Articles | Volume 22, issue 17
https://doi.org/10.5194/acp-22-11323-2022
© Author(s) 2022. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-22-11323-2022
© Author(s) 2022. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
02 Sep 2022
Research article |
| 02 Sep 2022
| 02 Sep 2022
Identification of highly oxygenated organic molecules and their role in aerosol formation in the reaction of limonene with nitrate radical
Yindong Guo
Department of Atmospheric and Oceanic Sciences & Institute of Atmospheric Sciences, Fudan University, Shanghai 200438, China
Hongru Shen
Department of Atmospheric and Oceanic Sciences & Institute of Atmospheric Sciences, Fudan University, Shanghai 200438, China
Iida Pullinen
Institute of Energy and Climate Research, IEK-8: Troposphere, Forschungszentrum Jülich GmbH, 52425 Jülich, Germany
now at: Department of Applied Physics, University of Eastern Finland, Kuopio 70210, Finland
Hao Luo
Department of Atmospheric and Oceanic Sciences & Institute of Atmospheric Sciences, Fudan University, Shanghai 200438, China
IRDR ICoE on Risk Interconnectivity and Governance on Weather/Climate Extremes Impact and Public Health, Fudan University, Shanghai 200438, China
Sungah Kang
Institute of Energy and Climate Research, IEK-8: Troposphere, Forschungszentrum Jülich GmbH, 52425 Jülich, Germany
Luc Vereecken
Institute of Energy and Climate Research, IEK-8: Troposphere, Forschungszentrum Jülich GmbH, 52425 Jülich, Germany
Hendrik Fuchs
Institute of Energy and Climate Research, IEK-8: Troposphere, Forschungszentrum Jülich GmbH, 52425 Jülich, Germany
Mattias Hallquist
Department of Chemistry and Molecular biology, University of Gothenburg, Göteborg 41258, Sweden
Ismail-Hakki Acir
Institute of Energy and Climate Research, IEK-8: Troposphere, Forschungszentrum Jülich GmbH, 52425 Jülich, Germany
now at: Institute of Nutrition and Food Sciences, University of Bonn, 53115 Bonn, Germany
Ralf Tillmann
Institute of Energy and Climate Research, IEK-8: Troposphere, Forschungszentrum Jülich GmbH, 52425 Jülich, Germany
Franz Rohrer
Institute of Energy and Climate Research, IEK-8: Troposphere, Forschungszentrum Jülich GmbH, 52425 Jülich, Germany
Jürgen Wildt
Institute of Energy and Climate Research, IEK-8: Troposphere, Forschungszentrum Jülich GmbH, 52425 Jülich, Germany
Astrid Kiendler-Scharr
Institute of Energy and Climate Research, IEK-8: Troposphere, Forschungszentrum Jülich GmbH, 52425 Jülich, Germany
Andreas Wahner
Institute of Energy and Climate Research, IEK-8: Troposphere, Forschungszentrum Jülich GmbH, 52425 Jülich, Germany
Department of Atmospheric and Oceanic Sciences & Institute of Atmospheric Sciences, Fudan University, Shanghai 200438, China
Shanghai Frontiers Science Center of Atmosphere–Ocean Interaction, Fudan University, Shanghai 200438, China
Institute of Eco-Chongming (IEC), 20 Cuiniao Rd., Chongming, Shanghai 202162, China
Institute of Energy and Climate Research, IEK-8: Troposphere, Forschungszentrum Jülich GmbH, 52425 Jülich, Germany
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Cited
18 citations as recorded by crossref.
- Effect of relative humidity on the molecular composition of secondary organic aerosols from α-pinene ozonolysis H. Luo et al. 10.1039/D3EA00149K
- Formation of highly oxygenated organic molecules from the oxidation of limonene by OH radical: significant contribution of H-abstraction pathway H. Luo et al. 10.5194/acp-23-7297-2023
- Influence of anthropogenic emissions on the composition of highly oxygenated organic molecules in Helsinki: a street canyon and urban background station comparison M. Okuljar et al. 10.5194/acp-23-12965-2023
- Contrasting Influence of Nitrogen Oxides on the Cloud Condensation Nuclei Activity of Monoterpene‐Derived Secondary Organic Aerosol in Daytime and Nighttime Oxidation C. Zhang et al. 10.1029/2022GL102110
- Organic Peroxides in Aerosol: Key Reactive Intermediates for Multiphase Processes in the Atmosphere S. Wang et al. 10.1021/acs.chemrev.2c00430
- Characterizing highly oxygenated organic molecules in limonene secondary organic aerosols: roles of temperature and relative humidity Y. Zhai et al. 10.1039/D4EA00153B
- Nitrate Radicals Suppress Biogenic New Particle Formation from Monoterpene Oxidation D. Li et al. 10.1021/acs.est.3c07958
- The Pivotal Role of Heavy Terpenes and Anthropogenic Interactions in New Particle Formation on the Southeastern Qinghai-Tibet Plateau Y. Liu et al. 10.1021/acs.est.4c04112
- Nighttime reactions of a series of unsaturated alcohols with NO3•: Kinetics, products and mechanisms study Y. Xu et al. 10.1016/j.jes.2024.03.043
- Large differences of highly oxygenated organic molecules (HOMs) and low-volatile species in secondary organic aerosols (SOAs) formed from ozonolysis of β-pinene and limonene D. Liu et al. 10.5194/acp-23-8383-2023
- Characterization and sources of carbonaceous aerosols in southwest plateau of China: Effects of biomass burning and low oxygen concentration J. Shi et al. 10.1016/j.atmosenv.2023.120250
- Recent advances in mass spectrometry techniques for atmospheric chemistry research on molecular‐level W. Zhang et al. 10.1002/mas.21857
- Resolving Atmospheric Oxygenated Organic Molecules in Urban Beijing Using Online Ultrahigh-Resolution Chemical Ionization Mass Spectrometry Y. Yuan et al. 10.1021/acs.est.4c04214
- Impact of HO2∕RO2 ratio on highly oxygenated α-pinene photooxidation products and secondary organic aerosol formation potential Y. Baker et al. 10.5194/acp-24-4789-2024
- Chemical ionization mass spectrometry: Developments and applications for on-line characterization of atmospheric aerosols and trace gases Y. Zhang et al. 10.1016/j.trac.2023.117353
- Molecular Characterization of Oxygenated Organic Molecules and Their Dominating Roles in Particle Growth in Hong Kong P. Zheng et al. 10.1021/acs.est.2c09252
- A nitrate ion chemical-ionization atmospheric-pressure-interface time-of-flight mass spectrometer (NO3− ToFCIMS) sensitivity study S. Alage et al. 10.5194/amt-17-4709-2024
- Peroxy Radical Autoxidation and Sequential Oxidation in Organic Nitrate Formation during Limonene Nighttime Oxidation R. Mayorga et al. 10.1021/acs.est.2c04030
17 citations as recorded by crossref.
- Effect of relative humidity on the molecular composition of secondary organic aerosols from α-pinene ozonolysis H. Luo et al. 10.1039/D3EA00149K
- Formation of highly oxygenated organic molecules from the oxidation of limonene by OH radical: significant contribution of H-abstraction pathway H. Luo et al. 10.5194/acp-23-7297-2023
- Influence of anthropogenic emissions on the composition of highly oxygenated organic molecules in Helsinki: a street canyon and urban background station comparison M. Okuljar et al. 10.5194/acp-23-12965-2023
- Contrasting Influence of Nitrogen Oxides on the Cloud Condensation Nuclei Activity of Monoterpene‐Derived Secondary Organic Aerosol in Daytime and Nighttime Oxidation C. Zhang et al. 10.1029/2022GL102110
- Organic Peroxides in Aerosol: Key Reactive Intermediates for Multiphase Processes in the Atmosphere S. Wang et al. 10.1021/acs.chemrev.2c00430
- Characterizing highly oxygenated organic molecules in limonene secondary organic aerosols: roles of temperature and relative humidity Y. Zhai et al. 10.1039/D4EA00153B
- Nitrate Radicals Suppress Biogenic New Particle Formation from Monoterpene Oxidation D. Li et al. 10.1021/acs.est.3c07958
- The Pivotal Role of Heavy Terpenes and Anthropogenic Interactions in New Particle Formation on the Southeastern Qinghai-Tibet Plateau Y. Liu et al. 10.1021/acs.est.4c04112
- Nighttime reactions of a series of unsaturated alcohols with NO3•: Kinetics, products and mechanisms study Y. Xu et al. 10.1016/j.jes.2024.03.043
- Large differences of highly oxygenated organic molecules (HOMs) and low-volatile species in secondary organic aerosols (SOAs) formed from ozonolysis of β-pinene and limonene D. Liu et al. 10.5194/acp-23-8383-2023
- Characterization and sources of carbonaceous aerosols in southwest plateau of China: Effects of biomass burning and low oxygen concentration J. Shi et al. 10.1016/j.atmosenv.2023.120250
- Recent advances in mass spectrometry techniques for atmospheric chemistry research on molecular‐level W. Zhang et al. 10.1002/mas.21857
- Resolving Atmospheric Oxygenated Organic Molecules in Urban Beijing Using Online Ultrahigh-Resolution Chemical Ionization Mass Spectrometry Y. Yuan et al. 10.1021/acs.est.4c04214
- Impact of HO2∕RO2 ratio on highly oxygenated α-pinene photooxidation products and secondary organic aerosol formation potential Y. Baker et al. 10.5194/acp-24-4789-2024
- Chemical ionization mass spectrometry: Developments and applications for on-line characterization of atmospheric aerosols and trace gases Y. Zhang et al. 10.1016/j.trac.2023.117353
- Molecular Characterization of Oxygenated Organic Molecules and Their Dominating Roles in Particle Growth in Hong Kong P. Zheng et al. 10.1021/acs.est.2c09252
- A nitrate ion chemical-ionization atmospheric-pressure-interface time-of-flight mass spectrometer (NO3− ToFCIMS) sensitivity study S. Alage et al. 10.5194/amt-17-4709-2024
Latest update: 08 May 2025
Short summary
The oxidation of limonene, a common volatile emitted by trees and chemical products, by NO3, a nighttime oxidant, forms many highly oxygenated organic molecules (HOM), including C10-30 compounds. Most of the HOM are second-generation organic nitrates, in which carbonyl-substituted C10 nitrates accounted for a major fraction. Their formation can be explained by chemistry of peroxy radicals. HOM, especially low-volatile ones, play an important role in nighttime new particle formation and growth.
The oxidation of limonene, a common volatile emitted by trees and chemical products, by NO3, a...
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