Articles | Volume 22, issue 17
https://doi.org/10.5194/acp-22-11323-2022
© Author(s) 2022. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-22-11323-2022
© Author(s) 2022. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Identification of highly oxygenated organic molecules and their role in aerosol formation in the reaction of limonene with nitrate radical
Yindong Guo
Department of Atmospheric and Oceanic Sciences & Institute of Atmospheric Sciences, Fudan University, Shanghai 200438, China
Hongru Shen
Department of Atmospheric and Oceanic Sciences & Institute of Atmospheric Sciences, Fudan University, Shanghai 200438, China
Iida Pullinen
Institute of Energy and Climate Research, IEK-8: Troposphere, Forschungszentrum Jülich GmbH, 52425 Jülich, Germany
now at: Department of Applied Physics, University of Eastern Finland, Kuopio 70210, Finland
Hao Luo
Department of Atmospheric and Oceanic Sciences & Institute of Atmospheric Sciences, Fudan University, Shanghai 200438, China
IRDR ICoE on Risk Interconnectivity and Governance on Weather/Climate Extremes Impact and Public Health, Fudan University, Shanghai 200438, China
Sungah Kang
Institute of Energy and Climate Research, IEK-8: Troposphere, Forschungszentrum Jülich GmbH, 52425 Jülich, Germany
Luc Vereecken
Institute of Energy and Climate Research, IEK-8: Troposphere, Forschungszentrum Jülich GmbH, 52425 Jülich, Germany
Hendrik Fuchs
Institute of Energy and Climate Research, IEK-8: Troposphere, Forschungszentrum Jülich GmbH, 52425 Jülich, Germany
Mattias Hallquist
Department of Chemistry and Molecular biology, University of Gothenburg, Göteborg 41258, Sweden
Ismail-Hakki Acir
Institute of Energy and Climate Research, IEK-8: Troposphere, Forschungszentrum Jülich GmbH, 52425 Jülich, Germany
now at: Institute of Nutrition and Food Sciences, University of Bonn, 53115 Bonn, Germany
Ralf Tillmann
Institute of Energy and Climate Research, IEK-8: Troposphere, Forschungszentrum Jülich GmbH, 52425 Jülich, Germany
Franz Rohrer
Institute of Energy and Climate Research, IEK-8: Troposphere, Forschungszentrum Jülich GmbH, 52425 Jülich, Germany
Jürgen Wildt
Institute of Energy and Climate Research, IEK-8: Troposphere, Forschungszentrum Jülich GmbH, 52425 Jülich, Germany
Astrid Kiendler-Scharr
Institute of Energy and Climate Research, IEK-8: Troposphere, Forschungszentrum Jülich GmbH, 52425 Jülich, Germany
Andreas Wahner
Institute of Energy and Climate Research, IEK-8: Troposphere, Forschungszentrum Jülich GmbH, 52425 Jülich, Germany
Department of Atmospheric and Oceanic Sciences & Institute of Atmospheric Sciences, Fudan University, Shanghai 200438, China
Shanghai Frontiers Science Center of Atmosphere–Ocean Interaction, Fudan University, Shanghai 200438, China
Institute of Eco-Chongming (IEC), 20 Cuiniao Rd., Chongming, Shanghai 202162, China
Institute of Energy and Climate Research, IEK-8: Troposphere, Forschungszentrum Jülich GmbH, 52425 Jülich, Germany
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Cited
14 citations as recorded by crossref.
- Effect of relative humidity on the molecular composition of secondary organic aerosols from α-pinene ozonolysis H. Luo et al. 10.1039/D3EA00149K
- Formation of highly oxygenated organic molecules from the oxidation of limonene by OH radical: significant contribution of H-abstraction pathway H. Luo et al. 10.5194/acp-23-7297-2023
- Influence of anthropogenic emissions on the composition of highly oxygenated organic molecules in Helsinki: a street canyon and urban background station comparison M. Okuljar et al. 10.5194/acp-23-12965-2023
- Contrasting Influence of Nitrogen Oxides on the Cloud Condensation Nuclei Activity of Monoterpene‐Derived Secondary Organic Aerosol in Daytime and Nighttime Oxidation C. Zhang et al. 10.1029/2022GL102110
- Organic Peroxides in Aerosol: Key Reactive Intermediates for Multiphase Processes in the Atmosphere S. Wang et al. 10.1021/acs.chemrev.2c00430
- Nitrate Radicals Suppress Biogenic New Particle Formation from Monoterpene Oxidation D. Li et al. 10.1021/acs.est.3c07958
- Nighttime reactions of a series of unsaturated alcohols with NO3•: Kinetics, products and mechanisms study Y. Xu et al. 10.1016/j.jes.2024.03.043
- Large differences of highly oxygenated organic molecules (HOMs) and low-volatile species in secondary organic aerosols (SOAs) formed from ozonolysis of β-pinene and limonene D. Liu et al. 10.5194/acp-23-8383-2023
- Characterization and sources of carbonaceous aerosols in southwest plateau of China: Effects of biomass burning and low oxygen concentration J. Shi et al. 10.1016/j.atmosenv.2023.120250
- Recent advances in mass spectrometry techniques for atmospheric chemistry research on molecular‐level W. Zhang et al. 10.1002/mas.21857
- Impact of HO2∕RO2 ratio on highly oxygenated α-pinene photooxidation products and secondary organic aerosol formation potential Y. Baker et al. 10.5194/acp-24-4789-2024
- Chemical ionization mass spectrometry: Developments and applications for on-line characterization of atmospheric aerosols and trace gases Y. Zhang et al. 10.1016/j.trac.2023.117353
- Molecular Characterization of Oxygenated Organic Molecules and Their Dominating Roles in Particle Growth in Hong Kong P. Zheng et al. 10.1021/acs.est.2c09252
- Peroxy Radical Autoxidation and Sequential Oxidation in Organic Nitrate Formation during Limonene Nighttime Oxidation R. Mayorga et al. 10.1021/acs.est.2c04030
13 citations as recorded by crossref.
- Effect of relative humidity on the molecular composition of secondary organic aerosols from α-pinene ozonolysis H. Luo et al. 10.1039/D3EA00149K
- Formation of highly oxygenated organic molecules from the oxidation of limonene by OH radical: significant contribution of H-abstraction pathway H. Luo et al. 10.5194/acp-23-7297-2023
- Influence of anthropogenic emissions on the composition of highly oxygenated organic molecules in Helsinki: a street canyon and urban background station comparison M. Okuljar et al. 10.5194/acp-23-12965-2023
- Contrasting Influence of Nitrogen Oxides on the Cloud Condensation Nuclei Activity of Monoterpene‐Derived Secondary Organic Aerosol in Daytime and Nighttime Oxidation C. Zhang et al. 10.1029/2022GL102110
- Organic Peroxides in Aerosol: Key Reactive Intermediates for Multiphase Processes in the Atmosphere S. Wang et al. 10.1021/acs.chemrev.2c00430
- Nitrate Radicals Suppress Biogenic New Particle Formation from Monoterpene Oxidation D. Li et al. 10.1021/acs.est.3c07958
- Nighttime reactions of a series of unsaturated alcohols with NO3•: Kinetics, products and mechanisms study Y. Xu et al. 10.1016/j.jes.2024.03.043
- Large differences of highly oxygenated organic molecules (HOMs) and low-volatile species in secondary organic aerosols (SOAs) formed from ozonolysis of β-pinene and limonene D. Liu et al. 10.5194/acp-23-8383-2023
- Characterization and sources of carbonaceous aerosols in southwest plateau of China: Effects of biomass burning and low oxygen concentration J. Shi et al. 10.1016/j.atmosenv.2023.120250
- Recent advances in mass spectrometry techniques for atmospheric chemistry research on molecular‐level W. Zhang et al. 10.1002/mas.21857
- Impact of HO2∕RO2 ratio on highly oxygenated α-pinene photooxidation products and secondary organic aerosol formation potential Y. Baker et al. 10.5194/acp-24-4789-2024
- Chemical ionization mass spectrometry: Developments and applications for on-line characterization of atmospheric aerosols and trace gases Y. Zhang et al. 10.1016/j.trac.2023.117353
- Molecular Characterization of Oxygenated Organic Molecules and Their Dominating Roles in Particle Growth in Hong Kong P. Zheng et al. 10.1021/acs.est.2c09252
Latest update: 16 Aug 2024
Short summary
The oxidation of limonene, a common volatile emitted by trees and chemical products, by NO3, a nighttime oxidant, forms many highly oxygenated organic molecules (HOM), including C10-30 compounds. Most of the HOM are second-generation organic nitrates, in which carbonyl-substituted C10 nitrates accounted for a major fraction. Their formation can be explained by chemistry of peroxy radicals. HOM, especially low-volatile ones, play an important role in nighttime new particle formation and growth.
The oxidation of limonene, a common volatile emitted by trees and chemical products, by NO3, a...
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