heterogeneous ice nucleation, we have subjected different ice nuclei to repeated freezing cycles and evaluated the freezing temperatures with different parameterizations of classical nucleation theory. It was found that two fit parameters were necessary to describe the temperature dependence of the nucleation rate.
Claudia Marcolli
Atmos. Chem. Phys., 17, 1595–1622, https://doi.org/10.5194/acp-17-1595-2017, https://doi.org/10.5194/acp-17-1595-2017, 2017
Short summary
Short summary
Laboratory studies from the last century have shown that some types of particles are susceptible to pre-activation, i.e. they are able to develop macroscopic ice at warmer temperatures or lower relative humidities after they had been involved in an ice nucleation event before. This review analyses these works under the presumption that pre-activation occurs by ice preserved in pores, and it discusses atmospheric scenarios for which pre-activation might be important.
Yvonne Boose, André Welti, James Atkinson, Fabiola Ramelli, Anja Danielczok, Heinz G. Bingemer, Michael Plötze, Berko Sierau, Zamin A. Kanji, and Ulrike Lohmann
Atmos. Chem. Phys., 16, 15075–15095, https://doi.org/10.5194/acp-16-15075-2016, https://doi.org/10.5194/acp-16-15075-2016, 2016
Short summary
Short summary
We compare the immersion freezing behavior of four airborne to 11 surface-collected dust samples to investigate the role of different minerals for atmospheric ice nucleation on desert dust. We find that present K-feldspars dominate at T > 253 K, while quartz does at colder temperatures, and surface-collected dust samples are not necessarily representative for airborne dust. For improved ice cloud prediction, modeling of quartz and feldspar emission and transport are key.
Andreas Peckhaus, Alexei Kiselev, Thibault Hiron, Martin Ebert, and Thomas Leisner
Atmos. Chem. Phys., 16, 11477–11496, https://doi.org/10.5194/acp-16-11477-2016, https://doi.org/10.5194/acp-16-11477-2016, 2016
Short summary
Short summary
The precipitation in midlatitude clouds proceeds predominantly via nucleation of ice in the supercooled droplets containing foreign inclusions, like feldspar mineral dust, that have been recently identified as one of the most active ice nucleating agents in the atmosphere. We have built an apparatus to observe the freezing of feldspar immersed in up to 1500 identical droplets simultaneously. With this setup we investigated four feldspar samples and show that it can induce freezing at −5 °C.
Claudia Marcolli, Baban Nagare, André Welti, and Ulrike Lohmann
Atmos. Chem. Phys., 16, 8915–8937, https://doi.org/10.5194/acp-16-8915-2016, https://doi.org/10.5194/acp-16-8915-2016, 2016
Short summary
Short summary
Silver iodide is one of the best-investigated ice nuclei. It has relevance for the atmosphere since it is used for glaciogenic cloud seeding. Nevertheless, many open questions remain. This paper gives an overview of silver iodide as an ice nucleus and tries to identify the factors that influence the ice nucleation ability of silver iodide.
Daniel O'Sullivan, Benjamin J. Murray, James F. Ross, and Michael E. Webb
Atmos. Chem. Phys., 16, 7879–7887, https://doi.org/10.5194/acp-16-7879-2016, https://doi.org/10.5194/acp-16-7879-2016, 2016
Short summary
Short summary
In the absence of particles which can trigger freezing, cloud droplets can exist in a supercooled liquid state well below the melting point. However, the sources of efficient ice-nucleating particles in the atmosphere are uncertain. Here we show that ice-nucleating proteins produced by soil fungi can bind to clay particles in soils. Hence, the subsequent dispersion of soil particles into the atmosphere acts as a route through which biological ice nucleators can influence clouds.
Kuan-Ting O and Robert Wood
Atmos. Chem. Phys., 16, 7239–7249, https://doi.org/10.5194/acp-16-7239-2016, https://doi.org/10.5194/acp-16-7239-2016, 2016
Short summary
Short summary
In this work, based on the well-known formulae of classical nucleation theory (CNT), the temperature at which the mean number of critical embryos inside a droplet is unity is derived from the Boltzmann distribution function and explored as a new simplified approximation for homogeneous freezing temperature. It thus appears that the simplicity of this approximation makes it potentially useful for predicting homogeneous freezing temperatures of water droplets in the atmosphere.
Martin Schnaiter, Emma Järvinen, Paul Vochezer, Ahmed Abdelmonem, Robert Wagner, Olivier Jourdan, Guillaume Mioche, Valery N. Shcherbakov, Carl G. Schmitt, Ugo Tricoli, Zbigniew Ulanowski, and Andrew J. Heymsfield
Atmos. Chem. Phys., 16, 5091–5110, https://doi.org/10.5194/acp-16-5091-2016, https://doi.org/10.5194/acp-16-5091-2016, 2016
Leonid Nichman, Claudia Fuchs, Emma Järvinen, Karoliina Ignatius, Niko Florian Höppel, Antonio Dias, Martin Heinritzi, Mario Simon, Jasmin Tröstl, Andrea Christine Wagner, Robert Wagner, Christina Williamson, Chao Yan, Paul James Connolly, James Robert Dorsey, Jonathan Duplissy, Sebastian Ehrhart, Carla Frege, Hamish Gordon, Christopher Robert Hoyle, Thomas Bjerring Kristensen, Gerhard Steiner, Neil McPherson Donahue, Richard Flagan, Martin William Gallagher, Jasper Kirkby, Ottmar Möhler, Harald Saathoff, Martin Schnaiter, Frank Stratmann, and António Tomé
Atmos. Chem. Phys., 16, 3651–3664, https://doi.org/10.5194/acp-16-3651-2016, https://doi.org/10.5194/acp-16-3651-2016, 2016
Short summary
Short summary
Processes in the atmosphere are often governed by the physical and chemical properties of small cloud particles. Ice, water, and mixed clouds, as well as viscous aerosols, were formed under controlled conditions at the CLOUD-CERN facility. The experimental results show a link between cloud particle properties and their unique optical fingerprints. The classification map presented here allows easier discrimination between various particles such as viscous organic aerosol, salt, ice, and liquid.
Peter A. Alpert and Daniel A. Knopf
Atmos. Chem. Phys., 16, 2083–2107, https://doi.org/10.5194/acp-16-2083-2016, https://doi.org/10.5194/acp-16-2083-2016, 2016
Short summary
Short summary
A stochastic immersion freezing model is introduced capable of reproducing laboratory data for a variety of experimental methods using a time and surface area dependent ice nucleation process. The assumption that droplets contain identical surface area is evaluated. A quantitative uncertainty analysis of the laboratory observed freezing process is presented. Our results imply that ice nuclei surface area assumptions are crucial for interpretation of experimental immersion freezing results.
Cited articles
Cziczo, D. J., Froyd, K. D., Gallavardin, S. J., Moehler, O., Benz, S.,
Saathoff, H., and Murphy, D. M.: Deactivation of ice nuclei due to
atmospherically relevant surface coatings, Environ. Res. Lett., 4,
044013, https://doi.org/10.1088/1748-9326/4/4/044013, 2009.
Dalirian, M., Ylisirniö, A., Buchholz, A., Schlesinger, D., Ström, J., Virtanen, A., and Riipinen, I.: Cloud droplet activation of black carbon particles coated with organic compounds of varying solubility, Atmos. Chem. Phys., 18, 12477–12489, https://doi.org/10.5194/acp-18-12477-2018, 2018.
Dawson, J. N., Malek, K. A., Razafindrambinina, P. N., Raymond, T. M.,
Dutcher, D. D., Asa-Awuku, A. A., and Freedman, M. A.: Direct Comparison of
the Submicron Aerosol Hygroscopicity of Water-Soluble Sugars, ACS Earth Space Chem., 4, 2215–2226, https://doi.org/10.1021/acsearthspacechem.0c00159, 2020.
Dusek, U., Frank, G. P., Hildebrandt, L., Curtius, J., Schneider, J.,
Walter, S., Chand, D., Drewnick, F., Hings, S., Jung, D., Borrmann, S., and
Andreae, M. O.: Size matters more than chemistry for cloud-nucleating
ability of aerosol particles, Science, 312, 1375–1378,
https://doi.org/10.1126/science.1125261, 2006.
Flory, P. J.: The Thermodynamics of High Polymer Solutions, J. Chem. Phys., 10, 51, https://doi.org/10.1063/1.1723621, 1942.
Gohil, K., Mao, C.-N., Rastogi, D., Peng, C., Tang, M., and Asa-Awuku, A.: Hybrid water adsorption and solubility partitioning for aerosol hygroscopicity and droplet growth, Atmos. Chem. Phys., 22, 12769–12787, https://doi.org/10.5194/acp-22-12769-2022, 2022.
Hatch, C. D., Wiese, J. S., Crane, C. C., Harris, K. J., Kloss, H. G., and
Baltrusaitis, J.: Water Adsorption on Clay Minerals As a Function of
Relative Humidity: Application of BET and Freundlich Adsorption Models,
Langmuir, 28, 1790–1803, https://doi.org/10.1021/la2042873, 2012.
Hatch, C. D., Greenaway, A. L., Christie, M. J., and Baltrusaitis, J.: Water
adsorption constrained Frenkel–Halsey–Hill adsorption activation theory:
Montmorillonite and illite, Atmos. Environ., 87, 26–33,
https://doi.org/10.1016/J.ATMOSENV.2013.12.040, 2014.
Herich, H., Tritscher, T., Wiacek, A., Gysel, M., Weingartner, E., Ulrike,
L., Urs, B., and Cziczo, D. J.: Water uptake of clay and desert dust aerosol
particles at sub- and supersaturated water vapor conditions, Phys. Chem.
Chem. Phys., 11, 7804–7809, https://doi.org/10.1039/B901585J, 2009.
Hoppel, W. A., Twomey, S., and Wojciechowski, T. A.: A segmented thermal
diffusion chamber for continuous measurements of CN, J. Aerosol Sci., 10, 369–373, https://doi.org/10.1016/0021-8502(79)90031-4, 1979.
Karydis, V. A., Tsimpidi, A. P., Bacer, S., Pozzer, A., Nenes, A., and Lelieveld, J.: Global impact of mineral dust on cloud droplet number concentration, Atmos. Chem. Phys., 17, 5601–5621, https://doi.org/10.5194/acp-17-5601-2017, 2017.
Koehler, K. A., Demott, P. J., Kreidenweis, S. M., Popovicheva, O. B.,
Petters, M. D., Carrico, C. M., Kireeva, E. D., Khokhlova, T. D., and
Shonija, N. K.: Cloud condensation nuclei and ice nucleation activity of
hydrophobic and hydrophilic soot particles, Phys. Chem. Chem. Phys., 11,
7906–7920, https://doi.org/10.1039/B905334B, 2009.
Köhler, H.: The nucleus in and the growth of hygroscopic droplets,
T. Faraday Soc., 32, 1152–1161, https://doi.org/10.1039/TF9363201152, 1936.
Kumar, P., Nenes, A., and Sokolik, I. N.: Importance of adsorption for CCN
activity and hygroscopic properties of mineral dust aerosol, Geophys. Res.
Lett., 36, L24804, https://doi.org/10.1029/2009GL040827, 2009.
Lintis, L., Ouf, F. X., Parent, P., Ferry, D., Laffon, C., and Vallières,
C.: Quantification and prediction of water uptake by soot deposited on
ventilation filters during fire events, J. Hazard. Mater., 403, 123916,
https://doi.org/10.1016/j.jhazmat.2020.123916, 2021.
Malek, K. A., Gohil, K., Al-Abadleh, H. A., and Asa-Awuku, A. A.:
Hygroscopicity of polycatechol and polyguaiacol secondary organic aerosol in
sub- and supersaturated water vapor environments, Environ. Sci.: Atmos.,
2, 24–33, https://doi.org/10.1039/D1EA00063B, 2022.
Mao, C. N., Malek, K. A., and Asa-Awuku, A.: Hygroscopicity and the
water-polymer interaction parameter of nano-sized biodegradable hydrophilic
substances, Aerosol Sci. Tech., 55, 1115–1124, https://doi.org/10.1080/02786826.2021.1931012, 2021.
Miles, R. E. H., Rudić, S., Orr-Ewing, A. J., and Reid, J. P.: Sources of
Error and Uncertainty in the Use of Cavity Ring Down Spectroscopy to Measure
Aerosol Optical Properties, Aerosol Sci. Tech., 45, 1360–1375,
https://doi.org/10.1080/02786826.2011.596170, 2011.
Moore, R. H., Nenes, A., and Medina, J.: Scanning Mobility CCN Analysis—A
Method for Fast Measurements of Size-Resolved CCN Distributions and
Activation Kinetics, Aerosol Sci. Tech., 44, 861–871,
https://doi.org/10.1080/02786826.2010.498715, 2010.
Navea, J. G., Richmond, E., Stortini, T., and Greenspan, J.: Water Adsorption
Isotherms on Fly Ash from Several Sources, Langmuir, 33, 10161–10171,
https://doi.org/10.1021/acs.langmuir.7b02028, 2017.
Ottewill, R. H. and Vincent, B.: Colloid and surface chemistry of polymer
latices. Part 1.—Adsorption and wetting behaviour of n-alkanols, J. Chem.
Soc. Farad. T. 1, 68, 1533–1543, https://doi.org/10.1039/F19726801533, 1972.
Pajunoja, A., Lambe, A. T., Hakala, J., Rastak, N., Cummings, M. J., Brogan,
J. F., Hao, L., Paramonov, M., Hong, J., Prisle, N. L., Malila, J.,
Romakkaniemi, S., Lehtinen, K. E. J., Laaksonen, A., Kulmala, M., Massoli,
P., Onasch, T. B., Donahue, N. M., Riipinen, I., Davidovits, P., Worsnop, D.
R., Petäjä, T., and Virtanen, A.: Adsorptive uptake of water by
semisolid secondary organic aerosols, Geophys. Res. Lett., 42, 3063–3068, https://doi.org/10.1002/2015GL063142, 2015.
Peng, C., Razafindrambinina, P. N., Malek, K. A., Chen, L., Wang, W., Huang, R.-J., Zhang, Y., Ding, X., Ge, M., Wang, X., Asa-Awuku, A. A., and Tang, M.: Interactions of organosulfates with water vapor under sub- and supersaturated conditions, Atmos. Chem. Phys., 21, 7135–7148, https://doi.org/10.5194/acp-21-7135-2021, 2021.
Peng, C., Malek, K. A., Rastogi, D., Zhang, Y., Wang, W., Ding, X.,
Asa-Awuku, A. A., Wang, X., and Tang, M.: Hygroscopicity and cloud
condensation nucleation activities of hydroxyalkylsulfonates, Sci. Total
Environ., 830, 154767, https://doi.org/10.1016/j.scitotenv.2022.154767, 2022.
Pethrick, R.: Polymer physics, edited by: Rubinstein, M., and
Colby, R. H., Oxford University Press, Oxford, 440 pp., ISBN 019852059X, Wiley, 2003.
Petters, M. D. and Kreidenweis, S. M.: A single parameter representation of hygroscopic growth and cloud condensation nucleus activity, Atmos. Chem. Phys., 7, 1961–1971, https://doi.org/10.5194/acp-7-1961-2007, 2007.
Petters, M. D. and Kreidenweis, S. M.: A single parameter representation of hygroscopic growth and cloud condensation nucleus activity – Part 2: Including solubility, Atmos. Chem. Phys., 8, 6273–6279, https://doi.org/10.5194/acp-8-6273-2008, 2008.
Petters, M. D., Kreidenweis, S. M., Snider, J. R., Koehler, K. A., Wang, Q.,
Prenni, A. J., and Demott, P. J.: Cloud droplet activation of polymerized
organic aerosol, Tellus B, 58, 196–205, https://doi.org/10.1111/j.1600-0889.2006.00181.x, 2006.
Petters, M. D., Kreidenweis, S. M., Prenni, A. J., Sullivan, R. C., Carrico,
C. M., Koehler, K. A., and Ziemann, P. J.: Role of molecular size in cloud
droplet activation, Geophys. Res. Lett., 36, L22801, https://doi.org/10.1029/2009GL040131, 2009.
Pettersson, A., Lovejoy, E. R., Brock, C. A., Brown, S. S., and Ravishankara,
A. R.: Measurement of aerosol optical extinction at 532 nm with pulsed
cavity ring down spectroscopy, J. Aerosol Sci., 35, 995–1011,
https://doi.org/10.1016/j.jaerosci.2004.02.008, 2004.
Reitz, P., Spindler, C., Mentel, T. F., Poulain, L., Wex, H., Mildenberger, K., Niedermeier, D., Hartmann, S., Clauss, T., Stratmann, F., Sullivan, R. C., DeMott, P. J., Petters, M. D., Sierau, B., and Schneider, J.: Surface modification of mineral dust particles by sulphuric acid processing: implications for ice nucleation abilities, Atmos. Chem. Phys., 11, 7839–7858, https://doi.org/10.5194/acp-11-7839-2011, 2011.
Roberts, G. C. and Nenes, A.: A Continuous-Flow Streamwise Thermal-Gradient
CCN Chamber for Atmospheric Measurements, Aerosol Sci. Tech., 39, 206–221, https://doi.org/10.1080/027868290913988, 2005.
Rose, D., Gunthe, S. S., Mikhailov, E., Frank, G. P., Dusek, U., Andreae, M. O., and Pöschl, U.: Calibration and measurement uncertainties of a continuous-flow cloud condensation nuclei counter (DMT-CCNC): CCN activation of ammonium sulfate and sodium chloride aerosol particles in theory and experiment, Atmos. Chem. Phys., 8, 1153–1179, https://doi.org/10.5194/acp-8-1153-2008, 2008.
Singh, S., Fiddler, M. N., Smith, D., and Bililign, S.: Error analysis and
uncertainty in the determination of aerosol optical properties using cavity
ring-down spectroscopy, integrating nephelometry, and the
extinction-minus-scattering method, Aerosol Sci. Tech., 48, 1345–1359, https://doi.org/10.1080/02786826.2014.984062, 2014.
Sorjamaa, R. and Laaksonen, A.: The effect of H2O adsorption on cloud drop activation of insoluble particles: a theoretical framework, Atmos. Chem. Phys., 7, 6175–6180, https://doi.org/10.5194/acp-7-6175-2007, 2007.
Sullivan, R. C., Moore, M. J. K., Petters, M. D., Kreidenweis, S. M., Roberts, G. C., and Prather, K. A.: Effect of chemical mixing state on the hygroscopicity and cloud nucleation properties of calcium mineral dust particles, Atmos. Chem. Phys., 9, 3303–3316, https://doi.org/10.5194/acp-9-3303-2009, 2009.
Sullivan, R. C., Petters, M. D., DeMott, P. J., Kreidenweis, S. M., Wex, H., Niedermeier, D., Hartmann, S., Clauss, T., Stratmann, F., Reitz, P., Schneider, J., and Sierau, B.: Irreversible loss of ice nucleation active sites in mineral dust particles caused by sulphuric acid condensation, Atmos. Chem. Phys., 10, 11471–11487, https://doi.org/10.5194/acp-10-11471-2010,
2010.
Tang, M., Cziczo, D. J., and Grassian, V. H.: Interactions of Water with
Mineral Dust Aerosol: Water Adsorption, Hygroscopicity, Cloud Condensation,
and Ice Nucleation, Chem. Rev., 116, 4205–4259,
https://doi.org/10.1021/acs.chemrev.5b00529, 2016.
Wang, S. C. and Flagan, R. C.: Scanning electrical mobility spectrometer,
Aerosol Sci. Tech., 13, 230–240, https://doi.org/10.1080/02786829008959441, 1990.
Short summary
The impact of molecular-level surface chemistry for aerosol water uptake and droplet growth is not well understood. In this work we show changes in water uptake due to molecular-level surface chemistry can be measured and quantified. In addition, we develop a single-parameter model, representing changes in aerosol chemistry that can be used in global climate models to reduce the uncertainty in aerosol-cloud predictions.
The impact of molecular-level surface chemistry for aerosol water uptake and droplet growth is...
Altmetrics
Final-revised paper
Preprint